SUBJECT CHEMISTRY ACADEMIC YEAR 2021/2022

QUIZ NO. 1 GRADE SCORE

TOPIC Carbonyl compounds TIME ALLOTMENT 35 minutes
SEMESTER 2 TOTAL MARKS 25 points 25

STUDENT’S NAME
BINUSIAN ID NO. SUBJECT TEACHER J V Mathew
STUDENT’S CLASS DATE

READ THESE INSTRUCTIONS FIRST

1. Write your name, Binusian ID, class, date, and your teacher’s name in the box above and on
all extra sheets you hand in with this quiz paper.
2. Write in black or dark blue pen.
3. Do not open this quiz paper until instructed to do so.
4. Use soft pencil for shading answers in Section A or on any diagrams, graphs, or rough
working only.
5. Do not use highlighters, glue, or correction fluid/tape. Strikethrough all mistakes.
6. Answer all the questions.
7. The use of an electronic calculator is expected, where appropriate.
8. You are reminded of the need for clear presentation in your answers.
9. You are not allowed to talk during the quiz. If you need anything or have questions, ask the
teacher to assist you.
10. The number of marks is given in brackets [ ] at the end of each question or part question.
11. The total number of marks for this paper is 25.
12. At the end of the quiz, staple all your work securely together.

“I affirm by answering the questions in this assessment, that I will not give nor receive any
unauthorized help, and that all work will be my own. I will not give nor receive information on
this assessment and will inform the school if I have knowledge of such information being
circulated. I understand that based on the school policy, violation of these principles will lead to
a zero score on this assessment."

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

Section A

For each question there are four possible answers A, B, C and D. Choose the one you consider
correct and shade the circle that corresponds to the letter of your choice. Use only pencil in shading.

1 A compound Y is treated with warm acidified potassium dichromate (VI). The

resulting organic product gives an orange precipitate with
2,4-dinitrophenylhydrazine reagent but does not give a silver mirror with Tollens’
reagent.
What is Y?

A propan-1-ol B propan-2-ol
C propanal D 2-methylpropan-2-ol

2 Compound X changes the colour of warm acidified sodium dichromate (VI) from
orange to green.
1 mol of X reacts with 2 mol of HCN in the presence of KCN.
What could X be?

A CH3CH2CH2CHO B CH3COCH2COCH3
C H2C=CHCH2CHO D OHCCH2CH2CHO

3 Pentanol, C5H11OH, has four structural isomers that are primary alcohols.
How many of these primary alcohols contain a chiral carbon atom?

A 0 B 1
C 2 D 3

4 Aldehydes and ketones are carbonyl compounds.

Which of them react with NaBH4 and react with Fehling’s reagent?

A both aldehydes and ketones B aldehydes only

C ketones only D neither aldehydes nor ketones

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

5 Which alcohol has a chiral centre and can be oxidised to a ketone?

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

A pentan-2-ol
B pentan-3-ol
C 3-methylhexan-1-ol
D 3-methylhexan-3-ol

6 What is the general formula of carbonyl compounds?

A CnH2n+1O
B CnH2nO
C CnH2n+2O
D CnH2n CO

7 Which of the following is a functional group isomer of butanone?

A CH3CH2CH2OH
B CH3CH2COCH2CH3
C CH3CH2CHO
D CH3CH2CH2CHO

8 Which of the following compound is a product of oxidation of butan-2-ol?

A butanal
B butanoic acid
C butanone
D butane

9 What is the IUPAC name of the following compound?

CH3COCH2CH(CH3)2

A 4-methylhexan-2-one
B 2-methylhexan-4-one
C 4-methylpentan-2-one
D 2-methylpentan-4-one

10 Which of the following test will distinguish propanal from propanone?

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

A Reduction with NaBH4

B Reaction with 2,4-DNPH
C Iodoform test
D Starch test

[Total: 10]

Section B

Answer all the questions in the spaces provided. You may lose marks if you do not show your working
or if you do not use appropriate units.

11 P, Q and R are structural isomers with the molecular formula C4H8.

All three compounds readily decolourise bromine in the dark.
P and Q do not exhibit stereoisomerism, but R exists as a pair of geometrical (cis-trans)
isomers.
All three compounds react with hot concentrated, acidified potassium manganate (VII) to
produce a variety of products as shown in the table.

S reacts with 2,4-dinitrophenylhydrazine reagent, 2,4-DNPH, to form an orange crystalline

product but does not react with Fehling’s reagent.

(a) Give the structural formulae of P, Q, R and S.

P ............................................................... Q ................................................................
R ................................................................ S ...............................................................
[4]

(b) State a reagent that could be used for the reduction of S and name the organic product of
this reduction.
reagent ......................................................... product .........................................................
[2]

(c) Give a test to distinguish compound S from pentan-3-one?

………………………………………………………………………………………………………

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

………………………………………………………………………………………………………
………………………………………………………………………………………………………
[1]

[Total: 7]

12 Consider the following reaction scheme:

C2H5Br Step I C2H5OH CH3CH(OH)CH2NH2

Step VI

Step VII Step III Step II

Step VIII Step V

CH2CH2 CH3CHO Step IV CH3CH(OH)CN

Write the reagents and conditions for the conversion involved in each of the above steps?
Step I
…...........................................................................................................................................
Step II
…...........................................................................................................................................
Step III
…...........................................................................................................................................
Step IV
…...........................................................................................................................................
Step V
…...........................................................................................................................................
Step VI
…...........................................................................................................................................
Step VII
…...........................................................................................................................................
Step VIII

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 Chemistry Quiz # 1
Topic: Carbonyl compounds
AY 2021-2022

…...........................................................................................................................................

[Total: 8]

* END OF TEST *

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