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--
cCC

note: double bond _ ~~ n'' to be shown

1
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(d) -OC(CH 2 )..CONH(CH2)E NH-

11

(1) :~
amide lini<age correct; (1}
correct repeat tJnits; (1)
continuation bonds shown;
 - --- - - - - - - - - - - - - - -- - - - -· --- ----.

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3 (a) (i) M1 Contain carbon , hydrogen and oxygen (only) (11

. M2 hydrogen and oxygen is in a 2:1 ratio (or in the same ratio as water) (1)

(ii) M1 -0- linkage (1)

M2 3 monomer units with 3 blocks and 3 Oxygen atoms Cond [1]

-Q-o-Q-o-Q-o- •2 .....

I •

- o-0-p-Q-o-O-o- •l!Nlft

(b) catalyst . [1]

biological or protein (1]

(c) (i) C A B · [2]

ABC = = =
1 ACB 1 ,BCA 1' CBA 1 BAC = =0
Allow 70 for C, 40 for B1and 20 for A

(ii) M1 Energy mark: at higher temperature particles/molecules more have more energy or
move faster [1]

M2 Collision frequency mark: collide more frequently/often or more collisions per unit
time or higher rate of collisions. [1]
Ignore: 'more collisions'

M3 Collision energy mark: more molec0l~s h~ve :8inough energy to react or more
I
collisions are above activation energy IIor successfu'
' I
(1)
111

(Ill) Crate zero or enzymes denatured (1)

[rotal: 12]
1,

11
110,1 l ~ 11
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 Save My Exams! - The Home of Revision
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[1]
4 (a) (I) CH:rCH=CH--CH3 (1)
(ii) one oorrect amide linkage between two rectangles (1)

oorrect sequencing of a second amide link and monomers (1)

two oorrect amide links and rest of structure correct (induding additional
monomers if seen) and oorrect oontinuation bonds (1) [3]

0 0
II n
-c C-N--D -N- 3nwtca
I - I
H H

(iii) protein or polypeptide or named protein (1) .[1] .

.(iv), addition: only the polymer or one product is formed (1)

oond~nsation: the polymer and a small molecule/ water/ HC l is formed ( 1) (2)

'·
(b) (i) does not break down or rot or deoompose (1)

by n:1icrobes or fungi or bacteria or by living organisms (1) [2]

(ii) Any th~ from: [3]

visual pollution (1)

(shortage of) landfill sites (1)

danger to wildlife/ animals (in duding at sea) · ( 1)

toxic gases when burnt or greenhouse gases produced when burned (1)

(c) Any two from: [2]

resistant to oorrosion / unreactive to water I more durable (1)

' lighter/ less dense (1)

easier to manufacture/ can be moulded (1)

good insulator I keeps the water cold (1)

[Total: 141
 11 ·1 jJ,ril I
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1
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or
1

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7 (a) burning I , :I
produces toxic gases / harmful to health 1
increases greenhouse gases / global wanning
reduces visual pollution / litter .
reduces risks to wildlife l1' .· ,1 I

sho~ge of lan~~l'f ~it~s ' r educes space needed.in landfi!I ~:ites / ~Yes space
1

non-b1odegrad~bl~ ltl,~ng time to rot / decompose / accumulates waste

b~ming ~~~]I o~ energy / 1~sed to g,enerate electr~city ·

recycl~~-111 1 . I

C?nserves ~~ol~u?1 { nijt~ral1,resources , . - ·

difficult to ~ ytl;,/ Mx~ns1ve / takes much ,energy
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recycllng I I 1

1 [4J
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(b) (i) addition (polyme~isation);. [1]

I

(polymer) onl~Ip~1:11ct / ~o by-products; [1]

condensation ir ~'il 'l'Ili

;fj5~1:1
(polrr~ '' . [1]

(polymer and) sim~~ , .• 11 I• , ~~-r1i _hydrogen chloride/ one other product~; [1)
II, !!I • .
1
1

a correct linkage (f~~I , ·, .

. ' • . li 11 11 l 1 I I ' 1 11 11 I
1

~,r~;-,
1

(II) I, .1 _ [1.)
1

1 1
two different mo•n
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_. ,~ 11 ,_I 11

II I : ! • . I 1, !: I 1
'1 I 1'
,f' I II ,,!' I '\if 1 [Total: 10}
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11:

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