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Student: ___________________________________________________________________________
1.
2.
Which of the following is required for the determination of the VSEPR model and the molecular shape?
A. Atomic mass
B. Number of protons
C. Oxidation number
D. Lewis structure
E. None of the answers is correct.
3.
According to the VSEPR model, the predicted molecular geometry of the SO3 molecule is
A. pyramidal.
B. tetrahedral.
C. trigonal planar.
D. seesaw.
E. square planar.
4.
What is the predicted molecular geometry of the CH4 molecule according to the VSEPR model?
A. tetrahedral
B. trigonal pyramidal
C. trigonal planar
D. square planar
E. seesaw
5.
Using the VSEPR model, what is the predicted molecular geometry of the PCl3 molecule?
A. linear
B. bent
C. trigonal planar
D. trigonal pyramidal
E. tetrahedral
6.
What is the predicted molecular geometry of the H2O molecule according to the VSEPR model?
A. tetrahedral
B. trigonal pyramidal
C. bent
D. square planar
E. seesaw
7.
What is the predicted molecular geometry of the IBr3 molecule according to the VSEPR model?
A. tetrahedral
B. T-shaped
C. bent
D. trigonal planar
E. seesaw
8.
According to the VSEPR model, the molecular geometry of the carbonate ion, CO32–, is
A. square planar.
B. tetrahedral.
C. pyramidal.
D. trigonal planar.
E. octahedral.
9.
A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.
10.
According to the VSEPR model, the predicted molecular geometry of ammonia, NH3, is
A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.
11.
A. H2S
B. HCN
C. BF3
D. H2CO
E. SO3
12.
According to the VSEPR model, which molecule is predicted to have a molecular geometry that is trigonal
bipyramidal?
A. SF4
B. XeF4
C. NF3
D. SF6
E. PF5
13.
According to the VSEPR model, which molecule has a predicted tetrahedral molecular geometry?
A. XeF4
B. BF3
C. AsF5
D. CF4
E. NH3
14.
Using the VSEPR model, predict the molecular geometry around the central atom in PO43–.
A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral
15.
Using the VSEPR model, predict the molecular geometry around the central atom in SO32–.
A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral
16.
What is the total number of electron domains around the central atom for a molecule having a trigonal
pyramidal molecular geometry, such as NH3?
A. 5
B. 2
C. 3
D. 4
E. 6
17.
What is the total number of electron domains around the central atom for a molecule having a T-shaped
molecular geometry, such as BrF3?
A. 5
B. 2
C. 3
D. 4
E. 6
18.
What is the total number of electron domains around the central atom for a molecule having a square
pyramidal molecular geometry, such as ClF5?
A. 5
B. 2
C. 3
D. 4
E. 6
19.
What is the total number of electron domains around the central atom for a molecule having a square planar
molecular geometry, such as XeBr4?
A. 2
B. 3
C. 4
D. 5
E. 6
20.
What is the number of lone electron pairs on the central atom of a molecule having a seesaw molecular
geometry, such as SF4?
A. 1
B. 2
C. 3
D. 4
E. 6
21.
What is the number of lone electron pairs on the central atom of a molecule having a trigonal pyramidal
molecular geometry, such as NH3?
A. 1
B. 2
C. 3
D. 0
E. 4
22.
What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as CO2?
A. 1
B. 2
C. 3
D. 0
E. 4
23.
What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as ClF2–?
A. 1
B. 2
C. 3
D. 0
E. 4
24.
According to the VSEPR model, a molecule with the general formula AB3 with no lone pairs on the central
atom will have a ______ molecular shape.
A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. trigonal pyramidal
25.
According to the VSEPR model, a molecule with the general formula AB5 with no lone pairs on the central
atom will have a ______ molecular geometry.
A. tetrahedral
B. trigonal planar
C. trigonal pyramidal
D. trigonal bipyramidal
E. seesaw
26.
According to the VSEPR model, a molecule with the general formula AB2 with two lone pairs on the central
atom will have a _____ molecular geometry.
A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. seesaw
27.
According to the VSEPR model, a molecule with the general formula AB5 with one lone pair on the central
atom will have a ______ molecular geometry.
A. tetrahedral
B. trigonalbipyramidal
C. square pyramidal
D. octahedral
E. seesaw
28.
A. trigonal pyramidal
B. trigonal planar
C. tetrahedral
D. bent
E. linear
29.
What is the molecular geometry of the thiocyanate anion, SCN–, as predicted by the VSEPR model? (Carbon
is the central atom.)
A. linear
B. bent
C. tetrahedral
D. trigonal planar
E. trigonal pyramidal
30.
A. tetrahedral
B. bent
C. trigonal planar
D. linear
E. trigonal pyramidal
31.
A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal
32.
A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal
33.
A. trigonal pyramidal
B. square planar
C. square pyramidal
D. tetrahedral
E. octahedral
34.
A. trigonal pyramidal
B. bent
C. tetrahedral
D. linear
E. trigonal planar
35.
A. square planar
B. tetrahedral
C. square pyramidal
D. seesaw
E. octahedral
36.
A. linear
B. bent
C. seesaw
D. T-shaped
E. trigonal bipyramidal
37.
A. trigonal bipyramidal
B. octahedral
C. tetrahedral
D. seesaw
E. square pyramidal
38.
According to the VSEPR model, what is the predicted electron-domain geometry around the central iodine
atom in the ion lF2– ?
A. octahedral
B. trigonal bipyramidal
C. tetrahedral
D. trigonal planar
E. bent
39.
According to the VSEPR model, which one of the following molecules and ions will definitely have at least
one 90 bond angle in it? (In each case, except water, the central atom is the first one in the formula.)
A. AlCl4–
B. NH3
C. PCl5
D. CO2
E. H2O
40.
According to the VSEPR model, what is the predicted Cl–C–Cl bond angle in CCl4?
A. 90
B. 109.5
C. 120
D. 145
E. 180
41.
Which is the most reasonable prediction for the H–N–H bond angle in NH3?
A. 90
B. 109.5
C. 120
D. 107
E. 105
42.
A. 60
B. 90
C. 109.5
D. 120
E. 180
43.
Which is the most reasonable prediction for the H–O–H bond angle in H2O?
A. 90
B. 109.5
C. 120
D. 107
E. 105
44.
Which is the most reasonable prediction for the Cl–N–Cl bond angle in NCl3?
A. 120
B. 111
C. 109.5
D. 107
E. 90
45.
Which is the most reasonable prediction for the three F–Br–F bond angles in BrF3?
46.
Which is the most reasonable prediction for the H–C–H bond angle in CH4?
A. 90
B. 109.5
C. 120
D. 107
E. 105
47.
How do you describe the molecular geometry of a molecule that has more than one central atom?
A. You describe the molecular geometry around the most electronegative atom.
B. You describe the molecular geometry around each central atom separately.
C. You describe the molecular geometry around the most electropositive atom.
D. You describe the molecular geometry around the atom with the largest atomic radius.
E. You describe the molecular geometry around the atom with the largest bond angle.
48.
A. NH3
B. OF2
C. CH3Cl
D. H2O
E. BeCl2
49.
50.
A. CO2
B. PF3
C. KCl
D. IBr3
E. CHCl3
51.
A. CO
B. CH2Cl2
C. SO3
D. SO2
E. NH3
52.
A. PBr5
B. CCl4
C. BrF5
D. XeF2
E. XeF4
53.
A. linear, polar
B. linear, nonpolar
C. bent, polar
D. bent, nonpolar
E. trigonal planar, polar
54.
A. linear, polar
B. linear, nonpolar
C. tetrahedral, nonpolar
D. bent, nonpolar
E. bent, polar
55.
A. CH4
B. CHBr3
C. F2
D. CBr4
E. CO2
56.
A. BeCl2
B. SF2
C. KrF2
D. CO2
E. CCl4
57.
A. N2O
B. NF3
C. H2S
D. SeO3
E. CH3Cl
58.
What is the name given to the attractive forces that hold particles together in the condensed phase?
A. ionic bonds
B. covalent bonds
C. intermolecular forces
D. electronegativity
E. electron attraction
59.
A. I and III
B. II only
C. III only
D. I, II, and III
E. I only
60.
Which of the following is defined as the attractive forces between polar molecules?
I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions
A. I and III
B. II only
C. III only
D. I, II, and III
E. I only
61.
In a sample of hydrogen iodide, __________________ are the most important intermolecular forces.
A. dipole-dipole forces
B. London dispersion forces
C. hydrogen bonding
D. covalent bonds
E. polar covalent bonds
62.
The strongest intermolecular interactions between hydrogen sulfide (H2S) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. disulfide linkages.
63.
A. PH3
B. He
C. H2S
D. CH4
E. CH3OH
64.
Which of the responses includes all of the following that can form hydrogen bonds with water molecules?
A. I and II
B. I and III
C. II and III
D. II and IV
E. III and IV
65.
A. (CH3)3N
B. CH3–O–CH3
C. CH3CH2–OH
D. CH3CH2–F
E. HI
66.
Which one of the following pure substances will exhibit hydrogen bonding?
A. CH4
B. H2C=CH2
C. H2O
D. CHCl3
E. CHF3
67.
A. S
B. O
C. F
D. N
E. H
68.
The strongest intermolecular interactions between ethyl alcohol (CH3CH2OH) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-oxygen bonds.
69.
The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. ionic bonds.
70.
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. ionic bonding.
71.
A. II and III
B. I, II, and III
C. I only
D. III only
E. I and III
72.
In which of the following compounds will the molecules not form hydrogen bonds with each other?
A.
B.
C.
D.
E.
73.
A. ion-dipole interactions
B. dipole-dipole interactions
C. hydrogen bonding
D. covalent forces
E. London forces
74.
The strongest intermolecular interactions between pentane (C5H12) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-carbon bonds.
75.
A. I only
B. II only
C. III only
D. I, II, and III
E. I and III
76.
Helium atoms do not combine to form He2 molecules, yet He atoms do attract one another weakly through
A. dipole-dipole forces.
B. ion-dipole forces.
C. dispersion forces.
D. dipole-induced dipole forces.
E. hydrogen bonding.
77.
Which one of the following pure substance has both dispersion forces and dipole-dipole forces?
A. HCl
B. BCl3
C. Br2
D. H2
E. CO2
78.
For which of the following pure substances are the intermolecular interactions entirely due to dispersion
forces?
A. C2H6
B. CH3OCH3
C. NO2
D. H2S
E. Ca(NO3)2
79.
Which of the following pure substances has the strongest dispersion forces?
A. C4H10
B. C5H12
C. C6H14
D. C7H16
E. C8H18
80.
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. intramolecular forces.
81.
Octane is a component of fuel used in internal combustion engines. The dominant intermolecular forces in
octane are
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonds.
E. carbon-hydrogen bonds.
82.
83.
What is the intermolecular force that exists between a calcium ion and water?
A. dipole-dipole forces
B. London dispersion forces
C. ion-dipole forces
D. covalent bonding
E. ion-ion forces
84.
What is the intermolecular force that exists between a magnesium ion and hydrogen sulfide?
A. dipole-dipole forces
B. London dispersion forces
C. ionic bonding
D. ion-dipole forces
E. ion-ion forces
85.
Which of the following pairs is arranged with the particle of higher polarizability listed first?
A. Se2–, S2–
B. I, I–
C. Mg2+, Mg
D. Br, I
E. None of these choices is correct.
86.
Which of the following pairs is arranged with the particle of higher polarizability listed first?
A. CCl4, CI4
B. H2O, H2Se
C. C6 H14, C4H10
D. NH3, NF3
E. None of these choices is correct.
87.
Which of the following pure substances has the highest boiling point?
A. CF4
B. CCl4
C. CBr4
D. CI4
E. CH4
88.
Which of the following pure substances has the highest boiling point?
A. CH4
B. Cl2
C. Kr
D. CH3Cl
E. N2
89.
Choose the response that lists the member of each of the following pairs that has the higher boiling point.
90.
Arrange the following in order of increasing boiling point: RbCl, CH3Cl, CH3OH, CH4.
91.
A. hydrogen bonding.
B. stronger dispersion forces.
C. permanent dipole moment.
D. ionic bonds.
E. greater ionization energy.
92.
Indicate the type of hybrid orbitals used by the central atom in PCl3.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
93.
Indicate the type of hybrid orbitals used by the central atom in CCl4.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
94.
Indicate the type of hybrid orbitals used by the central atom in SF6.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
95.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
96.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
97.
A. SO2
B. N2O
C. BeCl2
D. NF3
E. PF5
98.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
99.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
100.
A. sp.
B. sp2.
C. sp3.
D. sp3d.
E. sp3d2.
101.
A molecule with the formula AB3 and a trigonal planar molecular geometry uses _________ to form its
bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
102.
A molecule with the formula AB4 and a tetrahedral molecular geometry uses _________ to form its bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
103.
A molecule with the formula AB4 and a square planar molecular geometry uses _________ to form its
bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
104.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
105.
Valence bond theory predicts that carbon will use _____ hybrid orbitals in the carbonate anion, CO32–.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
106.
Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide, SO2 .
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
107.
When PCl5 solidifies it forms PCl4+cations and PCl6– anions. According to valence bond theory, what hybrid
orbitals are used by phosphorus in the PCl4+cation?
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
108.
Valence bond theory predicts that iodine will use _____ hybrid orbitals in ICl2–.
A. sp2
B. sp3
C. sp3d
D. sp3d2
E. None of these choices is correct.
109.
110.
For which one of the following molecules is the indicated type of hybridization not appropriate for the central
atom?
A. BeCl2; sp2
B. SiH4; sp3
C. BF3; sp2
D. C2H2; sp
E. H2O; sp3
111.
A. sp3
B. sp2
C. sp
D. sp3d
E. sp3d2
112.
How many bonds are there in one molecule of acrylonitrile (shown below)?
A. 1
B. 2
C. 3
D. 5
E. 9
113.
How many bonds are there in one molecule of 1,5-hexadiyne (shown below)?
A. 2
B. 4
C. 6
D. 11
E. 15
114.
According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of
115.
A. 0.
B. 1.
C. 2.
D. 3.
E. 4.
116.
Consider the species F2+, F2, and F2–. Which of these species will be paramagnetic?
117.
Consider the species N2–, N2, and N2+. Which of these species will be paramagnetic?
A. N2 and N2–
B. N2+ and N2
C. N2+ and N2–
D. N2–, N2, and N2+
E. None is paramagnetic.
118.
For a homonuclear diatomic molecule, which molecular orbital is the highest in energy?
A.
B.
C.
D.
119.
For a homonuclear diatomic molecule, which molecular orbital is the lowest in energy?
A.
B.
C.
D.
Which figure best illustrates the hybrid orbitals on carbon in benzene, C6H6?
A.
B.
C.
D.
E.
121.
A.
B.
C.
D.
E.
122.
A.
B.
C.
D.
E.
123.
124.
According to molecular orbital (MO) theory, the twelve valence electrons in the O2 molecule are distributed
as follows:
125.
According to molecular orbital theory, what is the bond order in the O2+ ion?
A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5
126.
According to molecular orbital theory, what is the bond order in the O2– ion?
A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5
127.
The nitrosonium ion, NO+, forms a number of interesting complexes with nickel, cobalt, and iron. According
to molecular orbital theory, which statement about NO+ is correct?
128.
Hyposulfite, SO22–, is a polyatomic ion that has not yet been definitively confirmed to exist. However, the
VSEPR model may still be applied to yield a prediction on its molecular geometry. What is the most reasonable
estimate for the O–S–O bond angle in hyposulfite?
A. 90
B. 106
C. 109.5
D. 112
E. 120
130.
For a polyatomic ion having the general formula AB3n, where A is an atom from Group 6A, B is an atom from
Group 7A, and the ionic charge is n, what charge must the ion have in order to yield a molecular geometry
that is trigonal pyramidal?
A. 3–
B. 1–
C. 1+
D. 3+
E. 5+
131.
Which molecular formula corresponds to a structural formula with carbon atoms having hybridizations of sp,
sp2, and sp3?
A. C3H6
B. C4H4
C. C4H6
D. C5H6
E. C5H8
132.
Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl5?
A.
B.
C.
D.
E.
133.
Allene, C3H4 (shown below), is one component of gas used for high-temperature welding. According to the
valence bond model, which is a proper description of the bonding on the central carbon atom in allene?
A. It shares four bonds, two with each carbon atom on either side.
B. It shares four bonds, two with each carbon atom on either side.
C. It shares one bond and one bond with each carbon atom on either side.
D. It shares two bonds with the carbon atom on the left, and two bonds with the carbon atom on the right.
E. It shares two bonds with the carbon atom on the right, and two bonds with the carbon atom on the left.
134.
According to molecular orbital theory, what is the bond order of the hypofluorite ion, OF–?
A. 0
B. 0.5
C. 1
D. 1.5
E. 2
135.
Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the
models, if any, are not shown.)
A.
B.
C.
D.
E.
136.
For different structural arrangements of atoms having the formula XeF2Cl2, which structures represent polar
molecules? (Black = Xe, Yellow = F, Green = Cl)
A. I and III
B. II only
C. I, II and III
D. II and III
E. None of these structures are polar.
137.
Thiocarbonyl disulfide (CSF2), based on the coordinate axes provided below, in which direction does the net
molecular dipole moment point for the molecule?
139.
140.
A. The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B. A molecular orbital can accommodate up to two electrons.
C. When electrons are added to orbitals of the same energy, the most stable arrangement is predicted by Hund's
rule.
D. Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E. Antibonding molecular orbitals are higher in energy than all of the bonding molecular orbitals.
141.
According to the VSEPR model, a molecule with the general formula AB4 with two lone pairs on the central
atom will have a _____ molecular geometry.
A. tetrahedral
B. square pyramidal
C. square planar
D. octahedral
E. seesaw
142.
Octane, C8H18, boils at 125C, whereas water boils at 100C. This information suggests that the dispersion
forces in nonpolar octane molecules are stronger than the dispersion forces and hydrogen bonding in water.
True False
143.
The energy of a hydrogen bond is greater than that of a typical covalent bond.
True False
144.
Only molecules which do not have dipole moments can experience dispersion forces.
True False
145.
To correctly determine the molecular shape of a molecule requires that you first draw the Lewis structure for
the molecule.
True False
146.
According to molecular orbital theory, all diatomic molecules with an even number of electrons are
diamagnetic.
True False
147.
In the valence bond treatment, a bond is formed when two p orbitals overlap side to side.
True False
148.
In the valence bond treatment, overlap of an s orbital on one atom with an sp3 orbital on another atom gives
rise to a bond.
True False
149.
Atoms of period 3 and beyond can undergo sp3d2 hybridization, but atoms of period 2 cannot.
True False
150.
True False
151.
The bond angle for an sp hybrid orbital is smaller than the bond angle for an sp2 hybrid orbital.
True False
152.
To make an sp3 hybrid orbital, one s atomic orbital is mixed with three p atomic orbitals.
True False
153.
A molecule which contains polar bonds will always have a dipole moment.
True False
154.
According to the VSEPR model, a molecule with the general formula AB3 possessing two lone pairs on the
central atom has a trigonal planar molecular geometry.
True False
155.
The number of lone pairs of electrons on the central atoms is an important factor used to determine the
molecular shape or molecular geometry.
True False
156.
Pi bonds are covalent bonds in which the electron density is concentrated above and below the plane of the
nuclei of the bonding atoms.
True False
157.
The BrF5 molecule has polar bonds and has a net dipole moment.
True False
158.
___________ is the electron-domain geometry and _________ is the molecular geometry for ammonia.
________________________________________
159.
Water has ___________ (number) lone pair(s) of electrons on the central oxygen.
________________________________________
160.
________________________________________
161.
________________________________________
162.
________________________________________
163.
The number of lone pairs on the central atom is used to determine the ____________.
________________________________________
164.
________________________________________
165.
________________ _________ are the attractions that hold particles together in condensed phases.
________________________________________
166.
167.
168.
170.
Use the VSEPR model to predict the molecular geometry of H3O+ (hydronium ion).
171.
172.
174.
How many electron domains are on the central atom for a sp2 hybridized atom?
175.
How many electron domains are on the central atom for a sp3d hybridized atom?
176.
What name is given to the shape of a molecule with no lone pairs of electrons on the central atom and 6
electron domains on the central atom?
177.
The Lewis structure of formaldehyde, CH2O, is shown. Use VSEPR model to predict the molecular geometry
and the H–C–H bond angle. Outline your reasoning.
178.
179.
In not more than two sentences, explain when and why chemists make use of the concept of hybridization.
180.
1.
Blooms: 1. Remember
Chapter - Chapter 7 #1
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
2.
Which of the following is required for the determination of the VSEPR model and the molecular shape?
A. Atomic mass
B. Number of protons
C. Oxidation number
D. Lewis structure
E. None of the answers is correct.
Blooms: 1. Remember
Chapter - Chapter 7 #2
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
3.
According to the VSEPR model, the predicted molecular geometry of the SO3 molecule is
A. pyramidal.
B. tetrahedral.
C. trigonal planar.
D. seesaw.
E. square planar.
Blooms: 3. Apply
Chapter - Chapter 7 #3
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
4.
What is the predicted molecular geometry of the CH4 molecule according to the VSEPR model?
A. tetrahedral
B. trigonal pyramidal
C. trigonal planar
D. square planar
E. seesaw
Blooms: 3. Apply
Chapter - Chapter 7 #4
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
5.
Using the VSEPR model, what is the predicted molecular geometry of the PCl3 molecule?
A. linear
B. bent
C. trigonal planar
D. trigonal pyramidal
E. tetrahedral
Blooms: 3. Apply
Chapter - Chapter 7 #5
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
6.
What is the predicted molecular geometry of the H2O molecule according to the VSEPR model?
A. tetrahedral
B. trigonal pyramidal
C. bent
D. square planar
E. seesaw
Chapter - Chapter 7 #6
Difficulty: Easy
7.
What is the predicted molecular geometry of the IBr3 molecule according to the VSEPR model?
A. tetrahedral
B. T-shaped
C. bent
D. trigonal planar
E. seesaw
Blooms: 3. Apply
Chapter - Chapter 7 #7
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
8.
According to the VSEPR model, the molecular geometry of the carbonate ion, CO32–, is
A. square planar.
B. tetrahedral.
C. pyramidal.
D. trigonal planar.
E. octahedral.
Blooms: 3. Apply
Chapter - Chapter 7 #8
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
9.
A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.
Blooms: 3. Apply
Chapter - Chapter 7 #9
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
10.
According to the VSEPR model, the predicted molecular geometry of ammonia, NH3, is
A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.
Blooms: 3. Apply
Chapter - Chapter 7 #10
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
11.
A. H2S
B. HCN
C. BF3
D. H2CO
E. SO3
Blooms: 4. Analyze
Chapter - Chapter 7 #11
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
12.
According to the VSEPR model, which molecule is predicted to have a molecular geometry that is trigonal
bipyramidal?
A. SF4
B. XeF4
C. NF3
D. SF6
E. PF5
Blooms: 4. Analyze
Chapter - Chapter 7 #12
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
13.
According to the VSEPR model, which molecule has a predicted tetrahedral molecular geometry?
A. XeF4
B. BF3
C. AsF5
D. CF4
E. NH3
Blooms: 4. Analyze
Chapter - Chapter 7 #13
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
14.
Using the VSEPR model, predict the molecular geometry around the central atom in PO43–.
A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral
Blooms: 4. Analyze
Chapter - Chapter 7 #14
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
15.
Using the VSEPR model, predict the molecular geometry around the central atom in SO32–.
A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral
Blooms: 4. Analyze
Chapter - Chapter 7 #15
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
16.
What is the total number of electron domains around the central atom for a molecule having a trigonal
pyramidal molecular geometry, such as NH3?
A. 5
B. 2
C. 3
D. 4
E. 6
Blooms: 4. Analyze
Chapter - Chapter 7 #16
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
17.
What is the total number of electron domains around the central atom for a molecule having a T-shaped
molecular geometry, such as BrF3?
A. 5
B. 2
C. 3
D. 4
E. 6
Blooms: 4. Analyze
Chapter - Chapter 7 #17
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
18.
What is the total number of electron domains around the central atom for a molecule having a square
pyramidal molecular geometry, such as ClF5?
A. 5
B. 2
C. 3
D. 4
E. 6
Blooms: 4. Analyze
Chapter - Chapter 7 #18
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
19.
What is the total number of electron domains around the central atom for a molecule having a square planar
molecular geometry, such as XeBr4?
A. 2
B. 3
C. 4
D. 5
E. 6
Blooms: 4. Analyze
Chapter - Chapter 7 #19
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
20.
What is the number of lone electron pairs on the central atom of a molecule having a seesaw molecular
geometry, such as SF4?
A. 1
B. 2
C. 3
D. 4
E. 6
Blooms: 4. Analyze
Chapter - Chapter 7 #20
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
21.
What is the number of lone electron pairs on the central atom of a molecule having a trigonal pyramidal
molecular geometry, such as NH3?
A. 1
B. 2
C. 3
D. 0
E. 4
Blooms: 4. Analyze
Chapter - Chapter 7 #21
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
22.
What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as CO2?
A. 1
B. 2
C. 3
D. 0
E. 4
Blooms: 4. Analyze
Chapter - Chapter 7 #22
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
23.
What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as ClF2–?
A. 1
B. 2
C. 3
D. 0
E. 4
Blooms: 3. Apply
Chapter - Chapter 7 #23
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
24.
According to the VSEPR model, a molecule with the general formula AB3 with no lone pairs on the central
atom will have a ______ molecular shape.
A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. trigonal pyramidal
Blooms: 3. Apply
Chapter - Chapter 7 #24
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
25.
According to the VSEPR model, a molecule with the general formula AB5 with no lone pairs on the central
atom will have a ______ molecular geometry.
A. tetrahedral
B. trigonal planar
C. trigonal pyramidal
D. trigonal bipyramidal
E. seesaw
Blooms: 3. Apply
Chapter - Chapter 7 #25
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
26.
According to the VSEPR model, a molecule with the general formula AB2 with two lone pairs on the central
atom will have a _____ molecular geometry.
A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. seesaw
Blooms: 3. Apply
Chapter - Chapter 7 #26
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
27.
According to the VSEPR model, a molecule with the general formula AB5 with one lone pair on the central
atom will have a ______ molecular geometry.
A. tetrahedral
B. trigonalbipyramidal
C. square pyramidal
D. octahedral
E. seesaw
Blooms: 3. Apply
Chapter - Chapter 7 #27
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
28.
A. trigonal pyramidal
B. trigonal planar
C. tetrahedral
D. bent
E. linear
Blooms: 4. Analyze
Chapter - Chapter 7 #28
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
29.
What is the molecular geometry of the thiocyanate anion, SCN–, as predicted by the VSEPR model? (Carbon
is the central atom.)
A. linear
B. bent
C. tetrahedral
D. trigonal planar
E. trigonal pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #29
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
30.
A. tetrahedral
B. bent
C. trigonal planar
D. linear
E. trigonal pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #30
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
31.
A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #31
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
32.
A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #32
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
33.
A. trigonal pyramidal
B. square planar
C. square pyramidal
D. tetrahedral
E. octahedral
Blooms: 4. Analyze
Chapter - Chapter 7 #33
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
34.
A. trigonal pyramidal
B. bent
C. tetrahedral
D. linear
E. trigonal planar
Blooms: 4. Analyze
Chapter - Chapter 7 #34
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
35.
A. square planar
B. tetrahedral
C. square pyramidal
D. seesaw
E. octahedral
Blooms: 4. Analyze
Chapter - Chapter 7 #35
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
36.
A. linear
B. bent
C. seesaw
D. T-shaped
E. trigonal bipyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #36
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
37.
A. trigonal bipyramidal
B. octahedral
C. tetrahedral
D. seesaw
E. square pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #37
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
38.
According to the VSEPR model, what is the predicted electron-domain geometry around the central iodine
atom in the ion lF2– ?
A. octahedral
B. trigonal bipyramidal
C. tetrahedral
D. trigonal planar
E. bent
Blooms: 4. Analyze
Chapter - Chapter 7 #38
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
39.
According to the VSEPR model, which one of the following molecules and ions will definitely have at least
one 90 bond angle in it? (In each case, except water, the central atom is the first one in the formula.)
A. AlCl4–
B. NH3
C. PCl5
D. CO2
E. H2O
Blooms: 5. Evaluate
Chapter - Chapter 7 #39
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
40.
According to the VSEPR model, what is the predicted Cl–C–Cl bond angle in CCl4?
A. 90
B. 109.5
C. 120
D. 145
E. 180
Blooms: 4. Analyze
Chapter - Chapter 7 #40
Difficulty: Easy
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
41.
Which is the most reasonable prediction for the H–N–H bond angle in NH3?
A. 90
B. 109.5
C. 120
D. 107
E. 105
Blooms: 4. Analyze
Chapter - Chapter 7 #41
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
42.
A. 60
B. 90
C. 109.5
D. 120
E. 180
Blooms: 4. Analyze
Chapter - Chapter 7 #42
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
43.
Which is the most reasonable prediction for the H–O–H bond angle in H2O?
A. 90
B. 109.5
C. 120
D. 107
E. 105
Blooms: 4. Analyze
Chapter - Chapter 7 #43
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
44.
Which is the most reasonable prediction for the Cl–N–Cl bond angle in NCl3?
A. 120
B. 111
C. 109.5
D. 107
E. 90
Blooms: 4. Analyze
Chapter - Chapter 7 #44
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
45.
Which is the most reasonable prediction for the three F–Br–F bond angles in BrF3?
Blooms: 4. Analyze
Chapter - Chapter 7 #45
Difficulty: Hard
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
46.
Which is the most reasonable prediction for the H–C–H bond angle in CH4?
A. 90
B. 109.5
C. 120
D. 107
E. 105
Blooms: 4. Analyze
Chapter - Chapter 7 #46
Difficulty: Easy
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
47.
How do you describe the molecular geometry of a molecule that has more than one central atom?
A. You describe the molecular geometry around the most electronegative atom.
B. You describe the molecular geometry around each central atom separately.
C. You describe the molecular geometry around the most electropositive atom.
D. You describe the molecular geometry around the atom with the largest atomic radius.
E. You describe the molecular geometry around the atom with the largest bond angle.
Blooms: 2. Understand
Chapter - Chapter 7 #47
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
48.
A. NH3
B. OF2
C. CH3Cl
D. H2O
E. BeCl2
Blooms: 5. Evaluate
Chapter - Chapter 7 #48
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
49.
Blooms: 5. Evaluate
Chapter - Chapter 7 #49
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
50.
A. CO2
B. PF3
C. KCl
D. IBr3
E. CHCl3
Blooms: 5. Evaluate
Chapter - Chapter 7 #50
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
51.
A. CO
B. CH2Cl2
C. SO3
D. SO2
E. NH3
Blooms: 5. Evaluate
Chapter - Chapter 7 #51
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
52.
A. PBr5
B. CCl4
C. BrF5
D. XeF2
E. XeF4
Blooms: 5. Evaluate
Chapter - Chapter 7 #52
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
53.
A. linear, polar
B. linear, nonpolar
C. bent, polar
D. bent, nonpolar
E. trigonal planar, polar
Blooms: 4. Analyze
Chapter - Chapter 7 #53
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
54.
A. linear, polar
B. linear, nonpolar
C. tetrahedral, nonpolar
D. bent, nonpolar
E. bent, polar
Blooms: 4. Analyze
Chapter - Chapter 7 #54
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
55.
A. CH4
B. CHBr3
C. F2
D. CBr4
E. CO2
Blooms: 5. Evaluate
Chapter - Chapter 7 #55
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
56.
A. BeCl2
B. SF2
C. KrF2
D. CO2
E. CCl4
Blooms: 5. Evaluate
Chapter - Chapter 7 #56
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
57.
A. N2O
B. NF3
C. H2S
D. SeO3
E. CH3Cl
Blooms: 5. Evaluate
Chapter - Chapter 7 #57
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
58.
What is the name given to the attractive forces that hold particles together in the condensed phase?
A. ionic bonds
B. covalent bonds
C. intermolecular forces
D. electronegativity
E. electron attraction
Blooms: 2. Understand
Chapter - Chapter 7 #58
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
59.
A. I and III
B. II only
C. III only
D. I, II, and III
E. I only
Blooms: 2. Understand
Chapter - Chapter 7 #59
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
60.
Which of the following is defined as the attractive forces between polar molecules?
I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions
A. I and III
B. II only
C. III only
D. I, II, and III
E. I only
Blooms: 2. Understand
Chapter - Chapter 7 #60
Difficulty: Easy
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
Topic: Molecular Shape
61.
In a sample of hydrogen iodide, __________________ are the most important intermolecular forces.
A. dipole-dipole forces
B. London dispersion forces
C. hydrogen bonding
D. covalent bonds
E. polar covalent bonds
Blooms: 4. Analyze
Chapter - Chapter 7 #61
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
62.
The strongest intermolecular interactions between hydrogen sulfide (H2S) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. disulfide linkages.
Blooms: 4. Analyze
Chapter - Chapter 7 #62
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
63.
A. PH3
B. He
C. H2S
D. CH4
E. CH3OH
Blooms: 4. Analyze
Chapter - Chapter 7 #63
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
64.
Which of the responses includes all of the following that can form hydrogen bonds with water molecules?
A. I and II
B. I and III
C. II and III
D. II and IV
E. III and IV
Blooms: 5. Evaluate
Chapter - Chapter 7 #64
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
65.
A. (CH3)3N
B. CH3–O–CH3
C. CH3CH2–OH
D. CH3CH2–F
E. HI
Blooms: 5. Evaluate
Chapter - Chapter 7 #65
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
66.
Which one of the following pure substances will exhibit hydrogen bonding?
A. CH4
B. H2C=CH2
C. H2O
D. CHCl3
E. CHF3
Blooms: 5. Evaluate
Chapter - Chapter 7 #66
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
67.
A. S
B. O
C. F
D. N
E. H
Blooms: 5. Evaluate
Chapter - Chapter 7 #67
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
68.
The strongest intermolecular interactions between ethyl alcohol (CH3CH2OH) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-oxygen bonds.
Blooms: 4. Analyze
Chapter - Chapter 7 #68
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
69.
The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. ionic bonds.
Blooms: 4. Analyze
Chapter - Chapter 7 #69
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
70.
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. ionic bonding.
Blooms: 4. Analyze
Chapter - Chapter 7 #70
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
71.
A. II and III
B. I, II, and III
C. I only
D. III only
E. I and III
Blooms: 4. Analyze
Chapter - Chapter 7 #71
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
72.
In which of the following compounds will the molecules not form hydrogen bonds with each other?
A.
B.
C.
D.
E.
Blooms: 5. Evaluate
Chapter - Chapter 7 #72
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
73.
A. ion-dipole interactions
B. dipole-dipole interactions
C. hydrogen bonding
D. covalent forces
E. London forces
Blooms: 2. Understand
Chapter - Chapter 7 #73
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
74.
The strongest intermolecular interactions between pentane (C5H12) molecules arise from
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-carbon bonds.
Blooms: 4. Analyze
Chapter - Chapter 7 #74
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
75.
A. I only
B. II only
C. III only
D. I, II, and III
E. I and III
Blooms: 4. Analyze
Chapter - Chapter 7 #75
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
76.
Helium atoms do not combine to form He2 molecules, yet He atoms do attract one another weakly through
A. dipole-dipole forces.
B. ion-dipole forces.
C. dispersion forces.
D. dipole-induced dipole forces.
E. hydrogen bonding.
Blooms: 2. Understand
Chapter - Chapter 7 #76
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
77.
Which one of the following pure substance has both dispersion forces and dipole-dipole forces?
A. HCl
B. BCl3
C. Br2
D. H2
E. CO2
Blooms: 4. Analyze
Chapter - Chapter 7 #77
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
78.
For which of the following pure substances are the intermolecular interactions entirely due to dispersion
forces?
A. C2H6
B. CH3OCH3
C. NO2
D. H2S
E. Ca(NO3)2
Blooms: 4. Analyze
Chapter - Chapter 7 #78
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
79.
Which of the following pure substances has the strongest dispersion forces?
A. C4H10
B. C5H12
C. C6H14
D. C7H16
E. C8H18
Blooms: 4. Analyze
Chapter - Chapter 7 #79
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
80.
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. intramolecular forces.
Blooms: 4. Analyze
Chapter - Chapter 7 #80
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
81.
Octane is a component of fuel used in internal combustion engines. The dominant intermolecular forces in
octane are
A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonds.
E. carbon-hydrogen bonds.
Blooms: 4. Analyze
Chapter - Chapter 7 #81
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
82.
Blooms: 4. Analyze
Chapter - Chapter 7 #82
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
83.
What is the intermolecular force that exists between a calcium ion and water?
A. dipole-dipole forces
B. London dispersion forces
C. ion-dipole forces
D. covalent bonding
E. ion-ion forces
Blooms: 4. Analyze
Chapter - Chapter 7 #83
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
84.
What is the intermolecular force that exists between a magnesium ion and hydrogen sulfide?
A. dipole-dipole forces
B. London dispersion forces
C. ionic bonding
D. ion-dipole forces
E. ion-ion forces
Blooms: 4. Analyze
Chapter - Chapter 7 #84
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
85.
Which of the following pairs is arranged with the particle of higher polarizability listed first?
A. Se2–, S2–
B. I, I–
C. Mg2+, Mg
D. Br, I
E. None of these choices is correct.
Blooms: 5. Evaluate
Chapter - Chapter 7 #85
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity)
Topic: Chemical Periodicity
Topic: Molecular Shape
86.
Which of the following pairs is arranged with the particle of higher polarizability listed first?
A. CCl4, CI4
B. H2O, H2Se
C. C6 H14, C4H10
D. NH3, NF3
E. None of these choices is correct.
Blooms: 5. Evaluate
Chapter - Chapter 7 #86
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity)
Topic: Chemical Periodicity
Topic: Molecular Shape
87.
Which of the following pure substances has the highest boiling point?
A. CF4
B. CCl4
C. CBr4
D. CI4
E. CH4
Blooms: 5. Evaluate
Chapter - Chapter 7 #87
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
88.
Which of the following pure substances has the highest boiling point?
A. CH4
B. Cl2
C. Kr
D. CH3Cl
E. N2
Blooms: 5. Evaluate
Chapter - Chapter 7 #88
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
89.
Choose the response that lists the member of each of the following pairs that has the higher boiling point.
Blooms: 5. Evaluate
Chapter - Chapter 7 #89
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
90.
Arrange the following in order of increasing boiling point: RbCl, CH3Cl, CH3OH, CH4.
Blooms: 5. Evaluate
Chapter - Chapter 7 #90
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
91.
A. hydrogen bonding.
B. stronger dispersion forces.
C. permanent dipole moment.
D. ionic bonds.
E. greater ionization energy.
Blooms: 5. Evaluate
Chapter - Chapter 7 #91
Difficulty: Medium
Subtopic: Phase Changes
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
92.
Indicate the type of hybrid orbitals used by the central atom in PCl3.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #92
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
93.
Indicate the type of hybrid orbitals used by the central atom in CCl4.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #93
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
94.
Indicate the type of hybrid orbitals used by the central atom in SF6.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #94
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
95.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #95
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
Topic: Molecular Shape
96.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #96
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
Topic: Molecular Shape
97.
A. SO2
B. N2O
C. BeCl2
D. NF3
E. PF5
Blooms: 4. Analyze
Chapter - Chapter 7 #97
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
98.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #98
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
99.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #99
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
100.
A. sp.
B. sp2.
C. sp3.
D. sp3d.
E. sp3d2.
Blooms: 4. Analyze
Chapter - Chapter 7 #100
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
Topic: Electron Configuration
101.
A molecule with the formula AB3 and a trigonal planar molecular geometry uses _________ to form its
bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
Blooms: 4. Analyze
Chapter - Chapter 7 #101
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
102.
A molecule with the formula AB4 and a tetrahedral molecular geometry uses _________ to form its bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
Blooms: 4. Analyze
Chapter - Chapter 7 #102
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
103.
A molecule with the formula AB4 and a square planar molecular geometry uses _________ to form its
bonds.
A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals
Blooms: 4. Analyze
Chapter - Chapter 7 #103
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
104.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #104
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
105.
Valence bond theory predicts that carbon will use _____ hybrid orbitals in the carbonate anion, CO32–.
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #105
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
106.
Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide, SO2 .
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #106
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
107.
When PCl5 solidifies it forms PCl4+cations and PCl6– anions. According to valence bond theory, what hybrid
orbitals are used by phosphorus in the PCl4+cation?
A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #107
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
108.
Valence bond theory predicts that iodine will use _____ hybrid orbitals in ICl2–.
A. sp2
B. sp3
C. sp3d
D. sp3d2
E. None of these choices is correct.
Blooms: 4. Analyze
Chapter - Chapter 7 #108
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
109.
Blooms: 4. Analyze
Chapter - Chapter 7 #109
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
110.
For which one of the following molecules is the indicated type of hybridization not appropriate for the central
atom?
A. BeCl2; sp2
B. SiH4; sp3
C. BF3; sp2
D. C2H2; sp
E. H2O; sp3
Blooms: 4. Analyze
Chapter - Chapter 7 #110
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
111.
A. sp3
B. sp2
C. sp
D. sp3d
E. sp3d2
Blooms: 4. Analyze
Chapter - Chapter 7 #111
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
112.
How many bonds are there in one molecule of acrylonitrile (shown below)?
A. 1
B. 2
C. 3
D. 5
E. 9
Blooms: 4. Analyze
Chapter - Chapter 7 #112
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
113.
How many bonds are there in one molecule of 1,5-hexadiyne (shown below)?
A. 2
B. 4
C. 6
D. 11
E. 15
Blooms: 4. Analyze
Chapter - Chapter 7 #113
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
114.
According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of
Blooms: 4. Analyze
Chapter - Chapter 7 #114
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
115.
A. 0.
B. 1.
C. 2.
D. 3.
E. 4.
Blooms: 4. Analyze
Chapter - Chapter 7 #115
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
116.
Consider the species F2+, F2, and F2–. Which of these species will be paramagnetic?
Blooms: 4. Analyze
Chapter - Chapter 7 #116
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
117.
Consider the species N2–, N2, and N2+. Which of these species will be paramagnetic?
A. N2 and N2–
B. N2+ and N2
C. N2+ and N2–
D. N2–, N2, and N2+
E. None is paramagnetic.
Blooms: 4. Analyze
Chapter - Chapter 7 #117
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
118.
For a homonuclear diatomic molecule, which molecular orbital is the highest in energy?
A.
B.
C.
D.
Blooms: 3. Apply
Chapter - Chapter 7 #118
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
119.
For a homonuclear diatomic molecule, which molecular orbital is the lowest in energy?
A.
B.
C.
D.
Blooms: 3. Apply
Chapter - Chapter 7 #119
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
120.
Which figure best illustrates the hybrid orbitals on carbon in benzene, C6H6?
A.
B.
C.
D.
E.
Blooms: 4. Analyze
Chapter - Chapter 7 #120
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
121.
A.
B.
C.
D.
E.
Blooms: 4. Analyze
Chapter - Chapter 7 #121
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
122.
A.
B.
C.
D.
E.
Blooms: 4. Analyze
Chapter - Chapter 7 #122
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
123.
Blooms: 2. Understand
Chapter - Chapter 7 #123
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
124.
According to molecular orbital (MO) theory, the twelve valence electrons in the O2 molecule are distributed
as follows:
Blooms: 4. Analyze
Chapter - Chapter 7 #124
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
125.
According to molecular orbital theory, what is the bond order in the O2+ ion?
A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5
Blooms: 4. Analyze
Chapter - Chapter 7 #125
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
126.
According to molecular orbital theory, what is the bond order in the O2– ion?
A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5
Blooms: 4. Analyze
Chapter - Chapter 7 #126
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
127.
The nitrosonium ion, NO+, forms a number of interesting complexes with nickel, cobalt, and iron. According
to molecular orbital theory, which statement about NO+ is correct?
Blooms: 4. Analyze
Chapter - Chapter 7 #127
Difficulty: Hard
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
128.
Blooms: 5. Evaluate
Chapter - Chapter 7 #128
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Representing Organic Molecules (Structural Formulas)
Topic: Molecular Shape
Topic: Organic Molecules
129.
Hyposulfite, SO22–, is a polyatomic ion that has not yet been definitively confirmed to exist. However, the
VSEPR model may still be applied to yield a prediction on its molecular geometry. What is the most reasonable
estimate for the O–S–O bond angle in hyposulfite?
A. 90
B. 106
C. 109.5
D. 112
E. 120
Blooms: 4. Analyze
Chapter - Chapter 7 #129
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
130.
For a polyatomic ion having the general formula AB3n, where A is an atom from Group 6A, B is an atom from
Group 7A, and the ionic charge is n, what charge must the ion have in order to yield a molecular geometry
that is trigonal pyramidal?
A. 3–
B. 1–
C. 1+
D. 3+
E. 5+
Blooms: 4. Analyze
Chapter - Chapter 7 #130
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
131.
Which molecular formula corresponds to a structural formula with carbon atoms having hybridizations of sp,
sp2, and sp3?
A. C3H6
B. C4H4
C. C4H6
D. C5H6
E. C5H8
Blooms: 5. Evaluate
Chapter - Chapter 7 #131
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Representing Organic Molecules (Structural Formulas)
Subtopic: Writing Lewis Dot Structures
Topic: Covalent Bond Theories
Topic: Molecular Shape
Topic: Organic Molecules
132.
Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl5?
A.
B.
C.
D.
E.
Blooms: 5. Evaluate
Chapter - Chapter 7 #132
Difficulty: Hard
Subtopic: Hunds Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
133.
Allene, C3H4 (shown below), is one component of gas used for high-temperature welding. According to the
valence bond model, which is a proper description of the bonding on the central carbon atom in allene?
A. It shares four bonds, two with each carbon atom on either side.
B. It shares four bonds, two with each carbon atom on either side.
C. It shares one bond and one bond with each carbon atom on either side.
D. It shares two bonds with the carbon atom on the left, and two bonds with the carbon atom on the right.
E. It shares two bonds with the carbon atom on the right, and two bonds with the carbon atom on the left.
Blooms: 3. Apply
Chapter - Chapter 7 #133
Difficulty: Hard
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
134.
According to molecular orbital theory, what is the bond order of the hypofluorite ion, OF–?
A. 0
B. 0.5
C. 1
D. 1.5
E. 2
Blooms: 4. Analyze
Chapter - Chapter 7 #134
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
135.
Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the
models, if any, are not shown.)
A.
B.
C.
D.
E.
Blooms: 5. Evaluate
Chapter - Chapter 7 #135
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
136.
For different structural arrangements of atoms having the formula XeF2Cl2, which structures represent polar
molecules? (Black = Xe, Yellow = F, Green = Cl)
A. I and III
B. II only
C. I, II and III
D. II and III
E. None of these structures are polar.
Blooms: 4. Analyze
Chapter - Chapter 7 #136
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
137.
Thiocarbonyl disulfide (CSF2), based on the coordinate axes provided below, in which direction does the net
molecular dipole moment point for the molecule?
Blooms: 4. Analyze
Chapter - Chapter 7 #137
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
138.
Blooms: 4. Analyze
Chapter - Chapter 7 #138
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
139.
Blooms: 4. Analyze
Chapter - Chapter 7 #139
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
140.
A. The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B. A molecular orbital can accommodate up to two electrons.
C. When electrons are added to orbitals of the same energy, the most stable arrangement is predicted by Hund's
rule.
D. Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E. Antibonding molecular orbitals are higher in energy than all of the bonding molecular orbitals.
Blooms: 4. Analyze
Chapter - Chapter 7 #140
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
141.
According to the VSEPR model, a molecule with the general formula AB4 with two lone pairs on the central
atom will have a _____ molecular geometry.
A. tetrahedral
B. square pyramidal
C. square planar
D. octahedral
E. seesaw
Blooms: 4. Analyze
Chapter - Chapter 7 #141
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Electron Configuration
Topic: Molecular Shape
142.
Octane, C8H18, boils at 125C, whereas water boils at 100C. This information suggests that the dispersion
forces in nonpolar octane molecules are stronger than the dispersion forces and hydrogen bonding in water.
TRUE
Blooms: 4. Analyze
Chapter - Chapter 7 #142
Difficulty: Easy
Subtopic: Phase Changes
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
143.
The energy of a hydrogen bond is greater than that of a typical covalent bond.
FALSE
Blooms: 3. Apply
Chapter - Chapter 7 #143
Difficulty: Medium
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
144.
Only molecules which do not have dipole moments can experience dispersion forces.
FALSE
Blooms: 4. Analyze
Chapter - Chapter 7 #144
Difficulty: Easy
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
Topic: Molecular Shape
145.
To correctly determine the molecular shape of a molecule requires that you first draw the Lewis structure for
the molecule.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #145
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
146.
According to molecular orbital theory, all diatomic molecules with an even number of electrons are
diamagnetic.
FALSE
Blooms: 4. Analyze
Chapter - Chapter 7 #146
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
147.
In the valence bond treatment, a bond is formed when two p orbitals overlap side to side.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #147
Difficulty: Easy
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
148.
In the valence bond treatment, overlap of an s orbital on one atom with an sp3 orbital on another atom gives
rise to a bond.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #148
Difficulty: Medium
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
149.
Atoms of period 3 and beyond can undergo sp3d2 hybridization, but atoms of period 2 cannot.
TRUE
Blooms: 3. Apply
Chapter - Chapter 7 #149
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Periodic Classification of the Elements
Topic: Chemical Periodicity
Topic: Covalent Bond Theories
150.
FALSE
Blooms: 2. Understand
Chapter - Chapter 7 #150
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
151.
The bond angle for an sp hybrid orbital is smaller than the bond angle for an sp2 hybrid orbital.
FALSE
Blooms: 2. Understand
Chapter - Chapter 7 #151
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
152.
To make an sp3 hybrid orbital, one s atomic orbital is mixed with three p atomic orbitals.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #152
Difficulty: Easy
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
153.
A molecule which contains polar bonds will always have a dipole moment.
FALSE
Blooms: 4. Analyze
Chapter - Chapter 7 #153
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
154.
According to the VSEPR model, a molecule with the general formula AB3 possessing two lone pairs on the
central atom has a trigonal planar molecular geometry.
FALSE
Blooms: 4. Analyze
Chapter - Chapter 7 #154
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Electron Configuration
Topic: Molecular Shape
155.
The number of lone pairs of electrons on the central atoms is an important factor used to determine the
molecular shape or molecular geometry.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #155
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
156.
Pi bonds are covalent bonds in which the electron density is concentrated above and below the plane of the
nuclei of the bonding atoms.
TRUE
Blooms: 2. Understand
Chapter - Chapter 7 #156
Difficulty: Easy
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
157.
The BrF5 molecule has polar bonds and has a net dipole moment.
TRUE
Blooms: 4. Analyze
Chapter - Chapter 7 #157
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Exceptions to the Octet Rule
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
158.
___________ is the electron-domain geometry and _________ is the molecular geometry for ammonia.
Blooms: 4. Analyze
Chapter - Chapter 7 #158
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
159.
Water has ___________ (number) lone pair(s) of electrons on the central oxygen.
two
Blooms: 4. Analyze
Chapter - Chapter 7 #159
Difficulty: Easy
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
160.
Blooms: 2. Understand
Chapter - Chapter 7 #160
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
161.
London forces
Blooms: 2. Understand
Chapter - Chapter 7 #161
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
162.
electron–domain geometry
Blooms: 2. Understand
Chapter - Chapter 7 #162
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
163.
The number of lone pairs on the central atom is used to determine the ____________.
molecular geometry
Blooms: 2. Understand
Chapter - Chapter 7 #163
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
164.
Hydrogen bonding
Blooms: 2. Understand
Chapter - Chapter 7 #164
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
165.
________________ _________ are the attractions that hold particles together in condensed phases.
Intermolecular forces
Blooms: 2. Understand
Chapter - Chapter 7 #165
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
166.
ionic
Blooms: 4. Analyze
Chapter - Chapter 7 #166
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
167.
dipole-dipole
Blooms: 4. Analyze
Chapter - Chapter 7 #167
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
168.
hydrogen bonding
Blooms: 4. Analyze
Chapter - Chapter 7 #168
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
169.
dispersion
Blooms: 4. Analyze
Chapter - Chapter 7 #169
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
170.
Use the VSEPR model to predict the molecular geometry of H3O+ (hydronium ion).
trigonal pyramidal
Blooms: 4. Analyze
Chapter - Chapter 7 #170
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
171.
trigonal planar
Blooms: 4. Analyze
Chapter - Chapter 7 #171
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
172.
one
Blooms: 4. Analyze
Chapter - Chapter 7 #172
Difficulty: Hard
Subtopic: Representing Organic Molecules (Structural Formulas)
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Subtopic: Writing Lewis Dot Structures
Topic: Covalent Bond Theories
Topic: Molecular Shape
Topic: Organic Molecules
173.
nonpolar
Blooms: 4. Analyze
Chapter - Chapter 7 #173
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Exceptions to the Octet Rule
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
174.
How many electron domains are on the central atom for a sp2 hybridized atom?
Blooms: 2. Understand
Chapter - Chapter 7 #174
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
175.
How many electron domains are on the central atom for a sp3d hybridized atom?
Blooms: 2. Understand
Chapter - Chapter 7 #175
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
176.
What name is given to the shape of a molecule with no lone pairs of electrons on the central atom and 6
electron domains on the central atom?
Octahedral
Blooms: 3. Apply
Chapter - Chapter 7 #176
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
177.
The Lewis structure of formaldehyde, CH2O, is shown. Use VSEPR model to predict the molecular geometry
and the H–C–H bond angle. Outline your reasoning.
There are three electron groups around the central atom, carbon. These are a double bond and two single bonds.
The molecule is thus of the AB3 type, and its geometry will be trigonal planar. The H–C–H bond angle is
slightly less than 120 due to the greater electron-pair repulsion that the C=O double bond (possessing two
electron pairs) has on each of the C–H single bonds (possessing only one electron pair each).
Blooms: 4. Analyze
Chapter - Chapter 7 #177
Difficulty: Hard
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
178.
A covalent bond forms when the orbitals of two atoms overlap and a pair of electrons occupies the region
between the nuclei.
Blooms: 2. Understand
Chapter - Chapter 7 #178
Difficulty: Easy
Subtopic: Covalent Bonding
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Chemical Bonding
Topic: Covalent Bond Theories
179.
In not more than two sentences, explain when and why chemists make use of the concept of hybridization.
Chemists postulate hybridization when the observed geometry of a molecule cannot be rationalized in terms
of the overlap of the s, p, and/or d orbitals of the atoms concerned.
Blooms: 2. Understand
Chapter - Chapter 7 #179
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
180.
Molecular orbitals are obtained by the linear combination (addition or subtraction) of atomic orbitals.
Blooms: 2. Understand
Chapter - Chapter 7 #180
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Chapter 7 - Molecular Geometry, Intermolecular Forces, and
Bonding Theories (test bank) Summary
Category # of Questions
Blooms: 1. Remember 2
Blooms: 2. Understand 26
Blooms: 3. Apply 18
Blooms: 4. Analyze 108
Blooms: 5. Evaluate 25
Chapter - Chapter 7 180
Difficulty: Easy 1
Difficulty: Easy 46
Difficulty: Hard 44
Difficulty: Medium 89
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle) 12
Subtopic: Bond Polarity 42
Subtopic: Covalent Bonding 1
Subtopic: Diamagnetism and Paramagnetism 4
Subtopic: Electron Configurations of Cations and Anions 23
Subtopic: Electronegativity 10
Subtopic: Exceptions to the Octet Rule 22
Subtopic: Hunds Rule 1
Subtopic: Hybridization of Atomic Orbitals 37
Subtopic: Lewis Dot Symbols 20
Subtopic: Molecular Orbital (MO) Theory 12
Subtopic: Molecular Polarity (Dipole Moment) 47
Subtopic: Octet Rule 19
Subtopic: Periodic Classification of the Elements 1
Subtopic: Phase Changes 6
Subtopic: Representing Organic Molecules (Structural Formulas) 3
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic 2
Radius, Electron Affinity)
Subtopic: Types of Intermolecular Forces 39
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds)) 13
Subtopic: Valence-Shell Electron- 74
Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures 53
Topic: Chemical Bonding 68
Topic: Chemical Periodicity 3
Topic: Covalent Bond Theories 55
Topic: Electron Configuration 44
Topic: Intermolecular Forces 43
Topic: Molecular Shape 113
Topic: Organic Molecules 3