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A review on additive manufacturing of SS-Ni multi-material fabrication


Rupendra Singh Tanwar, Suyog Jhavar ⇑
School of Mechanical Engineering, VIT-AP University, Inavolu, Beside AP Secretariat Amaravati, Andhra Pradesh 522237, India

a r t i c l e i n f o a b s t r a c t

Article history: Additive manufacturing (AM) is an emerging technology used to fabricate complex and near net shape
Available online xxxx components with minimum tooling and material wastage. This technology has found its application in
biomedical, aerospace, automobile and structural elements. Multi material additive manufacturing
Keywords: (MMAM) process is able to manufacture components built with a combination of different materials like
Multi-material AM metals, ceramics, and reinforced materials to achieve the desired properties at a specific location. Many
LPBF multi-material combinations have been fabricated through MMAM such as Al-Fe, Al-Cu, SS-Ni, Ni-Ti, Ti-
WAAM
SS, diamond-W-Cu etc. The most common combination among these discussed materials are SS-Ni multi-
DED
SS/Ni multi-material
material for its wide range of applications in gas turbine parts, energy industry, petrochemical industry,
Microstructure marine industry, nuclear fission reactors, aerospace structure and aerospace engines. The processing of
Mechanical properties SS-Ni multi-material using LPBF, DED and WAAM has been found to provide superior properties such
as high strength at extreme temperature environment, corrosion resistance, oxidation resistance, higher
toughness at low cost when compared with conventional manufacturing methods thereby, motivating
the present review on SS-Ni multi-material AM. This review aims to summarize the various methods
used for the fabrication of SS-Ni multi-material AM, different combination strategies and its effect on
the quality of fabrication, their microstructure variations, property enhancement, challenges and
applications.
Ó 2023 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the International Conference on Advances in Smart
Materials, Chemical & Biochemical Engineering.

1. Introduction method classified based on binding mechanism, type of feed stock,


and nature of heat source. In metal AM feedstock is either in the
The manufacturing world is ever-changing, emergence of state- form of powder [5] or wire [6] is completely melted by heat source
of-art of manufacturing technology is most significant driver for (laser or electron beam) and transformed into net near shape solid
this continuous change. Combined with other trends such as per- using layer by layer approach [7]. The most eminent metal AM pro-
sonalization, servitisation, and prosumption, the dawn of additive cesses are powder bed fusion (PBF) [8], Laser Direct Energy Depo-
manufacturing as on demand manufacturing process is leading sition (LDMD) [9], wire arc additive manufacturing (WAAM) [6],
manufacturer to emend where and how performed manufacturing laser direct metal deposition (LMD) [10], laser engineered net
activities. Additive manufacturing (AM), is a process of fabricating shaping (LENS) [11]. Despite different AM methods, all AM method
3-dimensional object of intricate shapes such as colling channels follows same approach: it starts with 3D CAD model, it is created
with minimum tooling at lowest material waste, successive layers on computer, created model is sliced into thin layers generally
of materials deposited to one over other followed by the CAD layer thickness from 20 lm1 mm [12].
model [1,2]. AM has a potential to replace all conventional manu- Each metal AM method has its strength and shortcomings, such
facturing methods, AM process reduce the need of tooling, gives as laser or electron beam powder bed fusion (PBF) can achieve
design flexibility and customization of product as compared to high-geometric accuracy fabrication depends on their high energy
conventional manufacturing methods [3]. Last decade grabs a lot densities, with this it has some limitations such as expensive
of attention towards AM because of its intrinsic advantages such equipment, low production efficiency, and narrow range of pro-
as less processing time and high material utilization [4]. AM cessing parameters. Moreover, high reflective material, recycling
of powder, health hazards also limit the use of laser PBF, high
energy density also a serious cause of defects such as pores, cracks,
⇑ Corresponding author.

https://doi.org/10.1016/j.matpr.2023.03.044
2214-7853/Ó 2023 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the International Conference on Advances in Smart Materials, Chemical & Biochemical Engineering.

Please cite this article as: R. Singh Tanwar and S. Jhavar, A review on additive manufacturing of SS-Ni multi-material fabrication, Materials Today: Proceed-
ings, https://doi.org/10.1016/j.matpr.2023.03.044
R. Singh Tanwar and S. Jhavar Materials Today: Proceedings xxx (xxxx) xxx

harmful interface reactions, and ceramic particle dissolution. As try, automotive, aerospace, offshore industries, nuclear, supportive,
compared to PBF, wire arc additive manufacturing (WAAM) based and structural industry [18]. SS based alloys has high affinity with
on arc welding, low-cost technology, which offers high deposition adjacent substance because of high solubility of principal elements
rate, good adoptability to process, materials, and environment and (Fe, Cr and Ni) even towards the precipitate elements [23] whereas
high handling mobility. Therefore, WAAM is suitable for manufac- steel-based alloys available at low cost. Using the advantage of
turing large components at low cost, for moderately complex both material and overcome the shortcoming by fabricating
geometries [6,13] with this it has also limitations such as in-situ bimetallic or FGM components. Fabricating Stainless steel and Ni
product has less surface roughness, heat treatment required, based alloys bimetallic or FGM component gives high mechanical
porosity, oxidation. strength, excellent corrosion resistance at elevated temperature
The pure metal gives specified value of mechanical properties, it [24]. SS-Ni alloys are two widely used metals for bimetallic or
is modified or improved by alloying of pure metals with other met- FGM structures in power generation, aerospace, chemical, petro-
als or non-metals. Fig. 1 shows comparison of pure metal, conven- chemical, and marine applications [25,26].
tional alloying, and multi-metal structure. Now a days engineering This paper discusses different metal AM processes such as pow-
applications urge metallic material with improved, customized, der bed fusion, direct energy deposition, and wire arc additive
and site-specific properties that alloy or pure metal could not sat- manufacturing used to fabricate SS-Ni multi-materials, applica-
isfy [14]. With the development of engineering and societal needs, tions, microstructure. All the above method modified form of
single-material product cannot fulfil the customize requirements. multi-metal additive fabrication. Challenges occurs during the
Customized product fabricated using multiple materials has a bet- multi-material fabrication such as optimization of parameters to
ter application possibility due to combination of excellent proper- fabricate defect free component. This review gives the insight of
ties of different materials. Multi-material AM (MMAM) has a microstructure and mechanical properties such as tensile strength,
capable to deal with wide range of materials and fabricate multi- hardness, wear behaviour substrate preheat and addition of carbon
material component. AM method can tailor the compositions at fibre and other material elements added in SS-Ni to improve prop-
user specified locations, it alters the properties such as strength, erties of SS-Ni AM components.
hardness, corrosion resistance, wear resistance in a single compo-
nent at a desired position and desired amount [13]. 2. Overview of multi-metal additive manufacturing (MMAM)
Bimetallic structure, combining two distinct metals and func- methods
tionally graded material (FGM), varying in proportion of materials
[15] it varies microstructure, mechanical properties with position AM is a process of fabricating 3D object by joining of materials
there have many multi-metal combinations fabricated through using layer-by-layer approach. It is opposite to subtractive manu-
various AM processes such as Al-Fe [16], Al-Cu [17], SS-Ni [18], facturing methods [27]. Fig. 2 (a-c) represents various methods
Ni-Ti [19], Ti-SS [20], diamond-W-Cu [21]. Ni based alloys has a used for multi-mateiral AM. For fabricating SS-Ni multi-material
wide range of applications due to its excellent properties such as using different AM method such as LAM-DED [5,10], Laser Engi-
high toughness, high hardness, and high hot strength. With this neered Net Shaping (LENS) [28], PBF [8], WAAM [29]. Powder
many other properties like can be used for wide range of temper- Bed Fusion (PBF) is also called selective laser melting, in this
ature, high corrosion resistance, at elevated temperature shows method focused energy heat source (laser or electron) is used to
phase stability, and better creep resistance. As a result of that melt powder which is on a substrate. For manipulating position
broad range of applications particularly in powder industries, of heat source, a system of lens and mirrors are used. Power, scan
defence, space shuttle engines, nuclear, and aerospace [22] speed, scan strategy etc. play important role in the final fabricated
whereas Ni based alloys has high cost. SS based alloys also has a component. For multi-material fabrication use two powder supply
wide range of applications because of its unique properties like chambers, two excess powder collecting pots, with one roller or
strength, hardness, toughness, excellent weldability. Hence finds soft powder distribution coater blade which spread the powder
many applications in distillation industry, phosphoric acid indus- on a build surface or bed. The powder is taken from the supply

Fig. 1. Methods of material preparation.

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R. Singh Tanwar and S. Jhavar Materials Today: Proceedings xxx (xxxx) xxx

Fig. 2. Multi-metal AM methods (a) powder DED, (b) twin wire arc AM and (c) powder bed fusion.

chamber and spread on the substrate using coater, after melting of bimetallic component, first blown one material powder for a cer-
powder by beam, un-melted powder collect in a collecting pot by tain height, after that next material is supplied [20].
coater and next metal powder is spread on a substrate and the WAAM is also a part of DED processes, WAAM is budding
whole process repeat itself until the whole component not fabri- technology it uses electric arc as a heat source for fabricating
cated. After completing each layer fabrication powder bed lowers metallic component, WAAM got extensive attention from indus-
and powder supply bed moves up. Generally, argon gas used for trialist and experts due to its unique qualities such as high depo-
shielding in case of laser heat source and vacuum is maintained sition efficiency at low cost, flexibility, unlimited deposition
in case of electron beam heat source [8]. capacity, environmental friendliness [33]. The electric arc gener-
In DED process the FGM and bimetallic component fabricated ated by different arc welding methods such as gas tungsten arc
using two or more than two powders, the gas atomized alloy pow- welding (GTAW), gas metal arc welding (GMAW), plasma arc
der with some specific size in range of 45 – 106 lm used as a feed- welding (PAW) each one has distinct set of advantages and limi-
stock material. The DED process accomplished CNC platform tations with respect to productivity, material properties and res-
combines with laser or electron beam and two or more powder olution [34]. Wire feed speed, voltage, current, travel speed, gas
feeders a schematic diagram as shown in Fig. 2(a) [26]. Laser flow rate, and nozzle-to-work distance are important parameters
power, scan speed, hatch distance, hatch rotation angle, contact for defect free fabrication [35]. multi-material component fabri-
tip to work-piece distance (CTWD) and powder feed rate also cated using two or more than two wires called twin wire
important during DED fabrication. The mixing of two powder has (T-WAAM) a schematic diagram as shown in Fig. 2(b) [36].
been done in a mixing chamber or supplied individually [30,31]. Initially root-pass and inter-pass layers produced using material
Powders blown from feeder counts individually using argon gas A wire, after certain layers of welding passes, material B
with a specified feed rate. Laser and powder feeding are co-axial, deposited on it to fabricate bimetallic component. During this
as powder blown on a surface and melted simultaneously it form deposition process generally, argon is supplied as a shielding
a layer. If it is FGM component the certain volume fraction of gas [37]. Table 1 presents a brief overview of different AM
one material powder increases and other material powder methods used for fabrication of SS-Ni combinations, their pre
decreases after some specified number of layers [32]. In case of and post processing used in various literatures.

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Table 1
Various alloy combinations, AM methods and post processing.

AM methods Different SS-Ni Combination Pre or Post processing Author


PBF or SLM SS316L/IN718 — [42,56,60]
Liquid dispersed metal PBF SS316L/IN625 — [8]
Laser DED SS316L/IN718 — [24,26,40,46,51,52,53,58]
SS316L/IN625 — [28,47,54]
Laser Synchronous preheating [10]
SS316L/Carbon fibre/IN718 — [49]
SS420/IN718 — [39]
SS304L/IN625 — [57]
SS316L/Ni-Cr-B-Si — [5]
SS304L/No-20Cr — [32]
AISI1045/IN718 — [26]
Laser DED + Thermal milling SS316L/IN718 — [50]
LENS SS316L/IN625 — [59]
WAAM SS321/IN625 — [44]
SS316L/IN625 [36]
SS316L/Nickel Aluminium Bronze(NAB) — [18]
SS316L/IN625 — [25]
RMD 248/ ERNiCr-3 — [43]
Electron Beam Melting 316L/IN718 — [55]
3D plasma metal deposition SS316L/Ni80-20 and SS316L/Ni 625 — [45]

3. Microstructure and mechanical properties of SS-Ni additively eters. [45] fabricated SS316L and Ni based alloy using 3D plasma
manufactured components metal deposition, on the macroscopic scale, lack of fusion observed
at the SS316L side whereas cracks at Ni625 side [46] secondary
In this section, discuss about the microstructure characteriza- dendrite arm spacing is observed in mixed portion of the sample
tion and evaluation of properties of SS-Ni multi-material part fab- and it depends on the laser power and metal powder feed rate in
ricated through various additive manufacturing methods such as laser DED [47] researcher uses two different strategy type-1
Laser PBF, Laser DED, electron beam PBF, laser engineered net (In625 on SS316L) gradual composition it results epitaxial growth
shaping (LENS), Wire arc additive manufacturing (WAAM). The due to SS316L has lower density and lower viscosity increases the
microstructure characterization has been done by scanning- remelting of SS316L to flow upward and mix with In625 whereas
electron microscopy (SEM), optical microscopy, X-ray diffraction in type-2 (SS316L on In625) abrupt composition results no epitax-
(XRD), electron back scattered diffraction (EBSD) etc. mechanical ial growth observed due contrary property of In625 with respect to
properties such as strength, hardness, fracture toughness, friction SS316L i.e., no mixing occurs. Researcher [32] fabricated NiCr and
wear behaviour evaluated by tensile testing, microhardness, tri- SS316L part using LDED, researcher found that hardness is the
bometer etc. function of NiCr percentage in a functionally graded component
in other words increases the percentage of NiCr hardness value
increases because NiCr rich region has FCC structure whereas SS
3.1. Microstructural characterization rich region has BCC structure [28] uniform interface region
achieved using LENS fabricated FGM component of SS316L and
For the fabrication of SS-Ni multi-material, different additive IN625, in the microstructure bcc ferrite, fcc austenite, carbide
manufacturing methods such as LPBF, SLM, EBM, LMD, WAAM, and martensite are found [48] found that columnar texture
LENS etc. used, [10,38] fabricated functionally graded material along h0 0 1i direction in both SS316L and IN718, it expects FCC
(FGM) of varying the percentage of either SS and Ni alloy and crystal structure when building direction aligned with compatible
Bimetallic components on metal over the other one. [38,39] uses grain growth for crystal structure. It is because of both material
Laser DED for the fabrication of SS420 and IN718, along the build shows coherent grain growth across interface.
direction found equiaxed grains in SS420 whereas IN718 shows To improve the properties of SS-Ni part researcher applied var-
columnar grains with dendrite structure. In mixed portion of ious strategies such as [49] researcher added carbon fibre between
SS420 and In718 shows has carbide and lave phases, carbide SS316L and IN718, due to carbon fibre large carbides formed, the
phases formed due to presence of reactive metallic element such addition of carbon fibre improves the wear resistant of the compo-
as Mo and Nb. [40] uses horizontal and vertical strategies for the nent [10] uses LMD integrated with preheating for fabrication of
fabrication of SS-Ni FGM part researcher found in both cases cellu- FGM part of SS316L and IN625, preheating leads to transformed
lar, and columnar dendrite structure found for horizontal gradient lave phases to carbide phases and achieve prominent columnar
sample and columnar and equiaxed for vertical gradient this differ- dendrites [50] there is no diffusion layer formed when applied a
ent structure because of colling rate and temperature gradient. thermal milling between the deposition of each powder. No ele-
Whereas [25,36] suggested during fabrication of bimetallic compo- ment segregation found on SS316L, whereas Nb segregation found
nent using WAAM, at the interface Cr is homogenously distributed on IN718. Researcher [51] performed numerical modelling and
at both metal side, while Ni, Nb and Mo more distributed towards experimental analysis for the printability and microstructure of
IN625 and Fe distributed more towards SS316L side. Using gradual SS316L and IN718 component using direct energy deposition, in
variation, no secondary phases such as metallic carbide and d- a multi-material component increase number of layers leads to
phase found. In other hand [41,42] uses SLM for the fabrication heat accumulation are more prone to compositional changes
of SS-Ni multi-material, researcher found that there is no carbide defects and distortion. While on the other hand, for initial layer
and lave phases observed. [43,44] founds tempered martensite, fabrication lack of fusion occurs due to heat loss through the sub-
carbides, tempered sorbite and retained austenite. The variation strate. Due to difference of CTE, last layer of IN718 is prone to dis-
in microstructure observed because of variation in welding param- tortion, whereas SS316L has lack of fusion and compositional
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R. Singh Tanwar and S. Jhavar Materials Today: Proceedings xxx (xxxx) xxx

change found for the initial layers [52] varying the percentage of value varies along the length of gradient zone [51]. Due to
one material during fabrication, there is irregular changes observed microstructure coarsening, hardness variation is observed in
it is due to segregation of material during solidification. As increas- multi-material part with increasing the number of layers more
ing the percentage of SS316L, Nb and Mo precipitation found along hardness observed at the IN718 side, it is because of higher yield
the length of cracks, whereas percentage of IN718 leads to lave strength of material matrix and laves intermetallic phases in the
phases. Increase the cooling rate hinder the growth of segregation mixed region remarkable changes are observed in microhardness
and lave phases. When fabrication starts, cooling rate is high it is because of the dilution of SS316L and IN718 mixed and solid-
because heat transferred quickly to substrate, it results less Nb seg- ified. Hardness reduces due to diffusion of solid-solution reinforced
regation and lave phases [41,53] there is no cracks or pores are particles. For a graded sample. Ultimate tensile strength, yield
observed during fabrication of IN718/316L using LMD because strength, and elongation is less than the single material it is
both materials are completely adhered to each other. Increasing because of difference in properties of materials it leads to defects
the percentage of IN718 gives deep dimple and sharp tearing edges and stress concentration. Researcher fabricated two sample
observed by fracture morphologies of tensile test [24] fabricated grade10 (i.e., variation of IN718 10% per layer) and grade25 (i.e.,
FGM component of different variation of IN718 and SS316L, there variation of Inconel 25%), grade25 has many deeper dimples are
are defects are found it is because of high laser irradiation oxida- found at the fracture surface it shows ductile fracture whereas
tion of ceramic compound Al2O3 and TiO2 are formed [18] using grade shows brittle fracture, it is because of pores and stress con-
WAAM, fabricated bimetallic component of Nickel-aluminium- centration by internal cracks.
bronze (NAB) with SS316L, liquification cracks are observed at The heat rate and feed stock rate plays an important role to fab-
the NAB/SS interface, these are intragranular cracks and propa- ricate a defect free component, these two parameters should be
gated in the heat affected zone direction. It is occurred due to phys- optimum, there are four possible cases such as 1) laser power
ical property (such as coefficient of thermal expansion, melting and powder feed rate both are low it leads to under-deposition,
point etc.) difference between NAB and SS alloy. Cracks can be min- 2) in the same if both parameters are high it leads to over-
imized by optimizing the heat input [42]. Multi-material SS316L deposition, 3) if laser power is low and powder feed rate is high
and IN718 fabricated through selective laser melting (SLM), there it leads to lack of fusion, and 4) if laser power high and powder feed
are very narrow region found at the interface it shows it has good rate low generated keyhole and porosity. Fig. 3 represents the rela-
bonding strength, some cracks and pores are observed through tionship between these paramters. Pitting resistance and corrosion
optical microscopy. Due to unmolten particles at interface, lower resistance reduces due to depletion of Mo and Nb during EBM AM
thermal stresses, nucleation, and growth of micro-voids occurs at of SS316L and IN718. LENS used to fabricate SS316L and IN718
the interface it leads to cracks at SS316L side [10] researcher multi-material component, from the microchemical analysis found
observed that more cracks are observed at the higher percentage that there is small variation in between theoretical and experimen-
of SS316L, it is because Mo and Nb precipitate formed. While in tal value it is because of SS316L not meted properly at the transi-
case of preheated sample no cracks are observed [8] uses liquid tion zone [59]. Cr and Ni content higher whereas Fe content lower
dispersed metal powder bed fusion to fabricate Inconel-steel alter- than the expected value [50] researcher uses hybrid additive man-
nate layers multi-metal part. Researcher concluded that by varying ufacturing (laser DED and thermal milling) for the fabrication of
the percentage of metal powder able to tailored the properties as bimetal steel and Inconel, for each metal powder deposition ther-
per requirement. Researcher [54] fabricated a component using mal milling applied to surface quality and dimensional accuracy
Laser Engineered Net Shaping (LENS), XRD analysis conforms, there achieved. The tensile properties of mixed material lower than the
is no variation in peaks for the gradient section it shows uniform both base metals, and fracture surface morphology similar to
microstructure [55] reported using EBM form a less precipitate as SS316L fracture morphology with large number of strip bulges
compared to DED for bimetallic component [38] reported that [42] fracture surface of the mixed region of SS316L and IN718
XRD analysis conforms the lave phases segregated with element SLM part shows dimples, flat ridges, sharp edges, and gradual
of Nb and Mo. [56] during production of IN718 and SS316L using ridge, it shows it has ductile and brittle fracture [40] researcher
LPBF, elemental diffusion of nickel concentration reduces whereas performed hardness and wear test for mechanical characterization,
iron concentration increases. microhardness increases as increase the percentage of IN718 due
to increase of Cr, Mo etc. content its effect on solid solution
3.2. Mechanical properties

Based on the literature review, various test has been performed


by the researchers such as tensile testing, wear testing, hardness
test and observe the fracture surface of SS-Ni multi-material fabri-
cated through different AM methods [39] researcher found that
mixed portion has lower hardness and tensile strength as com-
pared to the unmixed single alloy it is because of carbide and lave
phases weaken the mixed portion. Also found the optimum mixed
proportion to achieve highest strength and ductility [46]
researcher observed that tensile strength is proportional to mass
flow of powder rate whereas inversely proportional to laser power
[26] perform machinability test on SS316L and IN718 component,
at a section where IN718 content more than SS316L it shows
higher hardness and strength. It results it exhibit higher cutting
force and more heat is generated [57,58] using Laser DED fabri-
cated alternate layers of IN718 and SS316L, during the fabrication
researcher found sharp interface and gradual interface, sharp inter-
face found because of low laser power setting for IN718 deposition
it is not enough for SS316L, gradual interface found because of high
laser power and sufficient to melt both metals, the microhardness Fig. 3. Infulence of heat rate and feed stock rate in defect formation.

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R. Singh Tanwar and S. Jhavar Materials Today: Proceedings xxx (xxxx) xxx

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