12.

IUPAC name of the compound is

a) pent-2-en-1-al b) But-2-en-1-al
c) pent-3-en-4-al d) pent-3-en-5-al

21. Structures and are

a) Chain isomers b) Position isomers

c) Both chain & position isomers d) Not isomers
41. In which of the following, the group attached to the benzene ring shows +R effect?

a) b) c) d) All of these

1. The radius of Na+ and Cl– ions are 95 pm and 181 pm respectively. The edge length
of NaCl unit cell is
a) 276 pm b) 138 pm c) 552 pm d) 415 pm
10. In a face –centred cubic lattice, atom A occupies the corner positions and atom B
occupies the face centre positions. If one atom of B is missing from one of the face
centred points, the formula of the compound is:
a) A2B b) AB2 c) A2B3 d) A2B5
15. Vapor pressure of benzene at 300C is 121.8 mm. When 15 g of a non–volatile
solute is dissolved in 250 g of benzene its vapour pressure decreased to 120.2 mm.
The molecular weight of the solute is (mol wt of solvent =78)
a) 356.2 b) 456.8 c) 530.1 d) 656.7
26. Review the equilibrium and choose the correct statement
HClO4 + H2O H3O+ +
a) HClO4 is the conjugate acid of H2O b) H3O+ is the conjugate base of H2O
c) H2O is the conjugate acid of H3O+ d) is the conjugate base of HClO4

O
40. Calculate H (in joules) for C (graphite)  C (diamond), From the following data

C (graphite) + O2(g)  CO2(g) ; H = – 393.5kJ

C (diamond) + O2(g)  CO2(g) ; H = – 395.4kJ
a) 1900 b) – 788.9  103 c) 190000 d) +788.9  103

41. Calculate the work done when 1 mol of an ideal gas is compressed reversibly from
1 bar to 4 bar at a constant temperature of 300 K
a) 4.01 kJ b) 3.458 kJ c) 18.02 kJ d) –14.01 kJ
42. Which of the following is correct option for free expansion of an ideal gas under
adiabatic condition
a) q = 0, T < 0,   0 b) q = 0, T  0,  = 0
c) q  0, T = 0,  = 0 d) q = 0, T = 0,  = 0