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Solution Manual for Chemistry Atoms First 2nd Edition Burdge

Professor ISBN 0073511188 9780073511184


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Chapter 7 - Molecular Geometry, Intermolecular Forces, and


Bonding Theories (test bank)

Student: ___________________________________________________________________________

1.

What does the abbreviation VSEPR stand for?

A. Very Specific Electron and Proton Repair


B. Variable Selective of Electron and Protons
C. Valence Shell for Every Proton
D. Very Selective Electron Pair theory
E. Valence-Shell Electron-Pair Repulsion

2.

Which of the following is required for the determination of the VSEPR model and the molecular shape?

A. Atomic mass
B. Number of protons
C. Oxidation number
D. Lewis structure
E. None of the answers is correct.
3.

According to the VSEPR model, the predicted molecular geometry of the SO3 molecule is

A. pyramidal.
B. tetrahedral.
C. trigonal planar.
D. seesaw.
E. square planar.

4.

What is the predicted molecular geometry of the CH4 molecule according to the VSEPR model?

A. tetrahedral
B. trigonal pyramidal
C. trigonal planar
D. square planar
E. seesaw

5.

Using the VSEPR model, what is the predicted molecular geometry of the PCl3 molecule?

A. linear
B. bent
C. trigonal planar
D. trigonal pyramidal
E. tetrahedral

6.

What is the predicted molecular geometry of the H2O molecule according to the VSEPR model?

A. tetrahedral
B. trigonal pyramidal
C. bent
D. square planar
E. seesaw
7.

What is the predicted molecular geometry of the IBr3 molecule according to the VSEPR model?

A. tetrahedral
B. T-shaped
C. bent
D. trigonal planar
E. seesaw

8.

According to the VSEPR model, the molecular geometry of the carbonate ion, CO32–, is

A. square planar.
B. tetrahedral.
C. pyramidal.
D. trigonal planar.
E. octahedral.

9.

According to the VSEPR model, the predicted molecular geometry of SiCl4 is

A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.

10.

According to the VSEPR model, the predicted molecular geometry of ammonia, NH3, is

A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.
11.

According to the VSEPR model, which molecule is predicted to be linear?

A. H2S
B. HCN
C. BF3
D. H2CO
E. SO3

12.

According to the VSEPR model, which molecule is predicted to have a molecular geometry that is trigonal
bipyramidal?

A. SF4
B. XeF4
C. NF3
D. SF6
E. PF5

13.

According to the VSEPR model, which molecule has a predicted tetrahedral molecular geometry?

A. XeF4
B. BF3
C. AsF5
D. CF4
E. NH3

14.

Using the VSEPR model, predict the molecular geometry around the central atom in PO43–.

A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral
15.

Using the VSEPR model, predict the molecular geometry around the central atom in SO32–.

A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral

16.

What is the total number of electron domains around the central atom for a molecule having a trigonal
pyramidal molecular geometry, such as NH3?

A. 5
B. 2
C. 3
D. 4
E. 6

17.

What is the total number of electron domains around the central atom for a molecule having a T-shaped
molecular geometry, such as BrF3?

A. 5
B. 2
C. 3
D. 4
E. 6

18.

What is the total number of electron domains around the central atom for a molecule having a square
pyramidal molecular geometry, such as ClF5?

A. 5
B. 2
C. 3
D. 4
E. 6
19.

What is the total number of electron domains around the central atom for a molecule having a square planar
molecular geometry, such as XeBr4?

A. 2
B. 3
C. 4
D. 5
E. 6

20.

What is the number of lone electron pairs on the central atom of a molecule having a seesaw molecular
geometry, such as SF4?

A. 1
B. 2
C. 3
D. 4
E. 6

21.

What is the number of lone electron pairs on the central atom of a molecule having a trigonal pyramidal
molecular geometry, such as NH3?

A. 1
B. 2
C. 3
D. 0
E. 4

22.

What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as CO2?

A. 1
B. 2
C. 3
D. 0
E. 4
23.

What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as ClF2–?

A. 1
B. 2
C. 3
D. 0
E. 4

24.

According to the VSEPR model, a molecule with the general formula AB3 with no lone pairs on the central
atom will have a ______ molecular shape.

A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. trigonal pyramidal

25.

According to the VSEPR model, a molecule with the general formula AB5 with no lone pairs on the central
atom will have a ______ molecular geometry.

A. tetrahedral
B. trigonal planar
C. trigonal pyramidal
D. trigonal bipyramidal
E. seesaw

26.

According to the VSEPR model, a molecule with the general formula AB2 with two lone pairs on the central
atom will have a _____ molecular geometry.

A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. seesaw
27.

According to the VSEPR model, a molecule with the general formula AB5 with one lone pair on the central
atom will have a ______ molecular geometry.

A. tetrahedral
B. trigonalbipyramidal
C. square pyramidal
D. octahedral
E. seesaw

28.

What is the molecular geometry of N2O as predicted by the VSEPR model?

A. trigonal pyramidal
B. trigonal planar
C. tetrahedral
D. bent
E. linear

29.

What is the molecular geometry of the thiocyanate anion, SCN–, as predicted by the VSEPR model? (Carbon
is the central atom.)

A. linear
B. bent
C. tetrahedral
D. trigonal planar
E. trigonal pyramidal

30.

What is the molecular geometry of BeH2 as predicted by the VSEPR model?

A. tetrahedral
B. bent
C. trigonal planar
D. linear
E. trigonal pyramidal
31.

What is the molecular geometry of NOCl as predicted by the VSEPR model?

A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal

32.

What is the molecular geometry of NO2– as predicted by the VSEPR model?

A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal

33.

What is the molecular geometry of ClO3F as predicted by the VSEPR model?

A. trigonal pyramidal
B. square planar
C. square pyramidal
D. tetrahedral
E. octahedral
34.

What is the molecular geometry of HOF as predicted by the VSEPR model?

A. trigonal pyramidal
B. bent
C. tetrahedral
D. linear
E. trigonal planar

35.

What is the molecular geometry of XeO2F2 as predicted by the VSEPR model?

A. square planar
B. tetrahedral
C. square pyramidal
D. seesaw
E. octahedral

36.

What is the molecular geometry of ClF2– as predicted by the VSEPR model?

A. linear
B. bent
C. seesaw
D. T-shaped
E. trigonal bipyramidal
37.

What is the molecular geometry of SiF62– as predicted by the VSEPR model?

A. trigonal bipyramidal
B. octahedral
C. tetrahedral
D. seesaw
E. square pyramidal

38.

According to the VSEPR model, what is the predicted electron-domain geometry around the central iodine
atom in the ion lF2– ?

A. octahedral
B. trigonal bipyramidal
C. tetrahedral
D. trigonal planar
E. bent

39.

According to the VSEPR model, which one of the following molecules and ions will definitely have at least
one 90 bond angle in it? (In each case, except water, the central atom is the first one in the formula.)

A. AlCl4–
B. NH3
C. PCl5
D. CO2
E. H2O
40.

According to the VSEPR model, what is the predicted Cl–C–Cl bond angle in CCl4?

A. 90
B. 109.5
C. 120
D. 145
E. 180

41.

Which is the most reasonable prediction for the H–N–H bond angle in NH3?

A. 90
B. 109.5
C. 120
D. 107
E. 105

42.

What is the predicted O–C–O bond angle in CO2?

A. 60
B. 90
C. 109.5
D. 120
E. 180

43.

Which is the most reasonable prediction for the H–O–H bond angle in H2O?

A. 90
B. 109.5
C. 120
D. 107
E. 105
44.

Which is the most reasonable prediction for the Cl–N–Cl bond angle in NCl3?

A. 120
B. 111
C. 109.5
D. 107
E. 90

45.

Which is the most reasonable prediction for the three F–Br–F bond angles in BrF3?

A. 90, 90, and 180


B. 86, 94, and 180
C. 86, 86, and 172
D. 94, 94, and 172
E. 120, 120, and 120

46.

Which is the most reasonable prediction for the H–C–H bond angle in CH4?

A. 90
B. 109.5
C. 120
D. 107
E. 105

47.

How do you describe the molecular geometry of a molecule that has more than one central atom?

A. You describe the molecular geometry around the most electronegative atom.
B. You describe the molecular geometry around each central atom separately.
C. You describe the molecular geometry around the most electropositive atom.
D. You describe the molecular geometry around the atom with the largest atomic radius.
E. You describe the molecular geometry around the atom with the largest bond angle.
48.

Which one of the following molecules is nonpolar?

A. NH3
B. OF2
C. CH3Cl
D. H2O
E. BeCl2

49.

The PCl5 molecule has

A. nonpolar bonds, and is a nonpolar molecule.


B. nonpolar bonds, but is a polar molecule.
C. polar bonds, and is a polar molecule.
D. polar bonds, but is a nonpolar molecule.

50.

Which one of the following molecules is nonpolar?

A. CO2
B. PF3
C. KCl
D. IBr3
E. CHCl3

51.

Which one of the following molecules has a zero dipole moment?

A. CO
B. CH2Cl2
C. SO3
D. SO2
E. NH3
52.

Which one of the following molecules is polar?

A. PBr5
B. CCl4
C. BrF5
D. XeF2
E. XeF4

53.

Predict the molecular geometry and polarity of the SO2 molecule.

A. linear, polar
B. linear, nonpolar
C. bent, polar
D. bent, nonpolar
E. trigonal planar, polar

54.

Predict the molecular geometry and polarity of the CS2 molecule.

A. linear, polar
B. linear, nonpolar
C. tetrahedral, nonpolar
D. bent, nonpolar
E. bent, polar

55.

Which one of the following molecules is polar?

A. CH4
B. CHBr3
C. F2
D. CBr4
E. CO2
56.

Which of the following molecules has a nonzero dipole moment?

A. BeCl2
B. SF2
C. KrF2
D. CO2
E. CCl4

57.

Which has a dipole moment of zero?

A. N2O
B. NF3
C. H2S
D. SeO3
E. CH3Cl

58.

What is the name given to the attractive forces that hold particles together in the condensed phase?

A. ionic bonds
B. covalent bonds
C. intermolecular forces
D. electronegativity
E. electron attraction

59.

Which are considered van der Waals forces?


I. dispersion forces
II. dipole-dipole interactions
III. hydrogen bonding

A. I and III
B. II only
C. III only
D. I, II, and III
E. I only
60.

Which of the following is defined as the attractive forces between polar molecules?
I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions

A. I and III
B. II only
C. III only
D. I, II, and III
E. I only

61.

In a sample of hydrogen iodide, __________________ are the most important intermolecular forces.

A. dipole-dipole forces
B. London dispersion forces
C. hydrogen bonding
D. covalent bonds
E. polar covalent bonds

62.

The strongest intermolecular interactions between hydrogen sulfide (H2S) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. disulfide linkages.

63.

Which substance should exhibit hydrogen bonding in the liquid phase?

A. PH3
B. He
C. H2S
D. CH4
E. CH3OH
64.

Which of the responses includes all of the following that can form hydrogen bonds with water molecules?

I. Na+, II. CH3COOH, III. C2H6, IV. CH3NH2

A. I and II
B. I and III
C. II and III
D. II and IV
E. III and IV

65.

Which substance will exhibit hydrogen bonding between molecules?

A. (CH3)3N

B. CH3–O–CH3
C. CH3CH2–OH
D. CH3CH2–F
E. HI

66.

Which one of the following pure substances will exhibit hydrogen bonding?

A. CH4
B. H2C=CH2
C. H2O
D. CHCl3
E. CHF3

67.

Which of the following atoms does not participate in hydrogen bonding?

A. S
B. O
C. F
D. N
E. H
68.

The strongest intermolecular interactions between ethyl alcohol (CH3CH2OH) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-oxygen bonds.

69.

The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. ionic bonds.

70.

Ammonia's unusually high melting point is the result of

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. ionic bonding.

71.

What types of intermolecular forces exist between hydrogen fluoride molecules?


I. London forces
II. dipole-dipole interactions
III. hydrogen bonding
IV. ion-dipole interactions

A. II and III
B. I, II, and III
C. I only
D. III only
E. I and III
72.

In which of the following compounds will the molecules not form hydrogen bonds with each other?

A.

B.

C.

D.

E.
73.

What is another name given to dispersion forces?

A. ion-dipole interactions
B. dipole-dipole interactions
C. hydrogen bonding
D. covalent forces
E. London forces

74.

The strongest intermolecular interactions between pentane (C5H12) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-carbon bonds.

75.

Which kinds of intermolecular forces exist between propane molecules?


I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions

A. I only
B. II only
C. III only
D. I, II, and III
E. I and III

76.

Helium atoms do not combine to form He2 molecules, yet He atoms do attract one another weakly through

A. dipole-dipole forces.
B. ion-dipole forces.
C. dispersion forces.
D. dipole-induced dipole forces.
E. hydrogen bonding.
77.

Which one of the following pure substance has both dispersion forces and dipole-dipole forces?

A. HCl
B. BCl3
C. Br2
D. H2
E. CO2

78.

For which of the following pure substances are the intermolecular interactions entirely due to dispersion
forces?

A. C2H6
B. CH3OCH3
C. NO2
D. H2S
E. Ca(NO3)2

79.

Which of the following pure substances has the strongest dispersion forces?

A. C4H10
B. C5H12
C. C6H14
D. C7H16
E. C8H18

80.

At a temperature of 27 K, neon condenses due to

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. intramolecular forces.
81.

Octane is a component of fuel used in internal combustion engines. The dominant intermolecular forces in
octane are

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonds.
E. carbon-hydrogen bonds.

82.

Which one of the following involves ion-dipole interactions?

A. Na+ and Cl–


B. H+ and F–
C. Na+ and Mg2+
D. two water molecules
E. Na+ and H2O

83.

What is the intermolecular force that exists between a calcium ion and water?

A. dipole-dipole forces
B. London dispersion forces
C. ion-dipole forces
D. covalent bonding
E. ion-ion forces

84.

What is the intermolecular force that exists between a magnesium ion and hydrogen sulfide?

A. dipole-dipole forces
B. London dispersion forces
C. ionic bonding
D. ion-dipole forces
E. ion-ion forces
85.

Which of the following pairs is arranged with the particle of higher polarizability listed first?

A. Se2–, S2–
B. I, I–
C. Mg2+, Mg
D. Br, I
E. None of these choices is correct.

86.

Which of the following pairs is arranged with the particle of higher polarizability listed first?

A. CCl4, CI4
B. H2O, H2Se
C. C6 H14, C4H10
D. NH3, NF3
E. None of these choices is correct.

87.

Which of the following pure substances has the highest boiling point?

A. CF4
B. CCl4
C. CBr4
D. CI4
E. CH4

88.

Which of the following pure substances has the highest boiling point?

A. CH4
B. Cl2
C. Kr
D. CH3Cl
E. N2
89.

Choose the response that lists the member of each of the following pairs that has the higher boiling point.

I. H2O or KI, II. HF or HI, III. Cl2 or Br2

A. H2O, HF, and Cl2


B. KI, HF, and Br2
C. KI, HI, and Br2
D. H2O, HI, and Cl2
E. KI, HF, and Cl2

90.

Arrange the following in order of increasing boiling point: RbCl, CH3Cl, CH3OH, CH4.

A. CH3OH < CH3Cl < RbCl < CH4


B. CH3OH < CH4 < CH3Cl < RbCl
C. RbCl < CH3 Cl < CH3 OH < CH4
D. CH4 < CH3OH < CH3Cl < RbCl
E. CH4 < CH3Cl < CH3OH < RbCl

91.

Krypton has a higher melting point than argon because of its

A. hydrogen bonding.
B. stronger dispersion forces.
C. permanent dipole moment.
D. ionic bonds.
E. greater ionization energy.

92.

Indicate the type of hybrid orbitals used by the central atom in PCl3.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
93.

Indicate the type of hybrid orbitals used by the central atom in CCl4.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

94.

Indicate the type of hybrid orbitals used by the central atom in SF6.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

95.

What is the hybridization of the As atom in the AsF5 molecule?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

96.

What is the hybridization on the central atom in NO3– ?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
97.

In which molecule is the central atom sp2 hybridized?

A. SO2
B. N2O
C. BeCl2
D. NF3
E. PF5

98.

What is the hybridization of As in the AsF4– ion?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

99.

What is the hybridization of the central atom in ClO3–?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

100.

The hybridization of the central nitrogen atom in the molecule N2O is

A. sp.
B. sp2.
C. sp3.
D. sp3d.
E. sp3d2.
101.

A molecule with the formula AB3 and a trigonal planar molecular geometry uses _________ to form its 
bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

102.

A molecule with the formula AB4 and a tetrahedral molecular geometry uses _________ to form its  bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

103.

A molecule with the formula AB4 and a square planar molecular geometry uses _________ to form its 
bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

104.

Carbon uses ______ hybrid orbitals in ClCN.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2
105.

Valence bond theory predicts that carbon will use _____ hybrid orbitals in the carbonate anion, CO32–.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

106.

Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide, SO2 .

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

107.

When PCl5 solidifies it forms PCl4+cations and PCl6– anions. According to valence bond theory, what hybrid
orbitals are used by phosphorus in the PCl4+cation?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

108.

Valence bond theory predicts that iodine will use _____ hybrid orbitals in ICl2–.

A. sp2
B. sp3
C. sp3d
D. sp3d2
E. None of these choices is correct.
109.

Which statement about orbital hybridization is incorrect?

A. The carbon atom in CH4 is sp3 hybridized.


B. The carbon atom in CO2 is sp hybridized.
C. The nitrogen atom in NH3 is sp2 hybridized.
D. sp2 hybrid orbitals are coplanar, and at 120 to each other.
E. sp hybrid orbitals lie at 180 to each other.

110.

For which one of the following molecules is the indicated type of hybridization not appropriate for the central
atom?

A. BeCl2; sp2
B. SiH4; sp3
C. BF3; sp2
D. C2H2; sp
E. H2O; sp3

111.

What is the hybridization of phosphorus in PCl3?

A. sp3
B. sp2
C. sp
D. sp3d
E. sp3d2
112.

How many bonds are there in one molecule of acrylonitrile (shown below)?

A. 1
B. 2
C. 3
D. 5
E. 9

113.

How many bonds are there in one molecule of 1,5-hexadiyne (shown below)?

A. 2
B. 4
C. 6
D. 11
E. 15
114.

According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of

A. three  bonds and no bonds.


B. two  bonds and one bond.
C. one  bond and two bonds.
D. no  bonds and three bonds.
E. one  bond, one bond, and one bond intermediate between  and .

115.

The number of bonds in phosgene, COCl2, is

A. 0.
B. 1.
C. 2.
D. 3.
E. 4.

116.

Consider the species F2+, F2, and F2–. Which of these species will be paramagnetic?

A. F2+, F2, and F2–


B. F2+ and F2
C. F2 and F2–
D. F2+ and F2–
E. None is paramagnetic.

117.

Consider the species N2–, N2, and N2+. Which of these species will be paramagnetic?

A. N2 and N2–
B. N2+ and N2
C. N2+ and N2–
D. N2–, N2, and N2+
E. None is paramagnetic.
118.

For a homonuclear diatomic molecule, which molecular orbital is the highest in energy?

A.

B.

C.

D.

E. All of these orbitals have the same energy.

119.

For a homonuclear diatomic molecule, which molecular orbital is the lowest in energy?

A.

B.

C.

D.

E. All of these orbitals have the same energy.


120.

Which figure best illustrates the hybrid orbitals on carbon in benzene, C6H6?

A.

B.

C.

D.
E.
121.

Which figure best illustrates the hybrid orbitals on phosphorous in PH3?

A.

B.

C.

D.
E.
122.

Which figure best illustrates the hybrid orbitals on iodine in ICl2–?

A.

B.

C.

D.

E.
123.

The electrons in the delocalized molecular orbitals of benzene (C6H6)

A. are confined between two adjacent bonding atoms.


B. are free to move around the six-membered ring.
C. form the electron pairs in the C–H bonds of the compound.
D. are unevenly distributed through the molecule.
E. give rise to alternating single and double bonds around the ring.

124.

According to molecular orbital (MO) theory, the twelve valence electrons in the O2 molecule are distributed
as follows:

A. 12 in bonding MOs, 0 in antibonding MOs.


B. 10 in bonding MOs, 2 in antibonding MOs.
C. 9 in bonding MOs, 3 in antibonding MOs.
D. 8 in bonding MOs, 4 in antibonding MOs.
E. 7 in bonding MOs, 5 in antibonding MOs.

125.

According to molecular orbital theory, what is the bond order in the O2+ ion?

A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5

126.

According to molecular orbital theory, what is the bond order in the O2– ion?

A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5
127.

The nitrosonium ion, NO+, forms a number of interesting complexes with nickel, cobalt, and iron. According
to molecular orbital theory, which statement about NO+ is correct?

A. NO+ has a bond order of 2 and is paramagnetic.


B. NO+ has a bond order of 2 and is diamagnetic.
C. NO+ has a bond order of 3 and is paramagnetic.
D. NO+ has a bond order of 3 and is diamagnetic.
E. NO+ has a bond order of 2.5 and is neither paramagnetic nor diamagnetic.

128.

Rank the following molecules in order of increasing dipole moment.

A. III < II < I


B. III < I < II
C. I < II < III
D. I < III < II
E. II < III < I
129.

Hyposulfite, SO22–, is a polyatomic ion that has not yet been definitively confirmed to exist. However, the
VSEPR model may still be applied to yield a prediction on its molecular geometry. What is the most reasonable
estimate for the O–S–O bond angle in hyposulfite?

A. 90
B. 106
C. 109.5
D. 112
E. 120

130.

For a polyatomic ion having the general formula AB3n, where A is an atom from Group 6A, B is an atom from
Group 7A, and the ionic charge is n, what charge must the ion have in order to yield a molecular geometry
that is trigonal pyramidal?

A. 3–
B. 1–
C. 1+
D. 3+
E. 5+

131.

Which molecular formula corresponds to a structural formula with carbon atoms having hybridizations of sp,
sp2, and sp3?

A. C3H6
B. C4H4
C. C4H6
D. C5H6
E. C5H8
132.

Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl5?

A.

B.

C.

D.

E.

133.

Allene, C3H4 (shown below), is one component of gas used for high-temperature welding. According to the
valence bond model, which is a proper description of the bonding on the central carbon atom in allene?

A. It shares four bonds, two with each carbon atom on either side.
B. It shares four  bonds, two with each carbon atom on either side.
C. It shares one  bond and one bond with each carbon atom on either side.
D. It shares two  bonds with the carbon atom on the left, and two bonds with the carbon atom on the right.
E. It shares two  bonds with the carbon atom on the right, and two bonds with the carbon atom on the left.
134.

According to molecular orbital theory, what is the bond order of the hypofluorite ion, OF–?

A. 0
B. 0.5
C. 1
D. 1.5
E. 2
135.

Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the
models, if any, are not shown.)

A.

B.

C.

D.

E.
136.

For different structural arrangements of atoms having the formula XeF2Cl2, which structures represent polar
molecules? (Black = Xe, Yellow = F, Green = Cl)

A. I and III
B. II only
C. I, II and III
D. II and III
E. None of these structures are polar.

137.

Thiocarbonyl disulfide (CSF2), based on the coordinate axes provided below, in which direction does the net
molecular dipole moment point for the molecule?

A. It points in the +x direction.


B. It points in the –x direction.
C. It points in the +y direction.
D. It points in the –y direction.
E. The molecule does not have a net molecular dipole moment.
138.

Which is true concerning the dipole moment of a CO2 molecule?

A. The dipole moment is zero because the C–O bond is nonpolar.


B. The dipole moment is zero because the molecule is linear.
C. The dipole moment is zero because the molecule is bent.
D. The dipole moment is nonzero because the molecule is linear.
E. The dipole moment is nonzero because the molecule is bent.

139.

Which is true concerning the molecular geometry of SF6?

A. The predicted F–S–F bond angle is 60.


B. The predicted F–S–F bond angle is 90.
C. The predicted F–S–F bond angles are 90 and 120.
D. The predicted F–S–F bond angles are 90 and 180.
E. The predicted F–S–F bond angles are 60, 120, and 180.

140.

Which statement is not true of molecular orbitals?

A. The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B. A molecular orbital can accommodate up to two electrons.
C. When electrons are added to orbitals of the same energy, the most stable arrangement is predicted by Hund's
rule.
D. Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E. Antibonding molecular orbitals are higher in energy than all of the bonding molecular orbitals.

141.

According to the VSEPR model, a molecule with the general formula AB4 with two lone pairs on the central
atom will have a _____ molecular geometry.

A. tetrahedral
B. square pyramidal
C. square planar
D. octahedral
E. seesaw
142.

Octane, C8H18, boils at 125C, whereas water boils at 100C. This information suggests that the dispersion
forces in nonpolar octane molecules are stronger than the dispersion forces and hydrogen bonding in water.

True False

143.

The energy of a hydrogen bond is greater than that of a typical covalent bond.

True False

144.

Only molecules which do not have dipole moments can experience dispersion forces.

True False

145.

To correctly determine the molecular shape of a molecule requires that you first draw the Lewis structure for
the molecule.

True False

146.

According to molecular orbital theory, all diatomic molecules with an even number of electrons are
diamagnetic.

True False

147.

In the valence bond treatment, a bond is formed when two p orbitals overlap side to side.

True False
148.

In the valence bond treatment, overlap of an s orbital on one atom with an sp3 orbital on another atom gives
rise to a  bond.

True False

149.

Atoms of period 3 and beyond can undergo sp3d2 hybridization, but atoms of period 2 cannot.

True False

150.

The angles between sp2 hybrid orbitals are 109.5.

True False

151.

The bond angle for an sp hybrid orbital is smaller than the bond angle for an sp2 hybrid orbital.

True False

152.

To make an sp3 hybrid orbital, one s atomic orbital is mixed with three p atomic orbitals.

True False

153.

A molecule which contains polar bonds will always have a dipole moment.

True False

154.

According to the VSEPR model, a molecule with the general formula AB3 possessing two lone pairs on the
central atom has a trigonal planar molecular geometry.

True False
155.

The number of lone pairs of electrons on the central atoms is an important factor used to determine the
molecular shape or molecular geometry.

True False

156.

Pi bonds are covalent bonds in which the electron density is concentrated above and below the plane of the
nuclei of the bonding atoms.

True False

157.

The BrF5 molecule has polar bonds and has a net dipole moment.

True False

158.

___________ is the electron-domain geometry and _________ is the molecular geometry for ammonia.

________________________________________

159.

Water has ___________ (number) lone pair(s) of electrons on the central oxygen.

________________________________________
160.

___________ ____________ are described by an instantaneous dipole.

________________________________________

161.

___________ ____________ is another name given for dispersion forces.

________________________________________

162.

The total number of electron domains is used to determine the ___________.

________________________________________

163.

The number of lone pairs on the central atom is used to determine the ____________.

________________________________________

164.

___________ ___________ is a special type of dipole-dipole interaction.

________________________________________
165.

________________ _________ are the attractions that hold particles together in condensed phases.

________________________________________

166.

Identify the dominant (strongest) type of intermolecular force present in RbCl(s).

167.

Identify the dominant (strongest) type of intermolecular force present in H2S(g).

168.

Identify the dominant (strongest) type of intermolecular force present in NH3(l).


169.

Identify the dominant (strongest) type of intermolecular force present in Cl2(l).

170.

Use the VSEPR model to predict the molecular geometry of H3O+ (hydronium ion).

171.

Use the VSEPR model to predict the molecular geometry of CO32.

172.

How many bonds are there in CH3COCH3?


173.

According to the VSEPR model, is the molecule PF5 polar or nonpolar?

174.

How many electron domains are on the central atom for a sp2 hybridized atom?

175.

How many electron domains are on the central atom for a sp3d hybridized atom?

176.

What name is given to the shape of a molecule with no lone pairs of electrons on the central atom and 6
electron domains on the central atom?
177.

The Lewis structure of formaldehyde, CH2O, is shown. Use VSEPR model to predict the molecular geometry
and the H–C–H bond angle. Outline your reasoning.

178.

In one sentence state the basic principle of valence bond theory.

179.

In not more than two sentences, explain when and why chemists make use of the concept of hybridization.
180.

In one sentence state how molecular orbitals are usually obtained.


Chapter 7 - Molecular Geometry, Intermolecular Forces, and
Bonding Theories (test bank) Key

1.

What does the abbreviation VSEPR stand for?

A. Very Specific Electron and Proton Repair


B. Variable Selective of Electron and Protons
C. Valence Shell for Every Proton
D. Very Selective Electron Pair theory
E. Valence-Shell Electron-Pair Repulsion

Blooms: 1. Remember
Chapter - Chapter 7 #1
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape

2.

Which of the following is required for the determination of the VSEPR model and the molecular shape?

A. Atomic mass
B. Number of protons
C. Oxidation number
D. Lewis structure
E. None of the answers is correct.

Blooms: 1. Remember
Chapter - Chapter 7 #2
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
3.

According to the VSEPR model, the predicted molecular geometry of the SO3 molecule is

A. pyramidal.
B. tetrahedral.
C. trigonal planar.
D. seesaw.
E. square planar.

Blooms: 3. Apply
Chapter - Chapter 7 #3
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

4.

What is the predicted molecular geometry of the CH4 molecule according to the VSEPR model?

A. tetrahedral
B. trigonal pyramidal
C. trigonal planar
D. square planar
E. seesaw

Blooms: 3. Apply
Chapter - Chapter 7 #4
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
5.

Using the VSEPR model, what is the predicted molecular geometry of the PCl3 molecule?

A. linear
B. bent
C. trigonal planar
D. trigonal pyramidal
E. tetrahedral

Blooms: 3. Apply
Chapter - Chapter 7 #5
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

6.

What is the predicted molecular geometry of the H2O molecule according to the VSEPR model?

A. tetrahedral
B. trigonal pyramidal
C. bent
D. square planar
E. seesaw

Chapter - Chapter 7 #6
Difficulty: Easy
7.

What is the predicted molecular geometry of the IBr3 molecule according to the VSEPR model?

A. tetrahedral
B. T-shaped
C. bent
D. trigonal planar
E. seesaw

Blooms: 3. Apply
Chapter - Chapter 7 #7
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

8.

According to the VSEPR model, the molecular geometry of the carbonate ion, CO32–, is

A. square planar.
B. tetrahedral.
C. pyramidal.
D. trigonal planar.
E. octahedral.

Blooms: 3. Apply
Chapter - Chapter 7 #8
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
9.

According to the VSEPR model, the predicted molecular geometry of SiCl4 is

A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.

Blooms: 3. Apply
Chapter - Chapter 7 #9
Difficulty: Easy
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

10.

According to the VSEPR model, the predicted molecular geometry of ammonia, NH3, is

A. linear.
B. trigonal planar.
C. bent.
D. tetrahedral.
E. trigonal pyramidal.

Blooms: 3. Apply
Chapter - Chapter 7 #10
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
11.

According to the VSEPR model, which molecule is predicted to be linear?

A. H2S
B. HCN
C. BF3
D. H2CO
E. SO3

Blooms: 4. Analyze
Chapter - Chapter 7 #11
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

12.

According to the VSEPR model, which molecule is predicted to have a molecular geometry that is trigonal
bipyramidal?

A. SF4
B. XeF4
C. NF3
D. SF6
E. PF5

Blooms: 4. Analyze
Chapter - Chapter 7 #12
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
13.

According to the VSEPR model, which molecule has a predicted tetrahedral molecular geometry?

A. XeF4
B. BF3
C. AsF5
D. CF4
E. NH3

Blooms: 4. Analyze
Chapter - Chapter 7 #13
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

14.

Using the VSEPR model, predict the molecular geometry around the central atom in PO43–.

A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral

Blooms: 4. Analyze
Chapter - Chapter 7 #14
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape
15.

Using the VSEPR model, predict the molecular geometry around the central atom in SO32–.

A. trigonal planar
B. trigonal pyramidal
C. tetrahedral
D. trigonal bipyramidal
E. octahedral

Blooms: 4. Analyze
Chapter - Chapter 7 #15
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape

16.

What is the total number of electron domains around the central atom for a molecule having a trigonal
pyramidal molecular geometry, such as NH3?

A. 5
B. 2
C. 3
D. 4
E. 6

Blooms: 4. Analyze
Chapter - Chapter 7 #16
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
17.

What is the total number of electron domains around the central atom for a molecule having a T-shaped
molecular geometry, such as BrF3?

A. 5
B. 2
C. 3
D. 4
E. 6

Blooms: 4. Analyze
Chapter - Chapter 7 #17
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

18.

What is the total number of electron domains around the central atom for a molecule having a square
pyramidal molecular geometry, such as ClF5?

A. 5
B. 2
C. 3
D. 4
E. 6

Blooms: 4. Analyze
Chapter - Chapter 7 #18
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
19.

What is the total number of electron domains around the central atom for a molecule having a square planar
molecular geometry, such as XeBr4?

A. 2
B. 3
C. 4
D. 5
E. 6

Blooms: 4. Analyze
Chapter - Chapter 7 #19
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

20.

What is the number of lone electron pairs on the central atom of a molecule having a seesaw molecular
geometry, such as SF4?

A. 1
B. 2
C. 3
D. 4
E. 6

Blooms: 4. Analyze
Chapter - Chapter 7 #20
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Lewis Dot Symbols
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
21.

What is the number of lone electron pairs on the central atom of a molecule having a trigonal pyramidal
molecular geometry, such as NH3?

A. 1
B. 2
C. 3
D. 0
E. 4

Blooms: 4. Analyze
Chapter - Chapter 7 #21
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape

22.

What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as CO2?

A. 1
B. 2
C. 3
D. 0
E. 4

Blooms: 4. Analyze
Chapter - Chapter 7 #22
Difficulty: Medium
Subtopic: Lewis Dot Symbols
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Chemical Bonding
Topic: Molecular Shape
23.

What is the number of lone electron pairs on the central atom of a molecule having a linear molecular
geometry, such as ClF2–?

A. 1
B. 2
C. 3
D. 0
E. 4

Blooms: 3. Apply
Chapter - Chapter 7 #23
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

24.

According to the VSEPR model, a molecule with the general formula AB3 with no lone pairs on the central
atom will have a ______ molecular shape.

A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. trigonal pyramidal

Blooms: 3. Apply
Chapter - Chapter 7 #24
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
25.

According to the VSEPR model, a molecule with the general formula AB5 with no lone pairs on the central
atom will have a ______ molecular geometry.

A. tetrahedral
B. trigonal planar
C. trigonal pyramidal
D. trigonal bipyramidal
E. seesaw

Blooms: 3. Apply
Chapter - Chapter 7 #25
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

26.

According to the VSEPR model, a molecule with the general formula AB2 with two lone pairs on the central
atom will have a _____ molecular geometry.

A. linear
B. bent
C. trigonal planar
D. tetrahedral
E. seesaw

Blooms: 3. Apply
Chapter - Chapter 7 #26
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
27.

According to the VSEPR model, a molecule with the general formula AB5 with one lone pair on the central
atom will have a ______ molecular geometry.

A. tetrahedral
B. trigonalbipyramidal
C. square pyramidal
D. octahedral
E. seesaw

Blooms: 3. Apply
Chapter - Chapter 7 #27
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

28.

What is the molecular geometry of N2O as predicted by the VSEPR model?

A. trigonal pyramidal
B. trigonal planar
C. tetrahedral
D. bent
E. linear

Blooms: 4. Analyze
Chapter - Chapter 7 #28
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
29.

What is the molecular geometry of the thiocyanate anion, SCN–, as predicted by the VSEPR model? (Carbon
is the central atom.)

A. linear
B. bent
C. tetrahedral
D. trigonal planar
E. trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #29
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

30.

What is the molecular geometry of BeH2 as predicted by the VSEPR model?

A. tetrahedral
B. bent
C. trigonal planar
D. linear
E. trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #30
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
31.

What is the molecular geometry of NOCl as predicted by the VSEPR model?

A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #31
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

32.

What is the molecular geometry of NO2– as predicted by the VSEPR model?

A. linear
B. trigonal planar
C. bent
D. tetrahedral
E. trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #32
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
33.

What is the molecular geometry of ClO3F as predicted by the VSEPR model?

A. trigonal pyramidal
B. square planar
C. square pyramidal
D. tetrahedral
E. octahedral

Blooms: 4. Analyze
Chapter - Chapter 7 #33
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

34.

What is the molecular geometry of HOF as predicted by the VSEPR model?

A. trigonal pyramidal
B. bent
C. tetrahedral
D. linear
E. trigonal planar

Blooms: 4. Analyze
Chapter - Chapter 7 #34
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
35.

What is the molecular geometry of XeO2F2 as predicted by the VSEPR model?

A. square planar
B. tetrahedral
C. square pyramidal
D. seesaw
E. octahedral

Blooms: 4. Analyze
Chapter - Chapter 7 #35
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
36.

What is the molecular geometry of ClF2– as predicted by the VSEPR model?

A. linear
B. bent
C. seesaw
D. T-shaped
E. trigonal bipyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #36
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
37.

What is the molecular geometry of SiF62– as predicted by the VSEPR model?

A. trigonal bipyramidal
B. octahedral
C. tetrahedral
D. seesaw
E. square pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #37
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
38.

According to the VSEPR model, what is the predicted electron-domain geometry around the central iodine
atom in the ion lF2– ?

A. octahedral
B. trigonal bipyramidal
C. tetrahedral
D. trigonal planar
E. bent

Blooms: 4. Analyze
Chapter - Chapter 7 #38
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape

39.

According to the VSEPR model, which one of the following molecules and ions will definitely have at least
one 90 bond angle in it? (In each case, except water, the central atom is the first one in the formula.)

A. AlCl4–
B. NH3
C. PCl5
D. CO2
E. H2O

Blooms: 5. Evaluate
Chapter - Chapter 7 #39
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
40.

According to the VSEPR model, what is the predicted Cl–C–Cl bond angle in CCl4?

A. 90
B. 109.5
C. 120
D. 145
E. 180

Blooms: 4. Analyze
Chapter - Chapter 7 #40
Difficulty: Easy
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

41.

Which is the most reasonable prediction for the H–N–H bond angle in NH3?

A. 90
B. 109.5
C. 120
D. 107
E. 105

Blooms: 4. Analyze
Chapter - Chapter 7 #41
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
42.

What is the predicted O–C–O bond angle in CO2?

A. 60
B. 90
C. 109.5
D. 120
E. 180

Blooms: 4. Analyze
Chapter - Chapter 7 #42
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

43.

Which is the most reasonable prediction for the H–O–H bond angle in H2O?

A. 90
B. 109.5
C. 120
D. 107
E. 105

Blooms: 4. Analyze
Chapter - Chapter 7 #43
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
44.

Which is the most reasonable prediction for the Cl–N–Cl bond angle in NCl3?

A. 120
B. 111
C. 109.5
D. 107
E. 90

Blooms: 4. Analyze
Chapter - Chapter 7 #44
Difficulty: Medium
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

45.

Which is the most reasonable prediction for the three F–Br–F bond angles in BrF3?

A. 90, 90, and 180


B. 86, 94, and 180
C. 86, 86, and 172
D. 94, 94, and 172
E. 120, 120, and 120

Blooms: 4. Analyze
Chapter - Chapter 7 #45
Difficulty: Hard
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
46.

Which is the most reasonable prediction for the H–C–H bond angle in CH4?

A. 90
B. 109.5
C. 120
D. 107
E. 105

Blooms: 4. Analyze
Chapter - Chapter 7 #46
Difficulty: Easy
Subtopic: Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

47.

How do you describe the molecular geometry of a molecule that has more than one central atom?

A. You describe the molecular geometry around the most electronegative atom.
B. You describe the molecular geometry around each central atom separately.
C. You describe the molecular geometry around the most electropositive atom.
D. You describe the molecular geometry around the atom with the largest atomic radius.
E. You describe the molecular geometry around the atom with the largest bond angle.

Blooms: 2. Understand
Chapter - Chapter 7 #47
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
48.

Which one of the following molecules is nonpolar?

A. NH3
B. OF2
C. CH3Cl
D. H2O
E. BeCl2

Blooms: 5. Evaluate
Chapter - Chapter 7 #48
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

49.

The PCl5 molecule has

A. nonpolar bonds, and is a nonpolar molecule.


B. nonpolar bonds, but is a polar molecule.
C. polar bonds, and is a polar molecule.
D. polar bonds, but is a nonpolar molecule.

Blooms: 5. Evaluate
Chapter - Chapter 7 #49
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
50.

Which one of the following molecules is nonpolar?

A. CO2
B. PF3
C. KCl
D. IBr3
E. CHCl3

Blooms: 5. Evaluate
Chapter - Chapter 7 #50
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

51.

Which one of the following molecules has a zero dipole moment?

A. CO
B. CH2Cl2
C. SO3
D. SO2
E. NH3

Blooms: 5. Evaluate
Chapter - Chapter 7 #51
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
52.

Which one of the following molecules is polar?

A. PBr5
B. CCl4
C. BrF5
D. XeF2
E. XeF4

Blooms: 5. Evaluate
Chapter - Chapter 7 #52
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

53.

Predict the molecular geometry and polarity of the SO2 molecule.

A. linear, polar
B. linear, nonpolar
C. bent, polar
D. bent, nonpolar
E. trigonal planar, polar

Blooms: 4. Analyze
Chapter - Chapter 7 #53
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
54.

Predict the molecular geometry and polarity of the CS2 molecule.

A. linear, polar
B. linear, nonpolar
C. tetrahedral, nonpolar
D. bent, nonpolar
E. bent, polar

Blooms: 4. Analyze
Chapter - Chapter 7 #54
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

55.

Which one of the following molecules is polar?

A. CH4
B. CHBr3
C. F2
D. CBr4
E. CO2

Blooms: 5. Evaluate
Chapter - Chapter 7 #55
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
56.

Which of the following molecules has a nonzero dipole moment?

A. BeCl2
B. SF2
C. KrF2
D. CO2
E. CCl4

Blooms: 5. Evaluate
Chapter - Chapter 7 #56
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

57.

Which has a dipole moment of zero?

A. N2O
B. NF3
C. H2S
D. SeO3
E. CH3Cl

Blooms: 5. Evaluate
Chapter - Chapter 7 #57
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Electronegativity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape
58.

What is the name given to the attractive forces that hold particles together in the condensed phase?

A. ionic bonds
B. covalent bonds
C. intermolecular forces
D. electronegativity
E. electron attraction

Blooms: 2. Understand
Chapter - Chapter 7 #58
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

59.

Which are considered van der Waals forces?


I. dispersion forces
II. dipole-dipole interactions
III. hydrogen bonding

A. I and III
B. II only
C. III only
D. I, II, and III
E. I only

Blooms: 2. Understand
Chapter - Chapter 7 #59
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
60.

Which of the following is defined as the attractive forces between polar molecules?
I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions

A. I and III
B. II only
C. III only
D. I, II, and III
E. I only

Blooms: 2. Understand
Chapter - Chapter 7 #60
Difficulty: Easy
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
Topic: Molecular Shape

61.

In a sample of hydrogen iodide, __________________ are the most important intermolecular forces.

A. dipole-dipole forces
B. London dispersion forces
C. hydrogen bonding
D. covalent bonds
E. polar covalent bonds

Blooms: 4. Analyze
Chapter - Chapter 7 #61
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
62.

The strongest intermolecular interactions between hydrogen sulfide (H2S) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. disulfide linkages.

Blooms: 4. Analyze
Chapter - Chapter 7 #62
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

63.

Which substance should exhibit hydrogen bonding in the liquid phase?

A. PH3
B. He
C. H2S
D. CH4
E. CH3OH

Blooms: 4. Analyze
Chapter - Chapter 7 #63
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
64.

Which of the responses includes all of the following that can form hydrogen bonds with water molecules?

I. Na+, II. CH3COOH, III. C2H6, IV. CH3NH2

A. I and II
B. I and III
C. II and III
D. II and IV
E. III and IV

Blooms: 5. Evaluate
Chapter - Chapter 7 #64
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

65.

Which substance will exhibit hydrogen bonding between molecules?

A. (CH3)3N
B. CH3–O–CH3
C. CH3CH2–OH
D. CH3CH2–F
E. HI

Blooms: 5. Evaluate
Chapter - Chapter 7 #65
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
66.

Which one of the following pure substances will exhibit hydrogen bonding?

A. CH4
B. H2C=CH2
C. H2O
D. CHCl3
E. CHF3

Blooms: 5. Evaluate
Chapter - Chapter 7 #66
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

67.

Which of the following atoms does not participate in hydrogen bonding?

A. S
B. O
C. F
D. N
E. H

Blooms: 5. Evaluate
Chapter - Chapter 7 #67
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
68.

The strongest intermolecular interactions between ethyl alcohol (CH3CH2OH) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-oxygen bonds.

Blooms: 4. Analyze
Chapter - Chapter 7 #68
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

69.

The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. ionic bonds.

Blooms: 4. Analyze
Chapter - Chapter 7 #69
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
70.

Ammonia's unusually high melting point is the result of

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. ionic bonding.

Blooms: 4. Analyze
Chapter - Chapter 7 #70
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

71.

What types of intermolecular forces exist between hydrogen fluoride molecules?


I. London forces
II. dipole-dipole interactions
III. hydrogen bonding
IV. ion-dipole interactions

A. II and III
B. I, II, and III
C. I only
D. III only
E. I and III

Blooms: 4. Analyze
Chapter - Chapter 7 #71
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
72.

In which of the following compounds will the molecules not form hydrogen bonds with each other?

A.

B.

C.

D.

E.
Blooms: 5. Evaluate
Chapter - Chapter 7 #72
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

73.

What is another name given to dispersion forces?

A. ion-dipole interactions
B. dipole-dipole interactions
C. hydrogen bonding
D. covalent forces
E. London forces

Blooms: 2. Understand
Chapter - Chapter 7 #73
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
74.

The strongest intermolecular interactions between pentane (C5H12) molecules arise from

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. ion-dipole interactions.
E. carbon-carbon bonds.

Blooms: 4. Analyze
Chapter - Chapter 7 #74
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

75.

Which kinds of intermolecular forces exist between propane molecules?


I. dispersion forces
II. dipole-dipole interactions
III. ion-dipole interactions

A. I only
B. II only
C. III only
D. I, II, and III
E. I and III

Blooms: 4. Analyze
Chapter - Chapter 7 #75
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
76.

Helium atoms do not combine to form He2 molecules, yet He atoms do attract one another weakly through

A. dipole-dipole forces.
B. ion-dipole forces.
C. dispersion forces.
D. dipole-induced dipole forces.
E. hydrogen bonding.

Blooms: 2. Understand
Chapter - Chapter 7 #76
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

77.

Which one of the following pure substance has both dispersion forces and dipole-dipole forces?

A. HCl
B. BCl3
C. Br2
D. H2
E. CO2

Blooms: 4. Analyze
Chapter - Chapter 7 #77
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
78.

For which of the following pure substances are the intermolecular interactions entirely due to dispersion
forces?

A. C2H6
B. CH3OCH3
C. NO2
D. H2S
E. Ca(NO3)2

Blooms: 4. Analyze
Chapter - Chapter 7 #78
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

79.

Which of the following pure substances has the strongest dispersion forces?

A. C4H10
B. C5H12
C. C6H14
D. C7H16
E. C8H18

Blooms: 4. Analyze
Chapter - Chapter 7 #79
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
80.

At a temperature of 27 K, neon condenses due to

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonding.
E. intramolecular forces.

Blooms: 4. Analyze
Chapter - Chapter 7 #80
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

81.

Octane is a component of fuel used in internal combustion engines. The dominant intermolecular forces in
octane are

A. dipole-dipole forces.
B. London dispersion forces.
C. hydrogen bonding.
D. covalent bonds.
E. carbon-hydrogen bonds.

Blooms: 4. Analyze
Chapter - Chapter 7 #81
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
82.

Which one of the following involves ion-dipole interactions?

A. Na+ and Cl–


B. H+ and F–
C. Na+ and Mg2+
D. two water molecules
E. Na+ and H2O

Blooms: 4. Analyze
Chapter - Chapter 7 #82
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

83.

What is the intermolecular force that exists between a calcium ion and water?

A. dipole-dipole forces
B. London dispersion forces
C. ion-dipole forces
D. covalent bonding
E. ion-ion forces

Blooms: 4. Analyze
Chapter - Chapter 7 #83
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape
84.

What is the intermolecular force that exists between a magnesium ion and hydrogen sulfide?

A. dipole-dipole forces
B. London dispersion forces
C. ionic bonding
D. ion-dipole forces
E. ion-ion forces

Blooms: 4. Analyze
Chapter - Chapter 7 #84
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
Topic: Molecular Shape

85.

Which of the following pairs is arranged with the particle of higher polarizability listed first?

A. Se2–, S2–
B. I, I–
C. Mg2+, Mg
D. Br, I
E. None of these choices is correct.

Blooms: 5. Evaluate
Chapter - Chapter 7 #85
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity)
Topic: Chemical Periodicity
Topic: Molecular Shape
86.

Which of the following pairs is arranged with the particle of higher polarizability listed first?

A. CCl4, CI4
B. H2O, H2Se
C. C6 H14, C4H10
D. NH3, NF3
E. None of these choices is correct.

Blooms: 5. Evaluate
Chapter - Chapter 7 #86
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic Radius, Electron Affinity)
Topic: Chemical Periodicity
Topic: Molecular Shape

87.

Which of the following pure substances has the highest boiling point?

A. CF4
B. CCl4
C. CBr4
D. CI4
E. CH4

Blooms: 5. Evaluate
Chapter - Chapter 7 #87
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
88.

Which of the following pure substances has the highest boiling point?

A. CH4
B. Cl2
C. Kr
D. CH3Cl
E. N2

Blooms: 5. Evaluate
Chapter - Chapter 7 #88
Difficulty: Medium
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape

89.

Choose the response that lists the member of each of the following pairs that has the higher boiling point.

I. H2O or KI, II. HF or HI, III. Cl2 or Br2

A. H2O, HF, and Cl2


B. KI, HF, and Br2
C. KI, HI, and Br2
D. H2O, HI, and Cl2
E. KI, HF, and Cl2

Blooms: 5. Evaluate
Chapter - Chapter 7 #89
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape
90.

Arrange the following in order of increasing boiling point: RbCl, CH3Cl, CH3OH, CH4.

A. CH3OH < CH3Cl < RbCl < CH4


B. CH3OH < CH4 < CH3Cl < RbCl
C. RbCl < CH3 Cl < CH3 OH < CH4
D. CH4 < CH3OH < CH3Cl < RbCl
E. CH4 < CH3Cl < CH3OH < RbCl

Blooms: 5. Evaluate
Chapter - Chapter 7 #90
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Phase Changes
Topic: Intermolecular Forces
Topic: Molecular Shape

91.

Krypton has a higher melting point than argon because of its

A. hydrogen bonding.
B. stronger dispersion forces.
C. permanent dipole moment.
D. ionic bonds.
E. greater ionization energy.

Blooms: 5. Evaluate
Chapter - Chapter 7 #91
Difficulty: Medium
Subtopic: Phase Changes
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
92.

Indicate the type of hybrid orbitals used by the central atom in PCl3.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #92
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

93.

Indicate the type of hybrid orbitals used by the central atom in CCl4.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #93
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
94.

Indicate the type of hybrid orbitals used by the central atom in SF6.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #94
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

95.

What is the hybridization of the As atom in the AsF5 molecule?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #95
Difficulty: Medium
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
Topic: Molecular Shape
96.

What is the hybridization on the central atom in NO3– ?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #96
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
Topic: Molecular Shape

97.

In which molecule is the central atom sp2 hybridized?

A. SO2
B. N2O
C. BeCl2
D. NF3
E. PF5

Blooms: 4. Analyze
Chapter - Chapter 7 #97
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
98.

What is the hybridization of As in the AsF4– ion?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #98
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

99.

What is the hybridization of the central atom in ClO3–?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #99
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
100.

The hybridization of the central nitrogen atom in the molecule N2O is

A. sp.
B. sp2.
C. sp3.
D. sp3d.
E. sp3d2.

Blooms: 4. Analyze
Chapter - Chapter 7 #100
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
Topic: Electron Configuration

101.

A molecule with the formula AB3 and a trigonal planar molecular geometry uses _________ to form its 
bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

Blooms: 4. Analyze
Chapter - Chapter 7 #101
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
102.

A molecule with the formula AB4 and a tetrahedral molecular geometry uses _________ to form its  bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

Blooms: 4. Analyze
Chapter - Chapter 7 #102
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

103.

A molecule with the formula AB4 and a square planar molecular geometry uses _________ to form its 
bonds.

A. sp hybrid orbitals
B. sp2 hybrid orbitals
C. sp3 hybrid orbitals
D. sp3d hybrid orbitals
E. sp3d2 hybrid orbitals

Blooms: 4. Analyze
Chapter - Chapter 7 #103
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
104.

Carbon uses ______ hybrid orbitals in ClCN.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #104
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

105.

Valence bond theory predicts that carbon will use _____ hybrid orbitals in the carbonate anion, CO32–.

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #105
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
106.

Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide, SO2 .

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #106
Difficulty: Hard
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

107.

When PCl5 solidifies it forms PCl4+cations and PCl6– anions. According to valence bond theory, what hybrid
orbitals are used by phosphorus in the PCl4+cation?

A. sp
B. sp2
C. sp3
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #107
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
108.

Valence bond theory predicts that iodine will use _____ hybrid orbitals in ICl2–.

A. sp2
B. sp3
C. sp3d
D. sp3d2
E. None of these choices is correct.

Blooms: 4. Analyze
Chapter - Chapter 7 #108
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

109.

Which statement about orbital hybridization is incorrect?

A. The carbon atom in CH4 is sp3 hybridized.


B. The carbon atom in CO2 is sp hybridized.
C. The nitrogen atom in NH3 is sp2 hybridized.
D. sp2 hybrid orbitals are coplanar, and at 120 to each other.
E. sp hybrid orbitals lie at 180 to each other.

Blooms: 4. Analyze
Chapter - Chapter 7 #109
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Exceptions to the Octet Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
110.

For which one of the following molecules is the indicated type of hybridization not appropriate for the central
atom?

A. BeCl2; sp2
B. SiH4; sp3
C. BF3; sp2
D. C2H2; sp
E. H2O; sp3

Blooms: 4. Analyze
Chapter - Chapter 7 #110
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration

111.

What is the hybridization of phosphorus in PCl3?

A. sp3
B. sp2
C. sp
D. sp3d
E. sp3d2

Blooms: 4. Analyze
Chapter - Chapter 7 #111
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
112.

How many bonds are there in one molecule of acrylonitrile (shown below)?

A. 1
B. 2
C. 3
D. 5
E. 9

Blooms: 4. Analyze
Chapter - Chapter 7 #112
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
113.

How many bonds are there in one molecule of 1,5-hexadiyne (shown below)?

A. 2
B. 4
C. 6
D. 11
E. 15

Blooms: 4. Analyze
Chapter - Chapter 7 #113
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
114.

According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of

A. three  bonds and no bonds.


B. two  bonds and one bond.
C. one  bond and two bonds.
D. no  bonds and three bonds.
E. one  bond, one bond, and one bond intermediate between  and .

Blooms: 4. Analyze
Chapter - Chapter 7 #114
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories

115.

The number of bonds in phosgene, COCl2, is

A. 0.
B. 1.
C. 2.
D. 3.
E. 4.

Blooms: 4. Analyze
Chapter - Chapter 7 #115
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
116.

Consider the species F2+, F2, and F2–. Which of these species will be paramagnetic?

A. F2+, F2, and F2–


B. F2+ and F2
C. F2 and F2–
D. F2+ and F2–
E. None is paramagnetic.

Blooms: 4. Analyze
Chapter - Chapter 7 #116
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration

117.

Consider the species N2–, N2, and N2+. Which of these species will be paramagnetic?

A. N2 and N2–
B. N2+ and N2
C. N2+ and N2–
D. N2–, N2, and N2+
E. None is paramagnetic.

Blooms: 4. Analyze
Chapter - Chapter 7 #117
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
118.

For a homonuclear diatomic molecule, which molecular orbital is the highest in energy?

A.

B.

C.

D.

E. All of these orbitals have the same energy.

Blooms: 3. Apply
Chapter - Chapter 7 #118
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories

119.

For a homonuclear diatomic molecule, which molecular orbital is the lowest in energy?

A.

B.

C.

D.

E. All of these orbitals have the same energy.

Blooms: 3. Apply
Chapter - Chapter 7 #119
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
120.

Which figure best illustrates the hybrid orbitals on carbon in benzene, C6H6?

A.

B.

C.

D.
E.

Blooms: 4. Analyze
Chapter - Chapter 7 #120
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
121.

Which figure best illustrates the hybrid orbitals on phosphorous in PH3?

A.

B.

C.

D.
E.

Blooms: 4. Analyze
Chapter - Chapter 7 #121
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
122.

Which figure best illustrates the hybrid orbitals on iodine in ICl2–?

A.

B.

C.

D.

E.
Blooms: 4. Analyze
Chapter - Chapter 7 #122
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories

123.

The electrons in the delocalized molecular orbitals of benzene (C6H6)

A. are confined between two adjacent bonding atoms.


B. are free to move around the six-membered ring.
C. form the electron pairs in the C–H bonds of the compound.
D. are unevenly distributed through the molecule.
E. give rise to alternating single and double bonds around the ring.

Blooms: 2. Understand
Chapter - Chapter 7 #123
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories

124.

According to molecular orbital (MO) theory, the twelve valence electrons in the O2 molecule are distributed
as follows:

A. 12 in bonding MOs, 0 in antibonding MOs.


B. 10 in bonding MOs, 2 in antibonding MOs.
C. 9 in bonding MOs, 3 in antibonding MOs.
D. 8 in bonding MOs, 4 in antibonding MOs.
E. 7 in bonding MOs, 5 in antibonding MOs.

Blooms: 4. Analyze
Chapter - Chapter 7 #124
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
125.

According to molecular orbital theory, what is the bond order in the O2+ ion?

A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5

Blooms: 4. Analyze
Chapter - Chapter 7 #125
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration

126.

According to molecular orbital theory, what is the bond order in the O2– ion?

A. 5.5
B. 5
C. 4
D. 2.5
E. 1.5

Blooms: 4. Analyze
Chapter - Chapter 7 #126
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
127.

The nitrosonium ion, NO+, forms a number of interesting complexes with nickel, cobalt, and iron. According
to molecular orbital theory, which statement about NO+ is correct?

A. NO+ has a bond order of 2 and is paramagnetic.


B. NO+ has a bond order of 2 and is diamagnetic.
C. NO+ has a bond order of 3 and is paramagnetic.
D. NO+ has a bond order of 3 and is diamagnetic.
E. NO+ has a bond order of 2.5 and is neither paramagnetic nor diamagnetic.

Blooms: 4. Analyze
Chapter - Chapter 7 #127
Difficulty: Hard
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
128.

Rank the following molecules in order of increasing dipole moment.

A. III < II < I


B. III < I < II
C. I < II < III
D. I < III < II
E. II < III < I

Blooms: 5. Evaluate
Chapter - Chapter 7 #128
Difficulty: Hard
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Representing Organic Molecules (Structural Formulas)
Topic: Molecular Shape
Topic: Organic Molecules
129.

Hyposulfite, SO22–, is a polyatomic ion that has not yet been definitively confirmed to exist. However, the
VSEPR model may still be applied to yield a prediction on its molecular geometry. What is the most reasonable
estimate for the O–S–O bond angle in hyposulfite?

A. 90
B. 106
C. 109.5
D. 112
E. 120

Blooms: 4. Analyze
Chapter - Chapter 7 #129
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape

130.

For a polyatomic ion having the general formula AB3n, where A is an atom from Group 6A, B is an atom from
Group 7A, and the ionic charge is n, what charge must the ion have in order to yield a molecular geometry
that is trigonal pyramidal?

A. 3–
B. 1–
C. 1+
D. 3+
E. 5+

Blooms: 4. Analyze
Chapter - Chapter 7 #130
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
131.

Which molecular formula corresponds to a structural formula with carbon atoms having hybridizations of sp,
sp2, and sp3?

A. C3H6
B. C4H4
C. C4H6
D. C5H6
E. C5H8

Blooms: 5. Evaluate
Chapter - Chapter 7 #131
Difficulty: Hard
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Representing Organic Molecules (Structural Formulas)
Subtopic: Writing Lewis Dot Structures
Topic: Covalent Bond Theories
Topic: Molecular Shape
Topic: Organic Molecules

132.

Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl5?

A.

B.

C.

D.

E.

Blooms: 5. Evaluate
Chapter - Chapter 7 #132
Difficulty: Hard
Subtopic: Hunds Rule
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
Topic: Electron Configuration
133.

Allene, C3H4 (shown below), is one component of gas used for high-temperature welding. According to the
valence bond model, which is a proper description of the bonding on the central carbon atom in allene?

A. It shares four bonds, two with each carbon atom on either side.
B. It shares four  bonds, two with each carbon atom on either side.
C. It shares one  bond and one bond with each carbon atom on either side.
D. It shares two  bonds with the carbon atom on the left, and two bonds with the carbon atom on the right.
E. It shares two  bonds with the carbon atom on the right, and two bonds with the carbon atom on the left.

Blooms: 3. Apply
Chapter - Chapter 7 #133
Difficulty: Hard
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories

134.

According to molecular orbital theory, what is the bond order of the hypofluorite ion, OF–?

A. 0
B. 0.5
C. 1
D. 1.5
E. 2

Blooms: 4. Analyze
Chapter - Chapter 7 #134
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration
135.

Which formula is incorrectly matched with its VSEPR model representation? (Note: Lone pairs on the
models, if any, are not shown.)

A.

B.

C.

D.

E.
Blooms: 5. Evaluate
Chapter - Chapter 7 #135
Difficulty: Hard
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape

136.

For different structural arrangements of atoms having the formula XeF2Cl2, which structures represent polar
molecules? (Black = Xe, Yellow = F, Green = Cl)

A. I and III
B. II only
C. I, II and III
D. II and III
E. None of these structures are polar.

Blooms: 4. Analyze
Chapter - Chapter 7 #136
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
137.

Thiocarbonyl disulfide (CSF2), based on the coordinate axes provided below, in which direction does the net
molecular dipole moment point for the molecule?

A. It points in the +x direction.


B. It points in the –x direction.
C. It points in the +y direction.
D. It points in the –y direction.
E. The molecule does not have a net molecular dipole moment.

Blooms: 4. Analyze
Chapter - Chapter 7 #137
Difficulty: Hard
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
138.

Which is true concerning the dipole moment of a CO2 molecule?

A. The dipole moment is zero because the C–O bond is nonpolar.


B. The dipole moment is zero because the molecule is linear.
C. The dipole moment is zero because the molecule is bent.
D. The dipole moment is nonzero because the molecule is linear.
E. The dipole moment is nonzero because the molecule is bent.

Blooms: 4. Analyze
Chapter - Chapter 7 #138
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

139.

Which is true concerning the molecular geometry of SF6?

A. The predicted F–S–F bond angle is 60.


B. The predicted F–S–F bond angle is 90.
C. The predicted F–S–F bond angles are 90 and 120.
D. The predicted F–S–F bond angles are 90 and 180.
E. The predicted F–S–F bond angles are 60, 120, and 180.

Blooms: 4. Analyze
Chapter - Chapter 7 #139
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
140.

Which statement is not true of molecular orbitals?

A. The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B. A molecular orbital can accommodate up to two electrons.
C. When electrons are added to orbitals of the same energy, the most stable arrangement is predicted by Hund's
rule.
D. Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E. Antibonding molecular orbitals are higher in energy than all of the bonding molecular orbitals.

Blooms: 4. Analyze
Chapter - Chapter 7 #140
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories

141.

According to the VSEPR model, a molecule with the general formula AB4 with two lone pairs on the central
atom will have a _____ molecular geometry.

A. tetrahedral
B. square pyramidal
C. square planar
D. octahedral
E. seesaw

Blooms: 4. Analyze
Chapter - Chapter 7 #141
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Electron Configuration
Topic: Molecular Shape
142.

Octane, C8H18, boils at 125C, whereas water boils at 100C. This information suggests that the dispersion
forces in nonpolar octane molecules are stronger than the dispersion forces and hydrogen bonding in water.

TRUE

Blooms: 4. Analyze
Chapter - Chapter 7 #142
Difficulty: Easy
Subtopic: Phase Changes
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

143.

The energy of a hydrogen bond is greater than that of a typical covalent bond.

FALSE

Blooms: 3. Apply
Chapter - Chapter 7 #143
Difficulty: Medium
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

144.

Only molecules which do not have dipole moments can experience dispersion forces.

FALSE

Blooms: 4. Analyze
Chapter - Chapter 7 #144
Difficulty: Easy
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
Topic: Molecular Shape
145.

To correctly determine the molecular shape of a molecule requires that you first draw the Lewis structure for
the molecule.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #145
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

146.

According to molecular orbital theory, all diatomic molecules with an even number of electrons are
diamagnetic.

FALSE

Blooms: 4. Analyze
Chapter - Chapter 7 #146
Difficulty: Medium
Subtopic: Diamagnetism and Paramagnetism
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Topic: Electron Configuration

147.

In the valence bond treatment, a bond is formed when two p orbitals overlap side to side.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #147
Difficulty: Easy
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
148.

In the valence bond treatment, overlap of an s orbital on one atom with an sp3 orbital on another atom gives
rise to a  bond.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #148
Difficulty: Medium
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories

149.

Atoms of period 3 and beyond can undergo sp3d2 hybridization, but atoms of period 2 cannot.

TRUE

Blooms: 3. Apply
Chapter - Chapter 7 #149
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Subtopic: Periodic Classification of the Elements
Topic: Chemical Periodicity
Topic: Covalent Bond Theories

150.

The angles between sp2 hybrid orbitals are 109.5.

FALSE

Blooms: 2. Understand
Chapter - Chapter 7 #150
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
151.

The bond angle for an sp hybrid orbital is smaller than the bond angle for an sp2 hybrid orbital.

FALSE

Blooms: 2. Understand
Chapter - Chapter 7 #151
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories

152.

To make an sp3 hybrid orbital, one s atomic orbital is mixed with three p atomic orbitals.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #152
Difficulty: Easy
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories

153.

A molecule which contains polar bonds will always have a dipole moment.

FALSE

Blooms: 4. Analyze
Chapter - Chapter 7 #153
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Molecular Polarity (Dipole Moment)
Topic: Chemical Bonding
Topic: Molecular Shape
154.

According to the VSEPR model, a molecule with the general formula AB3 possessing two lone pairs on the
central atom has a trigonal planar molecular geometry.

FALSE

Blooms: 4. Analyze
Chapter - Chapter 7 #154
Difficulty: Medium
Subtopic: Exceptions to the Octet Rule
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Electron Configuration
Topic: Molecular Shape

155.

The number of lone pairs of electrons on the central atoms is an important factor used to determine the
molecular shape or molecular geometry.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #155
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape

156.

Pi bonds are covalent bonds in which the electron density is concentrated above and below the plane of the
nuclei of the bonding atoms.

TRUE

Blooms: 2. Understand
Chapter - Chapter 7 #156
Difficulty: Easy
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Covalent Bond Theories
157.

The BrF5 molecule has polar bonds and has a net dipole moment.

TRUE

Blooms: 4. Analyze
Chapter - Chapter 7 #157
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Exceptions to the Octet Rule
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Molecular Shape

158.

___________ is the electron-domain geometry and _________ is the molecular geometry for ammonia.

Tetrahedral, trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #158
Difficulty: Medium
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
159.

Water has ___________ (number) lone pair(s) of electrons on the central oxygen.

two

Blooms: 4. Analyze
Chapter - Chapter 7 #159
Difficulty: Easy
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

160.

___________ ____________ are described by an instantaneous dipole.

London forces or Dispersion forces

Blooms: 2. Understand
Chapter - Chapter 7 #160
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

161.

___________ ____________ is another name given for dispersion forces.

London forces

Blooms: 2. Understand
Chapter - Chapter 7 #161
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
162.

The total number of electron domains is used to determine the ___________.

electron–domain geometry

Blooms: 2. Understand
Chapter - Chapter 7 #162
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

163.

The number of lone pairs on the central atom is used to determine the ____________.

molecular geometry

Blooms: 2. Understand
Chapter - Chapter 7 #163
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape

164.

___________ ___________ is a special type of dipole-dipole interaction.

Hydrogen bonding

Blooms: 2. Understand
Chapter - Chapter 7 #164
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces
165.

________________ _________ are the attractions that hold particles together in condensed phases.

Intermolecular forces

Blooms: 2. Understand
Chapter - Chapter 7 #165
Difficulty: Easy
Subtopic: Types of Intermolecular Forces
Topic: Intermolecular Forces

166.

Identify the dominant (strongest) type of intermolecular force present in RbCl(s).

ionic

Blooms: 4. Analyze
Chapter - Chapter 7 #166
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
167.

Identify the dominant (strongest) type of intermolecular force present in H2S(g).

dipole-dipole

Blooms: 4. Analyze
Chapter - Chapter 7 #167
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces

168.

Identify the dominant (strongest) type of intermolecular force present in NH3(l).

hydrogen bonding

Blooms: 4. Analyze
Chapter - Chapter 7 #168
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces
169.

Identify the dominant (strongest) type of intermolecular force present in Cl2(l).

dispersion

Blooms: 4. Analyze
Chapter - Chapter 7 #169
Difficulty: Easy
Subtopic: Bond Polarity
Subtopic: Types of Intermolecular Forces
Topic: Chemical Bonding
Topic: Intermolecular Forces

170.

Use the VSEPR model to predict the molecular geometry of H3O+ (hydronium ion).

trigonal pyramidal

Blooms: 4. Analyze
Chapter - Chapter 7 #170
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape
171.

Use the VSEPR model to predict the molecular geometry of CO32.

trigonal planar

Blooms: 4. Analyze
Chapter - Chapter 7 #171
Difficulty: Medium
Subtopic: Electron Configurations of Cations and Anions
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Electron Configuration
Topic: Molecular Shape

172.

How many bonds are there in CH3COCH3?

one

Blooms: 4. Analyze
Chapter - Chapter 7 #172
Difficulty: Hard
Subtopic: Representing Organic Molecules (Structural Formulas)
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Subtopic: Writing Lewis Dot Structures
Topic: Covalent Bond Theories
Topic: Molecular Shape
Topic: Organic Molecules
173.

According to the VSEPR model, is the molecule PF5 polar or nonpolar?

nonpolar

Blooms: 4. Analyze
Chapter - Chapter 7 #173
Difficulty: Medium
Subtopic: Bond Polarity
Subtopic: Exceptions to the Octet Rule
Subtopic: Molecular Polarity (Dipole Moment)
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Chemical Bonding
Topic: Electron Configuration
Topic: Molecular Shape

174.

How many electron domains are on the central atom for a sp2 hybridized atom?

Blooms: 2. Understand
Chapter - Chapter 7 #174
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
175.

How many electron domains are on the central atom for a sp3d hybridized atom?

Blooms: 2. Understand
Chapter - Chapter 7 #175
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories

176.

What name is given to the shape of a molecule with no lone pairs of electrons on the central atom and 6
electron domains on the central atom?

Octahedral

Blooms: 3. Apply
Chapter - Chapter 7 #176
Difficulty: Easy
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Topic: Molecular Shape
177.

The Lewis structure of formaldehyde, CH2O, is shown. Use VSEPR model to predict the molecular geometry
and the H–C–H bond angle. Outline your reasoning.

There are three electron groups around the central atom, carbon. These are a double bond and two single bonds.
The molecule is thus of the AB3 type, and its geometry will be trigonal planar. The H–C–H bond angle is
slightly less than 120 due to the greater electron-pair repulsion that the C=O double bond (possessing two
electron pairs) has on each of the C–H single bonds (possessing only one electron pair each).

Blooms: 4. Analyze
Chapter - Chapter 7 #177
Difficulty: Hard
Subtopic: Valence-Shell Electron-Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures
Topic: Molecular Shape
178.

In one sentence state the basic principle of valence bond theory.

A covalent bond forms when the orbitals of two atoms overlap and a pair of electrons occupies the region
between the nuclei.

Blooms: 2. Understand
Chapter - Chapter 7 #178
Difficulty: Easy
Subtopic: Covalent Bonding
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds))
Topic: Chemical Bonding
Topic: Covalent Bond Theories

179.

In not more than two sentences, explain when and why chemists make use of the concept of hybridization.

Chemists postulate hybridization when the observed geometry of a molecule cannot be rationalized in terms
of the overlap of the s, p, and/or d orbitals of the atoms concerned.

Blooms: 2. Understand
Chapter - Chapter 7 #179
Difficulty: Medium
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
180.

In one sentence state how molecular orbitals are usually obtained.

Molecular orbitals are obtained by the linear combination (addition or subtraction) of atomic orbitals.

Blooms: 2. Understand
Chapter - Chapter 7 #180
Difficulty: Medium
Subtopic: Molecular Orbital (MO) Theory
Topic: Covalent Bond Theories
Chapter 7 - Molecular Geometry, Intermolecular Forces, and
Bonding Theories (test bank) Summary

Category # of Questions
Blooms: 1. Remember 2
Blooms: 2. Understand 26
Blooms: 3. Apply 18
Blooms: 4. Analyze 108
Blooms: 5. Evaluate 25
Chapter - Chapter 7 180
Difficulty: Easy 1
Difficulty: Easy 46
Difficulty: Hard 44
Difficulty: Medium 89
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle) 12
Subtopic: Bond Polarity 42
Subtopic: Covalent Bonding 1
Subtopic: Diamagnetism and Paramagnetism 4
Subtopic: Electron Configurations of Cations and Anions 23
Subtopic: Electronegativity 10
Subtopic: Exceptions to the Octet Rule 22
Subtopic: Hunds Rule 1
Subtopic: Hybridization of Atomic Orbitals 37
Subtopic: Lewis Dot Symbols 20
Subtopic: Molecular Orbital (MO) Theory 12
Subtopic: Molecular Polarity (Dipole Moment) 47
Subtopic: Octet Rule 19
Subtopic: Periodic Classification of the Elements 1
Subtopic: Phase Changes 6
Subtopic: Representing Organic Molecules (Structural Formulas) 3
Subtopic: Trends in Physical Properties (Atomic Radius, Ionization Energy, Ionic 2
Radius, Electron Affinity)
Subtopic: Types of Intermolecular Forces 39
Subtopic: Valence Bond Theory (Overlap of Hybrid Orbitals (s- and p-bonds)) 13
Subtopic: Valence-Shell Electron- 74
Pair Repulsion Theory (VSEPR) and Molecular Shape
Subtopic: Writing Lewis Dot Structures 53
Topic: Chemical Bonding 68
Topic: Chemical Periodicity 3
Topic: Covalent Bond Theories 55
Topic: Electron Configuration 44
Topic: Intermolecular Forces 43
Topic: Molecular Shape 113
Topic: Organic Molecules 3

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