University of Bahrain

Engineering College
Chemical Engineering Department
Process Instrumentation and Control Engineering

Analytical Measurement Systems II (PICENG-425) | 2nd Semester 2022/2023 | Dr. Ali Ridha Ali

May. 12, 2023 Assignment No.5 [10 points]

Question No.1: (1.5 points)

The spin quantum number for Hafnium nucleus of 177

72Hf is 7/2. Calculate the number of allowed
spin states and write them in a sequence.
Question No.2: (2.0 points)

What is the operating frequency (in MHz) of an H-NMR spectrometer if the device magnetic field
is 24 T?

Question No.3: (2.0 points)

For the energy difference between the transitions of 1H and 13C, fill the table below if the
magnetic field is 18 T. Note: 1 mole = 6.02214076×10²³ elementary entities.

𝜸 [rad/T.s] 𝚫𝐄 [J] 𝚫𝐄 [J/mole]

1
H: 2.6752×108
13
C: 6.7283×107
Question No.4: (1.0 point)

If the precession angular velocity of a nucleus is 270×106 rad/s, calculate Δ𝐸 observed in the H-
NMR spectrometer.

Question No.5: (3.5 points)

Consider the chemical compound given below. Find the following:

1. How many signals would appear in the H-NMR spectrometer? (0.5 point)
2. Which signal would be the most shielded and which signal would be the most de-
shielded? (0.5 point)
3. Which signal would be the tallest signal? (0.5 point)
4. Sort these signals according to their locations on the x-axis. (0.5 point)
5. Show the splitting pattern of each signal. (0.5 point)
6. Repeat the preceding five parts if the C-NMR spectrometer is used instead. (1 point)

𝐂𝐇𝟑 − 𝐂𝐇𝟐 − 𝐂𝐇𝟐 − 𝐂𝐥

[Good Luck]
Last Submission: May 20, 2023 @ 11:59 PM