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Solidification of metals
References:
[1] Serope Kalpakjian & Steven R. Schmid, “Manufacturing Engineering and Technology”,
Any edition (2001 to 2008), Prentice Hall.
[2] Prof. Karl B. Rundman: Dept. of Materials Science and Engineering, Michigan Tech.
University, “Metal Casting”
- The fluidity can be defined by the capability of molten metal to flow into the mold cavity
and to fill it before freezing.
-The fluidity can be tested using a spiral mold, see the Fig. It is a standard test. The fluidity
is specified by the fluidity index. The index is the length of the solidified metal in the
spiral passage [1]. The high fluidity is indicated by The long length of the solidified metal.
CF = %C + 1/4 x % Si + 1/2 x % P.
Thus, for an iron of composition 3.5 % C, 2.4 % Si, 0.04 %P, the fluidity is given by
As the pouring temperature increases the fluidity increases (at 2700 the fluidity is
41.39 in.) and as the composition decreases (increasing the temperature range over
which solidification occurs) to a hypoeutectic value (say 3.2% C, 2.1% Si, 0.04 %P)
the fluidity decreases to ~ 30.8 in. Clearly the fluidity needed to fill a mold cavity
will depend upon the section size of the casting being produced. Thin
sections
will naturally require higher fluidities to successfully be filled
before solidification, and therefore higher superheat temperatures.
Effect of Impurities
The fluidity of pure elements is greatly reduced by the presence of slight
impurities .
- By reducing the driving force of the heat transfer, equiaxed and coarse
grains are formed [1].
Microstructure - Dendrites
ρ = density
k = thermal conductivity
c = specific heat
• Subscripts
– c = casting
– m = mold
• ΔHf = latent heat of solidification
Insulating mold:
– kmold = 0.6 << kcasting = 154 W/m-K
Solidification time:
So
t = 57 s
Now, we have to take into account
cooling the liquid from (650 + 50) oC to 650oC
t = 79 s (a bit slower)
Example: Solidification times for various shapes
Three pieces being cast have the same volume but different shapes. One
is a sphere, one a cube, and the other a cylinder with a height equal to its
diameter. Which piece will solidify the fastest and which one the slowest?
SOLUTION:
Solidification time = C (volume/surface area)2
The volume is unity, so we have from the above Eq. :
Solidification time α 1/ (surface area)2
The respective surface areas are
Sphere: V = (4/3) πr3, r = (3/4 π)1/3, and A = 4 π r2 = 4 π (3/4 π)2/3 = 4.84;
Cube: V = a3, a = 1, and A = 6a2 = 6;
Cylinder: V = π r2h = 2 π r3, r = (1/2 π)1/3 and
A = 2 π r2 + 2 π rh = 6 π r2 = 6 π (1/2 π)2/3 = 5.54.
Thus, the respective solidification times t are tsphere = 0.043 C, tcube= 0.028
C, and tcylinder = 0.033 C.
Hence the cube-shaped casting will solidify the fastest and the sphere-
shaped casting will solidify
the slowest.