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• The third law of thermodynamics states that the entropy of a perfect crystal at absolute zero is

zero.

• This means that the entropy of a system approaches a constant value as the temperature
approaches absolute zero.

• The third law of thermodynamics was first proposed by Walther Nernst in 1906.

The third law of thermodynamics has two important consequences:

• It defines the sign of the entropy of any substance at temperatures above absolute zero as
positive.

• It provides a fixed reference point that allows us to measure the absolute entropy of any
substance at any temperature.

The third law of thermodynamics is a fundamental law of nature that has many important applications in
our world. It helps us to understand the concept of entropy and to measure the entropy of substances in
a variety of environments.

Here are some examples of the third law of thermodynamics in action:

• The entropy of a perfect crystal at absolute zero is zero.

• The entropy of a substance approaches a constant value as the temperature approaches


absolute zero.

• The third law of thermodynamics can be used to measure the absolute entropy of any substance
at any temperature.

The third law of thermodynamics is a fundamental law of nature that has many important applications in
our world. It helps us to understand the concept of entropy and to measure the entropy of substances in
a variety of environments.

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