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1 Abstract — In this work, we have conducted systematic Index Terms — Breakdown voltage (BV), gallium nitride 27
2 studies on the interfacial conditions for gallium nitride (GaN), leakage current, metal–insulator–semiconductor 28
3 (GaN)-based trench metal/insulator/semiconductor (MIS)- (MIS) structure, specific ON-resistance, trench MOS barrier 29
4 type barrier Schottky rectifier (TMBS) with the help of the Schottky (TMBS) rectifier. 30
5 T-CAD tools. Our results show that the donor-type traps
6 tend to reduce the Schottky barrier height (qϕs ), which
7 weakens the charge coupling effect, increases the leakage
I. I NTRODUCTION 31
8 current, and finally reduces the breakdown voltage (BV).
9 On the contrary, the acceptor-type traps at the contact inter-
10
11
12
face and mesa sidewall will increase qϕs and the turn-on
voltage (VON ) because they can capture electrons in the
mesa region and show the negative polarity. This then
G ALLIUM nitride (GaN)-based power devices, such as
GaN FET, p-i-n diodes, Schottky barrier diodes (SBDs),
and so on, have emerged as potential candidates for current
32
33
34
13 enhances the electron depletion at the contact interface and power transistors and diodes [1]. Most of these power devices 35
14 the mesa sidewall, resulting in an increase in qϕs and VON . have been investigated by adopting GaN heteroepitaxial layers 36
15 Therefore, this process can increase the reverse blocking grown on foreign substrates, such as SiC, sapphire, and Si. 37
16 characteristics. However, for solving the complicated inter-
17 facial conditions in the Schottky contact region, we propose Lateral AlGaN/GaN SBD taking advantage of 2-D electron 38
18 using an MIS structure with a 1-nm Al2 O3 insulation layer for gas (2-DEG) is one building block for power devices [2]. 39
19 the GaN-based TMBS rectifiers. Based on the results, the This type of device shows significant progress in produc- 40
20 tunneling process and thermionic-emission (TE) process ing low turn-on voltage (VON ) and high breakdown voltage 41
21 take into account for the current transport mechanism for (BV) over 10 kV [3], [4]. Quasi-vertical and full-vertical 42
22 the MIS-TMBS rectifiers. Meanwhile, the 1-nm thick Al2 O3
23 interlayer increases the effective Schottky barrier height GaN power diodes also have better thermal scalability and 43
24 (qϕs + qϕT ), which significantly reduces the reverse leakage. can produce large BV [5], [6]. In addition, compared with 44
25 In addition, this design offers more freedom in selecting the lateral AlGaN/GaN SBD, quasi-vertical and full-vertical GaN 45
26 Schottky contact electrode for the MIS-TMBS rectifier. power diodes are less sensitive to surface traps [7], [8]. 46
of Reliability and Intelligence of Electrical Equipment, Hebei University barrier lowering effect and an increased leakage current [9]. 50
of Technology, under Grant EERI_PI2020008; and in part by the Key To overcome this effect, a few effective edge termination 51
Laboratory of Nano-Devices and Applications, Suzhou Institute of Nano-
Tech and Nano-Bionics, Chinese Academy of Sciences, under Grant technologies have been proposed, i.e., using guard ring [10], 52
22ZS03. The review of this article was arranged by Editor K. Alam. p-type junction termination extension (JTE) [11], field plate 53
(Corresponding author: Zi-Hui Zhang.) [12], ion implantation [13], and so on. For the convenience 54
Fuping Huang, Zhizhong Wang, Chunshuang Chu, Qianqian Liu,
Yonghui Zhang, and Zi-Hui Zhang are with the State Key Laboratory of easier fabrication, a trench MOS barrier Schottky (TMBS) 55
of Reliability and Intelligence of Electrical Equipment and the School of rectifier has been proposed and developed for GaN and even 56
Electronics and Information Engineering, Hebei University of Technology, Ga2 O3 -based SBDs [14], [15], which show excellent electrical 57
Tianjin 300401, P. R. China, and also with the Key Laboratory of Elec-
tronic Materials and Devices of Tianjin, Hebei University of Technology, properties in manipulating the magnitude of the electric field 58
Tianjin 300401, P. R. China (e-mail: zh.zhang@hebut.edu.cn). and the depletion region boundary in the drift layer with the 59
Yongjian Li and Zhen Xin are with the State Key Laboratory of Reliability help of charge-coupling effect [16], [17]. 60
and Intelligence of Electrical Equipment, Hebei University of Technology,
Tianjin 300401, P. R. China. Among these reported GaN-based TMBS rectifiers at the 61
Qian Sun is with the Suzhou Institute of Nano-Tech and Nano-Bionics, current stage, the levels of specific ON-resistance (Rsp.on ) and 62
Chinese Academy of Sciences, Suzhou 215123, P. R. China. BV are far from the theoretical limit of GaN materials. The 63
Color versions of one or more figures in this article are available at
https://doi.org/10.1109/TED.2022.3201831. trap-related current transport process is among the mechanisms 64
Digital Object Identifier 10.1109/TED.2022.3201831 causing the degradation of device characteristics [18], [19]. 65
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2 IEEE TRANSACTIONS ON ELECTRON DEVICES
85 TMBS rectifiers. Section III proves that these donor-type and also shows the schematic of the depletion region boundary 123
86 acceptor-type surface traps make significant differences in for the MIS structure and the Schottky contact to reveal the 124
87 affecting the electrical characteristics. In Section III-A, the 2-D charge-coupling effect. Besides, the set regions for the 125
88 donor-type interface state such as N-vacancies is mainly sidewall traps and interface states have also been presented in 126
89 responsible for the decreased Schottky barrier, the weakened Fig. 1(a). 127
90 charge-coupling effect, the increased leakage current, and the In our numerical studies, we conduct the investigations of 128
91 reduced BV. On the contrary, acceptor-type traps such as gal- the GaN-based TMBS rectifiers by using advanced physical 129
92 lium (Ga) vacancies cause the increased Schottky barrier and models of semiconductor devices software (APSYS). Accord- 130
93 the enhanced charge-coupling effect, thus improving reverse ing to reports [27], [28], [29], [30], the shadow donor-type 131
94 blocking characteristics. In Section III-B, the donor-type side- trap level is set at 0.24 eV below the conduction band (i.e., 132
95 wall traps have a weak impact on the forward conduction. E C − 0.24 eV) with the capture cross section of 3.4 × 10−17 133
96 However, the acceptor-type traps will result in a narrow current cm2 . The acceptor-type trap level is set at 1.5 eV below 134
97 flow path and lead to a decreased forward current density. the conduction band (E C − 1.5 eV) with a capture cross 135
98 In addition, the acceptor-type traps can help to increase BV section of 2.1 × 10−15 cm2 . Moreover, the related Auger 136
99 because the accepter-type traps after capturing electrons serve recombination coefficient and the trap-related Shockley–Read– 137
100 as the virtual field plate. Section III also shows that the Hall (SRH) recombination lifetime are set to be 1.0 × 10−30 138
101 donor-type traps are more likely to cause premature breakdown cm6 · s−1 and 1 × 10−7 s in our work, respectively [31]. 139
102 for the current power devices. In Section III-C, we also The models for thermionic emission (TE), barrier lowering 140
103 propose, model, and demonstrate using a meta–insulator– model, trap-assisted tunneling model, impact ionization model, 141
104 semiconductor (MIS) structure with a 1-nm-thick Al2 O3 layer and so on are also considered in our work [18], [32], [33]. 142
105 in the GaN-based TMBS rectifiers. We find that the 1-nm- In addition, the thermionic-field emission (TFE) process [18] 143
106 thick Al2 O3 interlayer increases the effective Schottky barrier and Poole–Frenkel emission (P–F) process [19] have been 144
107 height (qϕ B ), and this significantly reduces the leakage current taken into account in the trap-assisted tunneling model accord- 145
108 even when surface traps and different Schottky metals are ing to the proposed surface trap model in our work. The 146
109 considered. The BV can also be increased. relevant carrier transport mechanisms at/near the Schottky 147
contact interface have also been shown in Fig. 1(b). The 148
111 Fig. 1(a) illustrates the device consisting of a 2-μm-thick bias state. The impact ionization rates of electrons and holes 151
112 n+ -GaN current spreading layer with a doping concentration for GaN can be calculated by using Chynoweth’s equation 152
113 of 5 × 1018 cm−3 and an 11-μm n− -GaN drift layer with a when referring to (1) and (2) for electrons and holes, respec- 153
114 background n-type doping concentration of 2 × 1016 cm−3 . tively [34] 154
115 We also set the mesa width (Wm ), the trench depth (Dtr ), and (−3.4×107 )
v/cm
116 the trench width (Wtr ) to be 2, 2, and 3 μm, respectively. αn = 2.9 × 108 cm−1 × e E (1) 155
Meanwhile, the field plate insulator is Al2 O3 with a thickness (−2.03×107 v/cm )
α p = 1.34 × 108 cm−1 × e
117
E (2) 156
118 (Tox ) of 700 nm. Then, the Schottky electrode is set on the
119 surface of the n− -GaN drift layer, and the ohmic cathode is where E defines the electric field in the drift layer. Moreover, 157
120 designed on the backside of the n+ -GaN substrate to form a some basic physical models, such as the continuity equations, 158
121 full-vertical structure. If it is not specified, the Schottky contact Poisson’s equations, the drift-diffusion equation, bandgap 159
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HUANG et al.: MIS-BASED GaN SBDs: INTERFACIAL CONDITIONS 3
190 the diode. Moreover, the 2-D current density profiles, as shown the increase of OFF-state leakage current according to the 197
191 in Fig. 3(a)–(c), prove the points of view in Fig. 2(a)–(d). conclusion in Fig. 2(a) and (b). However, the reduced BV 198
192 Fig. 4(a) demonstrates that the BV decreases from ∼1200 is speculated to the fact that the donor-type traps influence 199
193 to ∼300 V with the donor-type trap density increasing to the charge-coupling effect in the mesa region. According to 200
194 2 × 1014 from 1 × 1013 cm−2 . Moreover, the reverse leakage Fig. 4(b), an opposite trend is observed that the leakage current 201
195 current also increases significantly when the donor-type trap can be markedly reduced when the acceptor-type traps are 202
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4 IEEE TRANSACTIONS ON ELECTRON DEVICES
Fig. 5. (a) Electric field profiles along the mesa midline for the
studied TMBS rectifiers with different donor-type and acceptor-type trap
densities. (b) Extracted leakage current density as a function of the
density for the donor-type and acceptor-type interface traps when the
reverse bias voltage is 700 V.
Fig. 7. 2-D forward current profiles for the studied devices (a) without
traps and with (b) donor-type traps, and (c) acceptor-type traps. Note
that the trap concentration of 1 × 1017 cm−3 is set.
203 applied, and the increased acceptor-type trap density further traps will sacrifice the current density when the sidewall trap 234
204 enhances the BV. The increased qϕS leads to the decrease concentration exceeds 1 × 1015 cm−3 [see Fig. 6(b)]. The 235
205 of OFF-state leakage current, which agrees with Fig. 2(c) and decreased forward current density can be well attributed to 236
206 (d). Meanwhile, Fig. 4(c)–(e) visually shows the major leakage the weakened current spreading effect. Because the sidewall 237
207 current transport in the 2-D contour at the Schottky interface acceptor-type traps behave as negatively charged centers after 238
208 and the introduction of an acceptor-type trap shall reduce the capturing electrons, then the electrons will be pushed away 239
209 metal/semiconductor leakage process, which also agrees with from the mesa edge. This will result in a narrow current 240
210 Fig. 4(a) and (b). flow path and leads to a decreased forward current density. 241
211 Meanwhile, Fig. 5(a) and (b) presents that the acceptor- In addition, it is worth noting that the sidewall acceptor-type 242
212 type traps help to reduce the electric field magnitude and traps can help to reduce the leakage current [see Fig. 6(b)]. 243
213 leakage current at the contact interface, while these values Moreover, a significant current crowding effect in the mesa 244
214 will be increased when the donor-type traps are set therein. region is observed for the studied TMBS rectifier with the 245
215 Fig. 5(a) also reveals that the surface traps strongly affect the acceptor-type sidewall trap concentration of 1 × 1017 cm−3 246
216 charge-coupling effect between the Schottky junction and MIS according to Fig. 7(c) when compared to Fig. 7(a) and (b). 247
217 structure, such that the acceptor-type traps can even better On the other hand, we also systematically study the impact 248
218 favor the charge-coupling effect in the mesa region, and this of different types of sidewall traps on the reverse blocking 249
219 helps to reduce the electric field at the Schottky contact region. characteristics for GaN-based TMBS rectifiers, which are 250
220 In summary, the donor-type interface traps tend to reduce shown in Fig. 8(a) and (b). We can find that the donor-type or 251
221 the Schottky barrier height, weaken the charge-coupling effect, acceptor-type sidewall traps have less influence on the leakage 252
222 increase the leakage current, and reduce the BV. On the current and BV when the trap concentration is smaller than 1 × 253
223 contrary, the acceptor-type traps enable the increased Schottky 1016 cm−3 . However, the reduced BV can be generated when 254
224 barrier height and the enhanced charge-coupling effect, thus donor-type trap concentration reaches 1 × 1017 cm−3 . The 255
225 increasing the BV. Therefore, artificially introducing acceptor- opposite trend is observed in the case of acceptor-type traps 256
226 type states at the Schottky contact interface seems to improve [see Fig. 8(a) and (b)]. Besides, the results in Fig. 8(c) confirm 257
227 the OFF-state characteristics of GaN-based SBDs. that acceptor-type sidewall traps help to enhance the charge- 258
coupling effect in the mesa region when the trap concentration 259
229 As shown in Fig. 6(a), unlike the interface states in the The accepter-type traps after capturing electrons serve as the 262
230 Schottky contact region, the donor-type sidewall traps have virtual field plate. Nevertheless, positively charged donor-type 263
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HUANG et al.: MIS-BASED GaN SBDs: INTERFACIAL CONDITIONS 5
Fig. 9. (a) Forward I–V characteristics curves for the ideal TMBS rectifier
and the actual TMBS rectifier, and the curves in semi-log scale are also
shown. (b) Conduction band profiles for the studied ideal TMBS rectifier
and the actual TMBS rectifier.
Fig. 8. Reverse I–V characteristics by varying the trap concentration of
sidewall traps. (a) Donor-type trap and (b) acceptor-type trap. (c) Electric
field profiles along the mesa midline for the studied TMBS rectifiers with
the different sidewall trap concentrations.
298 BV (at 1 mA/cm2 ) can be obtained for the actual TMBS As a result, it seems that the donor-type traps are more 313
299 rectifier with trap models when compared to the ideal device, likely to strongly affect the forward and reverse characteris- 314
300 such that the BV is reduced to 800 V from 1200 V. The tics. It is possible to intentionally induce any acceptor-type 315
301 significant degradation of the reverse blocking performance states to compensate the donor-type traps according to our 316
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6 IEEE TRANSACTIONS ON ELECTRON DEVICES
Fig. 12. (a) Simulated forward I–V curves for the actual MIS-TMBS
rectifiers with different anode metals, i.e., W, Au, Ni, and Pt. (b) Exacted
turn-on voltage for the actual MIS-TMBS rectifiers and ideal TMBS
rectifiers.
338 makes the TE process less possible to take place. At the reduced Schottky barrier height when the metal with a small 354
339 reverse bias, the realignment for the Al2 O3 /GaN heterojunction work function is used. However, the reduced barrier height 355
340 generates a long tunneling distance in the scale of ∼200 nm, also generates an increased leakage current. Poor ON-state 356
341 which effectively suppresses the DT process of electrons. performance can be found for the actual MIS-TMBS rectifier 357
342 Moreover, the 1-nm Al2 O3 insulator can increase the effective with Pt Schottky electrode, which can be well attributed to the 358
343 barrier height (qϕS + qϕT ), and as a result, the reverse leakage fact that increased barrier height shall weaken the TE process. 359
344 current is significantly reduced. Such a big energy mismatch between Pt and Al2 O3 /GaN may 360
345 Fig. 12(a) and (b) shows that when compared with the ideal also increase the tunneling width and causes a reduced DT 361
346 TMBS rectifier, the forward current density within the biased process. Note that Fig. 12(a) also shows the multiple steps in 362
347 range and VON has less significant variation for the actual MIS- the current when the applied bias is smaller than the turn-on 363
348 TMBS rectifiers when Au and Ni are used as the Schottky voltage, especially in the case of Pt-based Schottky contact. 364
349 electrode. Note that the metal work functions are set to 4.55, This indicates that when the Al2 O3 thin layer is adopted, 365
350 5.10, 5.15, and 5.65 eV for W, Au, Ni, and Pt, respectively. a much more significant trap-assisted tunneling effect takes 366
351 The actual MIS-TMBS rectifier with W electrode shows an place [38], [39]. Thus, our carrier transport model in the 367
352 improved forward characteristic, i.e., the increased current Schottky contact region is valid. 368
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HUANG et al.: MIS-BASED GaN SBDs: INTERFACIAL CONDITIONS 7
trap density can reduce qϕS and results in decreased VON , 410
which reduces the barrier height and decreases the turn-on 414
voltage. Besides that, the enhanced TE process and the trap- 415
the sidewall traps, the donor-type sidewall traps have less 422
Fig. 14. 2-D leakage current profiles for (a) ideal TMBS rectifier and
(b) actual MIS-TMBS rectifier. Results are calculated at a reverse bias impact on the forward characteristics. However, because of the 423
of 900 V, and the Schottky electrode is Ni. negative polarity after the acceptor-type sidewall traps capture 424
electrons, the current spreading effect in the mesa region can 425
369 Fig. 13(a) also reveals that a lower leakage current is be decreased. Hence, the increased specific-ON resistance will 426
370 obtained for the actual MIS-TMBS rectifiers even if the W be generated. Nevertheless, such negative polarity on the mesa 427
371 electrode is adopted when compared to the ideal TMBS recti- sidewalls enhances the charge-coupling effect, thus increasing 428
372 fiers, which can be attributed to the higher barrier (qϕS + qϕT ) the BV. To suppress the influence of the surface traps on 429
373 at the contact interface according to the previous discussion. the electrical properties, a GaN-based MIS-TMBS rectifier is 430
374 Meanwhile, the donor-type traps can significantly regulate the proposed and studied. The existence of a higher contact barrier 431
375 Schottky barrier, and this, rather than the work function for the (qϕS + qϕT ) for the MIS-TMBS rectifier shall result in a low 432
376 Schottky metal, is the main factor affecting the leakage current. leakage current, then reducing the contribution to the impact 433
377 However, the leakage current can be markedly reduced when ionization process in the drift layer and remarkably increasing 434
378 the Schottky metals with large function (e.g., Pt) are applied the BV. We also show that more freedom can be offered 435
379 to the actual MIS-TMBS rectifiers [see Fig. 13(a) and (b)]. when choosing the Schottky contact electrode for the MIS- 436
380 We believe that the addition qϕT of 1.1 eV makes a major TMBS rectifier. We believe that our systematic research on 437
381 contribution to the reduced leakage current in Fig. 13(b). the interfacial conditions of GaN-based TMBS rectifiers will 438
382 We can also find that the value of BV can be markedly provide useful physical insight into the design and fabrication 439
383 increased for the actual MIS-TMBS rectifier, as shown in of current power diodes. 440
384 Fig. 13(a), e.g., the BV is ∼3200 V for all the MIS-TMBS
385 rectifiers in spite of the presence of the donor-type traps and
386 the value is ∼1200 V for the ideal TMBS rectifiers. Fig. 13(c) R EFERENCES 441
387 also shows that the electric field magnitude at the Schottky
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8 IEEE TRANSACTIONS ON ELECTRON DEVICES
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