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Off-Gas

Treatment Solutions for MERICON I, II, III ™ AcidOils

Processing Spent Caustics Applications Nitrogen

ScrubbingPhase $ Refinery Spent Caustics

MERICON™ I, II, III | Treatment Solutions Separation Neutralization
Processwatel

Oxidation $ Ethylene Spent Caustics

Developed by Merichem , MERICON I, II and III are on-site treatment
® ™

$ Other Spent Caustic Streams

technologies used in the processing of spent caustics for BOD/COD reduction,
AlkalineSolution
odor control and/or pH adjustment.
OxidationAir

These solutions employ either oxidation or acidification—along with the option FreshCaustic

of final neutralization—to yield a neutral brine effluent stream acceptable for Chemical Oxidation
disposal to wastewater treating facilities, evaporation ponds or waterways.
Advantages
MPSteam

MERICON™ I Advantages NeutralizedBrine

Best for destroying phenolics and

SpentCaustic
Best for sulfidic spent caustics treatment with less demanding lowering COD for smaller streams
COD specs in spent caustics
SulfuricAcid

Oxidizes
LEGEND: sulfides to sulfate and thiosulfate; oxidizes mercaptides to Uses hydrogen peroxide and an
Steam,Off-Gas,Nitrogen,Air,Water
disulfide oils iron catalyst
Caustic
Reduces chemical
SulfuricAcid oxygen demand (COD) by 75% Can be added to MERICON I, II ™

LowBrine
pressure and temperature operation allows the use of stainless and III as needed to meet
AcidOils
steel, reducing capital expenses product specs
Uses plant air—no dedicated air compressors required—reducing
operating expenses

MERICON™ II Advantages
Effective in treating all mixed refinery and ethylene caustics, including We offer multiple
naphthenic and phenolic caustics, to low COD specifications solutions for handling
Oxidizes spent caustics at high pressures (30-100 barg) and
temperatures (200° – 300° C) to reduce COD by 98+%.
spent caustic:
Oxidizes all sulfides and thiosulfates to sulfates; destroys phenolics,
REGEN® | Spent
naphthenics and mercaptides depending on oxidation temperature.
Caustic Regeneration
Effective in treating sulfidic caustics at low pressures and temperatures,
and in treating mixed refinery caustics, including naphthenic caustics at Regeneration and reuse of caustic
higher pressures and temperatures solution during the mercaptan
Non-catalyst process extraction process.
Minimum contaminates in the final brine
About REGEN »
MERICON™ III Advantages
Spent Caustic Management
Best for treating sulfidic and naphthenic spent caustics
Removes spent caustic products safely
Acidifies all spent caustics at low pressures and temperatures, releasing and reliably from your facility for
most high COD impurities from caustic; reduces COD by 90-95% beneficial reuse.
Allows recapture of organic compounds (naphthenates and phenolics)
if advantageous About Spent Caustic Management »
Flexible operation managing varying compositions and quantities of
spent caustic in a timely and responsible manner
Proven technology for removal of naphthenates in caustic streams

How It Works
MERICON I, II and III use on-site neutralization and/or oxidation on sulfidic and organic
™

spent caustics to produce a neutral brine effluent stream. Afterwards, the stream can
be routed to wastewater treating facilities, evaporation ponds or waterways. If
technology is not your solution for spent caustic regeneration or neutralization,
Merichem also offers spent caustic management services that allow you to ship your
®

caustic as non-hazardous waste.

SpentCausticTreatmentSystemEmployingWetAirOxidation

Off-Gas

AcidOils

Nitrogen

ScrubbingPhase
Separation Neutralization
Processwatel

Oxidation

AlkalineSolution
OxidationAir

FreshCaustic

MPSteam

NeutralizedBrine

SpentCaustic

SulfuricAcid

LEGEND:
Steam,Off-Gas,Nitrogen,Air,Water
Caustic
SulfuricAcid
Brine
AcidOils

'

MERICON™ I MERICON™ II MERICON™ III

History of Innovation
For nearly 75 years, Merichem has provided proven spent
®

caustic services and processing technologies to oil and gas

industry leaders. Our reputation for innovation, expertise
and dedication to customer service continue to
be unsurpassed.

Extensive Capabilities
To every challenge, we bring a comprehensive suite of
capabilities to help our customers address their treatment
issues. Whether it’s licensing technology, guidance, design,
engineering, fabrication, testing or implementation,
Merichem can apply the right resources, when and where
®

they’re needed.

Proven Flexibility, Global Reach

All over the world, Merichem has helped customers address some of their most
®

challenging treating problems with extensive capabilities and a flexible array of

supply-chain options.

We have licensed more than 35 MERICON units worldwide ™

MERICON™

We Evaluate. We Solve. We Prove.

MERICON : Extracting Value ™

Choosing the Optimal Treatment
from Caustic Treating Streams Technology for Effluent Caustics
MERICON™ | Spent Caustic MERICON™ | Spent Caustic

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Is MERICON ™
I, II, or III the
right solution for you?
At Merichem®, we are here to help you solve your
contaminant challenges, with comprehensive
end-to-end solutions.

Contact Our Experts »

About Merichem® Quick Links Upcoming Events / Recent News

& Resources Time to Process

Merichem  specializes in proven solutions for sulfur

®
& Contaminants We Treat
removal, caustic treating and spent caustic treatment
& Spent Caustic Handling
technologies. Merichem also provides spent caustic
®

handling services as an alternative to technology solutions. & Environmental Stewardship

Serving customers worldwide, our deep expertise and
& Request Technical Support
comprehensive capabilities encompass design and Cleaning sulphur from renewable
engineering, fabrication, research and testing, logistics, & 24/7 Logistics Support diesel production
implementation and technical support.
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& Employee Resources

SPECIAL FOCUS: REFINING

TECHNOLOGY

Phone Number: +1-713-428-5000 Address: Merichem Company 601 Sawyer Street, Suite 205, Houston, TX 77007, USA

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