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MARY-ANN V. GALO
UNIT 2
Lesson STOICHIOMETRY
1-4
Overview
In our daily activities we cannot avoid to do counting or measuring things. Counting is just simply as
tallying the object you are working on. These activities are easily done on objects of larger sizes. But have
you ever tried counting the number of particles in a kilo of rice, flour, corn grits, or mongo beans? Isn’t it
difficult? Definitely it is…because the particles are very small and are too many to count. So, instead of
buying it from a merchant by particles, what we normally and usually do is purchased such items in collective
counting form as by a cup, kilogram, bucket, or even by sack.
As we study Chemistry, we always deal with substances we used and produced during chemical
reactions, and knowing the mass of both reactants and products in a chemical reaction are of most
important. The branch of chemistry that deals with the counting of matter entities is Stoichiometry.
Stoichiometry is from the Greek words stoicheion and metron which mean element and measure,
respectively. This branch of chemistry involves in determining the quantitative relationships between
reactants and products in a certain chemical reaction grounded by the basic Laws of Matter. However, if rice
and flour particles are small, then how about atom that makes up the substance? We learned from the
previous lesson how small the atoms are. Chemists in the early times also encountered problems when they
try to count atoms. Because they are so small, it is difficult to measure the mass of each atom that you need
to take a very large number of them to get a gram of an element or compound. This unit will help you
understand, how masses and number of particles of each substance involve in a chemical reaction are being
determined.
Learning Objectives:
After going through with this Learning Material, you are expected to;
1. Explain relative mass and atomic mass unit
2. Define mole and Avogadro’s number;
3. Write the relationships between mass and mole, mole and amount of substance, and mass and amount
of substance;
4. Calculate percent composition of a compound in a given substance and vice versa;
5. Determine the empirical formula from the percent composition of a compound;
6. Calculate molecular formula given the molar mass
7 hours
Unlocking of Terms
Actual yields Are the amount of the products that are actually produced in a reaction.
Atomic Number Indicates the number of protons in an atom.
Avogadro’s Law States that equal volumes of all gases, under the same conditions of temperature
and pressure contain the same number of molecules.
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Empirical Formula Is the simplest formula. It shows the simplest whole number ratio of the elements
present in a compound. The formula obtained from percentage compositions are
the empirical formulas.
Excess Reactant
Molar mass (M) The mass of one mole of particles of any substance. The unit used is grams per
mole (g/mol).
Mole Is the unit of measurement for atoms and molecules.
Molecular Formula Is the true formula of a compound. It shows all the atoms present in a molecule.
Most empirical formulae are also the molecular formulae.
Limiting Reactant
Relative Atomic Mass Is the number of times the mass of one atom of an element is greater than 1/12 of
(A) the mass of one carbon-12 atom.
Stoichiometry Is the calculation of relative quantities of reactants and products in chemical
(stoi-kio-me-tree) reactions.
Theoretical yields Are the amount of products calculated from the complete reaction of the limiting
reactant.
You already know that atoms of different elements have different masses. The mass of an atom is
determined by the number of its subatomic particles, the electrons, protons, and neutrons. Since atom is too
small and impossible to weigh, its mass is determined relative to the mass of another atom.
By international agreement, the scientist agreed to use the most abundant isotope of the element
carbon which is the isotope Carbon-12. By then C-12 is set as the standard for measuring the mass of all
atoms. This isotope of carbon was chosen as reference because its mass in amu is given as a whole number
to five decimal places (12.00000 amu). This means that Carbon-12 is assigned to have exactly 12 units of
mass called Atomic Mass Unit (amu or u). One amu is equal to a mass of 1.660539 x 10-24 grams.
Thus, the RELATIVE ATOMIC MASS unit is defined as mass that is exactly one-twelfth (1/12) the
mass of one Carbon-12 atom. The symbol for relative atomic mass is Ar
From previous topic, the weighted average mass/weight of the element carbon is 12.011 amu, thus
the mass of Carbon atom is calculated as:
For example, one atom of oxygen is 16 times heavier than 1/12 of an atom of carbon-12. Oxygen has
a relative mass of 16. Relative atomic mass is a ratio and has no unit.
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Lesson 2: THE CONCEPT OF MOLE AND THE AVOGADRO’S NUMBER
The SI unit for the amount of substance by relating it to a number of particles of that substance is
called the mole (represented by n, and with a unit expressed as mol). A mole is the amount of a substance
that contains the same number of elementary entities as there are atoms in exactly 12 g of pure carbon-12
isotope.
The term mole is the collective counting word for substance and the Avogadro’s Number 6.022 x 1023 is
the total number of individual particle or formula unit present in that mole of the substance.
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This is analogous to when we say:
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The ream, tray, and dozen are the collective counting word which is similar to mole and the number of sheets
and pieces is similar to Avogadro’s Number, thus;
Note: For convenience, we will use the term molecule to describe particles of any type of compound.
In one mole of compound, the number of moles of an atom is equal to the atom’s subscript in the given
chemical formula:
1 mole of H2O
✓ (6.022 x 1023 )(2 atoms H) = 1.204 x 1024 H atoms
✓ (6.022 x 1023)(1 atom O) = 6.022 x 1023 O atoms
Or in one mole of ionic compound, the number of moles of an ion is equal to atoms’ subscript in a given
chemical formula:
1 mole AlCl3 (Al3+ and Cl-)
✓ (6.022 x 1023)(1 mole of Al3+ cation) = 6.022 x 1023 Al3+ cation
✓ (6.022 x 1023)(3 moles of Cl- anion) = 1.807 x 1024 Cl- anion
✓
For mole relationships of atom constituents in a given molecule of a substance, the mole relationship is
expressed in terms of mole ratio, for example:
Example: Calculate the amount in mole of oxygen atom (O) in 5 moles of Ca3(PO4)2 molecules.
Solution:
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Molar Mass/Molecular Mass/Formula Mass
This entails that the mass of one mole of a substance is numerically equal to the Atomic Weight of an atom
of an element, or the Molecular Weight/Molar Mass of a compound or the Formula Weight/Mass of an
ionic compound. The mass of one mole of a substance is called Molar Mass. To understand these statements
better, read through the examples given below.
A. For atoms
Consider a mole of Helium atom. Its molar mass is 4.00 g/mol which is equivalent to its atomic weight.
Therefore, one mole of He has a molar mass of 4.0 g/mol. One mole of He contains 6.02 x 1023 atoms. This
can be represented as
1.0 mole of He = 4.00 g = 6.02 x 1023 He atoms
Try this. Find the molar mass of Zn atom.
First step: Look for the atomic weight of Zinc in the periodic table.
Second step: Remember, the mass of one mole of Zn is equal to its atomic weight.
Third Step: Therefore, one mole of Zinc atom has a molar mass of ______ g.
One mole of Zinc atom contains ____________________ atoms.
Ans. 65.35 g/mol; 6.02 x 1023 atoms
B. For molecules
One mole of carbon tetrachloride (CCl4) contains 1 carbon atom and 4 chlorine atoms. To get its molecular
weight, we find:
C = 1 atom x atomic weight = 1 (12.00) = 12.00
Cl = 4 atoms x atomic weight = 4 (35.5) = 142.1
The molecular weight of CCl4 is 154.
Therefore, the mass of one mole of CCl4 is 154 g. One mole of CCl4 contains 6.02 x 1023 molecules. This can
be represented as:
1.00 mole CCl4 = 154 g = 6.02 x 1023 CCl4 molecules
Third step Therefore, the mass of one mole of CO2 is ________. One mole of CO2
contains ___________ molecules.
Ans. 44 g/mol; 6.022 x 1023 molecules
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C. For Ionic Compounds
Sodium chloride (NaCl) is a famous ionic compound. In its solid state, this substance forms a three-
dimensional array of charged particles. In such a case, molecular weight has no meaning, so the term formula
weight is used instead. One mole of NaCl contains one sodium ion and one chloride ion. To get its formula
weight, we find:
Na+ = 1 ion x atomic weight = 1 (23) = 23
Cl- = 1 ion x atomic weight = 1 (35.5) = 35.5
The formula weight of one mole of NaCl is 58.5 g.
Therefore, the molar mass of NaCl is 58.5 g. One mole of NaCl contains 6.02x10 23 NaCl ion pairs. This can be
represented as:
1.0 mole of NaCl = 58.5 g NaCl = 6.022 x 1023 NaCl ion pair
Third step Therefore, the mass of one mole of KBr is ________. One mole of KBr contains
___________ KBr ion pairs.
Ans. 119 g ; 6.022 x 1023 ion pairs
The above representations show the relationship between mass, mole, and number of particles expressed
as the Avogadro’s number.
Remember This:
One mole of any substance = molar mass of the substance = 6.022 x 1023 particles
Note: Conversion from mass substance directly to number of particles or the reverse is NOT
ACCEPTABLE. Mole serves as the bridge between any quantities, thus termed Mole Concept
Hint: The unit where the arrow head is pointed is always written on the numerator of the
corresponding factor
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Sample Problems
Case 1. Number of moles is given, mass is unknown
Solution:
Step 1. Identify the known and unknown
Given: 65.00 mol C14H18N2O5
Unknown: number of C14H18N2O5 molecules
Step 2. Set up the unit plan
Mole Number of particles
Step 3: Set up equation and substitute the values
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Case 4. Number of particles is given, Mole is unknown
4. Pheromones are a special type of compound secreted by the females of many insect species to
attract the males for mating. One pheromone has the molecular formula C19H38O. Normally, the
number of this pheromone molecules secreted by a female insect is about 2.13 x 109. How
many moles are there in this quantity?
Solution:
Step 1. Identify the known and unknown
Given: 2.13 x 109 C19H38O molecules
Unknown: number of moles of C19H38O
Step 2. Set up the unit plan
Number of particles Mole
Step 3: Set up equation and substitute the values
Solution:
Step 1. Identify the known and unknown
Given: 344.75 g Gold
Unknown: number of Gold atoms
Step 2. Set up the unit plan
mass/grams Mole number of particles (atoms)
Step 3: Set up equation and substitute the values
Solution:
Step 1. Identify the known and unknown
Given: 1.2 x 1024 molecules of C3H6
Unknown: mass of C3H6
Step 2. Set up the unit plan
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Step 3: Set up equation and substitute the values
Solution:
Step 1. Identify the known and unknown
Given: 25.6 g Urea [(NH2)2CO], (A)
Unknown: Number of H atom (B)
Step 2. Set up the unit plan
mass/grams A mole A mole B number of particles of B
Step 3: Set up equation and substitute the values
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Lesson 3: PERCENT COMPOSITION
The concept of percentage in chemistry is used to describe the composition by mass of each element in a
compound. It is important to write the correct formula of the compound and from there the percent by mass
of an element in the compound can be determined.
In general, the percent composition by mass of an element A in a compound can be determined using the
formula:
Step 2: Find its molar mass of the compound (Molar mass = No. of moles x atomic weight)
N: 2 mol x 14.01 g/mol = 28.02 g
H: 9 mol x 1.01 g/mol = 9.01 g
P: 1 mol x 30.97 g/mol = 30.97 g
O: 4 mol x 16.00 g/mol = 64.00 g
Molar mass 132.00 g
Step 3: Express the total mass of each element as a percentage of the molar mass.
Remember, the sum of the percentage must be 100.
28.02 g
%N= x 100% = 21.23%
132.00 g
9.01 g
%H= x 100% = 6.83%
132.00 g
30.97 g
%P= x 100% = 23.46%
132.00 g
64.00 g
%O= x 100% = 48.48%
132.00 g
To check, add the calculated percent values…if the sum is 100 or closest to 100 then
you did it RIGHT! (21.23% + 6.83% + 23.46% + 48.48% = 100%)
Note: If the problem statement on percent composition states the specific element to be
determined, then solve only for the percent composition of that element , however is the
problem states “...percent composition of the compound…” it means you need to calculate
the percent composition of all the elements present in a molecule of that compound.
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Determining the Mass of an Element from Its Mass Percent
Sample Problem:
Find the mass of oxygen in 15.5 g of nitrogen dioxide, (NO2).
Solution:
Given: 15.5 g NO2
Unknown: Mass of Oxygen
Step 1 : Solve for the molar mass of the compound
N: 1 mole x 14.01 g/mol = 14.01 g N
O: 2 moles x 16.00 g/mol = 32.00 g O
= 46.01 g NO2
32.00 g O
= 15.5 g NO2 x
46.01 g NO2
= 10.7825 g 𝑜𝑟 10.8 g O
1. Phosphoric acid (H3PO4 ) is a colorless, syrupy liquid used in detergents, fertilizers, toothpastes, and in
carbonated beverages for a “tangy” flavor. Calculate the percent composition by mass of P and O in
this compound. (ans: P= 31.61% ; O = 65.38%)
2. Cinnamic alcohol is used mainly in perfumery, particularly in soaps and cosmetics. Its molecular formula
is C9H10O. (a) Calculate the percent composition by mass of cinnamic alcohol. (b) How many molecules
of cinnamic alcohol are contained in a sample of mass 2.930 g? (c) If a sample of cinnamic alcohol has a
mass of 25.30 g, how many grams of C is in the given sample? (Ans: (a) C=80.55% ; H=7.53% ; O=11.92%
(b) 1.315 x 1022 molecules (c) 20.38 g C
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Lesson 4: EMPERICAL FORMULA and MOLECULAR FORMULA
Empirical formula of the compound gives the simplest whole-number ratio of atoms present in the
compound based on the mass percentage of its elements.
Molecular formula is the true formula of the compound. It gives the actual number of atoms of each
element in the compound.
Note: Knowledge in Percent composition and Mole relationships are very useful in determining the
empirical and molecular formula
of the compound
5. Use the mole ratio (in whole number) to write the empirical formula.
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Flow Diagram for Determining Empirical Formula
To determine the Molecular Formula of any compound, the equation below is used:
Step 3. Divide each mole with the smallest value. In our example the smallest value
obtained in step 2 is 3.406 mol
Step 4. Look for a factor to make the values in step 3 be in a whole number. Since one of
the values in step 3 is 1.33 then we will use the factor 3.
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Then the final value will be the subscript of the corresponding atom thus, our Empirical Formula, EF will be:
C3H4O3
Step 5. Calculate value of n to determine the molecular formula. Solve first for the molar
mass of the empirical formula
molar mass of EF = (3 x 12.01 g/mol) + (4 x 1.01 g/mol) + (3 x 16.00 g/mol)
= 88.07 g/mol
𝐌𝐅 = (𝐄𝐅)𝒏
𝐌𝐨𝐥𝐞𝐜𝐮𝐥𝐚𝐫 𝐖𝐞𝐢𝐠𝐡𝐭 𝐨𝐫 𝐌𝐨𝐥𝐚𝐫 𝐌𝐚𝐬𝐬
: 𝒏 = 𝐌𝐨𝐥𝐞𝐜𝐮𝐥𝐚𝐫 𝐖𝐞𝐢𝐠𝐡𝐭 𝐨𝐟 𝐭𝐡𝐞 𝐄𝐦𝐩𝐢𝐫𝐢𝐜𝐚𝐥 𝐅𝐨𝐫𝐦𝐮𝐥𝐚
𝟏𝟕𝟔 𝐠/𝐦𝐨𝐥
: 𝒏 = 𝟖𝟖.𝟎𝟕 𝐠/𝐦𝐨𝐥 = 𝟏. 𝟗𝟗𝟖 𝟐
Therefore:
𝐌𝐅 = (𝐄𝐅)𝒏
𝐌𝐅 = (𝐂𝟑 𝐇𝟒 𝐎𝟑 )𝟐
References:
Baguio, S.M. & Butaran, R.T. (2006). Breaking Through Chemistry. Quezon City: C & E Publishing, Inc..
Bayquen, A.V., & Pena, G.T. (2016). Exploring Life Through Science: General Chemistry 1. Quezon City:
Phoenix Publishing House.
Brown, T.L., LeMay, H.E., Bursten, B.E., Murphy, C.J., &Woodward, P.M. (2012). Chemistry: The Central
Science 12th edition. U.S.A..: Pearson Prentice Hall.
Chang, R. (2010). Chemistry. New York: McGraw-Hill.
Petrucci, R.H., Herring, F.G., Madura, J.D., & Bissonnet, C. (2011). General Chemistry: Principles and
Modern Applications 10th edition. Canada: Pearson Prentice Hall.
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