AITS 2223 FT VII JEEM Sol

FIITJEE
ALL INDIA TEST SERIES

FULL TEST – VII
JEE (Main)-2023
TEST DATE: 22-03-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. C
Sol. Acceleration = 0 6N
12N 7N 12N 10N 10N
f = 5N f = 5N f = 4N f=0
2. D
1 2
Sol. 0 kx 0  mgx 0
2
kx0
 mg …(i)
2
1
K.E.  k  x20  x 2   mg(x0  x)
2  
dK.E. 1
 k 0  2x   mg(0  1)
dx 2
kx = mg …(ii)
x
 x 0
2
1  x2  x
K.E.max  k  x02  0   mg 0
2  4  2
2 2
3 2 kx 0 kx0
 kx 0  
8 4 8
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AITS-FT-VII-PCM(Sol.)-JEE(Main)/2023 2
3. A
  
Sol. v  u  at 10 cos37
4 3
0  10   10  t  37
5 5
4 10 m/s
t   sec
3
Time for maximum height from ground 37
T 4 7
t   t   1   sec
2 3 3
4. D
 3 5 Hinge
Sol. Conservation of energy mg  2mg  m 2 2
2 2 2
7 5
mg  m2 2
2 2
7g Ny
 2
5
3
Ny  2mg  2m 2 Nx = 0
2
31
Ny  mg
5
2
 (3/2)
2mg
5. C
1 2Gmm0 2Gmm0 m
Sol. m0 v 2  
2  
3
2
  2  60 
/2
8Gm 8Gm 8Gm  1  30 m
   1  m C
 3   3
120
 
6. A
Sol. Buoyant force F1
11 3
FB  R g Fcurved
24
2 FB
 2 R   3R 
(P0  gR)R   P0  g      Fcurved  FB
 2   2 
 R2  1 3 F2
Fcurved = P0    gR
 4 6
 
3 AITS-FT-VII-PCM(Sol.)-JEE(Main)/2023
7. B
Sol. y = A  A cost 1 kg
y=0
= A[1 cos t] A t=0
m g y
y  A 1  cos t 
k
NB = MBg + ky
= MB g  MA g 1  cos t   40  10 1  cos t  4 kg
B
NB  50  10cos t
Weighing machine
8. D
Sol. Ui  WBattery  Uf  Heat
CV 2 4CV 2
  CV 2  Heat
3 3
5  2
Heat    1 CV 2  CV 2
3  3
9. C
1
Sol.   40 x , 0  x 
4
1
  0 , x0
4
1/ 4
3
qenc   4 xdx  4 
0
0 0 1
4 1 30 0 1 
 0    2  3
2 16 4 4  
qenc 70

0 80
7

8
10. B
2Rt
E   
Sol. Current through inductor, I  1  e 3L 
2R  

2Rt
dI E  2R  3L 
 0  e 
dt 2R  3L 

2Rt
dI E  3L
 e
dt 3L
dI 
2Rt
L 3L
Ee
I  dt 
R 3R
11. A
2
 B v  2B2 2 v 2 2  4  1 1
Sol. Heat    R 2  
 R  R 2
12. C
 A
x dx  x
Sol.  dR  
0
0  A

20 A
Current dx
V V20 A
I 
R 
I 2v0
J
A 
2v0
E 

0 E 2v0

x 
2vx
E 2

13. B
Sol. Modulation index
A 5
 m   0.5
A C 10
2  2000
Band width  2fm   2000Hz
2
14. C
v f 10
Sol. m  (  )  
u f  u 10  ( 20)
1
m 
3
 
vIM  m2 v OM
  1
vIM     8
9
   8 10
vIG  vIM  vMG    2  cm/s
9 9
15. C
Sol. A  13.6 eV; B  7.2 eV
K.E.B  2K.E.A
12400  12400 
 7.2  2   13.6 
   
12400
27.2  7.2 

12400
20 

 = 620Å
16. B
t0
Sol. 
2
0.693 t 0
 
 2
2n2

t0
2N0
 N0 et1
3
N0
 N0 et2
3
2  e(t2  t1 )
n2  (t 2  t1 )
2n2
n2  (t 2  t1 )
t0
t0
 (t 2  t1 )
2
(t 2  t 1 )  20
17. A
Sol. Radius of gyration, R  Gahb cc
a b c
M0LT0   M1L3 T 2  ML2 T 1  LT 1 
       
Comparing powers, a = 1/2, b = 1/2, c = 3/2
18. B
Sol. A B Y
1 0 1
0 1 1
1 1 0
0 0 1
19. B
Sol. Least count = 1 M.S.D  1 V.S.D
= 0.05  0.047 = 0.003
Reading = 6.10 + 24  0.003 = 6.172
20. B
100 R
Sol. 100    60 100C 0C
 5R  3
 6 
 
(where R is thermal resistance of each rod)
SECTION – B
21. 4
Vx
Sol. 2
4
Vx 8 2A 4 X 2
A Y
x  y = 36 V V 11
y = x 36 6A
Vy
I 6
11
22. 12
Sol. Let x be the amount of water and y be the amount of ice at the end of second minute
yLice  (x  y)Cwater T  30  60
400y  (x  y)4  2  1800 …(i)
(x  y)  4  6  30  60 …(ii)
Solving (i) and (ii)
1800
400y   2  1800
6
400y = 1200
 y = 3g
30  120
Initial amount of ice =  3  12g
400
23. 140
P  P 
Sol. W  nR(400)n  B   nR(300)n  D 
 PC   PA 
24. 10
1 1 1
Sol.  
fe v e ue
1 1 1
 
6.25 25 ue
1 1 1
 
ue 25 6.25
ue  5
| v 0 |  | ue | 15
v0 = 10 cm
1 1 1
 
f0 v0 u0
1 1 1
 
5 10 u0
u0 = 10
25. 16
4
I0  3  100
Sol.     15.82%  16%
24 I0
26. 8

Sol. P  P î  Pjˆ

rA  3i  4ˆj

rB  3i  4ˆj
 
KP  rA KP
VA  3

rA 125
 
KP  rB 7KP
VB  
rB3 125
8
Work done = q0 (VB  VA )  (KPq0 )  8 Joule
125
27. 6
Power 1
Sol. Intensity,  0E02C
Area 2
2.4 100 1
  0E02C
100 4(2)2 2
 E = 6 V/m
28. 8
d
Sol. BR2I  Mg
2
Mgd
I
2R2B
29. 5
VR 50 5 VL
Sol. cos    
V 130 13
VR2  VL2  (100)2
VR
130  VR2  (VL  VC )2
16900  VR2  14400 VC
VR  2500  50 V
30. 2
Sol. Apply Bernoulli’s between B and C
1 1
PB  VB2  PC  VC2 …(i)
2 2
Also, VC = 2VB …(ii)
2g
VB  hBC
3
Applying Bernoulli’s between A and B
1 1
PA  VA2  PB  VB2 …(iii)
2 2
 h 
VA  2g  BC  hAB 
 3 
Chemistry PART – B
SECTION – A
31. C
Sol. Molecule/ion Number of unpaired electron Bond order Magnetic character
O22 1 1.5 Para
O 2 1 2.5 Para
C22 0 3 Dia
N4
2 0 1 Dia
1
Bond length 
Bond order
32. B
Sol. P  V  b   RT
PV  bP  RT
Divide by RT
PV bP
 1
RT RT
 b 
Z  1  P
 RT 
Slope  b  size of atom.
33. A
Sol. Na  g  e  Na  g H  53 kJ / mole
Rest B, C and D are endothermic.
34. D
Sol. A, B and C are correct options.
35. D
n2
Sol. rn  ro
Z
ro
R  rn2  rn1 
Z
n
2
2  n12 
ro
He , R1 
2

 32  22  … (i)
ro
Li2 , R2 
3
 42  32   … (ii)
R1 3 5 15
  
R 2 2 7 14
36. C
Sol. OH
OTs
TsCl

Pyridine

A OTs
O
O
EtO 
 
 S 2 reaction
N
37. D
Sol. Biuret test detects presence of peptide bonds.
 Barfoed’s test based on reduction of copper (II) acetate to copper (I) oxide which forms brick
red precipitate.
 Molisch’s test is for presence of carbohydrate.
38. D
Sol. Glyptal is used to manufacture of paints and lacquers.
39. C
Sol. Due to deficiency of Vitamin E.
40. C
Sol. B.H.T. and BHA are most familiar anti oxidants.
41. A
Sol. CdS, ZnO, Graphite are the examples of hexagonal.
42. C
Sol. AB  A   B
K sp   A   B   5  109  10  109
 50  10 18  5  10 17 M2
43. D
Sol. OH OH
< (Correct acidic strength)

OH
OH
(pKa = 9.44) (pKa = 9.96)
44. C
Sol. Reverbertory furnace is used in sulphides of copper.
A, B and D are correct statements.
45. D
Sol. A – B has highest bond enthalpy so stiffest bond.
A – C has the largest bond length.
46. D
Sol. Let us assume reactivity of C – D is a and C – H is b.
2a 50

2a  6b 100
a
 0.5  a  0.5a  1.5b
a  3b
a 3
0.5a  1.5b  
b 1
47. B
Sol. Wave length range is 200 – 315 nm (UV region)
48. D
Sol. A, B and C are correct statements. Repeated used of DDT in insects is not good. So, Aldrin and
Dieldrin were introduced in place of DDT in the market.
49. C
Sol. In option A, B and D entropy is increasing where as in C option when pressure is increased O2
molecules come closer to each other hence entropy decreases S  0 .
50. C
Sol. Go  2.303 RT log10 K eq.
413.15  2.303  2  298 log10 K eq
 0.3010  log10 K eq
K eq  2
Hence, graph (C) matches correctly.
SECTION – B
51. 5
Sol. 3A  B
t0 a 0
t  240 hr ab b/3
b 3b 3a
a b  a b
3 4 4
a
 a to time given is 240 hours which is equal to 2t1/2 for A.
4
Hence, 2t1/2 = 240  t1/2  120 hrs  5 days
52. 4
Sol. Degree of unsaturation of C4 H7 Cl is 1 hence alkenes and cyclo compounds are possible.
Alkene isomers = 10
Cl Cl
Cl
Cl
(2)
cis-trans
Cl
Cl
Cl
Cl
trans cis
trans-cis
Cyclic isomers = 6
Cl
Cl Cl Cl Cl
Cl
x – y = 10 – 6 = 4
53. 4
Sol. Only CH3 CHO will react with Fehling solution.
CH3 CHO  2Cu2  CH3 COO   Cu 2 O   
44 F.S. 143 Re d
 143 gm of Cu2 O is formed by = 44 gm CH3 CHO
44
 0.975 gm of Cu2 O is formed by   0.975
143
0.3 gm of CH3 CHO
Mass of acetone = 0.2 gm
0.2
% of acetone   100  40%
0.5
x = 40
x
So, 4
10
54. 6
Sol. X Y
B B
H H H H
N N N N
B B B B
H H H H
N N
H H
(Y has 3 different positions) (X has 3 different positions)
Total position isomers = 3 + 3 = 6.
55. 6
Sol. NH2 CONH2  2NaOH  2NH3  Na2 CO3
100  2
Moles of NH3  moles of HCl  = 0.2 moles
1000
1 1
Moles of NH2 CONH2  moles of NH3   0.2  0.1
2 2
Mass of urea  0.1  60  6 gm
56. 5
Po  Ps n nA 9 o
Sol. o
   Ps  P
P N nB 10
9 o
Po  P
10 W M
o
 A  B
P W B M A
1 a 1 b
   5
10 b 2 a
57. 3
Sol. AB 2  g  A   g   B  g  B  g
Hr  2HA B  I.E. A   Heg  B 
 2  100  250  150
 200  250  150
= 300 kcal/mole.
x
So, x is 300 hence will be 3.
100
58. 6

Sol. 2NaClO3   2NaCl  3O2
NaCl  AgNO3  AgCl  NaNO3
2 2
Moles of O 2  moles of NaCl  moles of AgCl
3 3
2 2 2
Moles of AgCl  moles of O2  
3 3 32
2 2
Mass of AgCl    143.5 gm
3 32
= 5.97
6
59. 7
Sol. Seven chiral carbon atoms have hydrogen.
CHO
OH
H2N
60. 3
Sol. O NH NH CH(CH3)2
C
Mathematics PART – C
SECTION – A
61. C
3 3
 1   1  1 20 5
Sol. For one to 6, 3 black and 3 white and 7th ball is white = 6 C3       =
 2   2  2 128 32
62. C
Sol. (x + y)  (x + y + a) (1  (x + y + a))
 x + y  x + y + a  (x + y + a)2
 (x + y + a)2  a
x a y
63. A
  1
Sol. 8cosx  cos2 x  sin2    1
 6 2
64. D
Sol. It is differentiable at x = 0 also differentiable at x = 
65. B
Sol. Circum centre is mid point of AB B(, 6)
C
  A(, 2)
 , 2 
4 
66. C
tan5 x
Sol. Let I = In + I4 = (tan4x + tan6x)dx = tan4x + sec2x + dx = c
5
1
a= ,b=0
5
67. C
î ˆj kˆ
Sol. The normal vector is 1 2 3  5iˆ  7ˆj  3kˆ
2 1 1
5735 20
Now plane is 5x + 7y + 3z + 5= 0 distance from (1, 1, 1) = =
25  49  9 83
68. A
Sol. 5(sec2x  1) = 9cos2x + 7
Let cos2x = t
1 5
=t= ,t 
3 3
69. A
Sol. In = (n  1) (n  w) (n  w2)
In = n3  1
Sn = n3  n
70. A
Sol. See the figure AOB = 120°
A E
D
71. A
Sol. Let D  (0, 0) A
B  (b, 0)
C  (b, 0)
E
A (0, a)
F
B D C
72. B
Sol. The mid point lie on x + y = 0
Find the equation of the chord by T = S1 and by taking mid point (t, t)
73. A

Sol. Let R  xiˆ  yjˆ  zkˆ
   
RB  CB
î ˆj kˆ î ˆj kˆ
 x y z  4 3 7
1 1 1 1 1 1
74. D
3
Sol. Tn = n (n + 1)
4 3
Tn = n + n
75. C
x x
sin   cos  
Sol. f  x   2  2
x x
sec 2   cos ec 2  
2
  2
x x
sin   cos  
f  x  2  2
x x
sec cos ec
2 2
76. D
Sol. Put f 1(x) = t
1
f   t  dt
I=  5 = ln7
2 t  5t
77. A
2
Sol. Put x = t = dx = 2t dt
1
t  2t  dt
I= 
2

0 t  1 1  3t
2

3  t2 
78. B
Sol. Put x = 1, y = 1  f(1) = 0
Diff. w.r.t (x)
yf'(xy) = f(y) + yf'(x)
Put x = 1, yf'(y) = f(y) + y
79. D
Sol. Let x  1 = X
x1=0x=0
y2 = 5  x  y2 = 4  X …(1)
Let the circle is (X  r)2 + (y  0)2 = r2 …(2)
From (1) and (2)
X2  (2r + 1) x + 4 = 0
Now D = 0  r = 3/2
80. B
Sol. Point of intersection of tangents are (at1t3, a(t1 + t3))
From given we can conclude t1 and t3 both satisfying at 2 t 22 = 4b(t + t2)
 at 2 t 22  4bt  4bt2
4b 4bt 2
t1  t 3  , t1t 3 
at 22 at 22
SECTION – B
81. 3
Sol. 2sinx + tanx  3x
Also equality holds when x = 0
82. 15
Sol. Here focus chord is normal. Hence the focal chord is the major axis.
83. 8046
Sol. Write general terms of (1 + x2)6 (1 + x3)9 (1 + x4)12
84. 17
128 r r
Sol. Write general terms = 128
Cr  2  7
8
for r = 8k, k = 0 to 16 are possible.
85. 0
Sol. P3 = Q3 and P2Q = Q2P
3 2 3 2
P P Q=Q Q P
2 2
 P (P  Q) = Q (Q  P)
2 2
 |P (P  Q)| = |Q (Q  P)|
2 2
 |(P + Q ) (P  Q)| = 0
86. 1
5 3
2 2log10  log10
Sol. a = log532 35  3 5
2log10  log10
5 3
3 3log10  log10
b = log533 35  3 5
3log10  log10
Put the values of a and b is ab + 5(a  b).
87. 4
Sol. Let the equation of normal is y + tx = 4t + 2t3 and it passes through (3, 3)
3 + 3t = 4t + 2t2
This equation has only are real value of t i.e. t = 1
so only are normal ordinate = 2at = 4
88. 22
Sol. 60 = 2  2  3  5 = 22  3  5
22 can be distributed = 5 ways
3 and 5 both 3 ways
89. 1
P(1  h)  P(1)
Sol. |P'(1)| = lim
h 0 h
Also |P(1)|  0  P(1) = 0
P(1  h) eh  1
 |P'(1)| = lim  lim
h 0 h h 0 h
 |P'(1)|  1
90. 176
Sol. Apply vector triple product

AITS 2223 FT VII JEEM Sol

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AITS 2223 FT VII JEEM Sol

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< (Correct acidic strength)

for r = 8k, k = 0 to 16 are possible.

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