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Journal of Magnesium and Alloys 11 (2023) 15–47


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Review
Development and application of magnesium alloy parts for automotive
OEMs: A review
Bo Liu a,∗, Jian Yang a, Xiaoyu Zhang b, Qin Yang b, Jinsheng Zhang b, Xiaoqing Li b
a School of Mechanical Engineering, University of Science and Technology Beijing, Beijing 100083, China
b Global R&D Center, Chongqing Changan Automobile Co., Ltd, Chongqing 401120, China
Received 11 November 2022; received in revised form 31 December 2022; accepted 31 December 2022
Available online 27 January 2023

Abstract
China is currently vigorously implementing the “energy conservation and emission reduction” and “dual carbon” strategies. As the most
resource-advantaged light metal material in China, Magnesium (Mg) alloy is progressively expanding its application in automobile, rail
transportation, aerospace, medical, and electronic products. Chongqing University, Shanghai Jiaotong University, and Australian National
University have conducted extensive research on the preparation, properties, and processes of Mg alloys. In the past 20 years, the proportion
of Mg alloy in the automotive industry has gradually expanded, whereas currently the design and development of Mg alloy parts for
automobiles has rarely been reported. Thus, the application models and typical parts cases of Mg alloy are summarized mainly from the
four systems of the whole vehicle (body system, chassis system, powertrain system, interior, and exterior system). Subsequently, two actual
original equipment manufacturers (OEM) cases are used to introduce the development logic of reliable die-cast Mg alloy, including forward
design, formability analysis, process design analysis, structural redesign, manufacturing, and testing, aiming to share the methods, processes,
and focus of attention of automotive OEMs for developing Mg alloy parts to enhance the confidence and motivation of applying Mg alloy
in automotive field. Eventually, the multiple challenges faced by Mg alloy materials are sorted out and how to face these challenges are
discussed. National policies and regulations, environmental protection and energy saving, and consumer demand will continue to promote
the application of Mg.
© 2023 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
Peer review under responsibility of Chongqing University

Keywords: Magnesium alloy; Original equipment manufacturer; Automotive application; Development process.

1. Introduction ability [11], further broadening its application in the automo-


tive field [12].
Magnesium (Mg) is the lightest engineered metal with a With the gradual expansion of Mg alloy in various fields
low density of 1.74 g/cm3 [1–3]. The specific strength and has led to the diversification of the casting process [13]. Mg
specific stiffness are better than steel and aluminum (Al) al- alloy forming process can be mainly divided into die cast-
loy [4], which are far higher than engineering plastics [5]. ing process and deformation process. The die casting mainly
Compared with Al and steel materials, Mg has a higher includes gravity casting, low-pressure casting, semi-solid cast-
strength-to-weight ratio and better casting properties [6]. Mg ing, etc. Deformation process is also known as plastic process-
has no toxic hazards compared to other metals and polymers ing forming, including extrusion, forging, rolling, etc. [14,15].
[7,8]. Mg alloy has obvious advantages in thermal conduc- In recent years, Zeng [16] had taken a comprehensive look
tivity [9], vibration damping performance [10], and damping at additive manufacturing technologies for Mg alloys to date,
focusing on the challenges and possibilities in the field of me-
chanical metallurgy. In 2013, Luo [17] reviewed the history,
∗ Corresponding author. current, and potential structural uses of Mg, with a focus on
E-mail address: liubo1@ustb.edu.cn (B. Liu). automotive applications. Chongqing University summarized

https://doi.org/10.1016/j.jma.2022.12.015
2213-9567/© 2023 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access
article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/) Peer review under responsibility of Chongqing University
16 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

development process and performance requirements of Mg al-


Nomenclatures and Abbreviations loy parts are scarce. From years of business experience and
research analysis, the main reasons for this phenomenon are
Mg Magnesium the following:
Al Aluminum
OEM Original equipment manufacturer (1) The cost of Mg is too high compared to high strength
GMC General Motors Corporation steel and Al for auto parts.
VW Volkswagen (2) Mg raw material prices fluctuate a lot, the Mg market
IMA International Magnesium Association as a whole can’t keep stable operation in a long time.
USAMP U.S. Automotive Materials Partnership (3) Mg parts supplier system is not sound, which cannot be
NVH Noise, vibration, and harshnes compared with Al and steel companies.
FAW First Automobile Work (4) OEM has a lack of confidence in the corrosion resis-
CCB Cross car beam tance of Mg alloy.
SAIC Shanghai Automotive Industry Corporation (5) The current widely used Pijiang method of Mg refining
MASF Mg alloy seat frame technology is highly polluted and does not meet the
MAFC Mg alloy front-end carrier energy-saving and environmental protection policy.
(6) …

the trends of Mg alloys and dedicated to report and dissemi- How to promote Mg usage faster needs to increase the
nate the global Mg alloy research [18]. Santamaría [19] had overall investment and establish a complete R&D capabil-
developed models for predicting the mechanical properties of ity and system, which makes more companies to dock new
automotive Mg alloy die castings, allowing OEMs and de- market opportunities. For example, Baosteel entered the Mg
signers to give the most appropriate processing variables dur- alloy industry, which will give most OEMs to improve the
ing the design and simulation phases, which expands new development confidence. Meanwhile, OEMs and parts suppli-
ideas for the application of Mg alloy in automotive com- ers should increase the technical system of Mg alloy product
ponents. The European project CRAL is a viable and eco- design-development-verification integration. Moreover, vigor-
nomical casting solution for introducing non-combustible Mg ously develop green low-carbon Mg refining process, such
alloys into the automotive industry, dramatically reducing the as electrolytic Mg process, etc. As such, the purpose of this
global warming potential of the Mg casting process route [20]. review is to summarize the history and recent advances in
Golroudbary [21] evaluated the reuse of Mg in automotive the development of different series of Mg alloys for automo-
manufacturing processes as well as in casting and molding tive components, accompanied by a critical analysis of the
processes. The research showed the considerable potential of literature reported so far. Most importantly, the whole pro-
Mg as a lightweight material for energy saving and emission cess development technology route of die casting Mg alloy
reduction in the automotive industry. Although some literature is introduced through actual production cases to enhance the
[22–25] reviewed the structural applications of Mg alloys in confidence of OEMs in developing new parts, which is wor-
the automotive, aerospace, and power tool industries, most of thy of deep consideration by companies and manufacturers
the descriptions were not specific. The performance advan- of automotive lightweighting research. Simultaneously, under
tages of Mg alloys allow researchers to carry out research in the needs of national policies and regulations, environmen-
many areas, such as structural properties, functional materials, tal energy protection, and consumers, the various challenges
and die casting processes [26–28]. In addition to engineering faced by Mg alloy materials and how to overcome these chal-
applications, Mg is used in the health and biomedical indus- lenges are discussed, along with providing an outlook for the
tries due to its superior biodegradability [29]. In addition, in future. Therefore, a review of the application of Mg alloy in
the literature [30], Alias reviewed Mg metal matrix compos- automotive components is necessary, which also provides a
ites as an attractive material with great potential in biodegrad- reference and reference for OEMs to develop Mg alloy com-
able and automotive components. Yang [26] showed that the ponents. Simultaneously, new developments in this issue are
control of microstructure and mechanical properties of Mg combined with the confidence to drive more Mg use.
alloys has been the focus of research and revealed the future
prospects of functional Mg materials, Mg alloy corrosion ef- 2. Mg alloy properties and strategic requirements
fective protection and degradation rate control, and Mg alloy
advanced processing technology. 2.1. Resource advantages
Given the comprehensive reviews of Mg alloys from
Chongqing University, Shanghai Jiao Tong University, Ohio Mg is highly abundant and widely distributed in the Earth’s
State University, and Helmholtz Zentrum Geesthacht, this pa- crust, accounting for about 2.77% of the crustal surface metal
per will focus on the application of different series of Mg ore content [31]. China has more than 70% of the world’s Mg
alloys in automotive components. However, in recent years, resources, the world’s largest raw Mg reserves, the world’s
few review reports on the application of Mg in the automotive largest raw Mg production, and the world’s largest raw Mg
field, especially the information detailing the whole process export [32]. Magnesite resources are up to about 200 species,
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 17

including magnesite, dolomite, hydromagnesite, talc, and ser- ideal biodegradable implant material with good biocompati-
pentine minerals. In addition, the Mg content of seawater bility and in vivo degradability [44]. Table 1 illustrates the
reaches 2.1 × 1015 tons, which is extremely rich in resources comparison of the mechanical properties of different grades
[33,34]. Qinghai, the largest “rich mine” of salt lake distribu- of Mg alloys [45,46].
tion in China, is rich in potassium, Mg, lithium, and other salt
resources of great potential economic value [35,36]. China 2.3. Process performances
Qinghai Salt Lake Magnesium Industry used the abundant salt
lake brine resources to obtain high purity and uniform size Mg has a hexagonal dense packed crystal structure, which
of hydromagnesite, which is the high quality raw material for is different from most structural metals [47]. Few slip systems
Mg refining. However, Mg hydroxide and Mg oxide have ir- can be activated at room temperature and only basal slip sys-
regular particle shape, low quality, not enough advanced pro- tems on densely packed planes can be easily activated, which
cess technology, low added value, and other defects, far from greatly limits their room temperature deformation capacity
the advantages of Mg resources in Qinghai. Recently, some [48,49]. The lower strength properties of Mg alloy make it
new Mg-based functional materials have been developed grad- less susceptible to slip on non-substrate surfaces. In addition,
ually, and the research of high-purity Mg has been increased, non-base slip is only initiated when the temperature rises to
which expands the application of Mg resources in high value- about 200–300 °C, accompanied by multi-base slip that can
added fields [37]. In addition, the short-term goal can promote be well plasticized.
the rapid development of the whole industrial chain of “salt The excellent workability of Mg allows it to be formed
lake brine - water brine magnesite - anhydrous Mg chloride - by any established method. According to the different form-
electrolytic Mg metal - Mg metal - Mg alloy - Mg alloy pro- ing processes, Mg alloy materials are mainly divided into two
cessing industry” by optimizing and upgrading the Mg metal categories: cast Mg alloy and deformed Mg alloy. Die casting
plant. Simultaneously, based on Mg production, extend the is the most mature and widely used forming process for Mg
industrial chain to develop high-performance products appli- alloys, including sand casting, permanent casting, investment
cable to transportation, electronics industry, aerospace, and casting, disappearing, mold casting, die casting, etc. [17]. The
energy storage. liquid forming method makes the product dimensionally sta-
ble and highly productive. However, the process has the dis-
2.2. Functional characteristics advantages of large solidification shrinkage, low high temper-
ature strength, easy oxidation, inclusions and looseness, and
Mg alloys have a high relative strength. The specific stiff- difficult heat treatment after molding. Deformation process-
ness is about the same as Al and steel, but much greater than ing is used to obtain better properties through the control of
engineering plastics. Currently, the specific strength of ultra- material organization and the application of heat treatment
light and high-strength Mg-14Li-7Al (LA147, wt.%) is about processes [50,51]. The deformation process eliminates tissue
350 Nm/kg, which is unmatched by all other engineering al- defects and refines the grain, which requires less equipment
loys. In the same rigid conditions, 1 kg of Mg alloy strength but does not allow for secondary plastic deep machining. The
is almost equal to 1.8 kg of Al or 2.1 kg of steel, and the forming performance is weak in the low temperature state,
use of Mg alloy material to make seat, steering wheel, cross but it has high plasticity in the superplastic state, so it can be
car beam (CCB), and other parts considerably enhance the used to process parts with complex shapes.
comfort and maneuverability of the car. The semi-solid molding process has also received some
Mg alloys have high damping properties [38,39], and the research and application as a new casting process [52,53].
main mechanism is dislocation damping, which is generally During metal solidification, the crystallization process is con-
15 times higher than that of Al alloys and 60 times higher trolled at the solid-liquid two-phase coexistence temperature,
than that of steel. For example, at 35 MPa stress level, the and the metal solid-liquid mixed slurry is obtained by break-
attenuation coefficient of Mg alloy AZ91D is 25% and that of ing the dendrite structure through vigorous stirring. Semisolid
Al alloy A380 is only 1%. Under the stress level of 100 MPa, molding mainly includes electromagnetic stirring method,
the attenuation coefficients of Mg alloy AZ91D, AM60, and strain induced melting activation method, semisolid isother-
AS41 are 53%, 72%, and 70%, respectively, while that of Al mal heat treatment method, and chemical grain refinement
alloy A380 is only 4% [40]. method [54]. Technical advantages include less casting de-
In addition, the dimensional instability caused by changes fects, high mechanical properties, dimensional accuracy, and
in ambient temperature and time is significantly reduced in quality of products. However, this process is more expensive
Mg alloys compared to other metals. The overall thermal and has more complex equipment and process requirements,
conductivity and heat dissipation properties of Mg alloy are which is not suitable for a large number of applications in
better than Al alloy. Meanwhile, Mg alloy has been widely automotive parts.
used in electronic devices by virtue of the excellent elec-
tromagnetic shielding properties [41]. It is encouraging to 2.4. Energy demand and strategic advantages
note that Mg alloys have good energy properties and there-
fore show great potential as hydrogen storage materials and Since 2015, CO2 emission requirements have been reduced
battery anode materials [42,43]. Moreover, Mg alloy is an from 162 g/km to 118 g/km, and the average fuel consump-
18 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Table 1
Comparison of mechanical properties of Mg alloys.

Performance Unit Mg AZ91 AM50 AS41 AE42 AISI8Cu3


Density g/cm³ 1.74 1.81 1.77 1.77 1.79 2.75
Specific heat kJ/kgK 1.025 1.02 1.02 1.02 1.02 0.88
Thermal conductivity W/mK 154 51 65 68 84 120
Melting temperature °C 650 598 620 638 625 593
S olid-liquid conversion temperature °C 650 420–435 420–435 420–435 590 521
Conversion heat kJ/kg 368 370 370 370 370 500
Tensile strength MPa 165–205 240–250 210–230 215–240 230 331
Yield limit MPa 69–105 160 125 140 145 165
Elongation rate % 8–11.5 3–7 10–15 6–15 10–11 3
Elastic modulus GPa 45 45 45 45 45 71
Brinell hardness – 36 70 60 60 60 80

tion has been reduced from 6.9 L/100 km to 5.0 L/100 km. The automotive manufacturing industry has the highest
Based on the national dual carbon policy and energy sav- share in the consumption of Mg alloy, with about 70% [59].
ing and emission reduction strategy, lightweight materials and Mg-alloy automotive parts are diverse, with structural parts
lightweight technology for new energy vehicles are of great (seat frame and front-end frame), high-temperature resistant
strategic significance [55]. Preliminary estimates show that parts (cylinder block), and moving parts (wheel) all having the
the market capacity will reach 660,000 tons by 2022. It is common feature of withstanding low mechanical and chemi-
expected that the application of Mg alloy in the above fields cal loads. Fig. 1 summarizes the historical development of au-
will exceed 3 million tons in the next 10 years. tomotive Mg alloy components and gives practical examples
At present, the common use of the Pijiang method of Mg from OEMs. The development of Mg alloy is closely related
refining process, mainly with dolomite or magnesite as raw to policy, environment, demand, and other factors. The review
materials. Whereas the Pijiang method of Mg refining equip- divides the development of Mg alloy into four stages accord-
ment is relatively backward and workers labor intensity. Al- ing to the clues of time and OEM Mg alloy product cases.
though the new technology of vertical tank Mg refining has The article focuses on summarizing some OEM success cases
been successfully developed recently, and the production effi- in the last 20 years, mainly concentrated on stage 4.
ciency has been greatly improved, but it is still accompanied Stage 1: In 1808, the English chemist Humphry Davy
by the problems of high carbon emission and serious pollu- isolated Mg metal [60–62], but it was not until 1828 that
tion. China Qinghai Salt Lake electrolytic Mg is generally a Antoine-Alexander Bussy isolated pure Mg from anhydrous
green product with very low carbon emission level [56,57]. MgCl2 [63]. By the 1880s, Germany founded the world’s first
Enterprises and manufacturers make full use of local wind re- electrolytic Mg plant to start industrial production of Mg al-
sources for green power generation, which is in line with the loys. As early as the 1930s, Germany was the first to apply
way forward of the dual carbon strategy, a recyclable path to Mg alloy to the automobile manufacturing industry. A few
green Mg alloy materials. Energy and strategic needs are driv- years later, the Soviet government put Mg alloy into the man-
ing new technologies for more efficient and cost-effective Mg ufacturing production of aircraft. England first applied Mg al-
processing, contributing also to the implementation of national loy to the gearbox case of motorcycle. The production of Mg
strategies such as new materials and automotive lightweight- alloy reached 1200 tons/year during this period.
ing. Thus, in the face of the depletion of many traditional Stage 2: During World War II, the production of Mg al-
metal resources, accelerating the development of Mg materi- loy increased dramatically due to the manufacture of military
als for China to implement the “double carbon strategy” and equipment [64]. But after 1946, the development of Mg alloy
maintain the sustainable development of society has important began to level off.
strategic significance. Stage 3: Until the 1990s, influenced by automobile exhaust
emissions, energy consumption and environmental protection
3. Application of Mg alloy in automotive parts policies, countries around the world began to pay attention to
the development and research of Mg alloy.
The major auto parts manufacturers are investing in the Stage 4: By the 21st century 10 s, with excellent material
production and development of Mg alloy automotive die cast- properties, the application of Mg and Al alloy in body and
ing. According to the judgment of “Technology Roadmap for enclosed parts grew rapidly, especially for pure electric and
Energy Saving and New Energy Vehicles 2.0”, the overall hybrid vehicles. Especially in the last 20 years, major OEMs
vehicle lightweighting coefficient will progressively decrease have been enhancing the use of Mg alloys in automobiles,
[58]. At present, the global single-vehicle Mg alloy usage and resulting in many Mg alloy parts on the market.
2030 single-vehicle Mg alloy usage target value is still a huge Table 2 provides a comprehensive overview of the mapping
gap, and automotive Mg alloy demand expansion potential is relationships of different families of Mg alloys for automotive
strong. components [45]. Currently, AZ91D, AM60B, and AM50 are
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 19

Fig. 1. Mg alloy in the development of automotive parts of the historical process.

the most common in automotive Mg alloy applications. As some development work on cast Mg side door inner panels,
such, this section reviews and summarizes the applications as shown in Fig. 2(a) [100,101]. Fiat Chrysler Automobiles
of Mg alloys in body systems, chassis systems, powertrain recently announced the use of Mg die castings for the new
systems, and interior and exterior trim systems [21,29,65,66]. 2018 Jeep Wrangler rear back doors, as depicted in Fig. 2(b)
[102].
3.1. Body system The limited space available in door applications and the
limitations of open sections in die castings designed for com-
Mg alloy materials are ideal for thin-walled structural parts ponent ejection require creative design to meet stiffness and
and large internal structural parts due to their excellent casting crash requirements. In 2010, the Lincoln MKT inner door
flow properties. panel was the first ever die-cast Mg opening and closing part,
with the core technology being the use of proper reinforce-
3.1.1. Car door ment and smooth tooling by engineers in a continuous design
Mg alloy as a door inner panel material has the advantage optimization process [103,104]. For 2017, the Chrysler Paci-
of lightweight, generally choosing the tensile strength of more fica used Mg die castings in the tailgate, increasing some
than 220 MPa, elongation greater than 10% [89]. Due to the of the ribs and thickness to improve the performance of the
easy corrosion of Mg alloy, the connection is generally not tailgate. Meanwhile, the integrated design replaces nine parts
welded but bolted or glued. and reduces the total weight by 50%, as shown in Fig. 2(c)
In 2004, the Aston Martin DB9 was developed with Mg [105,106].
side door parts that weighed an estimated 43% less [97]. The The combination of Mg alloy and Al alloy outer panels is
one-piece die-cast inner panel of the Mercedes S-Class coupe a good alternative for the multi-material structure of the body
is only 4.56 kg [98]. In 2009, Mercedes continued to use [106]. The rear doors of the 2009 Mercedes-Benz E-Class
this technology to develop the E-Class T-Model car door. A Wagon were constructed using a mixture of Al and Mg. The
weight reduction evaluation by Lotus Engineering on the 2009 wall thicknesses of the large internal components are designed
Toyota Venza crossover vehicle found that more than 26 kg to vary from 2 mm to 5 mm and are reinforced with ribs in
of Mg castings were used inside the side doors and lift doors, several areas to ensure both weight advantages and increased
resulting in a weight reduction of 41% [99]. In 2012, a De- structural performance, as illustrated in Fig. 2(d).
partment of Energy sponsored project led by General Motors Daimler-Chrysler and Volkswagen (VW) have been exper-
Corporation (GMC) developed an integrated die-cast Mg door imenting with the design of Mg alloy bezel-less doors to ac-
interior structure, reducing the mass by 50% while incorporat- commodate impassable vehicle models, as given in Fig. 2(e)
ing the door speaker into the casting design [74]. In addition [107]. Ford designed an open die-cast Mg inner panel with
to Mercedes, the Aston Martin Vanquish S also underwent beltline reinforcements integrated into the hardware module,
20 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Table 2
Application areas of Mg alloy series in car body.

Mg alloy series Performance advantages Specific Applications Die casting process


classification
AZ (Mg-Al-Zn-Mn) Application to high strength, AZ91D Central control bracket [67], transmission • Gravity or low pressure
low ductility components in housing [68], oil pan [69], oil filter housing • Sand or metal mold
thermal environments below [70], cylinder header cover [71], steering • High pressure die casting
125 °C column bracket [72,73], inner panel [74], • Squeeze casting
clutch housing [75], swivel plate [76], starter • Thixocasting
housing [77], headlight bracket [68]
AZ61 Luggage rack skeleton [78], column beam [78]
AZ31 Inner panel [79], compressor housing [80]
AM (Mg-Al-Mn) Used in thermal environments AM50 Seat frame [81], wheel/hub [82], inside plate • Gravity or low pressure
up to 125 °C for lower strength, [83], steering wheel [84], • Sand or metal mold
but more ductile components AM60B Front-end frame [85], cross car beam [86], • High pressure die casting
seat frame [81], steering wheel [87], • Squeeze casting
wheel/hub [88], radiator bracket [85], inside • Thixocasting
door panel [89]
AS (Mg-Al-Si-Mn) Replaces AZ alloys at 125 °C AS41B Transmission housing [90], crankcase housing • High pressure die casting
in thermal environments due to [91]
increased creep strength
AE (Mg-Al-E-Mn) Higher crawling strength in AE44 Transmission case [92], oil pan [93], engine • High pressure die casting
150 °C drivetrain operating bracket [94]
environment, but expensive due
to E content
AXE and AJ Applications for high creep AJ52 Engine components [95] • High pressure die casting
(Mg-Al-Sr/Ca-Mn) strength powertrain components, AJ62 Engine block [96]
but with potential low cost AXJ530 Engine components [92]
compared to AE

Fig. 2. Development and application of Mg alloys in car doors: (a) Aston Martin Vanquish S with cast Mg side door inner; (b) All-new 2018 Jeep Wrangler
produced with a die-cast Mg rear swing gate; (c) Chrysler Pacifica showing the liftgate assembly highlighted by a Mg die-cast inner; (d) The rear end of the
Mercedes-Benz E-Class T-Model featuring the hybrid Mg-Al hatch back; (e) Inner door frame of the Daimler-Chrysler SL Roadster; (f) Ford’s concept die-cast
Mg door inner with an open architecture; (g) Integrated Mg die-cast door inner designed as part of a DOE sponsored project led by GMC; (h) Ultra-thin and
ultra-light Mg alloy door inner.

as presented in Fig. 2(f) [74]. Whereas examples exist of de- nesium Association (IMA) Excellence Award, as shown in
signs that integrate waist lines, hinges, and latches into the Fig. 2(h). Since then, many universities and automobile fac-
casting to improve security, an example of which is given in tories have invested in the research of Mg alloy car doors.
Fig. 2(g) [74]. In 2017, the ultra-thin Mg alloy inner door
panel developed by EONTEC and GMC is becoming a pio- 3.1.2. Front-end carrier and front upper component
neer in the development of lightweighting in the automotive Replacing hydraulically formed steel, tubular steel, ex-
industry. The design received the 2017 International Mag- truded Al, and plastic composites with die-cast Mg alloys for
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 21

front-end carrier components helps reduce additional variable and Al, respectively. In 2012, the Cadillac SLS introduced a
costs. In 2003, Ford developed a front-end support assembly Mg alloy trunk inner panel that can be assembled with the
for the F-150 light truck that reduced weight by about 4.6 kg. Al outer panel [114].
So far, Ford has cleverly used the flexibility of Mg alloy die
casting to keep its products competitive in the market [107]. 3.2. Chassis system
In 2007, the Chinese Ministry of Science and Technology,
the United States and Canada launched the project “Research The application of Mg alloys in chassis is severely chal-
and Development of Front-End Structures for Magnesium Ve- lenging for automotive lightweighting and safety performance,
hicles”, which is a good example of promoting front-end car- with strength, plasticity, and corrosion resistance all being
rier lightweighting [108,109]. The Tesla Model S was devel- considerations [115,116].
oped in 2012 with a one-piece die-cast Mg front-end carrier
weighing only 6.49 kg, as illustrated in Fig. 3(a). The front- 3.2.1. Wheel
end carrier of the Porsche Panamera G2 is made of AM50A, Compared with Al materials, Mg alloy wheels have higher
achieving a weight reduction of 3.5 kg (Fig. 3(b)). The front- strength and toughness. Aesthetics, shock absorption perfor-
end carrier material of Range Rover is AM60B, achieving mance, and heat dissipation are also major advantages of Mg
a weight reduction of 7.1 kg (Fig. 3(c)). In 2009, the front alloy wheels [117]. In the kart series we know, the average
upper component of the Jaguar XJ was made of Mg alloy weight of Mg alloy wheels is about 560 g, which is an im-
AM60B and weighed 4.6 kg, as shown in Fig. 3(d). This provement of about 300 g weight compared with the same
represents a 30% weight reduction compared to the previ- type of products. The wheel is an under spring rotating part
ous generation of hydraulically expanded Al-tube solutions. of the car, and the controllable performance and comfort per-
In 2015, the Mercedes-Benz AMG GT front upper compo- formance of the whole car are closely related to the Mg alloy
nent was made of Mg alloy AM60B, as depicted in Fig. 3(e). wheel [118].
The overall weight was 3.5 kg and the connection is bolted. However, currently only applicable to high-performance
The 2017 fourth-generation Audi A8 cabin mounts are made sports or racing cars due to the higher variable cost of Mg
of Mg alloy castings, which have reduced weight by 28%, as alloys and the problem of poor applicability. In 1967, Fer-
shown in Fig. 3(f). rari upgraded the 330P3 model to the 330P4 model with
For fuel cars, the engine is generally located at the front of Mg wheels and wider tires. Ferrari immediately used them
the vehicle resulting in uneven axle load distribution between for competition until 1992 when the first set of BBS Mg
the front and rear of the vehicle. Table 3 lists some application forged wheels were created. The German company Posche
examples of front-end carriers and front upper components has been using AM60A Mg alloy die-cast wheels since 1970.
to illustrate the advantages of Mg alloy in front-end weight Since 1998, GMC has been using Mg wheels on light duty
reduction for improving the overall vehicle handling stability. corvettes. Fig. 5(a) shows the low-pressure cast Mg wheels
of the Chevrolet Corvette. In particular, the United States has
3.1.3. Panel roof developed a Mg alloy wheel can continue to drive at a speed
In 1997, the Chevrolet C-5 Corvette was introduced with of no more than 48 km/h even after the tire is punctured. The
a one-piece die-cast Mg roof, which has been used by GMC Changan EADO EV not only offers a power change system,
and BMW 3 Series convertible to this day [110]. Mg is also but also features multi-spoke ZK61 wheels. The forging pro-
used on the hardtop roof and roof frame of the Cadillac XLR cess allows for less clearance between the wheel arches and
convertible. The Mercedes-Benz SL/SLK series cars have also hubs, achieving a reduction in weight [119].
been using Mg folding roofs, as shown in Fig. 4(a). Chrysler In 2014, Wang disclosed in patent [120] a preparation
introduced a lightweight Mg-intensive body structure in its method for producing wheels by forward and reverse extru-
high-fuel vehicle program, which can reduce the weight by sion using other metals such as Mg alloys and Al alloys, pro-
more than 40% using Mg alloy replacement panel roof ma- viding a prerequisite and guarantee for industrial production.
terial compared to conventional steel structures, as shown in Subsequently, wang authorized Linzhou Dingxin Magnesium
Fig. 4(b) [111]. Technology Co., Ltd. and Dewei Co., Ltd. to develop a su-
perplastic forming process of forging forward and reverse ex-
3.1.4. Hood and trunk lid trusion in one process, which requires only one press and im-
As early as 1951, GMC built a prototype hood for the proves material utilization and reduces costs through one for-
Buick LeSabre, followed by various body panels for the ward and reverse extrusion forming process [121]. The techni-
Chevrolet Corvette SS Race Car in 1957 and a hood in 1961. cal process is shown in Fig. 5(j), including blank cutting, one-
Mercedes-Benz also tried to make the trunk lid of the E-Series time forming by forward and reverse extrusion after homoge-
wagon with AM50, weighing 15,310 g, as shown in Fig. 4(c). nization treatment, machining, and surface coating. Extruded
Recently, VW made a Mg trunk lid and hood prototype for wheels made of AZ80 Mg alloy have been sold in small quan-
the Lupo, as shown in Fig. 4(d) [112,113]. Reinforcing parts tities, and the production efficiency has been dramatically im-
such as hinges and locks are joined together by punching and proved, with a broad development prospect and huge market
riveting, and the inner and outer plates are bonded by heat- space. In 2018, China Nonferrous Metals Industry Associa-
ing. Weight optimized by 50% and 15–20% compared to steel tion Magnesium Branch and experts discussed the patented
22 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 3. Development and application of Mg alloys in front-end carrier and front upper component: (a) Tesla Model S one-piece die-cast Mg front-end carrier;
(b) Porsche Panamera G2 front-end carrier; (c) Range Rover Mg alloy front-end carrier; (d) Jaguar XJ Mg alloy front upper component; (e) Mercedes-benz
AMG GT Mg alloy front upper component; (f) Audi A8 Mg cabin bracket.

technology of forging Mg alloy automotive wheel hub for- Currently, the processing processes of Mg alloy wheels are
ward and reverse extrusion in one go. The meeting agreed mainly casting and forging, forging process mainly includes
that the technology is innovative and is an important techno- isothermal extrusion, forging spin, and other processes [122].
logical breakthrough in achieving automotive lightweighting, Forged Mg alloy wheels have the characteristics of dense
accompanied by the basis for industrialization and large-scale organization and excellent mechanical properties, and have
production. been used in a large number of special vehicles and high-end
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 23

Table 3
Examples of Mg front-end carriers and front upper components of some models.

racing cars [123]. The isothermal superplastic die forging forming and successfully produced one-piece Mg alloy
can be used to form AZ80 automotive wheels in a single wheels from AZ80+ alloy extrusion. As shown in Fig. 5(b),
operation, which can achieve about 30 times higher vibration the first mass-produced forged-spin process Mg wheels will
damping performance than Al wheels and more than 16% be available as an option for the Cadillac V-Series, with
overall fuel savings, as shown in Fig. 5(d), (e), and (f) [124]. the 2022 CT4-V BLACKWING and CT5-V BLACKWING
In order to improve the strength of the spoke part, Wang also available in North America in the summer. In 2022,
[125,126] proposed a new method of hollow billet extrusion AMG Project One goes on sale with optional 9-spoke Mg
24 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 4. Development and application of Mg alloy on roof, hood, and trunk lid: (a) Mg alloy folding roof for Mercedes-Benz SL/SLK series cars; (b) Mg alloy
inner plate from Daimler-Chrysler; (c) Mercedes-Benz E-Class touring cassenger car trunk lid; (d) VW Lupo Mg trunk lid and hood.

forged wheels featuring a patented bionic design, as shown in The die casting molding process is the most common
Fig. 5(c). In April 2022, Bugatti unveiled the Chiron Super method for Mg alloy steering wheels today [129]. Chery
Sport 300+, with only 30 units produced worldwide. The AM50A Mg alloy steering wheel skeleton adopts cold
carbon fiber body and Mg wheels make this supercar as light chamber die casting to achieve more than 25% weight re-
as possible, allowing a further weight reduction of 16 kg duction. The body weight of the Mg alloy steering wheel for
under the springs, as illustrated in Fig. 5(g). In August 2022, passenger cars of Dongfeng Nissan and Shen Long is only
Porsche officially unveiled the new generation of the Porsche 876.5 g. Shenyang University of Technology put together
911 GT3 RS with Mg forged wheels that can be reduced the traditional welded structure and made a high toughness
by 8 kg, as seen in Fig. 5(h). In September 2022, Bandit9 Mg alloy steering wheel skeleton by one-piece die casting.
Motors of Vietnam launched a single-seater racing car under Chongqing Magnesium has provided more than 7000 pieces
the name of “Monaco” with a length, width and height of of A2401-002 Mg alloy steering wheel to Shanghai GMC,
3815/1955/980 mm, a wheelbase of 2850 mm, and a weight as shown in Fig. 6(a). Due to the elimination of the welding
of 795 kg, while the wheels are made of lightweight Mg process, the cost advantage of Mg alloy steering wheel
alloy and the tires are 315/35R20, as depicted in Fig. 5(i). has been favored by a large number of OEMs. In 2008,
Mao [130] analyzed the fatigue fracture of AM50HP-F by
3.2.2. Steering wheel experiments and scanning electron microscopy and discussed
The application of Mg alloy in steering wheels is a part its application prospects, as shown in Fig. 6(b). Flow-3D
with high recognition and acceptance in the world due to software is used to optimize die casting process parameters
its energy absorption and vibration damping properties [87]. such as filling speed, crystallizer temperature, and pouring
Mg alloy steering wheel has the performance advantages that temperature, along with this technology also provides some
traditional steering wheels such as mild steel and engineering development support to the actual manufacturing of host
plastics cannot match [127,128]. plants.
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 25

Fig. 5. The development and application of Mg alloy in the wheel: (a) Mg alloy wheel for Chevrolet corvette; (b) Cadillac CT4-V forged spun Mg wheel;
(c) AMG Project One 9-spoke Mg forged wheels with bionic design; (d) Hollow billet extruded Mg alloy wheel: (14 × 6) J; (e) Hollow billet extruded Mg
alloy wheel: (13 × 10) J; (f) Hollow billet extruded Mg alloy wheel: (13 × 8) J; (g) Bugatti Chiron Super Sport 300+ Mg wheel; (h) Porsche 911 GT3
RS Mg forged wheel; (i) Bandit9 electric racing Mg wheel; (j) Mg alloy car wheel forward and reverse extrusion forming technology process, from Dingxin
Magnesium Technology Co.
26 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 6. The development and application of Mg alloy in the steering wheel: (a) Mg alloy steering wheel frame produced by Chongqing Mg Industry; (b)
Surface defect probability simulation result; (c) Mg alloy steering wheel crash test.

Fig. 7. The development and application of Mg alloy in subframe: (a) Corvette Z06 Mg subframe; (b) Audi R8 Mg subframe; (c) 2016 Ford Focus Mg
subframe.

In addition, the steering wheel is directly related to the the assembly makes it easy to install and reduces assembly
safety of the driver’s head and chest in a serious colli- costs.
sion [131]. The steering wheel needs a certain strength In 1985, one of the basic ideas of the Volvo LCP 2000
and hardness in addition to a certain degree of flexibility. project was to take into account energy consumption over the
Altenhof [132] evaluated the crashworthiness of Mg alloy entire life of the vehicle. The vehicle used about 50 kg of
steering wheel armatures based on peak impact loads, peak Mg alloy, including the transmission housing, clutch housing,
crosshead displacements, performance response, percent elas- wheels, rear suspension, subframe, and cylinder block [135].
tic response, and energy absorption coefficients, as shown in In 2005, Corvette decided to use Mg front beams instead of
Fig. 6(c). Experimental results show that the elastic energy Al brackets to meet its goals of weight reduction and fuel sav-
recovery rate of Mg armatures is generally higher than that ings, as illustrated in Fig. 7(a). The core of this study is the
of Al armatures. This research is expected to inform engineers development of scientific and technical expertise to provide a
and designers in developing high energy absorbing armatures comprehensive overview of large die-cast Mg alloy structures
with small elastic energy response. [136,137]. The Audi R8 rear subframe material is AZ91, and
the weight reduction was achieved using a high-pressure die
casting process, as shown in Fig. 7(b). 2016 Ford Focus’s cast
3.2.3. Subframe Mg AE44 subframe achieved a 32% weight reduction over the
Mg alloy subframe is the most effective way to achieve the equivalent steel frame, and all joints were subjected to bolt
light weight of the car chassis structure, which also has the load retention tests, as shown in Fig. 7(c) [138]. Furthermore,
advantage of being able to isolate road vibration and improve vehicle corrosion tests and laboratory component corrosion
stability [133,134]. In addition, the small number of parts in tests verified the corrosion resistance requirements for mate-
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 27

Fig. 8. Mg alloy in powertrain applications: (a) Mg applications in the 1930s: crankcase and transmission housing; (b) Mg powertrain components from the
USAMP Mg powertrain cast components project; (c) The Mercedes 7-speed automatic transmission case; (d) Audi A8 (12-cylinder) intake manifold cover;
(e) BMW 6-cylinder R6 engine; (f) Engine cylinder head cover typical cases.

rial replacement [138]. Currently, GMC’s welded construction ertrains, such as the intake module of the W12 engine, the
midsize cars and BMW’s 5 and 7 series hydroformed tubular cylinder head of the V8 engine, and the five-speed manual
subframes are hollow construction. Mg alloy tube will bring transmission housing. About 600 transmission cases made of
lighter mass experience, so the hollow casting process has Mg alloy material are used every day in VW’s B-frame cars.
become the main mainstream technology. By the 1990s, simulation tools made it possible to cast a wider
range of products as well, including CCBs, seat frames, steer-
3.3. Powertrain system ing wheels, intake manifolds, and more [139].
In 2001, the U.S. Automotive Materials Partnership (US-
Due to the excellent casting properties of Mg alloys, engine AMP) and the U.S. Department of Energy initiated the Mg
blocks, cylinder heads, gearboxes, and oil pans are starting to Intensive V6 Engine Project, which successfully developed
change from the original Al alloy material [28]. Currently, a database of Mg alloy designs and common specifications,
both VW and Audi are equipped with Mg engines and trans- with 29% of the components replaced by Mg, as shown in
missions with materials operating below 120 °C, which is the Fig. 8(b) [141,142]. Other important applications include the
most critical opportunity for Mg lightweighting. new 7G-Tronic seven-speed automatic transmission housing
for Mercedes-Benz (see Fig. 8(c)) [66,143]. Changan’s trans-
3.3.1. Engine and transmission housing mission and cylinder heads and other parts have passed the
In the 1930s, Louris Chevrolet used Mg pistons for the bench test and road test, and have entered the market in large
first time in a racing car. Fig. 8(a) represents Chevrolet’s Mg quantities in 2004. Fig. 8(d) shows an Audi A8 intake mani-
alloy crankcase. Germany VW Beetle car powertrain used fold cover manufactured using the sand casting process, with
about 20 kg of Mg castings for the production of crankcase the first batch secured with Al screws and a final weight of
and transmission housing, car Mg consumption again acceler- 8.43 kg.
ated and reached a peak [139]. VW Germany’s Passat, Audi Due to the easy reaction between coolant and Mg material,
A4, and A6, and Ford’s truck gearbox housing use AZ91D the application of Mg alloy on power system is mainly fo-
Mg alloy [140]. Audi vehicles also use more Mg in their pow- cused on low temperature system. BMW’s 8-cylinder power
28 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 9. Development and application of Mg alloy in oil pan: (a) Valve-cover cast in AJ52x at Spartan Light Metal Products with very good results; (b) Oil
pan cast in AJ52x at Spartan Light Metal Products with very good results; (c) Honda Insight Mg alloy oil pan; (d) CA20 Mg alloy oil pan; (e) USAMP Mg
engine oil pan and engine cover; (f) High temperature creep resistant die-cast Mg alloy oil pan for FAW Beston car.

and the fully variable intake manifold of the VW Phaeton • The creep properties of AJ52x and AJ62x alloys are better
W12 engine feature a Mg housing. Corrosion problems limit than all other Mg alloys (50–70 MPa) at high temperatures
the application of Mg engines. Nevertheless, BMW has built a (150–175 °C) and under high stress.
composite Mg engine (R6), which is the world’s lightest 3.0- • AJ62x alloy has the highest tensile properties (room tem-
l inline six-cylinder gasoline engine [144,145]. BMW’s goal perature and high temperature).
was to achieve an engine that could increase power output and • AJ alloy has excellent corrosion resistance, with salt spray
higher torque, while also reducing fuel consumption and CO2 corrosion resistance up to or better than AZ91D.
emissions. The R6 is also an environmentally friendly engine • J62x alloy has excellent resistance to hot tearing and crack-
of recent years, using fewer components and combining in- ing and has a lower tendency to hot crack than Al alloy
novative design with metallurgy, as illustrated in Fig. 8(e). A380.
The replacement of the cylinder head cover from Al to Mg • AJ62x alloy has good die casting properties, better than
alloy material can achieve a weight reduction of about 33%, AJ52x alloy.
which can significantly improve the engine Noise, vibration, • AJ62x alloy is well suited for automotive powertrain com-
and harshness (NVH) performance. Fig. 8(f) shows several ponents.
examples of Mg alloys for cylinder head covers.
The oil pan is made of heat-resistant Mg alloy, which can
reduce weight up to 33% compared to Al alloy. The Mg alloy
3.3.2. Oil pan oil pan of both Honda Insight and CA20 achieves a large per-
The noise of the car at low and medium speeds mainly centage weight reduction, as shown in Fig. 9(c) and (d). For
comes from the radiation noise of the engine, while the oil the past 20 years, the USAMP has brought together represen-
pan, cylinder head cover and timing gear cover and other thin- tatives from Daimler Chrysler, GMC, Ford Motor Company,
walled parts of the radiation noise in the whole noise occupies and more than 40 other companies from the Mg casting in-
a considerable proportion [146,147]. In addition, the oil pan dustry to create and test a low-cost Mg alloy engine [149].
has clear requirements for various mechanical properties, es- Parts such as the oil pan were redesigned using high-pressure
pecially tensile strength. At present, most of the oil sump is die casting and sand casting processes, as shown in Fig. 9(e).
made of Al alloy. The trend towards vibration and noise re- In addition, the First Automobile Work shop (FAW) Besturn
duction has led to the need to find a lighter material, and oil pan (Fig. 9(f)) is another application of a high tempera-
Mg alloys are favored in this regard due to their advantages ture creep resistant die-cast Mg alloy [69]. The oil pan was
[148]. designed for FAW’s new generation of passenger car engines
Several die casting tests have been conducted in North with an operating temperature close to 150°C. Road tests have
America and Europe with AJ alloy. The valve cover in shown that the oil pan meets the temperature requirements.
Fig. 9(a) and the oil pan in Fig. 9(b) were die cast on Spartan
Light Metal Products using a cold chamber machine. Excel- 3.4. Internal system
lent pouring properties were observed in these alloys, with
no tendency to jam or crack and good flow properties. In Mg alloy automotive interior parts should have good
addition, Pekguleryuz [148] summarized the performance ad- strength, plasticity, energy absorption, and casting properties
vantages of the AJ series alloys as follows: as it relates to the safety performance of the vehicle. Some
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 29

Fig. 10. Application of Mg alloy on seat frame: (a) Changan E01 Mg alloy seat frame; (b) Future K50 Mg alloy seat frame; (c) Jaguar S Type’s Mg alloy
seat frame.

typical interior systems include seat frames, CCBs, center leather + Alcantara splicing material, as shown in Fig. 10(b).
console brackets, steering housings, etc. [150,151]. For 2017, the Jaguar S model received a major upgrade with
a die-cast Mg seat skeleton that weighs 3.08, 2.5 kg less than
3.4.1. Seat frame the previous model, as shown in Fig. 10(c).
The front seats are generally more functional and their The rear seats have relatively few functions and simple
structure is more complex, while the rear seats are less func- structures, and the use of Mg alloy can effectively reduce
tional and their structure is simpler [152]. Currently, the appli- weight. Most of the rear seats are made of die-cast Mg alloy,
cation of Mg alloy in the seat is mainly the backrest skeleton which can be integrally formed. 2005, Chrysler first applied
and seat basin skeleton [153–155]. the folding system on Stow’n Go seats, the second row of
In the 1990s, integrated three-point seat belts were first seats and rear seat frame used some Al, and the third row of
widely used in production vehicles. The seat of the Mercedes- folding seats are Mg castings. In terms of flexibility, the whole
Benz sports car used a new Mg die casting process to in- process can be completed in about one minute. Of course, the
tegrate the complex components into two parts: the backrest disadvantages of this Mg seat are very obvious. In addition
and the seat basin, with a total weight of 8.5 kg [156]. AM50 to the high cost, the seat size and thickness are very limited,
(for the backrest side supports and the entire seat frame) and which is not very popular for the Chinese market that seeks
AM20 (for the backrest shell) are two materials perfectly comfort.
adapted to the general requirements of Mg seats, which makes
it possible to produce cars with high rigidity and excellent
ductility of the frame parts. 3.4.2. Cross car beam
The design and manufacture of Mg seats have also un- The high integration of Mg CCB has a significant weight
dergone significant improvements in recent years. The Alfa reduction effect. The good vibration damping and dimensional
Romeo 156 model has a Mg alloy front seat skeleton with a stability can effectively eliminate the welding deformation
backrest weight of 1.0 kg and a seat basin weight of 1.2 kg, problem of the original steel structure [157,158]. Table 4 gives
a weight reduction of 2.8 kg compared to the original struc- some typical CCB cases to illustrate the advantages of Mg al-
tural steel skeleton. The Daimler Chrysler 500 SEL sports car loys for automotive applications.
and Hyundai Genesis coupe models both featured die-cast Mg In 1961, GMC introduced the first die-cast Mg alloy dash-
seat bones. In 2009, Changan Automobile forward developed board CCB. Although the thickness is generally 4–5 mm, but
a Mg alloy seat skeleton for the Oushang E01 model, achiev- still can reduce the weight of about 4 kg. Fig. 11(a) shows
ing a weight reduction of 25–30% and a yield of over 90%, the die-cast Mg alloy CCB of the Buick LaCrosse currently
as shown in Fig. 10(a). The seat of the K50 model is made of produced by GMC, about 6.9 kg. GMC’s use of die-cast Mg
Al–Mg alloy skeleton, with a backrest weight of 1.18 kg and CCB peaked around 2005 due to its high level of integration
a seat basin weight of 1.4 kg. The surface is covered with and improved dimensional stability [159].
30 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Currently, foreign Ferrari, Dodge Viper, Mercedes-Benz, tions, such as center console brackets. Currently, the Mg cen-
Volvo, Jaguar, Ford, Chrysler and other car companies com- ter console of the Porsche Cayman and Porsche PO series is
bined at least 20 models are using Mg alloy die cast- smaller in size, as shown in Fig. 12(a). In addition, the Volvo
ing CCB [160–163]. Domestically, Chery Ruiqi G6 and S80 and XC60 both have a center stand made of AM50A
Shanghai Automotive Industry Corporation (SAIC) Rongwei with a weight of 1 kg and 2.2 kg, respectively, as shown
550 and other senior cars have been used in bulk Mg alloy in Fig. 12(b). Dongguan EONTEC. Co., Ltd. has introduced
CCB, the material is AM60B, a single piece of lightweight AZ91D material center control bracket, which is die-cast by
accounted for more than 55%. In addition, Geely GS1.8, 2000–2500T die casting machine. The part has light weight,
SAIC W261, and other models also use Mg alloy CCB to good damping effect, and the wall thickness is only 2 mm.
improve the performance of the middle and senior cars and
the image of the independent car brand. In 2022, Shanghai 3.4.4. Other aspects
Jiaotong University and Voyah Automotive Technology Co., In the last two years, with the rapid development of intel-
Ltd. optimized the design of Mg alloy for the original steel ligence, Mg display back panel has appeared in Mg market
CCB solution and used AM50 material and high tenacity Mg- with a new posture. In addition, many emerging companies
alloy large integrated die casting technology to develop the are also gradually exploring the Mg market, such as NIO
Mg-alloy CCB, which was successfully applied to the Voyah Auto, Voyah Auto, etc. Many other auto parts also use Mg
FREE model, as shown in Fig. 11(b). The weight of Mg al- alloy, such as steering housing, center console bracket, hand-
loy CCB assembly is reduced from 12.1 kg to 6.7 kg, with brake, Mg alloy back panel, radiator bracket, car armrest seat,
a weight reduction ratio of 45%, which is an obvious ef- etc. Some typical cases are listed in Fig. 13.
fect of lightweighting. In addition, the strength, modal, crash
resistance, manufacturability, and other performance and pro- 4. Practical application cases from OEM
cess requirements meet the design requirements. The project
also received a special medal of honor at the 2020 China To enhance the confidence of enterprises in developing Mg
Bodywork Congress, a Top 10 Bodywork Award and a Best alloy parts and support the vision of mass production, the
Workmanship Award at the 2021 China Bodywork Congress. whole process case of developing Mg alloy parts for an OEM
Figs. 11(c), (d), (e), (f), and (g) represent the practical appli- of an independent brand car in recent years is shown in detail
cation cases of several Mg alloy CCBs. [164–166].

4.1. Mg seat development process


3.4.3. Central control bracket
Compared to Mg castings, wrought Mg offers further op- The development process of the Mg Alloy Seat Frame
portunities for substantial savings in many interior applica- (MASF) mainly includes performance analysis, material

Table 4
Some cases of typical Mg CCB in automotive applications.

(continued on next page)


B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 31

Table 4 (continued)

design, CAE analysis, and manufacturability analysis of steel and consists of a backrest and seat frame. The back-
[152,153,167], and the specific development process and rest is divided into upper and lower horizontal panels, side
analysis results are demonstrated in Fig. 14. panels, suspension wires, and adjustment components. The
seat frame is divided into side plate, seat basin, heightening
4.1.1. Program design pump, lifting four-link, and slide rail pieces. The overall
Taking a model of Changan Automobile as a prototype, material of MASF is Mg alloy and the material of functional
the traditional pressed and welded sheet metal seat is made parts is steel. MASF consists of backrest, seat frame, sus-
32 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 11. Several applications of Mg alloy CCB: (a) Buick Grand Touring die-cast Mg alloy CCB; (b) Mg alloy CCB on the Voyah FREE model; (c) Ferrari
Califoria die-cast Mg alloy CCB; (d) Mercedes-Benz M series die-cast Mg alloy CCB; (e) Volvo new XC90 K426 die-cast Mg alloy CCB; (f) Volvo new
S90 L541 die-cast Mg alloy CCB; (g) BAW ARCFOX-1 die-cast Mg alloy CCB.

pension wire, adjustment assembly, and slide rail assembly. mode with the help of CAE simulation technology. The static
The backrest skeleton is a large frame die casting, which is strength, modal, and mounting point fixation strength under
the most stressed part of the seat. Compared to traditional the actual working condition are analyzed to provide the ba-
press-welded sheet metal seats, MASF is highly integrated sis and plan for the optimization of the seat skeleton structure
and has fewer parts. The fatigue strength and NVH of Mg design to ensure the seat safety and regulatory requirements.
alloy are much better than steel, and fewer processing steps Static strength analysis. For the static strength analysis of
can reduce a lot of problems. the seat frame, 6 degrees of freedom at 4 mounting points of
In terms of materials, AM50 and AM60 have excellent the slider were constrained according to the actual working
elongation and energy absorption characteristics in addition conditions. The upper frame of the seat skeleton is loaded and
to high strength and casting properties. Furthermore, AM60B a moment of 530 N·m is applied backwards along the longi-
has relatively high tensile strength and is mainly used for au- tudinal direction with respect to the seat R point. For the seat
tomotive seat skeletons, instrument panels, brackets, steering headrest, a spherical model was used, and a moment based on
wheels, etc. In summary, AM60 was selected as the casting 373 N·m relative to the R point was applied to the backrest
material for MASF in this study, as shown in Fig. 14(a). model, and then gradually loaded to 890 N. The simulation
results in Fig. 14(a) show that the maximum stress and strain
4.1.2. CAE performance analysis of the backrest are 409.5 MPa and 0.001, respectively, and
Based on the preliminary data, the load-bearing perfor- the maximum stress and strain of the headrest are 640.6 MPa
mance of MASF is evaluated by converting various ultimate and 0.005, respectively, which means that the static strength
conditions into equivalent ultimate loads under static loading results all meet the performance requirements.
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 33

Fig. 12. Several applications of Mg alloy center bracket: (a) Porsche series Mg alloy center bracket; (b) Volvo series Mg alloy center bracket.

Safety belt fixing point strength analysis. To avoid occu- plate. The simulation results show that the strain value of the
pant injury or death, it is vital to improve the strength of latch is optimized to 0.131.
the seat belt system. The seat is fixed to the rigid body floor Modal analysis. Modal analysis provides the basis for vi-
and the maximum forward displacement and multiple strains bration characterization of structural systems, vibration fault
of the backrest are calculated under 20 times gravity loading diagnosis, and optimal design of structural dynamic character-
conditions. Safety belt installation fixed point and the sur- istics [168,169]. The seat skeleton mode must be greater than
rounding area allow plastic deformation, whereas not fracture 18 Hz to avoid resonance phenomena. Fig. 14(c) illustrates
or damage. The results in Fig. 14(b) show strain values of that the values of MASF left and right oscillation, forward
0.11 and 0.103 at the slide and seat basin, which are below and backward pitch and torsional conditions are all greater
the target value of 0.20 and meet the requirements. The strain than the target values and meet the design requirements.
in the latch was 0.322, which is higher than the target value
of 0.20. According to the judging guidelines, the seat strain 4.1.3. Die casting machine selection
is considered safe for materials less than 0.2. The strain be- Die casting machine is one of the most basic elements of
tween 0.2 and 0.25 is insufficient margin of safety. The strain die casting production [170]. The metal die casting mold is
between 0.25 and 0.3 should be warned. The strain greater realized by the operation of the die casting machine and is
than 0.3 is considered imminent material failure. Therefore, the basis of the die casting mold design [171]. Selecting a
for the material failure phenomenon at the latch, we increased die casting machine by clamping force is the most common
the thickness of the joint plate and installed a reinforcement method. Whereas for some major parts, safety parts, and parts
34 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 13. Some other Mg alloy parts for automobiles.


B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 35

Fig. 14. MASF full process analysis process and results.


36 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

with high quality requirements only by clamping force is not This simulation focuses on the numerical simulation of the
enough to ensure that the requirements are met, so the injec- flow and temperature fields of the metal filling process in the
tion of energy must also be considered [172]. Therefore, a die cavity.
horizontal cold chamber die casting machine was used in this In order to effectively avoid the phenomenon of solution
study. mixing during die casting and to improve the quality of cast-
The performance requirements for side pallet structure are ings, the slag bag was designed on both sides of the backing
relatively simple due to the relatively uniform forces on the pouring system, and a branch sprue was added at the cross
MASF as a whole. In addition, the seat basin skeleton has sprue of the pouring system of the seat basin to adjust the
a planar projection filling stroke of 175 mm, a deep cavity angle of feeding material. As shown in Fig. 14(d), the syn-
at the front and rear, and a wide range of solidification and chronization of each branch gate into the die casting process is
crystallization temperatures. The back end of the charge and better, the filling time is shorter, the filling area is clearer, and
angle adjustment system connected to the backrest requires the flow state of Mg liquid is smooth. However, the gas will
high strength to achieve the effectiveness of the distal pres- form defects such as shrinkage after the ingot is formed. After
sure transfer and the structural properties required to meet analysis, it is found that the shrinkage is mainly controlled
the strength requirements of the casting. Therefore, the com- on the inner side of the backrest, which is the location of
paction pressure is chosen to be 75 MPa ∼ 80 MPa. non-important bearing force. In the subsequent optimization
by setting local cooling points at the hot joints of the casting,
4.1.4. Process solution setting the shrinkage sparseness will be effectively suppressed.
The pouring system is the channel that fills the molten
metal in the cold chamber into the die cavity at high temper- 4.1.6. Trial production
ature and pressure and high speed, which includes the straight The production process of MASF went through five pro-
sprue, cross sprue, internal gate and overflow exhaust system cesses: mold, mold repair, ingot melting, die casting, and trim-
[173]. In the process of guiding the metal liquid to fill the ming. After the optimized design of the formability guideline
cavity, the pouring system plays an essential role in control- data, the process yield of the seat basin gets 96% and the
ling and regulating the flow state of the liquid, the speed process yield of the backrest skeleton reaches 92% when the
and pressure transfer, the exhaust effect, and the heat balance working condition of the die casting unit is good and each
state of the mold. Therefore, the design of the pouring and process parameter is stable at the optimized value. The main
exhausting system has a direct impact on the quality of die reason for the scrapping of the die casting parts is the unsta-
casting and die life [174]. ble process parameters of the die casting machine leading to
Fig. 14(e) shows the MASF pouring system scheme and poor filling quality. As shown in Fig. 14(f), the lower end of
pouring mold. Mg alloy backrest belongs to the large and the backrest was at the end of the pour, where several metal
medium-sized frame structure, left and right completely sym- streams converged, and metal flow back and the incomplete
metrical, casting length of 757 mm, and both sides of the v- fusion led to a slight cold separation. Therefore, the casting
shaped concave. The space inside the backrest frame is large, system needs to be adjusted.
so the gates are arranged inside the die casting, which can Finally, the product structure optimization design is guided
make the mold structure compact and ensure the thermal bal- by CAE analysis and mold flow analysis, and the finished
ance of the mold. In order to avoid the frontal impact of the product rate of MASF reaches over 90%. MASF weighs
metal fluid on the part and to allow the gas in the deep cavity 9.88 kg, a weight reduction of 3.23 kg compared to steel
to escape smoothly, an end-face side gate similar to the one seats, a 24.6% weight reduction.
used for the seat basin is used so that the metal fluid first fills
the bottom side of the cavity where the gas may be trapped. 4.1.7. Quality inspection
The total volume of the pouring system was 1083.4 cm3 , The process quality inspection of castings is divided into
accounting for 58% of the casting volume, and the process several parts, such as surface quality, inner quality, and geo-
yield of the casting was 42%. The structure of the seat basin metric dimensional inspection [177]. On-site process quality
is relatively simple, with a conventional 4-gate design. The inspection mainly uses the naked eye or magnifying glass
total volume of the pouring system is 1112.9 cm3 , accounting to check the surface defects of castings, such as deforma-
for 52% of the casting volume, and the process yield of the tion, cold separation, cracks, bruises, under-casting, and other
casting is 48%. defects. Intrinsic quality inspection contains casting internal
defects and intrinsic performance inspection [178]. The per-
4.1.5. Mold flow analysis formance inspection is mainly the chemical composition, his-
As the casting quality mainly depends on the filling so- tological organization, and tensile properties of the material.
lidification process, and the defects of the casting are mostly This study has no practical significance for the overall per-
formed in this process [175]. MAGMA software can simulate formance test, while the internal process quality inspection
the flow, temperature, stress, and microstructure of the cast- mainly uses X-ray inspection equipment to detect internal de-
ing during filling, solidification, and cooling, and predict the fects such as cracks, porosity, and shrinkage.
quality of the casting, optimize the casting equipment param- Flaw detection standards for any 30 mm diameter range of
eters and process plan based on these physical fields [176]. pore diameter less than or equal to 3 mm, 2–3 mm number of
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 37

pores less than or equal to 3, less than 2 mm number of pores selection, the MAFC assembly includes four metal materials,
are not required. Cracks are not allowed in the critical area AM60B, 6082, 6063, and DC01, as shown in Fig. 15(a).
and in the area from the edge of the part to 10 mm inward.
Simultaneously, no residue is allowed in the critical area, and 4.2.2. CAE performance analysis
the other areas are less than or equal to 2 mm of entrapped Seventeen rigid strength and modal analyses were per-
residue. The test results show that there are no pores, cracks, formed based on the actual assembly of MAFC, as shown
and slagging in all parts of MASF, and the internal quality in Table 5. The latch was loaded with 1000 N in Z-direction
conforms well, as depicted in Fig. 14(g). and X-direction, and the deformation was less than 3 mm
and 7 mm respectively. 3500 N was loaded in Z-direction
4.1.8. Test verification of the latch, and no damage such as fracture occurred un-
A three-point harness with a guide was installed at the der the ultimate tension. The latch is loaded with 2500 N in
MASF fixing point. A load of 13,500 N ± 200 N is applied ±Z direction, restraining the upper and lower left direction,
to the human body module using a simulated webbing in a and the other side is rotated by 9° angle around the central
direction parallel to the direction of travel of the vehicle and axis, and the maximum stress ≤ fracture strength∗ 0.8 when
at 10° to the horizontal. A force equal to 20 times the mass it continues to increase to 10° and 11°. The test results show
of the seat assembly is applied to the seat in the direction that MAFC does not show obvious permanent deformation,
of the load through the center of mass of the seat and in the cracking and other damage phenomena, in line with the stan-
horizontal forward direction along the longitudinal axis of the dard requirements. The specific simulation results are shown
vehicle. Continuously loaded by a specified force for a speci- in Figs. 10(b), (c), and (d).
fied period of time, permanent deformation of the fixed point
or surrounding area is allowed, including partial fracture or 4.2.3. Mold flow analysis
crack generation. The minimum interval of effective fixing The first round: The temperature modal flow analysis
points during the test should meet the requirements of the demonstrated that the material temperature was around 620 °C
fixing point installation position. For M1 class vehicles with when the metal liquid flowed to the end and had not yet
maximum total mass not more than 2500 kg, if the upper reached the solid quadrant temperature. The specific improve-
fixing point is on the seat skeleton, the forward displacement ments are:
of the upper effective fixing point should be within the trans-
verse plane through point R and point C. 1) Add oil circuit at the end of the mold for individual con-
The force of the upper and lower body module was trol.
13,540.6 N and 13,545.6 N respectively, and the force through 2) Add slag packs to the end of the product to raise the tem-
the center of mass of the seat was 2730.8 N, as tested by GB perature.
14,167-2013 standard. During the test, the continuous load- 3) Continue to optimize the flow channel program.
ing of the specified force reaches the set value and the fixed
point L2 under the seat belt of MASF meets the standard The second round: The blue area in the simulation results
requirements. According to GB14167-2013 standard require- indicates that the filling temperature is low, which is prone
ments for seat belt fixed point strength test, effective fixed to cold spacing and shrinkage defects. Thus, the runners are
point of the minimum interval to meet the fixed point in- designed in the four corner areas of the part to improve this
stallation position requirements, seat belt fixed point has not phenomenon.
failed. The third round: Adding slag packs at locations prone to
air rolls, insufficient venting and insufficient filling speed, and
4.2. Mg front-end carrier development process adjusting the flow path direction.
Through three rounds of mold flow analysis, the process
The development process of the Mg alloy front-end car- parameters were optimized iteratively to avoid defects such as
rier (MAFC) mainly includes alignment analysis, material de- cold separation and air roll, and the optimal casting process
sign, structural design, CAE analysis, process design, mold parameters were locked. The specific optimization steps and
flow analysis, mold design and manufacturing, product man- parameter settings are shown in Fig. 15(e) and Table 6.
ufacturing and inspection, and complete vehicle verification
[179]. The specific development process and analysis results 4.2.4. Trial production and redesign
are shown in Fig. 15. During the manufacturing process, the phenomenon of lo-
cal sticking to the mold often occurs, resulting in a lack of
4.2.1. Program design flesh at the top of several tendon positions of the mold. More-
MAFC has "ten" shaped reinforcement structures at the over, no improvement was achieved by adjusting the process
local assembly position and three "mouth" shaped notches on parameters, temperature, and spraying. Therefore, the inserts
the upper crossbeam, which ensure the torsional rigidity of the were made by wire cutting at ten high rib locations on the
assembly structure and facilitate the thermal performance of fixed die side and polished. In addition, the cold separation
the passenger cabin. The MAFC has a basic wall thickness of phenomenon was improved by adjusting the process parame-
2.5 mm and a design weight of 3.185 kg. In terms of material ters, temperature, and spraying, but could not be eradicated.
38 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 15. MAFC full process analysis process and results.


B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 39

Table 5
Strength and modal analysis results.

No. Type Load method Judgment criteria Result Qualified or not


1 Front cover lock stiffness -Z = 1000 N Displacement≤2 mm Displacement is 0.92424 mm OK
2 Front cover lock stiffness +Z = 1000 N Displacement≤2 mm Displacement is 1.47764 mm OK
3 Front cover lock stiffness X = 1000 N Displacement≤7 mm Displacement is 2.72917 mm OK
4 Front cover lock load limit X = 5000 N Stress≤fracture strength∗ 0.8 208.4 MPa (260.5 × 0.8) OK
5 Front cover lock ultimate Z = 3500 N No failure such as rupture Maximum stress value is OK
pull strength 161.239 MPa
6 Front cover lock strength -Z = 2500 N Stress≤fracture strength∗ 0.8 Maximum stress value is OK
165.625 MPa
7 Front cover lock strength +Z = 2500 N Stress≤fracture strength∗ 0.8 Maximum stress value is OK
157.088 MPa
8 Radiator system module -Z=−600 N (300×2), Displacement≤1 mm Maximum displacement OK
mounting point stiffness T = 85 °C value is 0.012 mm
9 Radiator system module X = 600 N (150×4), T = 85 °C Displacement≤1 mm Maximum displacement OK
mounting point stiffness value is 0.22 mm
10 Radiator system module -X = 600 N (150×4), Displacement≤1 mm Maximum displacement OK
mounting point stiffness T = 85 °C value is 0.219 mm
11 Headlight bracket -Z = 100 N Displacement≤1 mm 0.076 mm/0.15 mm OK
Z-directional stiffness
12 Headlight bracket X = 100 N Displacement≤1 mm 0.09 mm/0.088 mm OK
X-directional stiffness
13 Modal Analysis – First-order global 52.605 HZ OK
mode≥38.3 HZ
14 X-directional 3.5 g 3.5 g acceleration in X direction Stress≤fracture strength∗ 0.8 Maximum stress value is OK
acceleration shock 6.702 MPa
15 Y-directional 3.5 g 3.5 g acceleration in Y direction Stress≤fracture strength∗ 0.8 Maximum stress value is OK
acceleration shock 4.579 MPa
16 Z-directional 3.5 g 3.5 g acceleration in Z direction Stress≤fracture strength∗ 0.8 Maximum stress value is OK
acceleration shock 1.369 MPa
17 Torsional stiffness Constrain the upper, lower, and No obvious permanent Maximum stress value is OK
left directions, the other side deformation, cracks and 243.666 MPa
rotates around the central axis at other failure phenomena
an angle of 9° and continues to
increase to 10°, 11°

Table 6
Mold flow analysis parameter setting.

Material Mold Pressure chamber Material cake Filling rate/% Critical High
temperature/°C temperature/°C length/mm thickness/mm speed/m/s speed/m/s
Round 1 660 200 900 30 25 1.1 5
Round 2 680 220 900 30 25 1.1 5
Round 3 680 220 1050 20 30 0.5 6.5

Therefore, slag pockets were added at the corresponding loca- the simulation results and all meet the performance require-
tions where the molds do not have slag pockets. Microcracks ments. The vehicle equipped with MAFC had normal door
are reduced on both sides of the part by increasing the R- condition in the frontal 40% offset crash and 100% frontal
angle, but cannot be completely eliminated. Also, the distal crash tests, and all doors could open normally with good
molding of the part is lacking, accompanied by a lack of crashworthiness. According to the C–NCAP 2018 edition as-
shine. Hence, increasing the mesh along the red line posi- sessment, the virtual score meets the C–NCAP 5-star crash
tion can improve the flow direction of Mg liquid and allow requirements. The specific test results are shown in Fig. 15(g).
it to flow more smoothly to the end of the part. The specific
optimization steps are shown in Fig. 15(f).
4.3. Implications of the development process for actual
production
4.2.5. Test verification
Experimental verification of the simulated project was car- The MASF was designed using a new forward develop-
ried out after completing the production of the prototype. The ment logic that calculates preliminary version data after de-
z- and x-directional stiffnesses of the latch, the ultimate ten- termining the shape and rules. In the static loading mode,
sile strength of the front hood lock, the strength of the front various ultimate working conditions are converted into equiv-
hood lock, and the torsional stiffness test results are similar to alent ultimate loads to evaluate the load-bearing performance
40 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 16. MASF detailed development process.

of the seat. The maximum stress-strain of the seat skeleton type radiator structure, “mountain” type front bail mounting
under different working conditions is deduced through CAE bracket, “ten” type reinforcement structure, “box “T” type ra-
simulation analysis to provide solutions for structural design diator mounting structure, “T” type radiator mounting struc-
optimization. Using die casting process and mold flow analy- ture, and pedestrian protection fast charging bracket assembly.
sis to evaluate product molding process characteristics, realize The technical route and flowchart are shown in Fig. 17.
rapid scientific design of process parameters and molds, and As described in the introduction why Mg alloy is not uni-
carry out structural redesign based on the process. Under the versal in automotive applications, we introduce the whole
condition that the die casting machine set is in good working process development technology route of Mg alloy with the
condition and the process parameters are stable, the yield rate actual OEM production cases. The main purpose of the
of MASF reaches more than 90%, and its technical route and overview is to increase the confidence of OEMs in devel-
flowchart are presented in Fig. 16. oping new parts with practical examples, rather than simply
MAFC provides reinforcement structures and notch struc- describing the manufacturing process, which is worth con-
tures at local assembly locations to ensure torsional stiffness sidering for companies and manufacturing companies in their
while facilitating thermal performance in the passenger cabin automotive lightweighting research. We hope that the posi-
area. Seventeen rigid strength and modal analyses were per- tive development logic of MASF and MAFEC can provide
formed based on the actual assembly of MAFC, and the test ideas for the development of OEM die-cast Mg alloy parts
results all met the standard requirements. The process pa- and enhance the core capability of independent R&D in the
rameters were optimized iteratively and the optimal solution automotive industry.
is locked by three rounds of die-flow analysis. A series of
measures were taken to improve the problems of local sticky 5. Opportunities and challenges
mold, local cold separation, and local micro-cracking. Finally,
the door condition was normal in 40% offset collision and 5.1. Material and performance challenges
100% frontal collision cases, and all doors could open nor-
mally after the test, with good crash performance. Weight 5.1.1. Material challenges
savings of over 60% compared to a traditional steel front- At present, the development of high-performance Mg al-
end carrier and over 30% compared to an all-plastic front- loy is rapid, including high-strength casting Mg alloy, high-
end carrier. The assembly position is provided with “mouth” strength deformation Mg alloy, high-damping Mg alloy, high-
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 41

Fig. 17. MAFC detailed development process (The black arrow indicates that the condition is satisfied, and the red arrow indicates that the condition is not
satisfied).

temperature Mg alloy, biomedical Mg alloy, Mg-based en- tissue refinement, and purification. Whereas different com-
ergy storage alloy, ceramic-reinforced Mg matrix composites posites present different technical challenges:
and so on [180]. However, the lower cost cast Mg alloy has
gained wide application in daily life compared to steel and Al
grades. The actual developed material types to meet the diver- (1) From the solid solution elements and second phase consid-
sified needs of the market are few, which also reflects the phe- erations, the development of high strength and high damp-
nomenon of few independent grades of Mg alloys and narrow ing properties of synergistic Mg alloy still has certain tech-
practical applications. Whereas the grades of Mg alloys for nical bottlenecks.
automotive use are mainly concentrated on AZ91, AM50, and (2) Although a large variety of studies have reduced the heat-
AM60. To rationalize and increase the production of these ex- ing temperature from 300 °C to 150 °C, the temperature
isting grades is also one of the major objectives of this review. required to release hydrogen from Mg alloys is relatively
In addition, scholars around the world should strengthen co- high. We still require continued research on the alloying
operation to develop a set of Mg alloy material database and and nanosizing of Mg to bring the temperature down to
performance evaluation system that integrates design, prepara- below 100 °C.
tion, performance testing, and evaluation, which can enhance (3) The relationship between alloying elements, processing
the global Mg alloy material development process as a whole. technology, and electromagnetic shielding properties is the
key technology to develop medium-strength electromag-
5.1.2. Performance challenges netic shielding Mg alloys.
The low strength and high plastic forming cost of gen- (4) With oxide, ceramic reinforcements, and deformed Mg al-
eral Mg alloy materials can be effectively solved by adding loys, in-depth study of the relationship between reinforce-
reinforcements such as particles, whiskers, or fibers. Simul- ments, alloy composition and preparation and processing
taneously, parameters such as the type, size, and content of processes can break through the high modulus Mg alloy
the additive can modulate the performance index of the Mg challenges.
matrix composite. Some of the remaining specific measures (5) With carbon fiber, carbon nanotube and graphene as the
include precipitation phase morphology distribution control, reinforcement, the key to develop high strength Mg matrix
42 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

Fig. 18. Mg alloy corrosion protection solutions: (a) Mg seat backrest; (b) Mg seat basin; (c) Al isolator on Corvette front-end subframe; (d) Case of
anti-coupling corrosion of Voyah FREE automotive Mg alloy CCB.

composites is the relationship between the new reinforce- corrosion tests on the entire vehicle, no galvanic corrosion
ment, alloying elements and process. was observed on the inlay rivet nut and the Mg alloy CCB
body.
5.1.3. Corrosiveness and surface treatment On a microscopic level, a large number of studies have
Mg is chemically active, especially when exposed to corro- reported that the electrode potential can be improved by in-
sive electrolytes, and the high reduction potential accelerates creasing the purity of the Mg alloy or by additives that en-
its degradation [181]. Mg corrosion types can be divided into hance the corrosion resistance from the internal structure of
general, uniform, and localized, mainly manifested as gal- the Mg alloy. Solid solution strengthening and second phase
vanic coupling corrosion, pitting corrosion, filiform corrosion, strengthening are commonly used to further strengthen Mg
intergranular corrosion, spalling corrosion, crevice corrosion, alloys. Alloy composition and its chemical composition have
stress corrosion cracking, corrosion fatigue, and erosion cor- an important influence on the enhancement of the physical
rosion. However, the use of steel is most prevalent in auto- properties of Mg alloys. Commonly used alloys containing
motive structural components. Less reactive metals are used Al and Mg include AZ31 and AZ91 alloys. AZ31 is widely
for isolation to prevent the contact of Mg with the steel lead- used in the aircraft industry because of its low mass density
ing to electric coupling. In 1990, the Mercedes-Benz road- and good mechanical properties.
ster’s one-piece Mg seat replaced the bolt material so that all Then, many researchers have not made breakthroughs in
contact points were insulated and the long use test reduced this area due to the unstable chemical properties of Mg al-
galvanic corrosion, as shown in Fig. 18(a) and (b) [156]. Of loys themselves. Meanwhile, pure Mg is more widely used
course, isolation materials can also be used to isolate Mg in in metallurgy, chemistry and medicine, but is not an ideal
the case of metal attachment, such as the Al isolator placed material for practical engineering applications. Fully consid-
on the front crossmember of the Corvette sixth-generation ering the cost and technical issues, scholars have turned their
light sports car model Z06, as shown in the yellow area in research to the surface treatment technology of Mg alloys.
Fig. 18(c) [136]. At the macro level, this avoids direct contact, Electrochemical plating, conversion coating and anodic oxi-
but the complexity and high cost of the process often limit dation are common coating techniques.
its universal application. Another example that can be used to In medicine, it is difficult to achieve the required "service
illustrate this principle is the Mg CCB on the Voyah FREE life" of Mg alloys as implant components in the human body,
model, as illustrated in Fig. 18(d). Mg alloy adopts AM50 ma- and too rapid degradation can lead to hemolysis and osteol-
terial with passivation treatment on the surface, steel bracket ysis. Numerous studies have shown that the development of
adopts DC01 material with electrophoretic paint treatment on new series of Mg alloys can enhance the corrosion resistance.
the surface, accompanied by all fasteners requiring zinc plat- However, we believe that the composition, technical process-
ing and zinc-nickel plating. After 120 cycles of intensive road ing, and medical technology of new medical Mg alloys must
B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47 43

take full account of biosafety and compatibility. All Mg alloy universities and the lack of innovation capability of enter-
medical devices must be carried out in compliance with laws prises, the implementation of joint university-enterprise poli-
and regulations and medical safety. cies should be strengthened. Although the domestic consump-
tion of Mg and Mg alloy consumption is on the rise, the
5.2. Engineering technology challenges proportion of Mg alloy used for large structural parts is still
low. Meanwhile, despite the formation of a large number of
Mg alloy die casting technology is relatively mature, industrial base, but the Mg industry in general lack of compet-
but due to the limitations of porosity and heat treatment, itiveness, low industrial concentration and the overall strength
which restricts the large-scale expansion of Mg alloy appli- of enterprises is weak.
cations. Plastic forming and semi-solid thixotropic technol-
ogy can eliminate the influence of cast defects and signifi-
5.3.2. Environmental challenges
cantly improve the alloy properties with the help of deforma-
The current goal is not only to achieve weight reduc-
tion strengthening and heat treatment strengthening. However,
tion, but also structural, material, economic and environmen-
these technologies are not yet mature and there is a shortage
tal impacts, explaining lightweighting with environmental ap-
of talents, currently relying on foreign experts and talents.
proaches, alternative rules, and multi-material design [55].
Process parameters remain critical for Mg due to the need
With the continuous improvement of environmental protection
to improve the hot formability of the sheet and to control
standards, the former Mg enterprises face increasing environ-
edge cracking and surface quality. The relationship between
mental pressure due to the more prominent CO2 emissions
the processing process and the organization and properties is
and dust control comprehensive cost increases. However, the
a technical challenge for taking full advantage of the intrinsic
market demand for Mg and Mg alloys has declined due to
properties of Mg alloys.
the impact of the new crown epidemic and export restric-
In addition, the production safety of Mg alloy should not
tions. Limited by the external heating and vacuum process, the
be underestimated [182]. Due to the low melting point of Mg
existing Pijiang process itself has low production efficiency,
alloy, the dust back in the process of ignition, or even explo-
small scale, high labor costs, unstable product quality, high
sion. Using proper tools can avoid heat buildup, and avoiding
energy consumption, and other drawbacks, which cannot be
fine cutting and high-speed machining can also reduce fire
cured without a new alternative technology. With the gradual
hazards.
implementation of national energy conservation and emission
Mg alloy in the welding process crystallization tempera-
reduction, carbon peak, carbon neutral, carbon trading, and
ture zone is large, prone to thermal cracking, especially Mg
other policies, the Mg refining industry will face unprece-
in close to the melting temperature is prone to oxidation,
dented pressure on environmental protection and production
accompanied by the mechanical properties of the joint. Con-
costs.
sequently, Mg alloy is prone to defects such as cracks, poros-
The concept of Mg recycling is also gaining a lot of at-
ity, and spatter when welding, which poses a challenge to
tention from research experts [21,184]. The development of
its welded structural parts in vehicles. As described in Sec-
suitable sub-alloys facilitates the rational recycling and uti-
tion 5.1.3, corrosion and degradation of Mg alloys can dam-
lization of structural parts of vehicles at the end of their life.
age their mechanical properties and strength. Despite the sig-
In addition, the actual mass production and market promotion
nificant progress made so far, the technique of studying the
are difficult. A large number of Mg alloy materials are com-
resistance to corrosion of Mg alloys is still a major challenge
monly used in vehicle interior parts, and the development and
[183]. The development of advanced surface protection tech-
promotion of large external coverings are still challenging.
nology and the development of new joining technology and
equipment represented by stir friction welding is an urgent
task. 5.3.3. Cost challenges
The universal application of Mg alloys presupposes that
5.3. Policy, environmental, and cost challenges the material is compatible with the cost [185]. The lower the
cost, the greater the possibility of replacing Al, steel, and
5.3.1. Policy challenges plastics with Mg, but especially the automotive industry also
The last decade is the scale and efficiency of China’s Mg needs a reliable supply of high-quality alloys [186]. How-
industry continued to improve 10 years. The government’s ever, at present not only the cost of raw materials is high, but
policy of expanding and opening up, the policy of global- also the price of the touch into type equipment remains high.
ization and development, the development of national econ- According to the Mg market research, the cash price of Mg
omy related industries all make the Mg industry development material with tax has generally increased due to the epidemic.
mode, development level, and industrial structure constantly Mg alloy material industry long-term accumulation of struc-
optimized, laying a good foundation for further high-quality tural overcapacity, market supply and demand imbalance and
development in the future. However, the overall national and other deep-seated contradictions gradually emerged. Energy
corporate research and development investment in the Mg saving, material saving, environmental protection of the short
industry has yet to be strengthened. Facing the disconnect process preparation, and processing technology development
between the strong research and development capability of and application is still a long way to go.
44 B. Liu, J. Yang, X. Zhang et al. / Journal of Magnesium and Alloys 11 (2023) 15–47

6. Summary and prospect of Mg alloys to achieve breakthroughs will better meet the
growing demand for lighter weight vehicles.
As an engineering material, Mg has gained a firm foothold
in automotive industries with its excellent properties. The Acknowledgments
most important thing in this paper is to introduce the whole
process development technology route of die casting Mg alloy The project is supported partly by the Fundamental Re-
with the actual production cases of OEMs, which is worthy to search Funds for Central Universities (No. 06500203 and No.
be considered by enterprises and manufacturing companies in 00007735).
the research of automotive lightweighting. The main purpose
of the review is to illustrate the wide range of applications of References
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