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CHEMISTRY



  
   
  



         

  
      

  

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 "$#"

1 125 25
1. Area of ABE 
2

2.5 105 
0.05 103  
2

4
1.5 CD 3
Since, AEB and BCD are similar, therefore  CD  0.05  0.03
2.5 0.05 5
1 4.5 9 25 9
Area of BCD 
2

1.5 105 
0.03 103    WN 
2 4
  4J
4 4
2. Total energy released from Au198  Hg198

In ground state 
m loss  c 2

198
Energy released from Hg in first
Existed state  Hg in ground state 
1.6  
2  MeV

( Energy released from Ag198  Hg198

Second excited state  1.86  0.4  1.46  max. K.E of particle
3. Capacitor has maximum charge at steady state

q
 iR1
C
CER1
q
R1  R 2
ln q  ln C  ln E  LnR 1  ln
R 1  R 2 

q  C  E  R 1 *  R 1   R 2 5
   + 6
q C E R1 , R1  R 2 7

q C  E 01 1 ; R 2
   R 1 1  <
q C E 2 R1 R1  R 2 = R1  R 2
q 0.01 4 01 1; 6
   31  < 
q max 1 40 2 60 90 = 90
4. Place +m and – m particle at the vacant corner
 Assume the +m particle and the rest seven particles as system (1)
The total mass of system (1) is m1 =8m and the position vector of its com is

a a a
r1  ˆi  ˆj  kˆ and assume – m particle s system (ii)
2 2 2
m 2   m, r2  aiˆ  ajˆ  akˆ



m r  m 2 r2


8m  *+
aˆ aˆ a ˆ5
,2 2 2 7


i  j  k 6 
m  aiˆ  ajˆ  akˆ 
r cm  11 
m1  m 2 8m 
m 
3a ˆ 3a ˆ 3a ˆ
r i j k
7 7 7
5.

*A5 3
1 sin i   sin + 6 ,sin i 
,27 4
n1 sin 30o  1sin
e 
On differentiating both sides
dn sin 30o  decos
e 
dn
de 
2cos
e 
 dn

7
2x
4
2
de  dn ( de  dn
7
2.8x10 3 x2
de   2.1166mrad
7

m 2 / 3 2
6. T1  2  2
mg / 2 3g

m 2 m
T1  2  2
*  5 * 3mg 5
3 + mg  k 2 6 3+ 6
, 2 7 , 2 7
2
*  5 m 2
 + mgx   kx 6   2
, 2 7 3 9g

5
+ mgx k 26
,
2 7
2
m
3
2 2 2 * 1 5
T   + 1 6
3g 9g 3g , 37
 2
1  0.577   3.15sec
7. f1  f 0
cv
f2  f0
cv
* 2v 5
f b  256 + 6  1.6Hz
,cv7

8. F
yiˆ  2 xjˆ 
WAB 
1iˆ  '
1iˆ   1J

- ˆ  2 xjˆ 8
. F   1i 9
. ˆ 9
/ S  1i :
 Similarly,
WBC  1J
WCD  0.25J
WDE  0.5J
WEF  WFA  0J
New work in cycle = 0. 75 J
9. Let the impulse due to the rod be T.
mv  Tsin  3mv1 where, V1 is the speed of
A  C  just after the collision.
T cos  3mV2 where V2 is the speed of B from the inextensibility of rod AB
V1 sin  V2 cos

v cos 2 vsin 2
Thus, V1  & V2 
3 6
dU mv 2 nh
10. Centrifugal force kr  , Angular momentum, L  mvr 
dr

nh nh k 1 nh k
On solving, we get r  &v ;KE  mv 2 
2 km 2m m 2 4 m

kr 2 k * nh 5 nh k nh k
U  + 6  ;E  kE  U 
2 2 , 2 km 7 4 m 2 m
0i 4 4dx * 2 n2 5 d * 2 0n2 5 di
2 42 x
11. Flux through frame  + 0 6i  + 6
,  7 dt ,  7 dt
2 0i 0n2 * 5 * 2 i n2 5 * 5
 cos + t  6 ( Q  c  + 0 0 cos
6 +  t  6
 , 67 ,  7 , 67

* 2 0i 0n2 5 dq * 2 0i 02n2 5 * 5
Q max  max C  + 6 Cand i frame  + 6 + t  6
,  7 dt ,  7, 67
12. Let at any point E be field & intensity. Then Ohm’s Law

P0 I P0
E  P.J  . E .I …….(i)
1  x area 1 x
 P0 I
E.dx  dV ( dV  .dx
1 x
B 1 dx
 P0 I -/ln
1  x  8: 0  P0 I.ln 2
1
 4 dV  P.I 4
A 0 1 x

VA  VB 
P0 ln 2  I ( V  I.
P0 ln 2 

V 1 V V V 2V
So R 0   P0 ln 2, E  . , EA  EB  , EC 
I 1  x ln 2 ln 2 2ln 2 3ln 2
* .D 5 y.d
13. y+ 6 .n (n (D]
, d 7 
n=1, 2, 3, 4, …….. for maxima
n = 0.5, 1.5, 2.5, ……for minima
dy
D  x  vt n /  x  vt


5x 4x 12x
t ,n   n  1.5
3v 5x 8x
x
3
dA L
14. 
dt 2m
GMm
KE i 
2r
GMm
Ui 
r
GMm
TE i  
2r
6 GMm
KE f 
5 2r
6 Gm
Vf 
5 r
MEC
1 6 GM Gmm 1 2 GMm
m   mva 
2 5 R R 2 ra
 AMC
6 Gm
m R  mva ra
5 R
15. By angular momentum conservation about the hinge,
Li  L f
L mL2
mv  
2 3
3v 2L
 :t 
2L 3v
L 3v
vCM  
2 4
1 2 mv 2
KE f  I  25
2 L
2
1 mL2 * 3v 5
 + 6
2 3 , 2L 7
2 L 3 2
Later, Fhinge m mv
2 8
2
* 3v 5 mv * 3v 5 L
Impulse m + v 6 m+ 6
, 4 7 4 , 2L 7 2
mv L 9mv 2
Fhinge  " 
4 100v 8L
*a 5 * a5 1 3
16. F1  +  g6 +a 6  a g
,4 7 , 27 8
*3 5 * a5 3 3
F2  + ag 6 + a 6  a g
,4 7 , 27 8
*2 5 * a5 1 3
F3  + ag 6 + a 6  a g
,3 7 , 27 3
*1 5 * a5 1 3
F4  + ag 6 + a 6  a g
,3 7 , 27 6
KQ 1
17. (i) E  2 ( E
d d2
(ii) Dipole
2kp
E 3
1  3cos 2 
d
1
E 3 for dipole
d
(iii) For line charge
 2k
E
d
1
E
d
2K 2K -d    d  8
(iv) E    2K . 9:
d d / d 
2 2

2K
2 
E
- 2 8
d 2 .1  2 9
/ d :
1
E
d2
(v) Electric field due to sheet

&
2 &0
& v is independent of r
18.

Friction on Q will always be towards equilibrium and friction on P will be opposite to that
friction is only force acting on block Q in horizontal direction which is responsible for its
oscillation.
Friction force will be maximum at extreme position and zero at equilibrium.


Ph

OH PhH 2 CO Ph

N N
OH PhH 2 CO
O O
OCH3 3 OCH3
19. 2
 The molecular weight of final product is 519.
0.20 moles of reactant gives 50.6gm of final product with the given yield.
20.

(i) IF5 sp3 d 
(ii) ICl4 sp3 d 2

(iii) XeO 2 F2 sp3 d



(iv) NH 2 sp3 (v) BCl
sp 
3
2
(vi) BeCl2
sp 
(vii) AsCl
sp  
4
3
(viii) NO
sp 

2
2


(ix) ClO 2 sp 2
x 
sp  2  sp d
1  sp d
2   5
3 3 3 2

y  3,z  1; 5  3  1 ( 7
21. x= 0, y=3
22. All give oxygen on heating.
23.

COOH COOH
COOH COOH
CH 2 COOH
CH 3CH Ph  OH Ph  CH 2  CH
NH 2 NH 2 NH 2 NH 2
NH 2
Gly Val Al Phe Tyr
G V A P T
VGAPT VGPAT ;
3
VAGPT VPGAT < 6 combinations by each of V, A, P
VAPGT VPAGT 3=
Total 18 possible sequences.
24.
XeF4  O 2 F2  XeF6  O 2
Y

Y has 3 lone pair of electron in each fluorine and one lone pair of electron in xenon. Hence
total lone pair of electrons is 19.
q1 q 2 V V VV
25. Scycle  0    0, nRn 2  nRn 4  0, nR  n 2 4  0
T1 T2 V1 V3 V1V3
26. Reaction used in the question

1) KMnO 4  H 2 O 2 %%
H
 Mn 2
2) KMnO 4  MnSO 4 %%
 MnO 2
3) MnO 2  C 2 O 42 %% Mn 2  CO 2
29. B) Reactivity towards water ↑ from Li to Cs due to the ↓ melting points of metals
C) fact
D) KCl solubility in H2O = 27.77 g/100mL (0 °C)
KCl solubility in H2O = 36 g/100 ml pure water at T = 25 °C
31. 10 mole A and 10 mole B
PT  PA0 X A  PB0 X B
1 1
PT  0.6 9
2 2
 PT  0.75
Since 1/4 th mole will be converted
In vapour 4 moles total will be present. Assuming x mole to be of A.
Liquid Vapour
A 10  x x
B 5 x 5x
x 10  x 0.6

i  
5 15 PT

PT 

10  x  0.6
3x
5  x 5  x 0.9

ii  
5 15 PT

PT 

5  x  0.9
3
5  x 

(

10  x  6 
5  x  9
3x 3
5  x 
Simplifying x 2 45x 100 0
45 2425
x 2.125
2
34. 2X  Y  P
t  0 conc. 2 1 
t conc. 2  2x 1 x x
t  50 sec n Y  0.5 ( t1/2  50 sec

*X 5
A) 2K r n t  n + 0 6
, Xt 7
n2 0.693
t1/2    50
2K r n 2 2r n

K r n  0.693 102  6.93 103 sec1

A  is correct
(B) is correct

d X
(C)   2K r n X
dt
 2 6.93 103 1
 13.86 103 M sec 1
correct 
 dY
(D)   Kr n X
dt
35.

2a 4a 8a
(P) a %%%t1/3
18sec
 %%%
t1/3
  %%%t1/3

3 18sec 9 18sec
27

t19/17  54 sec

3a 9a
(Q) a %%%t1/ 4
16sec
 %%%t1/ 4
16sec

4 16

t 7/16  32 sec

2a
a

S K 3  x 5
(x a
18 30 9

a
a
2 x 7
T K x a
16 28

 
37. If child buys pencil on the first day then the remaining n-1 rupees can be spend in Sn 1 ways

and if he buys pen on the first day then the remaining n-2 rupees can be spend in Sn 2 ways

similarly Sn 2 ways for book on the first day.

the recurrence relation is
Sn  Sn 1  Sn 2  Sn 2
Sn  Sn 1  2Sn 2

Clearly S1  1,S2  3
1,1 ,2,2

Now,S3  S2  2S1  5
S4  5  2.3  11
S5  11  2 5  21
S6  21  22  43
S7  43  2 21
 43  42
= 85
 * Sn  Sn 1 5
+  S7 6  85  2  87
, Sn 2 7
40. Since z1  z 2  z 3  1

( z1  z 2  z 3  1
1 1 1
(   1 ( z 2 z 3  z 3z1  z1z 2  1
z1 z 2 z3
Now, consider a cubic equation having roots z1 ,z 2 ,z 3

z  z1 
z  z 2 
z  z3   z3 
z1  z 2  z 2  z 2 
z1z1  z 2z3  z3z1  z  z1z 2z3  0

( z3  z 2  z  1  0
( z 2
z  1  1
z  1  0
( z  1,z  i
Roots z1  i, z 2  1, z 3  i

z1  z 22  z 33

*
tan 1 +

n  2  
n  1 5 5
+ 6 6
 1 
n  1 
n  2 
41. ) tan 1 ++ , 7 6
1 * 1 5 1 * 1 56
n 0
+ 1  tan + 6 tan + 66
+ , n 17 ,n 276
, 7
* 1 * 1 5 1 * 1 5 5
+ tan + 6  tan + 6

, n 17 , n 27 6
) tan +
1

+  * 1 5  * 1 5
6
6
+ 1  tan + n  1 6 .tan + n  2 6 6
n 0 1 1

, , 7 , 77

* * 1 * 1 5 5 5 1 * 1 * 1 55
) + tan 1
+
,
tan + 6 6
, n 1777
6  tan +
,
tan + 66
, n  2 77
n 0 ,
*5
tan 1
tan 1
1   tan 1 + 6
,47
p 

cos 1
cos
  1     1  2.14

42. Given f
x  5   f
x   5 ....
1

f
x  1  f
x   1 ....
2 
 From (1) and (2) we can write
f
x   5  f
x  5  f
x  4   1

 f
x  3  2

 f
x  2  3

 f
x  1  4

 f
x  5
Equality exist every where
f
x  1  f
x   1
f
1  1

( f
2   2, f
3  3......f
2023  2023.

Now g
x   f
x   7  x ( g
2023  7

43. f
x   2x
2  x 


y  f f
f
x   ;0 x  2

y  32x
2  x 
x 1
2 2
2x 4x 1 ;0 x 2

44. Equation of tangent at
x i , yi  on the curve y  f
x  is: Y  yi  m
X  x i 

yi
Put Y  0,X  x i1 , then 0  yi  m
x i1  x i  ( x i1  x i  
m
x i1 y
1   i
xi mx i
 yi
If x1 , x 2 , x 3 ,........x n form G.P. then r  1   (Where r is common ratio of G.P)
mx i
dy y dy dx
m  (  0
dx
r  1 x y
r  1 x
* 1 5
( ny  + 6 nx  k
, r 17
1
( y
x  r 1  c

( r  2, xy  c,e  2
1 1
45.  1
x y
( x  y  xy
(
x  1
y  1  1
(x 2, y 2

a r x r
1 x
46. 1 x 3 n
)
1  x 
r 0
2r

n r
* 1  x3 5 n * x 5
+
1  x 3 6 )
(+ 6  a r+ 2 6
+  67
, 7 r 0
,
1  x
n r
* 1  x  x 2  3x  3x 5 n 03 x ;3
(+ 6 ) r1
 a 2<
+
1  x 
2
6 3
1  x 
, 7 r 0
2 =3
n r
* 3x 5 n 03 x ;3
+
1  x 2 6 )
( +1  6  ar 1 2<
, 7 r 0
23
1  x  =3
r r
n * x 5 n 03 x ;3
( ) Cr 3 +
+
1  x 2 6 )
n r
6  a r1 2<
r 0
, 7 r 0 23
1  x  =3
( a r  n Cr 3r
47. S
n,k  $ No. of ways to partition n distinct items into k parts.
First consider one particular element a1 forming one group and remaining n – 1. elements
forming k – 1 partitions.
 Second, consider n –1 elements forming k partitions and a, element going in one of ‘k’
groups.
Hence, S
n,k   S
n  1,k  1  kS
n  1,k 
No. of onto functions = k!S
n,k 

 - k n  k C1
k  1  k C2
k  2  ......8
n 2
/ :
1
S
5,3  -/35 5 C1 25  3 C215 8:  25
3!
No. of onto functions from 6 elements to 3 elements = 3!S
6,3
48. Any point on the given line will be

2  1, 3  1,   $
, ,
 0


x 
9 r r
Now Tr 1 9 Cr 2x 2

Cr
2x 2 
9 r

1
x
r 9 r


1 9Cr 29r x183r

r

18  3r  0 ( r  6

Coefficient of x  6
3

   
49. x a  y b  c  0 ( If x  y  1  0 then C lies on line segment AB.
If x>0, y>0 and x+y–1=0 then C lies on line segment AB.
If x<0,y>0 and x+y–1=0 then C lies on line but not on line segment AB.
If x>0,y<0 and x+y–1=0 then C lies on line but not on line segment
If x>0, y>o and x+y–1<0 the C lie inside AOB
50. A  BT  B 2
B  AT  A2
(
A  A T  
B  BT   B 2  A 2

( B2  A 2 is skew symmetric matrix of odd order

B2  A 2  0

Now take transpose of equation BT  B2  A

( B 
BT   A T
2
 (
BT   B  A T
2

(
BT   B  A 2  B (
BT   A 2
2 2
( B A

(
BT   B 
B 2  B T   B
2 2

( B 4  B 2 BT  BT B 2  0
( B 2
B 2  BT   BT B 2
3
( B 2 B 2  BT  B
2 3 2 3
( B A  B , similarly A B  A

( If B # 0 then A  B andif B  0 then A  0

( AB
51. (P) For line to become tangnet to ellipse

(Q)

2 2
 1, t1 t 2  4
t1 t 2
2 4
t 2   t1  
t1 t1

m   t1   2

(R) ty  x  t 2 ( ty  x  t 2 ......
1

t x  y  t 2 ( t x  y  t 2 ......
2 

1 and
2  areidentical

 1 t2
( t    2  t 4
t t

t 3  1 ( t  1
y  x  1
x  y 1 0 ( k  3
(S) ty  x  2t 2
1
y  x  2t
t
For line to become tangent to hyperbola.

1
4t 2  2
 3 ( 4t 4  3t 2  1  0
t
(
4t 2  1
t 2  1  0
1
t
2
1 1
 yx ( 2x  1   y
2 2
2x  y  1  0
*  5
+ 3
1  tan  
2 4 tan 6
52. (P) P
3cos ,2sin   $ + , 2 6
*
+ 1  tan 2  5 *  5 6
6 +1  tan 6 6
2
++
,, 27 , 277
 
tan can take infinite rational values
2
(Q) P
3,0  ,
0, 2 

(R) P
3 cos ,sin  

tan 
 k &Q
3
* 3 3k 5
( P+ , 6
, 1  3k 1  3k 2 7
2

1  3k 2
if  &Q
3
1
2  k 2 
3
Which can be expressed as product of two rationals in infinite ways
1
say for example k ;
2
2
k
3
7 1
(   ,k 
12 12
(S) P $
0, 1
54.

f
x   x2  2 x

1 1
! ! 2
2
1

0f
x   x 2  2x; 2  x  1
3
3 1; 1  x  0
g
x  1
3 0; 0x2
3f
x   x  2x; 2  x  3
2
2