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Chapter 06
Representing Molecules
1. What is defined as the distance between identical points on successive waves?
A. frequency
B. amplitude
C. magnitude
D. wavelength
E. light
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
2. Visible light, radio waves, microwave radiation, infrared, ultraviolet radiation, X-rays, and gamma rays all constitute the
electromagnetic spectrum. Which of the following characteristics do all of these kinds of radiation share?
A. They all have the ability to generate heat in objects.
B. They all have the same frequencies.
C. They are all the transmission of energy in the form of waves.
D. They have equal energies.
E. They have the same electron spin state.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
3. According to scientist James Clerk Maxwell in the year 1873, a(n) ______________ consists of an electric field component
and a magnetic field component.
A. electrostatic wave
B. isoelectric wave
C. atom
D. paramagnetic wave
E. electromagnetic wave
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
6-1
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent
of McGraw-Hill Education.
4. What is defined as the number of waves that pass through a particular point in one second?
A. light
B. amplitude
C. magnitude
D. wavelength
E. frequency
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
6-2
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent
of McGraw-Hill Education.
5. A(n) _________ is a point at which a standing wave has zero amplitude.
A. crevice
B. node
C. pit
D. burrow
E. orbital
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
6. When a solid is heated, it emits electromagnetic radiation known as ________________. An example of such radiation is the
element of a stove stop burning bright red.
A. isoelectric radiation
B. visible and ultraviolet radiation
C. blackbody radiation
D. paramagnetic radiation
E. whitebody radiation
Blooms: 2. Understand
Difficulty: Medium
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Topic: Quantum Theory and Atomic Structure
7. In the ___________, electrons are ejected from the surface of a metal exposed to light of a certain minimum frequency.
A. aura effect
B. photon effect
C. ritzwald effect
D. photoelectric effect
E. None of the answers is correct.
Blooms: 2. Understand
Difficulty: Medium
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
8. What is defined as the vertical distance from the midline of a wave to the top of the peak or the bottom of the trough?
A. light
B. amplitude
C. magnitude
D. wavelength
E. frequency
Blooms: 2. Understand
Difficulty: Medium
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Topic: Quantum Theory and Atomic Structure
9. What is the frequency of electromagnetic radiation with wavelength 532 nm? (c = 3.00 × 108 m/s)
A. 5.64 × 1014 s–1
B. 6.48 × 1012 s–1
C. 4.18 × 1018 s–1
D. 6.23 × 1014 s–1
E. 3.75 × 1015 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
6-3
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of McGraw-Hill Education.
10. What is the wavelength of light having a frequency of 4.8 × 1014 s–1? (c = 3.00 x 108 m/s)
A. 0.0016 nm
B. 1600 m
C. 630 nm
D. 1600 nm
E. 6.3 × 10–7 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
11. What is the frequency of light having a wavelength of 360 nm? (c = 3.00 x 108 m/s)
A. 8.3 × 1014 s–1
B. 1.2 × 10–6 s–1
C. 8.3 × 105 s–1
D. 108 s–1
E. 1.2 × 10–15 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
12. Select the arrangement of electromagnetic radiation which starts with the shortest wavelength and increases to longest
wavelength.
A. radio, infrared, ultraviolet, gamma rays
B. radio, ultraviolet, infrared, gamma rays
C. gamma rays, radio, ultraviolet, infrared
D. gamma rays, infrared, radio, ultraviolet
E. gamma rays, ultraviolet, infrared, radio
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
13. Select the arrangement of electromagnetic radiation which starts with the lowest energy and increases to the greatest energy.
A. radio, infrared, ultraviolet, gamma rays
B. radio, ultraviolet, infrared, gamma rays
C. gamma rays, infrared, radio, ultraviolet
D. gamma rays, ultraviolet, infrared, radio
E. infrared, ultraviolet, radio, gamma rays
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
6-4
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of McGraw-Hill Education.
14. What is the wavelength of radiation that has a frequency of 6.912 × 1014 s–1? (c = 3.00 × 108 m/s)
A. 1.447 × 10–15 nm
B. 4.337 × 102 nm
C. 2.304 × 106 nm
D. 2.074 × 1023 nm
E. 4.337 × 10–7 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
15. Calculate the frequency of visible light having a wavelength of 686 nm. (c = 3.00 × 108 m/s)
A. 4.37 × 1014 s-1
B. 4.34 × 105 s-1
C. 6.17 × 1014 s-1
D. 2.29 × 10–15 s-1
E. 2.29 × 10–6 s-1
Blooms: 3. Apply
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
16. The FM station KDUL broadcasts music at 99.1 MHz. Find the wavelength of these waves. (c = 3.00 × 108 m/s)
A. 1.88 × 10–2 m
B. 0.330 m
C. 3.03 m
D. 5.33 × 102 m
E. > 103 m
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
17. What is the energy in joules of a mole of photons associated with visible light of wavelength 486 nm? (c = 3.00 × 108 m/s; h
= 6.63 × 10–34 J • s; NA = 6.022 × 1023 moles–1)
A. 6.46 × 10–16 J
B. 6.46 × 10–25 J
C. 2.46 × 10–4 J
D. 12.4 kJ
E. 246 kJ
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
6-5
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of McGraw-Hill Education.
18. What is the energy in joules of a mole of photons associated with red light of wavelength 7.00 × 10 2 nm? (c= 3.00 × 108 m/s;
h = 6.63 × 10–34 J • s; NA = 6.022 × 1023 /mole)
A. 256 kJ
B. 1.71 × 105 J
C. 4.72 × 10–43 J
D. 12.4 kJ
E. 2.12 × 1042 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Subtopic: Units of Energy
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
19. A radio wave has a frequency of 8.6 × 10 8 Hz. What is the energy of one photon of this radiation? (h = 6.63 × 10–34 J • s)
A. 7.7 × 10–43 J
B. 2.3 × 10–34 J
C. 5.7 × 10–25 J
D. 1.7 × 10–16 J
E. > 10–15 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Subtopic: Units of Energy
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
20. The solar radiation spectrum peaks at a wavelength of approximately 500 nm. Calculate the energy of one photon of that
radiation (c = 3.00 × 108 m/s; h = 6.63 × 10–34 J • s).
A. 4 × 10–10 J
B. 6 × 1014 J
C. 1 × 10–27 J
D. 2 × 10–25 J
E. 4 × 10–19 J
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Subtopic: Units of Energy
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
6-6
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of McGraw-Hill Education.
21. If the energy of a photon is 1.32 × 10 –18 J, what is its wavelength in nm (c = 3.00 × 108 m/s; h = 6.63 × 10–34 J • s)?
A. 1.51 × 10–7 nm
B. 151 nm
C. 1.99 × 1015 nm
D. 1.99 × 1024 nm
E. None of these choices is correct.
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Subtopic: Units of Energy
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
22. A photon has an energy of 5.53 × 10–17 J. What is its frequency in s–1 (h = 6.63 × 10–34 J • s)?
A. 3.66 × 10–50 s–1
B. 1.20 × 10–17 s–1
C. 3.59 × 10–9 s–1
D. 2.78 × 108 s–1
E. 8.34 × 1016 s–1
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
23. Calculate the energy, in joules, required to excite a hydrogen atom by causing an electronic transition from the n = 1 to the n
= 4 principal energy level. Recall that the energy levels of the H atom are given by En = –2.18 × 10–18 J(1/n2 ).
A. 2.07 × 10–29 J
B. 2.19 × 105 J
C. 2.04 × 10–18 J
D. 3.27 × 10–17 J
E. 2.25 × 10–18 J
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
6-7
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of McGraw-Hill Education.
24. Calculate the wavelength, in nanometers, of the light emitted by a hydrogen atom when its electron falls from the n = 7 to the
n = 4 principal energy level. Recall that the energy levels of the H atom are given by En = –2.18 × 10–18 J (1/n2). (c = 3.00 × 108
m/s; h = 6.63 × 10–34 J • s)
A. 4.45 × 10–20 nm
B. 2.16 × 10–6 nm
C. 9.18 × 10–20 nm
D. 1.38 × 1014 nm
E. 2.17 × 103 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Subtopic: Units of Energy
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
Topic: Thermochemistry
25. Calculate the frequency of the light emitted by a hydrogen atom during a transition of its electron from the n = 4 to the n = 1
principal energy level. Recall that for hydrogen En = –2.18 × 10–18 J(1/n2 ). (h = 6.63 × 10–34 J • s)
A. 3.08 × 1015 s-1
B. 1.03 × 108 s-1
C. 2.06 × 1014 s-1
D. 1.35 × 10–51 s-1
E. 8.22 × 1014 s-1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
26. Use the Rydberg equation to calculate the frequency of a photon absorbed when the hydrogen atom undergoes a transition
from n1 = 2 to n2 = 4. (R = 1.096776 × 107 m–1; c = 3.00 × 108 m/s)
A. 2.06 × 106 s–1
B. 2.74 × 106 s–1
C. 6.17 × 1014 s–1
D. 8.23 × 1014 s–1
E. > 1015 s–1
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
6-8
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of McGraw-Hill Education.
27. Line spectra from all regions of the electromagnetic spectrum, including the Paschen series of infrared lines for hydrogen, are
used by astronomers to identify elements present in the atmospheres of stars. Calculate the wavelength of the photon emitted
when the hydrogen atom undergoes a transition from n = 5 to n = 3. (R = 1.096776 × 107 m–1)
A. 205.1 nm
B. 384.6 nm
C. 683.8 nm
D. 1282 nm
E. > 1500 nm
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
28. Calculate the wavelength associated with a 20Ne+ ion moving at a velocity of 2.0 × 105 m/s. The atomic mass of Ne-20 is
19.992 amu. (1 amu = 1.66 × 10–24 g and h = 6.63 × 10–34 J • s)
A. 1.0 × 10–13 m
B. 1.0 × 10–16 m
C. 1.0 × 10–18 m
D. 9.7 × 1012 m
E. 2.0 × 10–13 cm
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
29. Calculate the wavelength of a neutron that has a velocity of 200. cm/s. (mass of a neutron = 1.675 × 10 –27 kg and h = 6.63 ×
10–34 J • s)
A. 1.98 × 10–9 m
B. 216 nm
C. 1.8 × 1050 m
D. 198 nm
E. 5.05 mm
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
6-9
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of McGraw-Hill Education.
30. A sprinter must average 24.0 mi/h to win a 100-m dash in 9.30 s. What is his wavelength at this speed if his mass is 84.5 kg ?
(h = 6.63 × 10–34 J • s)
A. 7.31 × 10–37 m
B. 3.26 × 10–37 m
C. 5.08 × 10–30 m
D. 1.34 × 10–30 m
E. None of these choices is correct.
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Quantum Mechanics (Wave-Particle Duality and the Heisenberg Uncertainty Principle)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
31. The de Broglie equation predicts that the wavelength (in m) of a proton moving at 1000. m/s is ________________. (h = 6.63
× 10–34 J • s; mass of a proton = 1.673 × 10–24 g)
A. 3.96 × 10–10 m
B. 3.96 × 10–7 m
C. 2.52 × 106 m
D. 2.52 × 109 m
E. > 1010 m
Blooms: 3. Apply
Difficulty: Hard
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Quantum Mechanics (Wave-Particle Duality and the Heisenberg Uncertainty Principle)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
32. According to the Heisenberg uncertainty principle, if the uncertainty in the speed of an electron is 3.5 × 10 3 m/s, the
uncertainty in its position (in m) is at least ___________. (mass of an electron = 9.11 × 10–28 g)
A. 1.7 × 10–8 m
B. 6.6 × 10–8 m
C. 17 m
D. 66 m
E. None of these choices is correct.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Dimensional Analysis
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Quantum Mechanics (Wave-Particle Duality and the Heisenberg Uncertainty Principle)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
Topic: Study of Chemistry
6-10
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of McGraw-Hill Education.
33. What is the emission of light at only specific wavelengths?
A. Emission spectra
B. Hydrogen spectrum
C. Wave spectra
D. Limited spectra
E. Line spectra
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Atomic Spectra (Bohr Model of the Atom)
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Measurement (SI Units)
Subtopic: Scientific Notation and Significant Figures
Topic: Quantum Theory and Atomic Structure
34. The word _________ is used as an acronym for the amplification of light which is stimulated by the emission of radiation.
A. beam
B. laser
C. emit
D. brighten
E. light
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Topic: Quantum Theory and Atomic Structure
35. Which scientist proposed that energy of radiation is composed of extremely small indivisible packages called quanta?
(“Quanta” is the plural of “quantum.”)
A. Max Planck
B. Louis de Broglie
C. Clinton Davisson
D. Sir Isaac Newton
E. Lothan Meyer
Blooms: 2. Understand
Difficulty: Easy
Gradable: automatic
Subtopic: Electromagnetic Radiation (Wave Properties)
Subtopic: Plank's Quantum Theory and Einstein's Photoelectric Effect
Topic: Quantum Theory and Atomic Structure
6-11
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of McGraw-Hill Education.
37. The shape of an atomic orbital is associated with
A. the principal quantum number (n).
B. the angular momentum quantum number (l).
C. the magnetic quantum number (ml).
D. the spin quantum number (ms).
E. the magnetic and spin quantum numbers, together.
Blooms: 3. Apply
Difficulty: Medium
Gradable: automatic
Subtopic: Atomic Theories
Subtopic: Quantum Numbers
Topic: Components of Matter
Topic: Quantum Theory and Atomic Structure
6-12
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of McGraw-Hill Education.
41. Which of the following is a correct set of quantum numbers for an electron in a 3d orbital?
A. n = 3, l = 0, ml = –1
B. n = 3, l = 1, ml = +3
C. n = 3, l = 2, ml = 3
D. n = 3, l = 3, ml = +2
E. n = 3, l = 2, ml = –2
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
42. Which of the following is a correct set of quantum numbers for an electron in a 5f orbital?
A. n = 5, l = 3, ml = +1
B. n = 5, l = 2, ml = +3
C. n = 4, l = 3, ml = 0
D. n = 4, l = 2, ml = +1
E. n = 5, l = 4, ml = 3.
Blooms: 4. Analyze
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
43. In the quantum mechanical treatment of the hydrogen atom, which one of the following combinations of quantum numbers is
not allowed?
n l ml
A 3 0 0
–1
B 3 1
C 3 2 2
–1
D 3 2
E 3 3 2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
44. Which one of the following sets of quantum numbers can correctly represent a 3p orbital?
A B C D E
n=3 n=1 n=3 n=3 n=3
l=1 l=3 l=2 l=1 l=0
ml = 2 ml = 3 ml = 1 ml = –1 ml = 1
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
6-13
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of McGraw-Hill Education.
45. Which one of the following sets of quantum numbers is not possible?
n l ml ms
A 4 3 –2 +1/2
B 3 0 1 –1/2
C 3 0 0 +1/2
D 2 1 1 –1/2
E 2 0 0 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
46. Which one of the following sets of quantum numbers is not possible?
n l ml ms
A 4 3 –2 +1/2
B 3 2 –3 –1/2
C 3 0 0 +1/2
D 4 1 1 –1/2
E 2 0 0 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
47. What is the maximum number of electrons in an atom that can have the following set of quantum numbers?
n = 4, l = 3, ml = –2, ms = +1/2
A. 0
B. 1
C. 2
D. 6
E. 10
Blooms: 5. Evaluate
Difficulty: Hard
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
6-14
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of McGraw-Hill Education.
48. A possible set of quantum numbers for the last electron added to complete an atom of gallium (Ga) in its ground state is
n l ml ms
A 4 0 0 –1/2
B 3 1 0 –1/2
C 4 1 0 +1/2
D 3 1 1 +1/2
E 4 2 1 +1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
49. A possible set of quantum numbers for the last electron added to complete an atom of germanium in its ground state is
n l ml ms
A 4 0 0 +1/2
B 3 0 +1 –1/2
C 4 1 –1 +1/2
D 3 1 +1 –1/2
E 4 2 +2 –1/2
A. A
B. B
C. C
D. D
E. E
Blooms: 5. Evaluate
Difficulty: Medium
Gradable: automatic
Subtopic: Quantum Numbers
Topic: Quantum Theory and Atomic Structure
6-15
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Fam. Plethodontidæ.
Plethodon cinereus cinereus (Green). Sugar Grove.
Plethodon cinereus erythronotus (Green). Sugar Grove,
Columbus, and Worthington. In the early part of the year this is the
commonest salamander in the ravines in Franklin County. It is found
generally away from water, under loose debris two or more rods from
the stream.
Plethodon glutinosus (Green). Sugar Grove. This salamander is
found in such localities as were mentioned for P. c. erythronotus.
Gyrinophilus porphyriticus (Green). Sugar Grove.
Spelerpes bilineatus (Green). Sugar Grove. Habits apparently
aquatic.
Spelerpes longicauda (Green). Sugar Grove. This salamander is
abundant in this region where it may be found in May under stones
at the edge of the water together with its eggs; the eggs are attached
to the under side of a hollow stone. Some individuals were found in
May, 1900, away from water.
Spelerpes ruber (Daudin). Fairfield County.
Desmognathus fusca (Rafin). Sugar Grove and Perry Co.
Aquatic in habits.
Fam. Pleurodelidæ.
Diemictylus viridescens miniatus (Rafin). Sugar Grove.
Fam. Bufonidæ.
Bufo lentiginosus (Shaw). Columbus and Knox County. This is
the common toad of Central Ohio.
Bufo lentiginosus americanus LeConte. A specimen from the
sand dunes of Cedar Point, Sandusky, Ohio.
Fam. Hylidæ.
Acris gryllus crepitans Baird. Knox County, Central College and
Columbus. The common cricket-frog of Central Ohio is this
subspecies. The young resemble the species gryllus LeConte in
having the under surface of the thigh reticulated and blotched.
Chorophilus triseriatus (Wied.). Sugar Grove.
Hyla versicolor LeConte. Knox County and Columbus.
Hyla pickeringii Storer. Sugar Grove.
Fam. Ranidæ.
Rana virescens Kalm. Sugar Grove and Columbus.
Rana palustris LeConte. Sugar Grove.
Rana sylvatica LeConte. Knox County and Sugar Grove.
Rana clamata Daudin. Columbus.
Rana catesbiana Shaw. Columbus.
Summary for Batrachia.—Families 8, Genera 12, Species 25.
THE PROMETHEA MOTH, CALLOSAMIA
PROMETHEA.
Herbert Osborn.
The figures of the moth, male and female, were drawn twenty
one years ago, and having now come of age they may perhaps be
trusted to make their first public appearance.
MEETING OF THE BIOLOGICAL CLUB.
F. J. T.
Ohio State University
Six distinct and independent Colleges, each with a Dean and
Faculty of its own.
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