Method Statement of Pipe Painting Rev02

Method Statement for pipe painting
NEOM MOUNTAIN BASE CAMP PROJECT
Contract No. Document No.

Location
#4800000313/
Jabal al lwaz 000
Title: Page Rev No.
METHOD STATEMENT 1 of 44 0 2
FOR PIPE PAINTING
Method Statement
For
PIPE PAINTING
NEOM MOUNTAIN BASE CAMP PROJECT
Checked And
Rev. Reviewed By: Approved
Date Description Prepared By
No. By
Const. QA/QC HSE
0 27/03/2022 Issued for Approval Abdelaziz Alaa Mutaz Raft
Page 1 of 44
Classification | Internal
CONTENTS
1. SCOPE
2. PURPOSE
3. RESPONSIBILITES
4. SAFTY
5. PROCEDURES
6. Materials
7. References Documents
8. Painting Methodology
9. Storage of Paint
10.Repair / Touch-Up of Damage Coated
Surfaces
11. Coating
12.Products Data Sheet
Page 2 of 44
1. SCOPE:
The scope of this method statement covers painting procedure of firefighting

and fire protection pipe and fitting for NMBC project.
The pipe paint procedure defines the method use to insure the painting has been
carried out as per Neom specification and industry best practices, it gives details
of how the work will be carried out and what health, safety and quality
requirements and controls are necessary.
Scope of work includes all horizontal, vertical and welds area installed of pipe
network for firefighting &fire protection system inside the building using
HAMPLES red oxide Primer 12070 and HAMPALIN ENAMEL 52140 for final
coat
2. PURPOSE:
The Purpose of this method statement is to describe the materials which will be
used and work procedure.
3. RESPONSIBILITES:
-NESMA Engineers are responsible for ensuring that this method statement is fully
implemented upon approval by supervision consultant.
-NESMA Quality Control Engineer is responsible for the proper implementation of
the quality control procedures including inspection and testing of materials.
3.1 Coating Crew Supervisor: Candidate must demonstrate to the satisfaction of the
certified coating Inspector Level-2 (BGAS Grade-2 or NACE Certification Inspector)
& his understanding of ability to successfully meet all the specifications and refer
International Standards Evaluation of the Crew Supervisor shall include an
assessment of his ability to.
1) Exhibit a working knowledge of Safety standards
2) Communicate with and direct his workman, communicate with the Client
Representatives.
3) Understand and apply the safety requirements.
Page 3 of 44
4) Setup, maintain and troubleshoot blasting & coating equipment.

5) Demonstrate his capability to properly establish compressor capacity & establish
air &blast hose size that will achieve satisfactory nozzle pressures.
6) Demonstrate how to inspect moisture and oil separators and how to check that the
delivered air quality is free from oil, moisture, or the other contamination.
7) Recognize minimum & maximum blast profiles & surface preparation as per
applicable project specs (Near white blast clean SSPC-SP-10 with SA 2.5)
8) Use of proper solvent and detergent cleaning techniques.
9) Proper use of materials & techniques for mixing.
10) Instruct personnel regarding the importance of air metal temperatures, Relative
humidity, Dewpoint, wind, and other factors affecting successful application.
11) Demonstrate spray pattern control for different applications.
12) Use of WFT & DFT Gauges, conduct relative humidity tests, make adhesion
checks, perform holiday testing, detect coating defects, and make timely, effective
corrections.
3.2 Abrasive Blaster: The qualification procedure for the Abrasive blaster for the
industrial coatings shall consist of both oral & practical examinations of his job
knowledge & skills, The Abrasive Blaster shall be able to demonstrate his ability to
1) Setup Abrasive blast equipment.
2) Know when & how to properly use safety equipment and adhere to the basic safety
requirements.
3) Demonstrate hand signaling techniques.
4) Properly setup forced ventilation equipment for work in the confined spaces.
5) Demonstrate how to properly ground equipment to prevent shock or static electrical
discharge.
6) Select properly sized nozzle & hose assemblies to achieve correct air pressure &
proper flow of abrasives.
7) Adhere the cleanliness requirements for the metal before, recognize & correct
blasting deficiencies.
8) Recognize & differentiate between blast finishes, recognize & correct blasting
deficiencies.
3.3 Coating Applicator: The qualification procedure of the Coating Applicator for
industrial coatings shall exist for both oral & practical examination as per ASTM-D-
4228,
the Coating Applicator shall be able to demonstrate his ability
1) Setup coating application equipment.
2) Know when & how to obtain emergency medical care.
3) Know when & how to properly use safety equipment & adhere to the basic safety
requirements.
4) Demonstrate proper hand signaling techniques.

5) Properly setup forced ventilation equipment for work in the confined spaces
6) Demonstrate how to properly ground equipment to prevent shock or static electrical
discharge.
7) Properly mix critical coatings
8) Adhere to cleanliness requirements for the material before coating.
Page 4 of 44
9) Use properly sized nozzle & hose assemblies to achieve correct air pressure &
proper
flow of coating materials.
10) Identify the spray equipment requirements & demonstrate proper spraying
techniques.
11) Use of WFT & DFT gauges.
12) Recognize & correct coating defects.
HSE Manager:
HSE Manager is responsible for ensuring that chemical usage safely training with
SDS details are delivered to all employees, emergency teams and first aid teams.
Required PPE must be provided to employees, emergency teams and first aid teams
according to manufacturer SDS.
First aiders should also be trained on how to rescue, and approach chemical-affected
personnel, and how to provide first aid service.
Activity must be close monitoring by Safety Staffs.
PPE requirements have to fully implemented.
HSE Manager should determine emergency scenarios related to chemicals, add them
to the drill program and perform exercises periodically.
Permit Issuer:
Permit Issuer is responsible for ensuring that the work area prepared according to
manufacturer recommendation.
Permit Receiver:
Permit Receiver is responsible for ensuring that all safety measures specified in the
RAMS are implemented during the operation.
4. SAFTY:
As the following sheets
Page 5 of 44
5. PROCEDURES:
Preparation for pipes welded painting activity
sufficient manpower shall be arranged to carry out the work.

The works shall be executed in accordance with the following methodology and sequence:
Ensure that the aproned materials are available to carry out the work, as per the aproned
material submittal &contract specification.
Physical verification of material will be carried out for any damages prior taking from
store. prior to commencement of the work, areas and access will be inspected to confirm
that site is ready to commence the work as per approved drawings.
All items not be painted shall be suitably covered before any surface preparation is initiated
to prevent damages. Oil and grease to be removed by emulsion cleaning. Remove salts
loose paints and other impurities from the surface. Before painting clean the pipes by wire
brushing and insure that pipes surface is clean and dry.
Quality Engineer make sure that the painting procedure applied step by step as per
material data sheet as the follow:
1- Surface preparation.
2- Applied primer coat one layer 40 microns with re coat intervals minimum 8 hours
3- Applied top coat first layer 30 microns with re coat intervals minimum 8 hours
4- Applied top coat second layer 30 microns to become total Dry Film Thickness
40+30+30= 100 microns
6. Materials:
All painting materials to be supplied by NESMA shall follow the prescriptions of the
NEOM specifications, Technical documentation.
The scope includes the supply of all materials (painting, thinners, etc.) and consumables
necessary for the complete execution of painting activities.
It has to be clarified that NESMA responsibility involves the properly and timely purchase,
expediting, transportation to Site, unloading, management, inspection and storage of the
painting materials properly up to the completion of the painting works, as
previously described. The material uses at site as the follow:
HAMPLES red oxide Primer 12070
HAMPALIN ENAMEL 52140 for final coat
Page 17 of 44
7. References Documents.
NEOM SPECIFICTION 210500 section 3.8
SSPC/NACE & ISO 8501.
MANUFACTURE RECOMMENDATION
8. Painting Methodology:
Ensure that painting is carried out for surface preparation in the following sequences:
- 01 Coat as a primer coat one layer.

- 01Coat finish paint. Two layers
9. Storage of paint.
All paints shall be stored under cover and in conditions recommended by the paint
manufacturer and in accordance with the appropriate fire regulations.
Paint Storage:
1) Until required for use, containers of coating material shall remain unopened in
the original, manufactures containers in a clean dry place not exposed to direct
sunlight.
2) Coating material that has been jelled or otherwise deteriorated during the
storage shall not be used.
3) Manufacturers batch numbers shall be clearly marked on each original
container of the coating material.
4) Manufacturer data sheets for all coating material used, shall be available.
Page 18 of 44
10. Repair / Touch-Up of Damage Coated Surfaces.

- General
Areas subjected to severe damage or field weld shall be prepared and painted in
accordance with original specification used for surroundings paint works.
To achieve a sound firmly adherent applied paint system for the repaired areas, all
repair work and field weld painting, surface preparation and painting shall extend a
minimum of 25 mm onto surrounding paintwork. All such work shall achieve a high
standard of decorative finish blending in with the surrounding area.
Any defect shall be repaired. The Final report shall be submitted to the company &
contractor.
-Touch-Up
Prior to application of any subsequent coat, all defects and damage to the previous
coat(s)shall be repaired. Damage to finished work shall be thoroughly cleaned and re-
coated. Damaged areas shall be spot blast cleaned or power tool cleaned as necessary
to restore any exposed steel to its original degree of cleanliness. All loose, cracked,
and damaged coating shall be removed, and the adjacent sound coating feathered back
approximately 2 inches (50mm) to form a uniform and smooth surface. Feathering
shall be done by hand or power sanding with a grit wheel or sandpaper. The prepared
surface shall be free of loose, burnt, or blistered coating. Unless specified otherwise,
the coating used for repair shall be the same as the original and shall have the same
DFT.
11. Coating
Each coat shall be applied uniformly over entire surface. run, sags, and drips shall be
avoided. if they occur, they shall be removed and the surface recoated.
Each coat shall be allowed to dry for the time specified by manufacture before
application of any succeeding coat.
Any primer coat exposed to excess humidity or rain before drying shall be permitted to
dry ang the damage area of primer shall be removed and the surface again prepared and
primed. The time interval between applications of coat must not exceed that specified
by the manufacture. Coating shall be continuous, i.e. free of pin holes, voids, bubbles
and other defects.
Page 19 of 44
12. Product data sheet.
As the following sheets
Page 20 of 44
Safety Data Sheet
HEMPEL'S RED OXIDE PRIMER 12070
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 - Europe
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : HEMPEL'S RED OXIDE PRIMER 12070
Product identity : 1207012170
Product type : alkyd primer
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : -
Identified uses : Industrial applications.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 18 February 2019
Date of previous issue : 8 February 2019.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM) - Category 2
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H317 - May cause an allergic skin reaction.
H336 - May cause drowsiness or dizziness.
H372 - Causes damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention.
Storage : Keep cool.
Hazardous ingredients : white spirit
2-butanone oxime
cobalt bis(2-ethylhexanoate)
phthalic anhydride
Supplemental label elements : Repeated exposure may cause skin dryness or cracking.
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Version: 0.06 Page: 1/11

Safety Data Sheet

Tactile warning of danger : Not applicable.
2.3 Other hazards

Other hazards which do not result None known.
in classification :
SECTION 3: Composition/information on ingredients
3.2 Mixtures
.
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

white spirit REACH #: 01-2119458049-33 ≥25 - ≤50 Flam. Liq. 3, H226 - [1] [2]
EC: 265-191-7 STOT SE 3, H336
CAS: 64742-88-7 STOT RE 1, H372 (central nervous
Index: 649-405-00-X system (CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
xylene REACH #: 01-2119488216-32 ≥1 - ≤3 Flam. Liq. 3, H226 C [1] [2]
EC: 215-535-7 Acute Tox. 4, H312
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
zinc oxide REACH #: 01-2119463881-32 ≥1 - ≤3 Aquatic Acute 1, H400 (M=1) - [1]
EC: 215-222-5 Aquatic Chronic 1, H410 (M=1)
CAS: 1314-13-2
Index: 030-013-00-7
trizinc bis(orthophosphate) REACH #: 01-2119485044-40 ≤1 Aquatic Acute 1, H400 (M=1) - [1]
EC: 231-944-3 Aquatic Chronic 1, H410 (M=1)
CAS: 7779-90-0
Index: 030-011-00-6
2-butanone oxime REACH #: 01-2119539477-28 <1 Acute Tox. 4, H312 - [1]
EC: 202-496-6 Eye Dam. 1, H318
CAS: 96-29-7 Skin Sens. 1, H317
Index: 616-014-00-0 Carc. 2, H351
cobalt bis(2-ethylhexanoate) REACH #: 01-2119524678-29 <0.3 Eye Irrit. 2, H319 - [1]
EC: 205-250-6 Skin Sens. 1A, H317
CAS: 136-52-7 Repr. 1B, H360F (Fertility)
Aquatic Acute 1, H400 (M=1)
phthalic anhydride REACH #: 01-2119457017-41 ≤0.3 Acute Tox. 4, H302 - [1]
EC: 201-607-5 Skin Irrit. 2, H315
CAS: 85-44-9 Eye Dam. 1, H318
Index: 607-009-00-4 Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
See Section 16 for the full text of the H statements declared .
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
SECTION 4: First aid measures
4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and seek medical advice.

Safety Data Sheet

Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.
5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides
5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

Safety Data Sheet
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.
6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.
6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.
6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.
7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Product/ingredient name Exposure limit values
white spirit EU OEL (Europe).

(ACGIH) TWA: 25 ppm 8 hours.
(ACGIH) TWA: 145 mg/m³ 8 hours.
xylene EU OEL (Europe, 2/2017). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
Recommended monitoring procedures

Safety Data Sheet

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
No DNELs/DMELs available.
Predicted effect concentrations

No PNECs available.
8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator. If working areas have insufficient
ventilation: When the product is applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle
filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

Safety Data Sheet
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 38°C (100.4°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.6 - 6.7 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.258 g/cm³
Solubility(ies) : Very slightly soluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: >220°C (>428°F) (white spirit).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.
9.2 Other information

Solvent(s) % by weight : Weighted average: 32 %
Water % by weight : Weighted average: 0 %
VOC content : 405.4 g/l
TOC Content : Weighted average: 346 g/l
Solvent Gas : Weighted average: 0.073 m³/l
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability

The product is stable.
10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.
10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials, organic materials, alkalis and moisture.
10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides metal oxide/oxides

Safety Data Sheet
SECTION 11: Toxicological information
11.1 Information on toxicological effects

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
zinc oxide LC50 Inhalation Dusts and mists Rat >5.7 mg/l 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
trizinc bis(orthophosphate) LD50 Oral Rat >5000 mg/kg -
2-butanone oxime LD50 Dermal Rabbit 1001 mg/kg -
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 1.22 g/kg -
phthalic anhydride LD50 Dermal Rabbit >3160 mg/kg -
Acute toxicity estimates
Route ATE value
Dermal 43339.9 mg/kg
Inhalation (gases) 196999.4 ppm
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
2-butanone oxime Eyes - Severe irritant Rabbit - 100 microliters
phthalic anhydride Eyes - Moderate irritant Rabbit - 24 hours 50 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
phthalic anhydride skin Guinea pig Sensitizing
Mutagenic effects
No known significant effects or critical hazards.
Carcinogenicity
Reproductive toxicity
Teratogenic effects
Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
white spirit Category 3 Not applicable. Narcotic effects
phthalic anhydride Category 3 Not applicable. Respiratory tract irritation
Specific target organ toxicity (repeated exposure)
white spirit Category 1 Inhalation central nervous system (CNS)
Aspiration hazard
Safety Data Sheet
Product/ingredient name Result

white spirit ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure

Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Product/ingredient name Carcinogenic effects Mutagenic effects Developmental effects Fertility effects
2-butanone oxime Carc. 2, H351 - - -
cobalt bis(2-ethylhexanoate) - - - Repr. 1B, H360F
(Fertility)
Sensitization : Contains 2-butanone oxime, cobalt bis(2-ethylhexanoate), phthalic anhydride. May produce an allergic
reaction.
Other information : No additional known significant effects or critical hazards.
SECTION 12: Ecological information
12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
white spirit Acute EC50 4.6 - 10 mg/l Algae 72 hours
zinc oxide Acute EC50 0.17 mg/l Algae - Pseudokirchneriella subcapitata 72 hours
- Exponential growth phase
Acute EC50 1 mg/l Daphnia - Pseudokirchneriella 48 hours
subcapitata - Exponential growth phase
Acute LC50 24600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
trizinc bis(orthophosphate) Acute EC50 0.8 mg/l Algae 72 hours
Acute EC50 2.44 mg/l Daphnia 48 hours
phthalic anhydride Acute EC50 >640 mg/l Fresh water Daphnia 48 hours
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
xylene - >60 % - Readily - 28 days - -
phthalic anhydride - 85.2 % - Readily - 28 days - -
Product/ingredient name Aquatic half-life Photolysis Biodegradability

xylene - - Readily
phthalic anhydride - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
white spirit 3 - 7.3 - high
xylene 3.12 8.1 - 25.9 low
zinc oxide 2.2 60960 high
trizinc bis(orthophosphate) - 60960 high
2-butanone oxime 0.63 2.5 - 5.8 low
cobalt bis(2-ethylhexanoate) - 15600 high
phthalic anhydride 1.6 3.4 low
12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.
12.5 Results of PBT and vPvB assessment

PBT : Not applicable.
vPvB : Not applicable.
12.6 Other adverse effects

Safety Data Sheet

SECTION 13: Disposal considerations
13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.
SECTION 14: Transport information
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information
ADR/RID UN1263 PAINT 3 III Yes. The environmentally

Class hazardous substance mark
is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Tunnel code (D/E)
IMDG UN1263 PAINT. (white spirit) 3 III Yes. The marine pollutant
Class mark is not required
when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E
IATA UN1263 PAINT 3 III Yes. The environmentally

may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards
14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.

Safety Data Sheet
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2
6: Flammable (R10)
9ii: Toxic for the environment
15.2 Chemical Safety Assessment

This product contains substances for which Chemical Safety Assessments are still required.
SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H360F May damage fertility.
H372 (inhalation) Causes damage to organs through prolonged or repeated exposure if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS] : Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4
Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4
Acute Tox. 4, H332 ACUTE TOXICITY (inhalation) - Category 4
Aquatic Acute 1, AQUATIC HAZARD (ACUTE) - Category 1
H400
Aquatic Chronic 1, AQUATIC HAZARD (LONG-TERM) - Category 1
H410
H411
H412
Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
Carc. 2, H351 CARCINOGENICITY - Category 2
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Repr. 1B, H360F TOXIC TO REPRODUCTION (Fertility) - Category 1B
Resp. Sens. 1, H334 RESPIRATORY SENSITIZATION - Category 1
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Skin Sens. 1A, H317 SKIN SENSITIZATION - Category 1A
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (inhalation) -
(inhalation) Category 1
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Safety Data Sheet
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN SENSITIZATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Safety Data Sheet
Hempalin Enamel 52140
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempalin Enamel 52140
Product identity : 5214000010
Product type : alkyd paint
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : buildings , metal industry, ships and shipyards.
Identified uses : Professional applications, Used by spraying.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 10 December 2022
Date of previous issue : 21 November 2022.
2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Skin Sens. 1, H317 SKIN SENSITIZATION
Carc. 1B, H350 CARCINOGENICITY
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects)
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H317 - May cause an allergic skin reaction.
H336 - May cause drowsiness or dizziness.
H350 - May cause cancer.
H372 - Causes damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Obtain special instructions before use. Wear protective gloves, protective clothing, eye protection, face
protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Avoid release to the environment. Do not breathe vapor, mist or spray.
Response : Collect spillage. IF exposed or concerned: Get medical advice or attention.
Hazardous ingredients : hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
2-butanone oxime
cobalt bis(2-ethylhexanoate)
phthalic anhydride
cobalt(2+) propionate
Supplemental label elements : Repeated exposure may cause skin dryness or cracking.
Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe spray or mist.
Restricted to professional users.

Safety Data Sheet

Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.
2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :
3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type
hydrocarbons, C9-C12, n- REACH #: 01-2119458049-33 ≥25 - ≤50 Flam. Liq. 3, H226 - [1] [2]
alkanes, isoalkanes, cyclics, EC: 265-185-4 STOT SE 3, H336
aromatics (2-25%) CAS: 64742-82-1 STOT RE 1, H372
Index: 649-405-00-X (central nervous system
(CNS)) (inhalation)
Asp. Tox. 1, H304
EUH066
titanium dioxide REACH #: 01-2119489379-17 ≥10 - ≤25 Carc. 2, H351 - [1] [*]
EC: 236-675-5 (inhalation)
CAS: 13463-67-7
Index: 022-006-00-2
xylene REACH #: 01-2119488216-32 ≥1 - ≤3 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
2-butanone oxime REACH #: 01-2119539477-28 <1 Acute Tox. 3, H301 ATE [Oral] = 100 mg/kg [1]
EC: 202-496-6 Acute Tox. 4, H312 ATE [Dermal] = 1100 mg/kg
CAS: 96-29-7 Skin Irrit. 2, H315
Index: 616-014-00-0 Eye Dam. 1, H318
Skin Sens. 1, H317
Carc. 1B, H350
STOT SE 1, H370
(upper respiratory tract)
STOT SE 3, H336
STOT RE 2, H373
(blood system)
cobalt bis(2-ethylhexanoate) REACH #: 01-2119524678-29 <0.3 Eye Irrit. 2, H319 M [Acute] = 1 [1]
EC: 205-250-6 Skin Sens. 1A, H317
CAS: 136-52-7 Repr. 1B, H360F
Aquatic Acute 1, H400
phthalic anhydride REACH #: 01-2119457017-41 ≤0.3 Acute Tox. 4, H302 ATE [Oral] = 1530 mg/kg [1]
EC: 201-607-5 Skin Irrit. 2, H315
CAS: 85-44-9 Eye Dam. 1, H318
Index: 607-009-00-4 Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
trimethylolpropane REACH #: 01-2119486799-10 ≤0.3 Repr. 2, H361fd - [1]
EC: 201-074-9
CAS: 77-99-6
calcium bis(2-ethylhexanoate) EC: 205-249-0 ≤0.3 Eye Dam. 1, H318 - [1]
CAS: 136-51-6 Repr. 2, H361d
zirconium octoate REACH #: 01-2119979088-21 ≤0.3 Repr. 2, H361d (oral) - [1] [2]
EC: 245-018-1
CAS: 22464-99-9
cobalt(2+) propionate REACH #: 01-2119532653-41 <0.1 Acute Tox. 4, H302 ATE [Oral] = 500 mg/kg [1]
EC: 216-333-1 Acute Tox. 4, H332 ATE [Inhalation (dusts and
mists)] = 1.5 mg/l
CAS: 1560-69-6 Eye Irrit. 2, H319 M [Acute] = 1
Skin Sens. 1A, H317
Repr. 1B, H360F
Aquatic Acute 1, H400
See Section 16 for the full text of the H statements declared
above.

Safety Data Sheet

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[*] The classification as a carcinogen by inhalation applies only to mixtures placed on the market in powder form containing 1% or more of titanium
dioxide particles with aerodynamic diameter ≤ 10 μm not bound within a matrix.
4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and
seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact : Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

Safety Data Sheet
SECTION 5: Firefighting measures
5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.
5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides
5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective
measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.
6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.
6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.
6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.
7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

Safety Data Sheet
8.1 Control parameters

Product/ingredient name Exposure limit values
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, EU OEL (Europe, 2000).

aromatics (2-25%) TWA: 25 ppm 8 hours.
xylene EU OEL (Europe, 1/2022). [xylene, mixed isomers] Absorbed through skin.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
zirconium octoate EU OEL (Europe, 2010).
TWA: 5 mg/m³, (as Zr) 8 hours.
Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type Exposure Value Population Effects
hydrocarbons, C9-C12, n-alkanes, isoalkanes, DNEL Long term Dermal 21 mg/kg bw/day Workers Systemic
cyclics, aromatics (2-25%)
DNEL Long term Inhalation 330 mg/m³ Workers Systemic
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
2-butanone oxime DNEL Long term Inhalation 9 mg/m³ Workers Systemic
DNEL Long term Dermal 1.3 mg/kg bw/day Workers Systemic
phthalic anhydride DNEL Long term Dermal 10 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 32.2 mg/m³ Workers Systemic
trimethylolpropane DNEL Long term Dermal 0.94 mg/kg bw/day Workers Systemic
zirconium octoate DNEL Long term Dermal 6.49 mg/kg bw/day Workers Systemic
cobalt(2+) propionate DNEL Long term Inhalation 21.9 µg/m³ General Local
population
DNEL Long term Oral 33.1 µg/kg bw/day General Systemic
population
DNEL Long term Inhalation 139.2 µg/m³ Workers Local
Predicted effect concentrations
Product/ingredient name Compartment Detail Value Method Detail
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Marine water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
Sewage Treatment Plant 6.68 mg/l -
ethylbenzene Fresh water 0.1 mg/l -
Soil 2.68 mg/kg -
n-butyl acetate Fresh water 0.18 mg/l -
Marine 0.018 mg/l -
Soil 0.0903 mg/kg -
cobalt bis(2-ethylhexanoate) Sewage Treatment Plant 0.37 mg/l -
Fresh water 0.62 µg/l -
Marine water 2.36 µg/l -
Fresh water sediment 53.8 mg/kg dwt -
Marine water sediment 69.8 mg/kg dwt -
Soil 10.9 mg/kg dwt -
phthalic anhydride Soil 0.153 mg/kg -

Safety Data Sheet

Sewage Treatment Plant 10 mg/l -
Fresh water 1 mg/l -
zirconium octoate Sewage Treatment Plant 71.7 mg/l -
Soil 1.06 mg/kg -
Fresh water 0.36 mg/l -
dipropylene glycol methyl ether Fresh water 19 mg/l -
Fresh water sediment 70.2 mg/kg dwt -
Marine water sediment 7.02 mg/kg dwt -
Soil 2.74 mg/kg dwt -
Sewage Treatment Plant 4168 mg/l -
8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®, nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. When the product is applied by spraying and for continuous
or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or
a full face, powered air purifying filter. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

Safety Data Sheet
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : White
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : -66°C This is based on data for the following ingredient: hydrocarbons, C9-C12, n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 38°C (100.4°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.8 - 7.6 vol %
(flammable) limits :
Vapor pressure : 0.147 kPa This is based on data for the following ingredient: hydrocarbons, C9-C12, n-alkanes,
isoalkanes, cyclics, aromatics (2-25%)
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.084 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: 280 - 470°C (536 - 878°F) (hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics,
aromatics (2-25%)).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.
9.2 Other information

Solvent(s) % by weight : Weighted average: 40 %
Water % by weight : Weighted average: 0 %
VOC content : 431.5 g/l
TOC Content : Weighted average: 383 g/l
Solvent Gas : Weighted average: 0.088 m³/l
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability

The product is stable.
10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.
10.5 Incompatible materials

Reactive or incompatible with the following materials: oxidizing materials.
Slightly reactive or incompatible with the following materials: reducing materials.
10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:

Safety Data Sheet

Decomposition products may include the following materials: carbon oxides metal oxide/oxides
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.8 mg/l 4 hours
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
2-butanone oxime LD50 Dermal Rabbit 1001 mg/kg -
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >2000 mg/kg -
phthalic anhydride LD50 Dermal Rabbit >3160 mg/kg -
trimethylolpropane LD50 Oral Rat 14100 mg/kg -
zirconium octoate LC50 Inhalation Dusts and mists Rat >8800 mg/m³ 1 hours
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempalin Enamel 52140 26528.1 48965 222568.3
xylene 3523 1100 5000
2-butanone oxime 100 1100
cobalt bis(2-ethylhexanoate) 3129
phthalic anhydride 1530
trimethylolpropane 14100
cobalt(2+) propionate 500 1.5
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
titanium dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
2-butanone oxime Eyes - Severe irritant Rabbit - 100 microliters
phthalic anhydride Eyes - Moderate irritant Rabbit - 24 hours 50 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
cobalt bis(2-ethylhexanoate) skin Mouse Sensitizing
phthalic anhydride skin Guinea pig Sensitizing
skin Mouse Sensitizing
Mutagenic effects
Carcinogenicity
May cause cancer. Risk of cancer depends on duration and level of exposure.
Reproductive toxicity

Safety Data Sheet
Teratogenic effects
Specific target organ toxicity (single exposure)

hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 3 Narcotic effects
aromatics (2-25%)
2-butanone oxime Category 1 upper respiratory tract
Category 3 Narcotic effects
phthalic anhydride Category 3 Respiratory tract irritation
Specific target organ toxicity (repeated exposure)
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 1 inhalation central nervous system (CNS)
aromatics (2-25%)
2-butanone oxime Category 2 - blood system
Aspiration hazard
Product/ingredient name Result
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, ASPIRATION HAZARD - Category 1
aromatics (2-25%)
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains 2-butanone oxime, cobalt bis(2-ethylhexanoate), phthalic anhydride. May produce an allergic
reaction.
11.2 Information on other hazards
Endocrine disrupting properties : See Section 15 for details.
Other information : No additional known significant effects or critical hazards.
12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
hydrocarbons, C9-C12, n-alkanes, Chronic EC50 4.6 - 10 mg/l Algae 72 hours
isoalkanes, cyclics, aromatics
(2-25%)
Chronic EC50 10 - 20 mg/l Daphnia 48 hours
Chronic EC50 10 - 30 mg/l Fish 96 hours
titanium dioxide Acute LC50 >100 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
cobalt bis(2-ethylhexanoate) Acute LC50 0.1 - 1 mg/l Fish 96 hours
phthalic anhydride Acute EC50 >640 mg/l Fresh water Daphnia 48 hours
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
hydrocarbons, C9-C12, n-alkanes, OECD 301F Ready 74.7 % - Readily - 28 days - -
isoalkanes, cyclics, aromatics Biodegradability - Manometric
(2-25%) Respirometry Test
xylene OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
phthalic anhydride - 85.2 % - Readily - 28 days - -
trimethylolpropane OECD 302B Inherent 100 % - Readily - 28 days - -
Biodegradability: Zahn-Wellens/
EMPA Test
zirconium octoate - 99 % - Readily - 28 days 20 mg/l -

Safety Data Sheet
Product/ingredient name Aquatic half-life Photolysis Biodegradability

hydrocarbons, C9-C12, n-alkanes, - - Readily
isoalkanes, cyclics, aromatics
(2-25%)
xylene - - Readily
phthalic anhydride - - Readily
trimethylolpropane - - Readily
zirconium octoate - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics - 10 - 2500 high
(2-25%)
xylene 3.12 8.1 - 25.9 low
2-butanone oxime 0.63 2.5 - 5.8 low
cobalt bis(2-ethylhexanoate) - 15600 high
phthalic anhydride 1.6 3.4 low
trimethylolpropane -0.47 <1 low
calcium bis(2-ethylhexanoate) - 2.96 low
zirconium octoate - 2.96 low
cobalt(2+) propionate - 15600 high
12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.
12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Endocrine disrupting properties

See Section 15 for details.
12.7 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.

Safety Data Sheet
14.1 14.2 14.3 14.4 14.5

UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information
ADR/RID UN1263 PAINT 3 III Yes. The environmentally

is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Tunnel code (D/E)
IMDG UN1263 PAINT. (hydrocarbons, C9-C12, n- 3 III Yes. The marine pollutant
Class alkanes, isoalkanes, cyclics, mark is not required
aromatics (2-25%)) when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E
IATA UN1263 PAINT 3 III Yes. The environmentally

may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards
14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
Substances of very high concern
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Restricted to professional users.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2
15.2 Chemical Safety Assessment

Yes.

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration

Safety Data Sheet

Full text of abbreviated H statements : H226 Flammable liquid and vapor.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H351 Suspected of causing cancer.
H360F May damage fertility.
H361d Suspected of damaging the unborn child.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H370 Causes damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS] : Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 2 AQUATIC HAZARD (LONG-TERM) - Category 2
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Carc. 1B CARCINOGENICITY - Category 1B
Carc. 2 CARCINOGENICITY - Category 2
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 1B TOXIC TO REPRODUCTION - Category 1B
Repr. 2 TOXIC TO REPRODUCTION - Category 2
Resp. Sens. 1 RESPIRATORY SENSITIZATION - Category 1
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
Skin Sens. 1A SKIN SENSITIZATION - Category 1A
STOT RE 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SKIN SENSITIZATION Calculation method
CARCINOGENICITY Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Safe Use of Mixture Information
This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals for specialist applications, with good general room ventilation plus respiratory protection
This safe use information is : Professional spray painting, near-industrial setting
linked to Priority
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers
Operational conditions
Place of use : Indoor or outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions Assumes that activities are undertaken with appropriate and well maintained equipment by trained
personnel operating under supervision.
Others : Depending on actual conditions of application. Please consult your local HEMPEL representative
for further advise.
Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.
Loading of application PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
equipment and handling hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with
curing factor of at least 10. specific activity training.
Industrial application of PROC07 More than 4 Good general room 3-5 Use a properly fitted, air- Use eye protection Wear chemical-resistant
coatings by spraying hours ventilation - Outdoors purifying or air-fed according to EN 166. gloves (tested to EN374)
respirator. EN 14594 with in combination with
an assigned protection specific activity training.
factor of at least 20.
Film formation - force PROC04 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours ventilation - Outdoors according to EN 166. tested to EN374.
technologies
Cleaning PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
Waste management PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
See chapter 8 of this Safety Data Sheet for specifications.
The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 13/13

Method Statement of Pipe Painting Rev02

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Method Statement of Pipe Painting Rev02

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Method Statement for pipe painting

NEOM MOUNTAIN BASE CAMP PROJECT

Contract No. Document No.

Title: Page Rev No.

FOR PIPE PAINTING

NEOM MOUNTAIN BASE CAMP PROJECT

0 27/03/2022 Issued for Approval Abdelaziz Alaa Mutaz Raft

The scope of this method statement covers painting procedure of firefighting

4) Setup, maintain and troubleshoot blasting & coating equipment.

4) Demonstrate proper hand signaling techniques.

Preparation for pipes welded painting activity

sufficient manpower shall be arranged to carry out the work.

NEOM SPECIFICTION 210500 section 3.8

SSPC/NACE & ISO 8501.

- 01 Coat as a primer coat one layer.

10. Repair / Touch-Up of Damage Coated Surfaces.

12. Product data sheet.

As the following sheets

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.2 Label elements

Signal word : Danger

Version: 0.06 Page: 1/11

SECTION 2: Hazards identification

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

SECTION 4: First aid measures

4.1 Description of first aid measures

Version: 0.06 Page: 2/11

SECTION 4: First aid measures

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Version: 0.06 Page: 3/11

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

white spirit EU OEL (Europe).

Recommended monitoring procedures

Version: 0.06 Page: 4/11

SECTION 8: Exposure controls/personal protection

Predicted effect concentrations

8.2 Exposure controls

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

Version: 0.06 Page: 5/11

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials