5.Discuss electric current semi-conduction in amorphous materials.
Amorphous materials have disordered atomic-scale structure. The disorder in
these materials creates localized states that allow for the movement of electrons, leading to electrical conductivity By controlling the deposition conditions and the composition of the material, the electrical properties of amorphous materials can be tailored for specific applications. Amorphous materials lack the long- range order of a crystal lattice, which makes it difficult for electrons to move through the material. However, they do have some degree of short-range order that allows for some electrical conductivity. The mechanism behind semi-conduction in amorphous materials, is that the energy bandgap [which is in the range of two to three eV] is typically created by disorder in the material itself. This disorder can create localized states in the energy bandgap that allow for the movement of electrons, leading to electrical conductivity. Amorphous materials are commonly used in electronic devices such as solar cells and memory devices. These materials are suitable for these applications because they can be easily deposited in thin films using techniques such as evaporation or sputtering. Additionally, amorphous materials can be made to have specific electrical properties by controlling the deposition conditions and the composition of the material.
6.A] Explain why a semi-conductor exhibits a negative temperature
coefficient of resistivity. 1.Increase in carrier mobility: As the temperature of a semiconductor increases, the thermal energy of the atoms in the material increases, causing more atomic vibrations and making it easier for the charge carriers to move through the crystal lattice. This increased mobility of carriers leads to a decrease in resistivity. 2.Reduction of the scattering of carriers: At lower temperatures, charge carriers in a semiconductor are scattered by impurities, lattice vibrations, and other defects in the crystal lattice, which increases resistivity. As the temperature increases, the thermal energy can overcome some of these scattering mechanisms, leading to a decrease in resistivity.
B] Discuss why silver is the best metallic conductor of electricity.
- Silver has the highest electrical conductivity of all metals, with a conductivity of approximately 62.1 × 10^6 S/m at room temperature. This means that it can conduct electricity more efficiently than any other metal, making it the ideal choice for electrical applications where high conductivity is critical. - silver's combination of high electrical conductivity, low resistivity, high thermal conductivity, and resistance to corrosion make it the best metallic conductor of electricity.
C]Explain how conductivity modulation in semiconductors is used in
thermistors and photoconductors. Conductivity modulation is a process of changing the electrical conductivity of a semiconductor material by introducing impurities or defects into its crystal structure. In a thermistor this effect is achieved through the use of a semiconductor material, typically doped with impurities to produce the desired temperature sensitivity. When the temperature of the thermistor changes, the conductivity of the semiconductor material also changes, resulting in a change in resistance. In a photoconductor, the conductivity modulation is achieved through the use of light. When light is absorbed by a semiconductor material, it creates electron-hole pairs, which can increase the conductivity of the material. The amount of light absorbed by the material is directly proportional to the change in conductivity, which can be measured and used to infer the intensity of the incident light.
7.List four main causes of resistivity in metals.
-Temperature: As the temperature of a metal increases, the thermal energy causes more atomic vibrations, which can slow the flow of electric current through the metal, leading to an increase in resistivity. -Elastic scattering: Elastic scattering can impede the flow of electric current through the metal, leading to an increase in resistivity. -Grain boundaries: Discontinuous or misaligned boundaries can impede the flow of electric current through the metal, leading to an increase in resistivity. -Impurities: Impurities can disrupt the regular crystal lattice structure of a metal, making it more difficult for electric current to flow through the metal, leading to an increase in resistivity. 8. The resistivity of pure silicon is 2.3x10^3Ω - m at 27 °C. Find its conductivity at 200°C. Formula [ σ = 1/ρ] σ = σoe-Eg/2kT 1/2.3x10-3 = σoe-1.1/2x8.65x10-5x300 σo = 696581.9 conductivity at 200 degrees = 696581.9x6.242x10-10 = 1.08 Ω-1m-1