Amines Part-02

Amines DPP-01

1. Arrange the following in decreasing order of boiling point :

(I) CH3CH2CH2OH (II) CH3CH2CH2NH2
(III) (IV) CH3CH2—NH—CH3

(V) CH3CH2CH2CH3
(1) I > II > IV > III > V
(2) III > IV > II > I > V
(3) I > V > II > III > IV
(4) II > I > III > IV > V

2. Which of the following compound cannot be formed by Gabriel phthalimide synthesis :

(1)

(2)

(3) (CH3)2CH—NH2
(4) (C2H5)(CH3)CH—NH2

3. On heating an aliphatic primary amine with chloroform and ethanolic KOH, the organic compound
formed is
(1) an alkyl cyanide
(2) an alkyl isocyanide
(3) an alkanol
(4) an alkanediol

4. Which of the following compound gives a product with foul smell when reacted with chloroform in
presence of an alkali?
(1) (CH3)2NH
(2) CH3NH2

(3)

(4)

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Amines Part-02

5. Which one can give propanamine on reaction with LiAlH 4 ?

(1) Propyl cyanide
(2) N-Methyl Propanamide
(3) Propane nitrile
(4) Both (1) & (3)

6. Find out the structure of compound 'A'

(1)

(2)

(3)

(4)

7. In a set of reactions propionic acid yielded a compound D.

The structure of (D) would be :

(1)

(2)

(3)

(4)

8. Gabriel reaction for the synthesis of amines, involves the use of

(1) 1° amide
(2) 2° amide
(3) Imide
(4) Aliphatic amide

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Amines Part-02

Answer Key
Question 1 2 3 4 5 6 7 8
Answer 1 1 2 2 3 2 2 3

SOLUTIONS DPP-01

1. Boiling point  intermolecular forces of attraction

H-bonding is stronger in alcohols as compared to amines.
In case of amines, order of boiling point 1° > 2° > 3°.
In case of alkanes, intermolecular forces of attraction is weakest.

2. 1° aromatic amine can't be prepared by Gabriel phthalimide reaction.

3.

4.

5.

6.

7.

8.

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Amines Part-04

Amines DPP-02

Br /CCl
1. C6H5NH2 ⎯⎯⎯⎯⎯
2 4
→ ?
The product is :-
(1) Only o– bromoaniline
(2) 2, 4, 6–triboromoaniline
(3) o–and p–bromoaniline
(4) Only p–bromoaniline

2. Aniline on treatment with bromine water yields white precipitate of :-

(1) o–Bromoaniline
(2) p–Bromonailine
(3) 2, 4, 6–Tribromoaniline
(4) m–Bromoaniline

3. The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was:-
(1) Methylisocyanate
(2) Methylamine
(3) Ammonia
(4) Phosgene

4. Using Fe/HCl, which one of the following reaction is possible [Here  = C6H5]
(1) –NO2 → -NH–NH–
(2) –NO2 → –NH2
(3) –NO2 → –NHOH
(4) –NO2 → –N=N–

5. Which of following is insoluble in alkali?

(1)

(2)

(3)

(4) All of these

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Amines Part-04

6. Which of following is water insoluble and stable at room temperature.

(1) C6H5N2Cl
(2) C6H5N2BF4
(3) C6H5N2HSO4
(4) All

7. Product is :-

(1)

(2)

(3)

(4)

8.

Product A is :-

(1)

(2)

(3)

(4)

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Amines Part-04

Answer Key
Question 1 2 3 4 5 6 7 8
Answer 2 3 1 2 1 2 2 3

SOLUTIONS DPP-02

1.

2.

3. Methylisocyanate [CH3–N=C=O]

4.

5.

(No acidic H)

6.

7.

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Amines Part-04

8.

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