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Energy is a fundamental concept of thermodynamics and one of the most significant aspects
of engineering analysis.
Energy is a familiar notion, and you already know a great deal about it. A basic idea is that
energy can be stored within systems in various forms. Energy also can be converted from one
form to another and transferred between systems. For closed systems, energy can be
transferred by work and heat transfer. The total amount of energy is conserved in all
conversions and transfers.
The total energy of a system is constituted by the sum of energy that can exist in numerous
forms such as kinetic, potential, internal, etc.
The two primary forms of energy are macroscopic and microscopic. The macroscopic forms
of energy are the kinetic and potential energy which a system possesses as a whole and with
respect to an outside reference frame. The macroscopic energy of a system is related to motion
and the influence of some external effects such as gravity. Kinetic energy is what a system
possesses because of its motion relative to some reference frame. Potential energy is the
energy that a system possesses because of its elevation in a gravitational field.
Lower value of
potential energy in
this reference frame
Higher value of
potential energy
due to higher
elevation in a
different
reference frame
Meanwhile, the microscopic forms of energy are the several forms of energy that are related
to the molecular structure of a system and the degree of the molecular activity. Microscopic
forms of energy are independent of outside reference frames.
Internal energy is the sum of all the microscopic forms of energy of a system that is related to
the molecular structure and the degree of molecular activity. It can be viewed as the sum of the
kinetic and potential energies of the molecules. Some forms of energy that make up the
internal energy of a system are the following:
Sensible energy: associated with the kinetic energies of the molecules.
Latent energy: associated with the phase of a system (solid, liquid, or gas).
Chemical energy: associated with the atomic bonds in a molecule.
Nuclear energy: the tremendous amount of energy associated with the strong bonds within
the nucleus of the atom.
Two common terms related to energy are mechanical and thermal energy which are
alternative or collective term for the fundamental forms of energy. Mechanical energy is the
combined form of energy that can be converted to mechanical work completely and directly.
Kinetic and potential energies are considered forms of mechanical energy. Meanwhile,
thermal energy is the form of energy that cannot be converted to work directly and
completely.
The absolute value of the total energy that a system possesses cannot be easily quantified. Only
the change in the total energy is accounted and this change is considered important in the
analysis of systems in engineering.
Kinetic energy and potential energy are constituents in the total energy of the system and can
be calculated from other properties of the system. Internal energy is also accounted in the total
energy of the system, but this can be determined based on other properties if the system like
pressure and temperature.
E total energy
U total energy
m mass
PE = mgz
g gravitational acceleration
Sample Problems
Sample Problem 1: Calculate the total potential energy, in kJ, of an object whose mass is 20
kg when it is located 20 m below a datum level in a location where g = 9.5 m/s 2.
Illustration:
m = 20 kg
h = 20 m
Required value:
Potential energy in kJ
𝐏𝐄 = 𝐦𝐠𝐡
𝐏𝐄 = 𝟐𝟎 𝐤𝐠 (𝟗. 𝟓 𝐦⁄𝐬 𝟐 )(𝟐𝟎 𝐦)
𝐏𝐄 = 𝟑𝟖𝟎𝟎 𝐉
𝐏𝐄 = 𝟑. 𝟖𝟎 𝐤𝐉
HEAT AND WORK AS ENERGY TRANSFER
Forms of energy can be classified as either static or dynamic. Static forms of energy can be
contained or stored in that system whereas dynamic forms of energy or energy interactions
cannot be stored in a system. The dynamic forms of energy are accounted when they cross the
system boundary and as energy gained or lost during a process. The two distinct dynamic
forms of energy are heat and work. Energy crosses the system boundary as heat when there is
temperature difference. Energy crosses the system boundary as work when it is not heat.
Heat as Energy Transfer
Heat is the form of energy that is transferred between two systems or a system and its
surroundings due to temperature difference. The direction of energy transfer as heat is
always from the higher temperature body to the lower temperature body. Energy transfer
stops when equal temperature is reached. Heat transfer cannot happen between two
systems that are at the same temperature.
Figure 2: Heat transfer between systems and between system and surroundings
System A System B
at higher at lower
Heat transfer
Surroundings at Surroundings at
lower temperature higher temperature
System System
at higher Heat at lower
Heat
Heat takes the same unit as energy. The amount of heat transferred during the process from
one state to another is denoted by “Q 1-2” or just “Q”. Heat transfer per unit mass of a system
is denoted “q”. The rate of heat transfer is the amount of heat transferred per unit time
denoted
by “Q̇ ”. The units of rate of heat transfer is joule/second (J/s) or watt (W).
Adiabatic process is a process when there is no heat transfer. A process becomes adiabatic
when the system is well insulated so that only a negligible amount of heat crossing the
boundary. Another reason is when systems or both the system and the surroundings are
at the same temperature.
Work as Energy Transfer
Work is an energy interaction between a system and its surroundings. When energy crossing
the boundary of a closed system is not heat, then it is work. Specifically, work is the energy
transfer associated with a force acting through a distance.
Applied force
Work as a form of energy takes the units of energy. The work done during a process between
one state to another is denoted by W1-2 or simply “W”. The work done per unit mass of
a system is
denoted by “w”. The work done per unit time is called power and is denoted by “Ẇ ” with
the unit joule per second (J/s) or watt (W).