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01. dil.
NaOH
(A) heat
(B)
O
(B) HCN
(C) (CH
2OH)2
(D) H
2 —Ni
(E)
+
(E) CHCl
(F)
3 /KOH
H
2 —Ni
(G) H
3O
(H)
+
(H) MeI
Salt (I) H
3O
(J) i)
PTS ii) CH3CH2I
salt (K)
+
(K) H
3O
(L) i)
PTS ii) PhCH2I
Salt (M)
+ _ _ +
(D) i) (N)
CH3MgI ii) H3O
(P) i)
i) dil. OH ii) heat
(Q)
CH2(COOEt)2/EtONa ii) EtO Na / CH3I
+
(Q) H (R)
3O / heat i)
CH3MgI (excess) ii) hydrolysis
(S) CH 3OH/ dry HCl
(T)
Structure of (T) is :
Me Me Me Me
O OMe
O Me
OMe (b) O O
(a) OMe *(c) OMe (d) Me
Me Me Me
Me Me Me Me
Me
+ _
N Me3I _ _
02. OH
, heat
(A) i) (B)
ozonolysis ii) OH , then heat
Ph
_ +
(B) + 2, 2—dimethyl cyclohexanone OH
(C) i)
Br2 (1eq)/H ii) LDA
Product is :
O
(a) (b)
O
O O
O
(c) (d)
O
O O
page no # 3
03. An organic compound (A) {C70H140On} on reaction with excess Ac2O gives a product
(B) {C84HmOp} of MW = 1594. (A) can decolourise Br2—H2O but can’t reduce Fehling
solution. (A) on reaction with Bayer’s reagent gives (C) {C70HqOr}. One mole of (C) on
reaction with excess MeMgBr produces ‘V’ litre of gas (X) at N.T.P. (C) on reaction
with excess Ac2O gives a product (D) of MW =MO .
Calculate the value of {Vn — (m + p + q + r + MO)} . Ans : 1975
04. If the reaction sequence given below is carried out with 15 moles of acetylene, the
amount of the product D formed (in g) is ________
05.M Considering the reaction sequence given below, the correct statement(s) is/are :
07. The number of - CH2 (methylene) groups in the product formed from the following
reaction sequence is : Ans : 0
08. The total number of chiral molecules formed from one molecule of P on complete
ozonolysis (O3, Zn/H2O) is _____. Ans : 2
page no # 4