GARDEN CITY UNIVERSITY

SCHOOL OF SCIENCES
ADVANCED ORGANIC CHEMISTRY -II
Course code: 02ABOC19513
V semester
Assignment questions
1) Write any two difference between enantiomers and diastereomers?
2) Explain any two methods of separation of enantiomers?
3) What are decalins? Write its structure.
4) Explain chemical method of cyclisation of geometric isomers?
5) What are diastereomers? Give examples.
6) Explain Gabriel thalimide synthesis?
7) What is diazotization? Give an example.
8) Why pyrrole undergoes electrophilic substitution reaction?
9) Write any one method of preparation of furan?
10) What are heterocyclic compounds? Give examples.
11) Explain the types of vibrations present in the molecule.
12) Mention the types of ionization modes involved in mass spectroscopy.
13) Mention any two differences between chromophores and auxochromes.
14) Name the reference compound used in NMR spectroscopy and Write its structure.
15) Mention any two factors which affects the chemical shift in NMR spectroscopy.
16) Mention the IR active and inactive vibrations in CO2 molecule.
17) Mention any two applications of mass spectrometry.
18) Explain the methods of determination of geometric isomers.
19) Explain Hoffman-Bromamide reaction.
20) What are coupling reactions? Give one example.
21) Explain skraup synthesis.
22) Explain any two methods of distinguishing : primary, secondary and tertiary amines.
23) Explain fischer indole synthesis.
24) Write the structure of quinoline. Mention the number of pi bonds present in it.
25) Explain the preparation of thiophene from acetylene and butane?
26) What is Bischler-Napieralski reaction?
27) Mention the formula for the frequency of vibration of two atoms? Explain its terminology.
28) Mention the fingerprint and function group ranges in IR spectroscopy.
29) Explain the principle of NMR spectroscopy?
30) Explain shielding and de-shielding effects with an example in NMR spectroscopy.
31) Explain the principle of mass spectrometry?
32) Why the name mass spectrometry given to the technique instead of spectroscopy.
33) State Hook’s law?
34) State Beer lambert’s law? Write its equation with explanation of the terms.
35) Write any two difference between bathochromic and Hypsochromic shifts?
36) What is Hyperchromic shift?
37) Draw the energy level diagram of various electronic transitions in uv -visible spectroscopy?
38) Mention the electronic transitions present in ethanol?
39) Draw the structure of quinoline?
40) Why pyrrole is aromatic in nature?

41) What is mutarotation?

42) Mention any two limitations of open chain structure of glucose.
43) Draw the structure of maltose? Mention the glycosidic bond present in it.
44) Give any two names of mono-cyclic terpenoids.
45) What are the therapeutic uses of caffeine?
46) Mention any two medicinal uses of cocaine.
47) State Beer lambert’s law? Write its equation with explanation of the terms.
48) Explain cis-trans conformations of disubstituted cyclochexanes with illustrations for each.
49) Explain the types of exchanges in Ficher projection that converts the molecule into identical and
enantiomer with illustrations.
50) Explain the structural elucidation of glucose.
51) Explain the structural elucidation of citral.
52) What is isoprene rule?
53) Explain the classification of terpenoids.
54) Draw the energy level diagram of various electronic transitions in uv -visible
spectroscopy?
55) Mention the electronic transitions present in ethanol?

56) What are diastereomers? Give examples.

57) Explain chemical method of cyclisation of geometric isomers?
58) Mention any two types of exchanges that converts the molecule into enantiomer.
59) Write any two uses of limonene?
60) Give any two names of mono-cyclic terpenoids.