0

-300 200 700 1200 1700 2200

-500

-1000

-1500

-2000

Ca-liq
-2500

-3000

-3500

DG0, kJ/mol S2
H2(g)+Cl2(g) →   2HCl(g) Reacciones ajustadas

2Ca(s)+Cl2(g) →2  CaCl(s)

Ecuaciones de las tablas Kubachewki.

∆G°T (cal)=A+BTlogT+CT

Reaccion A B C Rango de
temperatura
1/2{ H2} +1/2 -21,770 0,99 -5,22 [298,2100]
(Cl2)=(HCL)

<Cacl2>=<ca>+(cl2) 189,900 --- -340 [298,1055]

T=(298) , ∆G° (HCl)= -21,770+[0,99(298)log(298)]+(- 5,22*298)=

-847,39 cal

T=(2100) , ∆G° (HCl)= -21,770+[0,99(2100)log(298)]+( -5,22*2100)=

-4076,876 cal

2Ca(s)+Cl2(g) →2  CaCl(s)

T=(298) , ∆G° <Cacl2>= 189,900 + (-340*298)= -101130,1 cal

T=(1055) , ∆G° <Cacl2>= 189,900 + (-340*1055)= -358510,1

1cal=4,184J
T=(298), 2*∆G° T(HCl)= -1694,78cal*(4,184J*[cal ^(-1)])=-7,103kJ

T=(2100), 2*∆G° T(HCl)= -4076,876*(4,184J*[cal ^(-1)])=-17,057kJ

T(298) ,2*∆G°T<Cacl2>=202260,2cal*(4,184J*[cal ^(-1)])=-846,25kJ

T(1055) ,2*∆G°T<Cacl2>=717020,2cal*(4,184J*[cal ^(-1)])=-3000.01kJ

°C=K-273,17

°C=298-273,15=24,85

°C=2100-273,15=1826,85

°C=1055-273,15=781,85