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experiment, it turned purplish. Since NaOH has a pH level surroundings, which is an exothermic reaction. The energy
of 13 and KOH has a pH level of 10-13 (depending on the is usually transferred as heat energy, causing the reaction
concentration in water), they are strong bases, and their mixture and its surroundings to be hotter. An increase in
reaction with phenolphthalein (changing the color of temperature corresponds to an increase in average kinetic
solution into purple) is instant. In contrast, upon addition of energy of the particles in reacting mixture. This explained
phenolphthalein to bases NH4OH and milk of magnesia why the temperature of the solution increased when HCl
[Mg(OH)2], no visible changes occurred because the two was added to NaOH.
mentioned reagents were only weak bases, and HIn cannot
indicate their pH anymore. 4. Determination of pH
Table 4.1. Data Gathered in Determining the pH of
Substances.
Computed
Substance pH Comparison
pH
pH = 14 + Theoretical value is
0.1 M
10.46 log (0.1) = greater than actual
NaOH
13 value by 2.54.
Figure 2.1. Bases NaOH, KOH, NH4OH, and milk of Mg Theoretical value is
(from left to right) reaction with phenolphthalein indicator. pH = -log
0.1 M HCl 1.38 less than the actual
(0.1) = 1
value by 0.38.
On the other hand, the addition of Na2CO3 to basic Comparison of strong and weak acids/bases
solutions of NaOH and KOH because Na2CO3 and the two Substance pH Comparison
solutions have the same level of basicity (both are strong HCl 1.38 Strong acid
bases). The difference in concentration and level of basicity, Acids Acetic
5.35 Weak acid
however, caused the NH4OH and milk of magnesia acid
(Mg(OH)2) to change the color of Na 2CO3 to purple/pink as NaOH 10.46 Weak base
Bases
compared to the other two reagents, because the two NH4OH 2.6 Strong acid
solutions are weak bases. Using a pH meter, results showed that 0.1 M
NaOH has a pH of 10.46, which is a weak base, while 0.1 M
HCl has a pH of 1.38, which is a strong acid. The computed
pH of NaOH is 13, which is a strong base, while HCl has a
computed pH of 1, which is a strong acid. Acetic acid
showed a pH of 5.36, which is a weak acid, while NH 4OH
yields a pH of 2.6, which is a strong acid.
The pH is a measure of hydrogen ion concentration
Figure 2.2. Bases NaOH, KOH, NH4OH, and milk of Mg
(from left to right) reaction with Na2CO3 in solutions, which shows whether a solution has acidic or
basic nature (Johnson, 2018). It is a log scale based on 10,
3. Determining the Temperature Changes During pH = -log [H+] which means that when the hydrogen
concentration of a solution is increasing, its pH is
Neutralization
Table 3.1. Data Recorded in Determining the Temperature decreasing (Zumdahl & Zumdahl, 2012).
Johnson (2018) explained that strong acids are
Changes During Neutralization.
those that completely dissociate in an aqueous solution and
Substance Temperature Observation
thus release hydrogen (H+) or hydronium (H3O+) to the
Acid (HCl) 34 °C Colorless solution, and generally. It has a pH range of a zero to three.
solution Meanwhile, a weak acid is one that does not ionize
Base (NaOH) 34 °C Colorless completely and has pH range of about five or just below
solution seven. Strong bases are also those that ionize completely,
Acid + Base 39.5° C The temperature but instead release hydroxide (OH-) to the solution. Strong
increased bases generally range from 12-14 pH values. Lastly, weak
Hydrochloric acid and sodium hydroxide solution bases are those that also do not ionize completely, and their
both appeared colorless and has a temperature of 34°C pH range goes somewhere between seven to ten.
(room temperature). When they were combined, the heat Hydrochloric acid (HCl) is one of the seven
increased up to 39.5 °C, while the solution remained common strong acids, the others are: hydrobromic acid
colorless. (HBr), hydroiodic acid (HI), sulfuric acid (H2SO4), nitric
When acids and bases are mixed, neutralization reaction acid (HNO3), perchloric acid (HClO4), and chloric acid
occurs. Neutralization reaction is when an acid and a base (HClO3) (Helmenstine, 2019). Theoretically, it has a pH
react to form ions that generate water and salt. Bonds are value of 1. The actual value of HCl, 1.38, was close to this
being made and energy is being released to the
Principle of Chemistry Laboratory (CHEM 1102 LAB)
Department of Chemistry
-5-
value. Meanwhile, sodium hydroxide is one of the strongest Write the chemical HC l (aq )+ NaO H ( aq) →
bases, which are generally hydroxides of group 1 and 2. equation
NaC l (aq )+ H 2 O(l)
Computation for the value of NaOH yields a result of 13.
The actual result is less than the theoretical value; It may be As shown in table 5.1, the HCl needed 0.6 mL of
because of some errors, like failure to calibrate the pH meter NaOH to completely neutralize or reach its endpoint, which
accurately, or because of human errors. turned into a bright color pink because phenolphthalein was
used as an indicator. The end point of a titration is the point
at which the indicator changes color. When phenolphthalein
is used as an indicator, the start will be a colorless solution,
and the end point will be signified by a pink color,
indicating that the solution turned from a basic to acidic
solution.
where HA is the acid, BOH is the base, and AB is the salt. Observation
There are three kinds of salts: the neutral, the basic, and the The CaCl2 were converted into liquid brine after some
acidic. Neutral salts are formed by strong acids and bases, time
basic salts are formed by weak acids and strong bases, while After leaving solid CaCl2 exposed to air after some
acidic salts are formed by strong acids and weak bases. time, the substance became liquified.
Sodium Chloride is formed by the reaction of HCl, Deliquescence is the process wherein a substance
a strong acid, and NaOH, a strong base. absorbs moisture from the atmosphere until a solution form.
HCl + NaOH H2O + NaCl It occurs when the partial pressure of water vapor in the air
Because of this, NaCl is considered a neutral salt, is greater than the vapor pressure of the solution formed
which explains why it made no reaction with all the (The Editors of Encyclopaedia Britannica, 2014).
indicators used. In this experiment, since CaCl 2 is very
Sodium acetate is formed by the reaction of deliquescent, it forms liquid brine when exposed to air as
CH3COOH, a weak acid, and NaOH, a strong base. time goes by. A brine is a solution with high concentration
CH3COOH + NaOH ↔ CH3COONa + H2O of salt.
Therefore, sodium acetate is considered a basic
salt, and this is the reason why the red litmus paper turned
into blue, because basic conditions turn litmus papers into
blue. Its basicity is also the reason why its color turned into
pink in the presence of phenolphthalein, because
phenolphthalein indicators turn to pink in basic solutions.
However, it made no reaction with sodium carbonate
because sodium carbonate is a basic salt as well, formed by
NaOH and H2CO3.
Sodium bisulfate, on the other hand, is formed by
the reaction of NaOH and H2SO4. Figure 7.1. Calcium chloride before deliquescence (left)
H2SO4 + NaOH NaHSO4 + H2O and calcium chloride after deliquescence (right)
However, although it came from a strong acid and
strong base, it is an acid salt. This is because H 2SO4 can 8. Examination on the Process of Efflorescence
further ionize and form H3O+, making it acidic. Table 8.1. The Effect of Efflorescence to ZnSO4.
NaHSO4 Na+ + HSO4- Observation
HSO4- + H2O SO42- + H3O+ The ZnSO4 was pulverized.
Due to its acidic nature, it turned the blue litmus
Efflorescence is a process of spontaneous loss of
paper into red, because acid conditions have the capacity to
water from a hydrated salt, which happens when the partial
turn litmus papers to red. It had no reaction with
pressure of the water vapour in the air is less than the
phenolphthalein because phenolphthalein do not change
aqueous vapor pressure of the hydrate (The Editors of
colors in acidic conditions, in fact, it becomes clearer in
Encyclopaedia Britannica, 2019). Zinc sulfate appears
acidic conditions. Sodium bisulfate became a pink solution
geologically as a white crumbly salt, and when it undergo
in the presence of Na2CO3 because Na2CO3 decomposes in
efflorescence process, it is known as “goslarite”, which is a
the presence of acidic conditions, turning into a pink or
heptahydrate of zinc sulfate.
violet solution, which made it an indicator of acids.
Since efflorescence simply means dehydration,
certain sulfate compunds, such as zinc sulfate that is used in
the experiment, can substitute metals as they lose water.
water of crystallization are called hydrates (Helmenstine, hydrated salt. Hydrated salts happen because of water of
2018). crystallization, where water molecules become bound within
Copper sulfate, in its pure form, is a white substance. the system of a salt crystal.
However, its most common form is its hydrated form; that
is, copper sulfate pentahydrate (CuSO4·5H2O), which is a References
blue compound.
Copper sulfate pentahydrate was made pure by
heating, which caused it to become a white powdery
substance. When copper sulfate was heated, the water
molecules bound to the crystals evaporated and left the
crystals, leaving only the pure copper sulfate. Upon addition
of water, however, water molecules entered the system
again, making it blue in color once again.
Conclusions
According to the Bronsted-Lowry definition of acids
and bases, acids are substances that donate protons in a
solution, while bases are substances that accept those
protons. The pH is a scale that shows the acidity or basicity
of a substance; the lower the pH is, the higher the acidity of
a substance is. Neutralization reaction is a process where
acids and bases are mixed to form a solution, which always
result to an exothermic reaction. Titrations are processes
done to neutralize an acid or a base, which is done with the
aid of indicators to indicate if a shift from an acid (or base)
to a base (or acid) already happened. When acids and bases
react together, they form water and salt. Salts formed can be
acidic, basic, or neutral, depending on the nature of the acid
and base formed. Acidic salt forms from a strong acid and a
weak base, basic salt forms from a weak acid and a strong
base, and neutral salts form from a strong acid and a strong
base. Deliquescence is the process wherein a salt absorbs
water from the atmosphere and forms a solution, while
efflorescence is the process wherein water is lost from a
Principles of Chemistry Laboratory (CHEM 1102 LAB)
Department of Chemistry
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Chang, R. (2010). Chemistry 10th ed. New York: The McGraw-Hill Companies, Inc.
Helmenstine, A. M. (2018, August 4). Water of Crystallization Definition. Retrieved from ThoughtCo.:
https://www.thoughtco.com/definition-of-water-of-crystallization-605786
The Editors of Encyclodaedia Britannica. (2018, November 23). Phenolphthalein. Retrieved from Britannica:
https://www.britannica.com/science/phenolphthalein
The Editors of Encyclopaedia Britannica. (2014, January 27). Deliquescence. Retrieved from Britannica:
https://www.britannica.com/science/deliquescence
The Editors of Encyclopaedia Britannica. (2019, August 07). Efflorescence. Retrieved from Britannica:
https://www.britannica.com/science/efflorescence
Zumdahl, S., & Zumdahl, S. (2012). Chemistry: An Atoms First Approach. United States of America: Brooks/Cole Cengage
Learning.
Questions:
1. What are some differences between acids and bases?
(Name at least 3)
Answer: First, acids are sour while bases are bitter.
Second, acids turn the blue litmus paper to red, while bases
turn the red litmus paper to blue. Lastly, acids have lower
pH levels, which means their [H +] are big, while bases have
higher pH levels, which means their [H+] are small.