Chemistry 4th Edition Burdge Test Bank 1

Solution Manual for Chemistry 4th Edition by Burdge ISBN
0078021529 9780078021527
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Chapter 06
Representing Molecules
1. What is defined as the distance between identical points on successive waves?
A. frequency
B. amplitude
C. magnitude
D. wavelength
E. light
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
2. Visible light, radio waves, microwave radiation, infrared, ultraviolet radiation, X-rays, and gamma rays all constitute the
electromagnetic spectrum. Which of the following characteristics do all of these kinds of radiation share?
A. They all have the ability to generate heat in objects.
B. They all have the same frequencies.
C. They are all the transmission of energy in the form of waves.
D. They have equal energies.
E. They have the same electron spin state.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
3. According to scientist James Clerk Maxwell in the year 1873, a(n) ______________ consists of an electric field component
and a magnetic field component.
A. electrostatic wave
B. isoelectric wave
C. atom
D. paramagnetic wave
E. electromagnetic wave
Difficulty: Easy
Gradable: automatic
6-1
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4. What is defined as the number of waves that pass through a particular point in one second?
A. light
B. amplitude
C. magnitude
D. wavelength
E. frequency
Difficulty: Easy
Gradable: automatic
6-2
5. A(n) _________ is a point at which a standing wave has zero amplitude.
A. crevice
B. node
C. pit
D. burrow
E. orbital
Difficulty: Easy
Gradable: automatic
6. When a solid is heated, it emits electromagnetic radiation known as ________________. An example of such radiation is the
element of a stove stop burning bright red.
A. isoelectric radiation
B. visible and ultraviolet radiation
C. blackbody radiation
D. paramagnetic radiation
E. whitebody radiation
Difficulty: Medium
Gradable: automatic
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
7. In the ___________, electrons are ejected from the surface of a metal exposed to light of a certain minimum frequency.
A. aura effect
B. photon effect
C. ritzwald effect
D. photoelectric effect
E. None of the answers is correct.
Difficulty: Medium
Gradable: automatic
8. What is defined as the vertical distance from the midline of a wave to the top of the peak or the bottom of the trough?
A. light
B. amplitude
C. magnitude
D. wavelength
E. frequency
Difficulty: Medium
Gradable: automatic
9. What is the frequency of electromagnetic radiation with wavelength 532 nm? (c = 3.00 × 108 m/s)
A. 5.64 × 1014 s–1
B. 6.48 × 1012 s–1
C. 4.18 × 1018 s–1
D. 6.23 × 1014 s–1
E. 3.75 × 1015 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Topic: Study of Chemistry
6-3
10. What is the wavelength of light having a frequency of 4.8 × 1014 s–1? (c = 3.00 x 108 m/s)
A. 0.0016 nm
B. 1600 m
C. 630 nm
D. 1600 nm
E. 6.3 × 10–7 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
11. What is the frequency of light having a wavelength of 360 nm? (c = 3.00 x 108 m/s)
A. 8.3 × 1014 s–1
B. 1.2 × 10–6 s–1
C. 8.3 × 105 s–1
D. 108 s–1
E. 1.2 × 10–15 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
12. Select the arrangement of electromagnetic radiation which starts with the shortest wavelength and increases to longest
wavelength.
A. radio, infrared, ultraviolet, gamma rays
B. radio, ultraviolet, infrared, gamma rays
C. gamma rays, radio, ultraviolet, infrared
D. gamma rays, infrared, radio, ultraviolet
E. gamma rays, ultraviolet, infrared, radio
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
13. Select the arrangement of electromagnetic radiation which starts with the lowest energy and increases to the greatest energy.
A. radio, infrared, ultraviolet, gamma rays
B. radio, ultraviolet, infrared, gamma rays
C. gamma rays, infrared, radio, ultraviolet
D. gamma rays, ultraviolet, infrared, radio
E. infrared, ultraviolet, radio, gamma rays
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
6-4
14. What is the wavelength of radiation that has a frequency of 6.912 × 1014 s–1? (c = 3.00 × 108 m/s)
A. 1.447 × 10–15 nm
B. 4.337 × 102 nm
C. 2.304 × 106 nm
D. 2.074 × 1023 nm
E. 4.337 × 10–7 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
15. Calculate the frequency of visible light having a wavelength of 686 nm. (c = 3.00 × 108 m/s)
A. 4.37 × 1014 s-1
B. 4.34 × 105 s-1
C. 6.17 × 1014 s-1
D. 2.29 × 10–15 s-1
E. 2.29 × 10–6 s-1
Blooms: 3. Apply
Gradable: automatic
16. The FM station KDUL broadcasts music at 99.1 MHz. Find the wavelength of these waves. (c = 3.00 × 108 m/s)
A. 1.88 × 10–2 m
B. 0.330 m
C. 3.03 m
D. 5.33 × 102 m
E. > 103 m
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
17. What is the energy in joules of a mole of photons associated with visible light of wavelength 486 nm? (c = 3.00 × 108 m/s; h
= 6.63 × 10–34 J • s; NA = 6.022 × 1023 moles–1)
A. 6.46 × 10–16 J
B. 6.46 × 10–25 J
C. 2.46 × 10–4 J
D. 12.4 kJ
E. 246 kJ
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Topic: Thermochemistry
6-5
18. What is the energy in joules of a mole of photons associated with red light of wavelength 7.00 × 10 2 nm? (c= 3.00 × 108 m/s;
h = 6.63 × 10–34 J • s; NA = 6.022 × 1023 /mole)
A. 256 kJ
B. 1.71 × 105 J
C. 4.72 × 10–43 J
D. 12.4 kJ
E. 2.12 × 1042 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Units of Energy
19. A radio wave has a frequency of 8.6 × 10 8 Hz. What is the energy of one photon of this radiation? (h = 6.63 × 10–34 J • s)
A. 7.7 × 10–43 J
B. 2.3 × 10–34 J
C. 5.7 × 10–25 J
D. 1.7 × 10–16 J
E. > 10–15 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
20. The solar radiation spectrum peaks at a wavelength of approximately 500 nm. Calculate the energy of one photon of that
radiation (c = 3.00 × 108 m/s; h = 6.63 × 10–34 J • s).
A. 4 × 10–10 J
B. 6 × 1014 J
C. 1 × 10–27 J
D. 2 × 10–25 J
E. 4 × 10–19 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
6-6
21. If the energy of a photon is 1.32 × 10 –18 J, what is its wavelength in nm (c = 3.00 × 108 m/s; h = 6.63 × 10–34 J • s)?
A. 1.51 × 10–7 nm
B. 151 nm
C. 1.99 × 1015 nm
D. 1.99 × 1024 nm
E. None of these choices is correct.
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
22. A photon has an energy of 5.53 × 10–17 J. What is its frequency in s–1 (h = 6.63 × 10–34 J • s)?
A. 3.66 × 10–50 s–1
B. 1.20 × 10–17 s–1
C. 3.59 × 10–9 s–1
D. 2.78 × 108 s–1
E. 8.34 × 1016 s–1
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
23. Calculate the energy, in joules, required to excite a hydrogen atom by causing an electronic transition from the n = 1 to the n
= 4 principal energy level. Recall that the energy levels of the H atom are given by En = –2.18 × 10–18 J(1/n2 ).
A. 2.07 × 10–29 J
B. 2.19 × 105 J
C. 2.04 × 10–18 J
D. 3.27 × 10–17 J
E. 2.25 × 10–18 J
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
6-7
24. Calculate the wavelength, in nanometers, of the light emitted by a hydrogen atom when its electron falls from the n = 7 to the
n = 4 principal energy level. Recall that the energy levels of the H atom are given by En = –2.18 × 10–18 J (1/n2). (c = 3.00 × 108
m/s; h = 6.63 × 10–34 J • s)
A. 4.45 × 10–20 nm
B. 2.16 × 10–6 nm
C. 9.18 × 10–20 nm
D. 1.38 × 1014 nm
E. 2.17 × 103 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
25. Calculate the frequency of the light emitted by a hydrogen atom during a transition of its electron from the n = 4 to the n = 1
principal energy level. Recall that for hydrogen En = –2.18 × 10–18 J(1/n2 ). (h = 6.63 × 10–34 J • s)
A. 3.08 × 1015 s-1
B. 1.03 × 108 s-1
C. 2.06 × 1014 s-1
D. 1.35 × 10–51 s-1
E. 8.22 × 1014 s-1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
26. Use the Rydberg equation to calculate the frequency of a photon absorbed when the hydrogen atom undergoes a transition
from n1 = 2 to n2 = 4. (R = 1.096776 × 107 m–1; c = 3.00 × 108 m/s)
A. 2.06 × 106 s–1
B. 2.74 × 106 s–1
C. 6.17 × 1014 s–1
D. 8.23 × 1014 s–1
E. > 1015 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
6-8
27. Line spectra from all regions of the electromagnetic spectrum, including the Paschen series of infrared lines for hydrogen, are
used by astronomers to identify elements present in the atmospheres of stars. Calculate the wavelength of the photon emitted
when the hydrogen atom undergoes a transition from n = 5 to n = 3. (R = 1.096776 × 107 m–1)
A. 205.1 nm
B. 384.6 nm
C. 683.8 nm
D. 1282 nm
E. > 1500 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
28. Calculate the wavelength associated with a 20Ne+ ion moving at a velocity of 2.0 × 105 m/s. The atomic mass of Ne-20 is
19.992 amu. (1 amu = 1.66 × 10–24 g and h = 6.63 × 10–34 J • s)
A. 1.0 × 10–13 m
B. 1.0 × 10–16 m
C. 1.0 × 10–18 m
D. 9.7 × 1012 m
E. 2.0 × 10–13 cm
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
29. Calculate the wavelength of a neutron that has a velocity of 200. cm/s. (mass of a neutron = 1.675 × 10 –27 kg and h = 6.63 ×
10–34 J • s)
A. 1.98 × 10–9 m
B. 216 nm
C. 1.8 × 1050 m
D. 198 nm
E. 5.05 mm
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
6-9
30. A sprinter must average 24.0 mi/h to win a 100-m dash in 9.30 s. What is his wavelength at this speed if his mass is 84.5 kg ?
(h = 6.63 × 10–34 J • s)
A. 7.31 × 10–37 m
B. 3.26 × 10–37 m
C. 5.08 × 10–30 m
D. 1.34 × 10–30 m
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Quantum Mechanics (Wave-Particle Duality and the Heisenberg Uncertainty Principle)
31. The de Broglie equation predicts that the wavelength (in m) of a proton moving at 1000. m/s is ________________. (h = 6.63
× 10–34 J • s; mass of a proton = 1.673 × 10–24 g)
A. 3.96 × 10–10 m
B. 3.96 × 10–7 m
C. 2.52 × 106 m
D. 2.52 × 109 m
E. > 1010 m
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
32. According to the Heisenberg uncertainty principle, if the uncertainty in the speed of an electron is 3.5 × 10 3 m/s, the
uncertainty in its position (in m) is at least ___________. (mass of an electron = 9.11 × 10–28 g)
A. 1.7 × 10–8 m
B. 6.6 × 10–8 m
C. 17 m
D. 66 m
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
6-10
33. What is the emission of light at only specific wavelengths?
A. Emission spectra
B. Hydrogen spectrum
C. Wave spectra
D. Limited spectra
E. Line spectra
Difficulty: Easy
Gradable: automatic
34. The word _________ is used as an acronym for the amplification of light which is stimulated by the emission of radiation.
A. beam
B. laser
C. emit
D. brighten
E. light
Difficulty: Easy
Gradable: automatic
35. Which scientist proposed that energy of radiation is composed of extremely small indivisible packages called quanta?
(“Quanta” is the plural of “quantum.”)
A. Max Planck
B. Louis de Broglie
C. Clinton Davisson
D. Sir Isaac Newton
E. Lothan Meyer
Difficulty: Easy
Gradable: automatic
36. The size of an atomic orbital is associated with

A. the principal quantum number (n).
B. the angular momentum quantum number (l).
C. the magnetic quantum number (ml).
D. the spin quantum number (ms).
E. the angular momentum and magnetic quantum numbers, together.
Difficulty: Easy
Gradable: automatic
Subtopic: Atomic Theories
Subtopic: Quantum Numbers
Topic: Components of Matter
6-11
37. The shape of an atomic orbital is associated with
E. the magnetic and spin quantum numbers, together.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
38. The orientation in space of an atomic orbital is associated with

E. none of these choices is correct.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
39. Atomic orbitals developed using quantum mechanics

A. describe regions of space in which one is most likely to find an electron.
B. describe exact paths for electron motion.
C. give a description of the atomic structure which is essentially the same as the Bohr model.
D. allow scientists to calculate an exact volume for the hydrogen atom.
E. are in conflict with the Heisenberg uncertainty principle.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
40. The energy of an electron in the hydrogen atom is determined by

A. the principal quantum number (n) only.
B. the angular momentum quantum number (l) only.
C. the principal and angular momentum quantum numbers (n & l).
D. the principal and magnetic quantum numbers (n & ml).
E. the principal, angular momentum, and magnetic quantum numbers.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-12
41. Which of the following is a correct set of quantum numbers for an electron in a 3d orbital?
A. n = 3, l = 0, ml = –1
B. n = 3, l = 1, ml = +3
C. n = 3, l = 2, ml = 3
D. n = 3, l = 3, ml = +2
E. n = 3, l = 2, ml = –2
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
42. Which of the following is a correct set of quantum numbers for an electron in a 5f orbital?
A. n = 5, l = 3, ml = +1
B. n = 5, l = 2, ml = +3
C. n = 4, l = 3, ml = 0
D. n = 4, l = 2, ml = +1
E. n = 5, l = 4, ml = 3.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
43. In the quantum mechanical treatment of the hydrogen atom, which one of the following combinations of quantum numbers is
not allowed?
n l ml
A 3 0 0
–1
B 3 1
C 3 2 2
–1
D 3 2
E 3 3 2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
44. Which one of the following sets of quantum numbers can correctly represent a 3p orbital?
A B C D E
n=3 n=1 n=3 n=3 n=3
l=1 l=3 l=2 l=1 l=0
ml = 2 ml = 3 ml = 1 ml = –1 ml = 1
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
6-13
45. Which one of the following sets of quantum numbers is not possible?
n l ml ms
A 4 3 –2 +1/2
B 3 0 1 –1/2
C 3 0 0 +1/2
D 2 1 1 –1/2
E 2 0 0 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
46. Which one of the following sets of quantum numbers is not possible?
n l ml ms
A 4 3 –2 +1/2
B 3 2 –3 –1/2
C 3 0 0 +1/2
D 4 1 1 –1/2
E 2 0 0 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
47. What is the maximum number of electrons in an atom that can have the following set of quantum numbers?
n = 4, l = 3, ml = –2, ms = +1/2
A. 0
B. 1
C. 2
D. 6
E. 10
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
6-14
48. A possible set of quantum numbers for the last electron added to complete an atom of gallium (Ga) in its ground state is
n l ml ms
A 4 0 0 –1/2
B 3 1 0 –1/2
C 4 1 0 +1/2
D 3 1 1 +1/2
E 4 2 1 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
49. A possible set of quantum numbers for the last electron added to complete an atom of germanium in its ground state is
n l ml ms
A 4 0 0 +1/2
B 3 0 +1 –1/2
C 4 1 –1 +1/2
D 3 1 +1 –1/2
E 4 2 +2 –1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
50. Electrons in an orbital with l = 3 are in a/an

A. d orbital.
B. f orbital.
C. g orbital.
D. p orbital.
E. s orbital.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
51. The number of orbitals in a d subshell is

A. 1.
B. 2.
C. 3.
D. 5.
E. 7.
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle)
Topic: Electron Configuration
6-15
52. The maximum number of electrons that can occupy an energy level described by the principal quantum number, n, is
A. n.
B. n + 1.
C. 2n.
D. 2n2
E. n2
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
53. How many orbitals are allowed in a subshell if the angular momentum quantum number for electrons in that subshell is 3?
A. 1
B. 3
C. 5
D. 7
E. 9
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
54. The Pauli exclusion principle states that no ____ electrons within an atom can have the same ____ quantum numbers.
A. 4; 6
B. 2; 4
C. 3; 6
D. 6; 10
E. 3; 8
Difficulty: Easy
Gradable: automatic
Subtopic: Pauli Exclusion Principle
55. Hund's rule states that the most stable arrangement of electrons in orbitals of equal energy is the one in which the number of
electrons with parallel spin is ______________.
A. minimized
B. nullified
C. neutral
D. maximized
E. not relevant
Difficulty: Easy
Gradable: automatic
6-16
56. ___________________ is the wavelength associated with a moving particle.
A. The de Broglie wavelength
B. The Heisenburg wavelength
C. The Hund wavelength
D. The Aufbau wavelength
Difficulty: Medium
Gradable: automatic
57. Atomic orbitals that have the same amount of energy are ______________.
A. regenerative
B. negatively charged
C. degenerate
D. positively charged
E. zwitterionic
Difficulty: Easy
Gradable: automatic
58. What type of configuration specifies the arrangement of electrons in the orbitals of an atom?
A. Heisenberg configuration
B. Nuclear configuration
C. Atomic configuration
D. Proton configuration
E. Electron configuration
Difficulty: Easy
Gradable: automatic
59. "No two electrons in an atom can have the same four quantum numbers" is a statement of
A. the Pauli exclusion principle.
B. Bohr's equation.
C. Hund's rule.
D. de Broglie's relation.
E. Dalton's atomic theory.
Difficulty: Easy
Gradable: automatic
60. The most stable arrangement of electrons in orbitals of equal energy is the one in which the number of electrons with the
same spin is maximized is
A. the Pauli exclusion principle.
B. Bohr's equation.
C. Hund's rule.
D. de Broglie's relation.
E. Dalton's atomic theory.
Difficulty: Easy
Gradable: automatic
Subtopic: Hund's Rule
6-17
61. How many orbitals are there in the n = 4 level of the H-atom?
A. 4
B. 6
C. 8
D. 16
E. 18
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
62. The orbital diagram for a ground-state nitrogen atom is

1s 2s 2p
A ↿⇂ ↿⇂ ↿ ↿ ↿
B ↿⇂ ↿ ↿⇂ ↿
C ↿⇂ ↿⇂ ↿⇂ ↿
D ↿⇂ ↿⇂ ↿⇂ ↿ ↿
E ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿
A. A
B. B
C. C
D. D
E. E
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
63. The orbital diagram for a ground-state oxygen atom is

1s 2s 2p
A ↿⇂ ↿⇂ ↿ ↿ ↿
B ↿⇂ ↿⇂ ↿⇂ ↿⇂
C ↿⇂ ↿⇂ ↿⇂ ↿
D ↿⇂ ↿⇂ ↿⇂ ↿ ↿
E ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿
A. A
B. B
C. C
D. D
E. E
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
6-18
64. The orbital diagram for a ground-state carbon atom is
1s 2s 2p
A ↿⇂ ↿⇂ ↿⇂
B ↿⇂ ↿ ↿ ↿ ↿
C ↿⇂ ↿⇂ ↿ ↿ ↿
D ↿⇂ ↿⇂ ↿ ↿
E ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿
A. A
B. B
C. C
D. D
E. E
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
65. Which ground-state atom has an electron configuration described by the following orbital diagram?
[Ar] ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿⇂ ↿ ↿
4s 3d 4p
A. phosphorus
B. germanium
C. selenium
D. tellurium
E. potassium
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
66. Which ground-state atom has an electron configuration described by the following orbital diagram?
[Ne] ↿⇂ ↿ ↿ ↿
3s 3p
A. phosphorus
B. nitrogen
C. arsenic
D. vanadium
E. sulfur
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
6-19
67. How many unpaired electrons does a ground-state atom of sulfur have?
A. 0
B. 1
C. 2
D. 3
E. 4
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
68. Which element has the following ground-state electron configuration?

1s2 2s2 2p6 3s2
A. Na
B. Mg
C. Al
D. Si
E. Ne
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
Subtopic: Energy-Level Splitting (Zeff and Shielding)

[Kr]5s24d105p3
A. Sn
B. Sb
C. Pb
D. Bi
E. Te
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic

[Kr]5s24d105p2
A. Sn
B. Sb
C. Pb
D. Ge
E. Te
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
6-20
71. The electron configuration of a ground-state Co atom is
A. [Ar]4s23d7.
B. 1s22s22p63s23d9.
C. [Ne]3s23d7.
D. [Ar]4s13d5.
E. [Ar]4s24d7.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
72. The electron configuration of a ground-state vanadium atom is

A. [Ar]4s24d3.
B. [Ar]4s24p3.
C.[Ar]4s23d3.
D. [Ar]3d5.
E. [Ar]4s23d7.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
73. The electron configuration of a ground-state copper atom is

A. [Ar]4s24d4.
B. [Ar]4s24p63d3.
C. [Ar]4s23d9.
D. [Ar]3d9.
E. [Ar]4s13d10.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
74. The ground-state electron configuration for an atom of indium is

A. [Kr]5s24p64d5.
B. [Ar]4s23d104p1.
C. [Ar]4s24p63d5.
D. [Kr]5s25p64d5.
E. [Kr]5s24d105p1.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-21
75. The ground-state electron configuration of a calcium atom is
A. [Ne]3s2.
B. [Ne]3s23p6.
C. [Ar]4s13d1.
D. [Ar]4s2.
E. [Ar]3d2.
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
76. Select the correct electron configuration for sulfur (Z = 16).

A. 1s21p62s22p6
B. 1s22s22p83s23p4
C. 1s22s22p83s23p2
D. 1s22s22p63s23p4
E. 1s22s22p63s23d4
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
77. Select the correct electron configuration for Cu (Z = 29).

A. [Ar]4s23d9
B. [Ar]4s13d10
C. [Ar]4s24p63d3
D. [Ar]4s24d9
E. [Ar]5s24d9
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
78. Select the correct electron configuration for Te (Z = 52).

A. [Kr]5s25p64d8
B. [Kr]5s25d105p4
C. [Kr]5s24d105p6
D. [Kr]5s24f14
E. [Kr]5s24d105p4
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-22
79. What is the correct electron configuration for a germanium (Ge) atom?
A. 1s22s22p63s23p64s24p2
B. 1s22s22p63s23p64s23d104p2
C. 1s22s22p63s23p2
D. 1s22s23s23p5
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
80. The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of

A. Kr.
B. Ni.
C. Fe.
D. Pd.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
81. How many electrons are in the 4p orbitals of selenium?

A. 0
B. 2
C. 4
D. 5
E. 6
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
82. How many electrons are in the 4p orbitals of vanadium?

A. 0
B. 2
C. 4
D. 5
E. 6
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-23
83. How many electrons are in the 4d orbitals of Tc?
A. 1
B. 2
C. 3
D. 4
E. 5
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
84. How many electrons are there in the 2nd principal energy level (n = 2) of a phosphorus atom?
A. 3
B. 5
C. 6
D. 8
E. 10
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
85. How many electrons are there in the 3rd principal energy level (n = 3) of a phosphorus atom?
A. 3
B. 5
C. 6
D. 8
E. 10
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
86. What element is represented by the electron configuration 1s22s22p63s23p64s13d5?

A. Mn
B. Ca
C. K
D. Cr
E. V
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-24
87. What element is represented by the electron configuration 1s22s22p63s23p64s23d104p65s14d10?
A. Ag
B. Rb
C. Cd
D. Sr
E. Cu
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
88. What is the electron configuration for tungsten?

A. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d6
B. 1s22s22p63s23p64s23d104p65s24d105p66s14f145d5
C. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d4
D. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d7
E. 1s22s22p63s23p54s23d104p65s24d105p66s24f145d7
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
89. What is the electron configuration for silicon?

A. 1s22s22p63s13p3
B. 1s22s22p63s23p2
C. 1s22s22p63s4
D. 1s22s22p63p4
E. 1s22s22p63s23p3
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
90. What is the electron configuration for bromine?

A. 1s22s22p63s23p64s14d104p6
B. 1s22s22p63s23p64s24d104p5
C. 1s22s22p63s23p64s13d104p6
D. 1s22s22p63s23p64s23d104p4
E. 1s22s22p63s23p64s23d104p5
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
6-25
91. Which of the following elements has the largest number of unpaired electrons in the ground state?
A. K
B. V
C. S
D. Si
E. Cl
Blooms: 4. Analyze
Difficulty: Hard
Gradable: automatic
Subtopic: Diamagnetism and Paramagnetism
92. Which of the following subshells has the highest energy in the element tantalum?
A. 4s
B. 4d
C. 5p
D. 4f
E. 6s
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
93. A 6.0-gram champagne cork is shot out of an opened champagne bottle and traveled at a speed of 65 km/hour. Calculate the
de Broglie wavelength (in meters) of the cork.
A. 6.1 × 10–33 m
B. 1.7 × 10–36 m
C. 6.1 × 10–36 m
D. 1.7 × 10–33 m
E. 5.5 × 10–20 m
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
94. List the following types of radiation from lowest frequency to highest frequency: microwave, X ray, ultraviolet, visible, and
infrared
A. microwave < infrared < visible < ultraviolet < X ray
B. X ray < ultraviolet < visible < infrared < microwave
C. visible < ultraviolet < microwave < X ray < infrared
D. infrared < X ray < microwave < ultraviolet < visible
E. infrared < visible < microwave < ultraviolet < X ray
Blooms: 5. Evaluate
Difficulty: Easy
Gradable: automatic
6-26
95. If one s orbital were combined with one p orbital (dumbbell shaped), which would best describe the resulting shape?
A. spherical
B. mostly spherical, slightly dumbbell
C. an equal ratio of spherical and dumbbell
D. slightly spherical, mostly dumbbell
E. mostly dumbbell
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
Subtopic: Hybridization of Atomic Orbitals
Topic: Covalent Bond Theories
96. What wavelength, in nm, can strike a metal surface and eject an electron at 1.89 × 10 –19 J if the binding energy of the metal is
289 kJ/mol?
A. 1.89 × 10–19 nm
B. 2.75 nm
C. 189 nm
D. 290 nm
E. 297 nm
Blooms: 4. Analyze
Difficulty: Hard
Gradable: automatic
97. Which is the correct electron configuration for gold?

A. [Xe]4f145d96s2
B. [Xe]4f145d106s1
C. [Xe]4f135d106s2
D. [Xe]4f145d106s1
E. None of the electron configurations is correct.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
98. An atom in its ground state contains 33 electrons. How many of these electrons are in p orbitals?
A. 15
B. 12
C. 3
D. 33
E. None of the
Difficulty: Medium
Gradable: automatic
6-27
99. Emission spectra
A. cannot be used to identify an unknown atom.
B. can be used to identify unknown atoms.
C. can be explained by the movement of protons colliding with electrons.
D. none of the.
Difficulty: Easy
Gradable: automatic
100. De Broglie explained electron movements by relating them to

A. waves only.
B. particles only.
C. waves and particles.
D. none of the.
Blooms: 1. Remember
Difficulty: Easy
Gradable: automatic
101. A neutral atom in its ground state contains 28 electrons. This element is considered a __________ element, and has _______
electrons in orbitals with l = 2.
A. main group, 8
B. actinide, 10
C. main group, 10
D. transition, 10
E. transition, 8
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
102. The unusual electron configuration of Mo indicates the

A. unusual stability of half-filled d-orbitals.
B. unpredictability of the electron filling patterns of the non-representative elements.
C. unusually large size of Mo atoms.
D. greater than expected electronegativity of Mo.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
103. The energy of a photon is directly proportional to the wavelength of the radiation.
FALSE
Difficulty: Medium
Gradable: automatic
104. The frequency of a photon is inversely proportional to the wavelength of the radiation.
TRUE
Difficulty: Medium
Gradable: automatic
6-28
105. The principal quantum number designates the size of the orbital.
TRUE
Difficulty: Easy
Gradable: automatic
106. The magnetic quantum number designates the shape of the atomic orbital.
FALSE
Difficulty: Medium
Gradable: automatic
107. If n = 2 then l = 0, –1, and 1.

FALSE
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
108. An electron in a 3p orbital could have a value of 2 for its angular momentum quantum number (l).
FALSE
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
109. Each shell (principal energy level) of quantum number n contains n subshells.
TRUE
Difficulty: Medium
Gradable: automatic
110. For all atoms of the same element, the 2s orbital is larger than the 1s orbital.
TRUE
Blooms: 3. Apply
Difficulty: Easy
Gradable: automatic
111. Electrons will not pair in degenerate orbitals if an empty orbital is available and, according to Hund's rule, the degenerate
orbitals must all contain one electron before any of them can contain two electrons.
TRUE
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
6-29
112. According to the Aufbau principle, the most stable arrangement of electrons places them in degenerate orbitals with the
same spin.
FALSE
Blooms: 3. Apply
Difficulty: Easy
Gradable: automatic
113. The electron configuration for chlorine is [Ne]3s2 3p5 .

TRUE
Blooms: 3. Apply
Difficulty: Easy
Gradable: automatic
114. The following combination of quantum numbers is not allowed. Correct this set of quantum numbers by changing only one
quantum number, and write in an appropriate corrected value.
n = 2, l = 2, ml = 2; Corrected: _____ = _____
n=3
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
115. ___________ is the distance between identical points on successive waves.

The wavelength
Difficulty: Easy
Gradable: automatic
116. ___________ is the number of waves passing through a specific point per second.
The frequency
Difficulty: Easy
Gradable: automatic
117. _____________ is directly proportional to the frequency of a wave.

Energy
Difficulty: Medium
Gradable: automatic
118. ___________ is an attempt to locate a subatomic particle acting as a wave even though it is impossible to know both the
momentum and position of the particle simultaneously.
The Heisenberg uncertainty principle
Difficulty: Easy
Gradable: automatic
6-30
119. ___________ is the quantum number which describes the size of an orbital.
The principal quantum number
Difficulty: Easy
Gradable: automatic
120. ___________ is the quantum number which describes the shape of an atomic orbital.
The angular momentum quantum number
Difficulty: Medium
Gradable: automatic
121. ___________ is the quantum number which describes the orientation of the orbital in space.
The magnetic quantum number
Difficulty: Medium
Gradable: automatic
122. ___________ is the number of orbitals in the p subshell.

3 or Three
Blooms: 3. Apply
Difficulty: Easy
Gradable: automatic
123. When n = 1 then l = __________

0
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
124. When l = 1 then ml can be __________

–1, 0, or +1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
125. ___________ is the number of subshells in the shell designated as n = 2.

2 or Two
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
6-31
126. According to ___________, no two electrons in an atom can have the same four quantum numbers.
the Pauli exclusion principle
Difficulty: Easy
Gradable: automatic
127. ___________ is the element represented by the electron configuration [Ne]3s2 3p1 .
Aluminum
Blooms: 4. Analyze
Difficulty: Easy
Gradable: automatic
128. In the __________ series, nf = 1 and you observe the ultraviolet region of the electromagnetic spectrum.
Lyman
Blooms: 1. Remember
Difficulty: Hard
Gradable: automatic
129. What is the difference in the electron configuration between carbon-14 and carbon-12?
There is no difference between the two electron configurations.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: manual
130. What is the total number of electrons that can occupy the 4f orbitals?
14
Blooms: 3. Apply
Difficulty: Medium
Gradable: manual
131. In which region of the electromagnetic spectrum would radiation of the wavelength λ = 147.3 nm be found?
ultraviolet region
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: manual
132. If one electron is added to the outer shell of chlorine, to which element would the configuration be similar?
Argon
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: manual
6-32
133. Why do we only see four lines in the emission spectrum of hydrogen?
Only four of the electronic transitions of hydrogen correspond to visible wavelengths.
Blooms: 4. Analyze
Difficulty: Hard
Gradable: manual
134. For the following equations

a. name the scientist to whom the equation is attributed.
b. in not more than three lines, explain clearly what the equation means or represents.
1. E = nhv
2. λ = h/mu
1.a. Planck
b. A blackbody can only emit or absorb certain amounts of energy, i.e., whole number multiples of hv. The energy
emitted/absorbed is quantized.
2.a. de Broglie
b. The equation is a quantitative representation of wave-particle duality. A wavelength (wave property) λ corresponds to a
momentum (particle property) of mu.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: manual
135. In not more than three lines for each answer, briefly outline one important scientific contribution of each of the following.
a) Planck
b) De Broglie
c) Heisenberg
a. Planck is responsible for first proposing that energy is quantized. He proposed that a blackbody can emit or absorb
electromagnetic energy E only in exact multiples of hv, giving rise to the equation E = nhv where n is a positive integer.
b. De Broglie proposed that particles can have some wavelike properties and developed a relationship which allows the
wavelength (a wave property) to be calculated from the momentum of a particle.
c. Heisenberg is responsible for the uncertainty principle which states that we cannot simultaneously know both the position (x)
and the momentum (mu) of a particle exactly. There is a minimum uncertainty, h/4 , in their product, which is a fundamental
property of matter, not an instrumental limitation.
Difficulty: Hard
Gradable: manual
6-33
Category # of Questions
Blooms: 1. Remember 2
Blooms: 2. Understand 32
Blooms: 3. Apply 37
Blooms: 4. Analyze 49
Blooms: 5. Evaluate 13
Difficulty: Easy 40
Difficulty: Hard 20
Difficulty: Medium 74
Gradable: automatic 128
Gradable: manual 7
Subtopic: Assigning Electrons to Atomic Orbitals (Aufbau Principle) 46
Subtopic: Atomic Spectra (Bohr Model of the Atom) 10
Subtopic: Atomic Theories 5
Subtopic: Diamagnetism and Paramagnetism 1
Subtopic: Dimensional Analysis 22
Subtopic: Electromagnetic Radiation (Wave Properties) 45
Subtopic: Energy-Level Splitting (Zeff and Shielding) 18
Subtopic: Hund's Rule 6
Subtopic: Hybridization of Atomic Orbitals 1
Subtopic: Measurement (SI Units) 24
Subtopic: Pauli Exclusion Principle 4
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect 21
Subtopic: Quantum Mechanics (Wave-
Particle Duality and the Heisenberg Uncertainty Principle) 8
Subtopic: Quantum Numbers 79
Subtopic: Scientific Notation and Significant Figures 23
Subtopic: Units of Energy 5
Topic: Components of Matter 5
Topic: Covalent Bond Theories 1
Topic: Electron Configuration 48
Topic: Quantum Theory and Atomic Structure 131
Topic: Study of Chemistry 24
Topic: Thermochemistry 6
6-34

Chemistry 4th Edition Burdge Test Bank 1

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Chemistry 4th Edition Burdge Test Bank 1

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Solution Manual for Chemistry 4th Edition by Burdge ISBN

36. The size of an atomic orbital is associated with

38. The orientation in space of an atomic orbital is associated with

39. Atomic orbitals developed using quantum mechanics

40. The energy of an electron in the hydrogen atom is determined by

50. Electrons in an orbital with l = 3 are in a/an

51. The number of orbitals in a d subshell is

62. The orbital diagram for a ground-state nitrogen atom is

63. The orbital diagram for a ground-state oxygen atom is

68. Which element has the following ground-state electron configuration?

69. Which element has the following ground-state electron configuration?

70. Which element has the following ground-state electron configuration?

72. The electron configuration of a ground-state vanadium atom is

73. The electron configuration of a ground-state copper atom is

74. The ground-state electron configuration for an atom of indium is

76. Select the correct electron configuration for sulfur (Z = 16).

77. Select the correct electron configuration for Cu (Z = 29).

78. Select the correct electron configuration for Te (Z = 52).

80. The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of

81. How many electrons are in the 4p orbitals of selenium?

82. How many electrons are in the 4p orbitals of vanadium?

86. What element is represented by the electron configuration 1s22s22p63s23p64s13d5?

88. What is the electron configuration for tungsten?

89. What is the electron configuration for silicon?

90. What is the electron configuration for bromine?

97. Which is the correct electron configuration for gold?

100. De Broglie explained electron movements by relating them to

102. The unusual electron configuration of Mo indicates the

107. If n = 2 then l = 0, –1, and 1.

113. The electron configuration for chlorine is [Ne]3s2 3p5 .

115. ___________ is the distance between identical points on successive waves.

117. _____________ is directly proportional to the frequency of a wave.

122. ___________ is the number of orbitals in the p subshell.

123. When n = 1 then l = __________

124. When l = 1 then ml can be __________

125. ___________ is the number of subshells in the shell designated as n = 2.

134. For the following equations

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