Urea Production

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ASPEN PLUS IS A TRADEMARK OF HOTLINE:

ASPEN TECHNOLOGY, INC. U.S.A. 888/996-7100
781/221-6400 EUROPE (44) 1189-226555
PLATFORM: WIN-X64 AUGUST 9, 2023

VERSION: 39.0 Build 116 WEDNESDAY
INSTALLATION: 10:45:41 A.M.
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE I

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP
ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

(ASPENTECH), AND MAY BE USED ONLY UNDER AGREEMENT WITH ASPENTECH.
RESTRICTED RIGHTS LEGEND: USE, REPRODUCTION, OR DISCLOSURE BY THE
U.S. GOVERNMENT IS SUBJECT TO RESTRICTIONS SET FORTH IN
(i) FAR 52.227-14, Alt. III, (ii) FAR 52.227-19, (iii) DFARS
252.227-7013(c)(1)(ii), or (iv) THE ACCOMPANYING LICENSE AGREEMENT,
AS APPLICABLE. FOR PURPOSES OF THE FAR, THIS SOFTWARE SHALL BE DEEMED
TO BE "UNPUBLISHED" AND LICENSED WITH DISCLOSURE PROHIBITIONS.
CONTRACTOR/SUBCONTRACTOR: ASPEN TECHNOLOGY, INC. 20 CROSBY DRIVE,
BEDFORD, MA 01730.
TABLE OF CONTENTS
RUN CONTROL SECTION.................................... 1

RUN CONTROL INFORMATION........................... 1
DESCRIPTION....................................... 1
FLOWSHEET SECTION...................................... 2
FLOWSHEET CONNECTIVITY BY STREAMS................. 2
FLOWSHEET CONNECTIVITY BY BLOCKS.................. 2
CONVERGENCE STATUS SUMMARY........................ 2
DESIGN-SPEC: D1.................................. 2
CONVERGENCE BLOCK: C-1........................... 3
COMPUTATIONAL SEQUENCE............................ 5
OVERALL FLOWSHEET BALANCE......................... 5
PHYSICAL PROPERTIES SECTION............................ 6
COMPONENTS........................................ 6
REACTION SECTION....................................... 7
REACTION: REACT2 TYPE: USER.................. 7
U-O-S BLOCK SECTION.................................... 8

BLOCK: A01 MODEL: RGIBBS.................... 8
BLOCK: A02 MODEL: RSTOIC.................... 9
BLOCK: E01 MODEL: RADFRAC................... 10
BLOCK: E02 MODEL: RSTOIC.................... 18
BLOCK: E03 MODEL: RADFRAC................... 19
BLOCK: F01 MODEL: FLASH2.................... 25
BLOCK: M01 MODEL: MIXER..................... 26
BLOCK: R01 MODEL: RPLUG..................... 27
BLOCK: SP1 MODEL: SEP....................... 33
STREAM SECTION......................................... 36
S01 S02 S03 S04 S05............................... 36
S06 S07 S08 S09 S10............................... 37
S11 S12 S13 S15 S17............................... 38
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE II
TABLE OF CONTENTS
PROBLEM STATUS SECTION................................. 39

BLOCK STATUS...................................... 39
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE 1

RUN CONTROL SECTION
RUN CONTROL INFORMATION

-----------------------
THIS COPY OF ASPEN PLUS LICENSED TO CARNEGIE MELLON UNIV
TYPE OF RUN: NEW
INPUT FILE NAME: _4527jmv.inm
OUTPUT PROBLEM DATA FILE NAME: _4527jmv

LOCATED IN:
PDF SIZE USED FOR INPUT TRANSLATION:

NUMBER OF FILE RECORDS (PSIZE) = 0
NUMBER OF IN-CORE RECORDS = 256
PSIZE NEEDED FOR SIMULATION = 256
CALLING PROGRAM NAME: apmain

LOCATED IN: C:\Program Files\AspenTech\Aspen Plus V12.1\Engine\\xeq
SIMULATION REQUESTED FOR ENTIRE FLOWSHEET
DESCRIPTION
-----------
STAMICARBON CO2 STRIPPING PROCESS H.P. SYNTHESIS SECTION This

model simulates the high-pressure synthesis loop of a plant to
produce urea by the Stamicarbon CO2-stripping process. The
simulation is based upon a closed-loop flowsheet. The downstream
section is approximated by using a SEP block to link the Stripper
bottom urea solution (S09) to the recycled carbamate soluti on
(S13).

FLOWSHEET SECTION
FLOWSHEET CONNECTIVITY BY STREAMS

---------------------------------
STREAM SOURCE DEST STREAM SOURCE DEST

S07 ---- E01 S01 ---- M01
S03 E02 R01 S04 R01 F01
S05 F01 E03 S06 F01 E01
S08 E01 M01 S09 E01 A02
S10 A02 SP1 S11 SP1 A01
S12 SP1 ---- S13 A01 E03
S15 E03 ---- S17 E03 M01
S02 M01 E02
FLOWSHEET CONNECTIVITY BY BLOCKS

--------------------------------
BLOCK INLETS OUTLETS

E02 S02 S03
R01 S03 S04
F01 S04 S05 S06
E01 S06 S07 S08 S09
A02 S09 S10
SP1 S10 S11 S12
A01 S11 S13
E03 S05 S13 S15 S17
M01 S01 S08 S17 S02
CONVERGENCE STATUS SUMMARY

--------------------------
DESIGN-SPEC SUMMARY
===================
DESIGN CONV
SPEC ERROR TOLERANCE ERR/TOL VARIABLE STAT BLOCK
------ ----- --------- ------- -------- ---- -----
D1 -0.77962E-03 0.10000E-02 -0.77962 0.40209 # C-1
TEAR STREAM SUMMARY

===================
STREAM VARIABLE MAXIMUM MAX. ERR. ABSOLUTE CONV

ID ID ERR/TOL RELATIVE ERROR STAT BLOCK
------ -------- -------- ------- --------- ---- -----
S02 CARB MOLEFLOW 0.22384 -0.22384E-04 0.17325E-05 # C-1
# = CONVERGED
* = NOT CONVERGED
LB = AT LOWER BOUNDS
UB = AT UPPER BOUNDS
DESIGN-SPEC: D1
----------------
SAMPLED VARIABLES:
T1 : SENTENCE=PARAM VARIABLE=TMAX IN UOS BLOCK R01

FLOWSHEET SECTION
DESIGN-SPEC: D1 (CONTINUED)
SPECIFICATION:
MAKE T1 APPROACH 183.000
WITHIN 0.00100000
MANIPULATED VARIABLES:
VARY : SENTENCE=CONV VARIABLE=CONV ID1=1 IN UOS BLOCK E02
LOWER LIMIT = 0.100000
UPPER LIMIT = 0.50000
FINAL VALUE = 0.40209
VALUES OF ACCESSED FORTRAN VARIABLES:

VARIABLE VALUE AT START FINAL VALUE UNITS
OF LOOP
-------- -------------- ----------- -----
T1 183.350 182.999 C
CONVERGENCE BLOCK: C-1

-----------------------
Tear Stream : S02
Tolerance used: 0.100D-03
Trace molefrac: 0.100D-05
SPECS: D1
MAXIT = 30 WAIT = 2
PERTURBATION SIZE (% OF RANGE): D1 0.10000
MAXIMUM STEP SIZE (% OF RANGE): D1 100.00
METHOD: BROYDEN STATUS: CONVERGED
TOTAL NUMBER OF ITERATIONS: 20
*** FINAL VALUES ***
VAR# TEAR STREAM VAR STREAM SUBSTREA COMPONEN UNIT VALUE

PREV VALUE ERR/TOL
---- ---------------- ------ -------- -------- ---- -----
---------- -------
1 TOTAL MOLEFLOW S02 MIXED KMOL/DAY 1.2929+05
1.2929+05 6.4630-03
2 MOLE-FLOW S02 MIXED UREA KMOL/DAY 69.9831
69.9846 -0.2004
3 MOLE-FLOW S02 MIXED CARB KMOL/DAY 6687.1877
6687.3374 -0.2238
4 MOLE-FLOW S02 MIXED CO2 KMOL/DAY 2.5525+04
2.5525+04 -0.1131
5 MOLE-FLOW S02 MIXED NH3 KMOL/DAY 8.2526+04
8.2526+04 6.7331-02
6 MOLE-FLOW S02 MIXED H2O KMOL/DAY 1.3165+04
1.3165+04 -2.7164-02
7 MOLE-FLOW S02 MIXED N2 KMOL/DAY 1145.8143
1145.8125 1.5564-02
8 MOLE-FLOW S02 MIXED O2 KMOL/DAY 171.0582
171.0566 9.5262-02
9 PRESSURE S02 MIXED KG/SQCM 141.0000
141.0000 0.0
10 MASS ENTHALPY S02 MIXED CAL/GM -1585.8494
-1585.8542 2.9741-02
DESIGN SP
VAR# VAR NAME CALCULATOR VARIABLE DESCRIPTION UNIT VALUE
PREV VALUE ERR/TOL
---- -------- ---------- -------------------- ---- -----
---------- -------
11 VARY D1 E02.CONV.CONV.1 0.4021
0.4151 -0.7796
*** ITERATION HISTORY ***


FLOWSHEET SECTION
CONVERGENCE BLOCK: C-1 (CONTINUED)
DESIGN-SPEC ID: D1
ITERATED: SENTENCE=CONV VARIABLE=CONV ID1=1 IN UOS BLOCK E02
ITERATION VARIABLE ERROR ERR/TOL

--------- -------- ----- -------
1 0.3800 0.3501 350.1
2 0.3800 0.4357 435.7
3 0.3800 0.5106 510.6
4 0.3804 0.4861 486.1
5 0.3883 -0.7799E-01 -77.99
6 0.3872 0.7057E-01 70.57
7 0.3879 0.6719E-01 67.19
8 0.3932 0.2982E-01 29.82
9 0.3975 -0.1787E-01 -17.87
10 0.3981 0.2709E-02 2.709
11 0.3966 0.3076E-02 3.076
12 0.4191 -0.3225 -322.5
13 0.3976 0.2911E-01 29.11
14 0.3995 0.3194E-01 31.94
15 0.4082 -0.8015E-01 -80.15
16 0.4018 0.6559E-02 6.559
17 0.4022 -0.5812E-03 -0.5812
18 0.4021 -0.9123E-03 -0.9123
19 0.4151 -0.1869 -186.9
20 0.4021 -0.7796E-03 -0.7796
TEAR STREAMS AND TEAR VARIABLES:
ITERATION MAX-ERR/TOL VAR# STREAM ID VAR DESCRIPTION SUBSTREA COMPONEN

ATTRIBUT ELEMENT
--------- ----------- ---- --------- --------------- -------- --------
-------- -------
1 -369.2 3 S02 MOLE-FLO MIXED CARB

8 87.80 3 S02 MOLE-FLO MIXED CARB

FLOWSHEET SECTION
COMPUTATIONAL SEQUENCE
----------------------
SEQUENCE USED WAS:

C-1 E02 R01 F01 E01 A02 SP1 A01 E03 M01
(RETURN C-1)
OVERALL FLOWSHEET BALANCE

-------------------------
*** MASS AND ENERGY BALANCE ***

IN OUT GENERATION RELATIVE DIFF.
CONVENTIONAL COMPONENTS
(KMOL/DAY)
UREA 0.00000 17012.9 17012.9 -0.824629E-07
CARB 0.00000 0.697618E-04 -0.149623 -2145.76
CO2 17076.0 63.5629 -17012.7 -0.169014E-04
NH3 34038.0 11.9931 -34025.5 0.163231E-04
H2O 190.000 17202.9 17012.9 -0.207899E-05
N2 1100.00 1100.00 0.00000 0.163128E-05
O2 150.000 149.998 0.00000 0.108655E-04
TOTAL BALANCE
MOLE(KMOL/DAY) 52554.0 35541.3 -17012.6 0.158999E-05
MASS(KG/HR ) 57093.1 57093.3 -0.340369E-05
ENTHALPY(MMKCAL/H) -89.9836 -100.319 0.103028
*** CO2 EQUIVALENT SUMMARY ***

FEED STREAMS CO2E 31313.0 KG/HR
PRODUCT STREAMS CO2E 116.558 KG/HR
NET STREAMS CO2E PRODUCTION -31196.4 KG/HR
UTILITIES CO2E PRODUCTION 0.00000 KG/HR
TOTAL CO2E PRODUCTION -31196.4 KG/HR

PHYSICAL PROPERTIES SECTION
COMPONENTS
----------
ID TYPE ALIAS NAME

UREA C CH4N2O UREA
CARB C NH2COONH4 AMMONIUM-CARBAMATE
CO2 C CO2 CARBON-DIOXIDE
NH3 C H3N AMMONIA
H2O C H2O WATER
N2 C N2 NITROGEN
O2 C O2 OXYGEN

REACTION SECTION
REACTION: REACT2 TYPE: USER

--------------------------------
Unit operations referencing this reaction model:
Reactor Name: R01 Block Type: RPLUG

U-O-S BLOCK SECTION
BLOCK: A01 MODEL: RGIBBS

------------------------------
INLET STREAM: S11
OUTLET STREAM: S13
PROPERTY OPTION SET: SR-POLAR REDLICH-KWONG-UNIFAC EQUATION OF STATE

TOTAL BALANCE
MOLE(KMOL/DAY) 22411.6 14534.2 -7877.43 0.811628E-16
MASS(KG/HR ) 20782.9 20782.9 -0.631724E-06
ENTHALPY(MMKCAL/H) -49.2727 -53.0037 0.703917E-01

*** INPUT DATA ***
EQUILIBRIUM SPECIFICATIONS:
ONLY CHEMICAL EQUILIBRIUM IS CONSIDERED, THE FLUID PHASE IS LIQUID
SYSTEM TEMPERATURE C 72.400
TEMPERATURE FOR FREE ENERGY EVALUATION C 72.400
SYSTEM PRESSURE KG/SQCM 141.00
FLUID PHASE SPECIES IN PRODUCT LIST:

UREA CARB CO2 NH3 H2O N2 O2
ATOM MATRIX:
ATOM C H O N
UREA 1.00 4.00 1.00 2.00
CARB 1.00 6.00 2.00 2.00
CO2 1.00 0.00 2.00 0.00
NH3 0.00 3.00 0.00 1.00
H2O 0.00 2.00 1.00 0.00
N2 0.00 0.00 0.00 2.00
O2 0.00 0.00 2.00 0.00
PRODUCT SPECIFICATIONS:
UREA 1.0000 FRACTION OF FEED
N2 1.0000 FRACTION OF FEED
O2 1.0000 FRACTION OF FEED
U-O-S BLOCK SECTION
BLOCK: A01 MODEL: RGIBBS (CONTINUED)
*** RESULTS ***

TEMPERATURE C 72.400
PRESSURE KG/SQCM 141.00
HEAT DUTY MMKCAL/HR -3.7310
VAPOR FRACTION 0.0000
NUMBER OF FLUID PHASES 1
FLUID PHASE MOLE FRACTIONS:
PHASE LIQ 1
OF TYPE LIQUID
PHASE FRACTION 1.000000
PLACED IN STREAM S13
CO2 0.9299293E-04
H2O 0.6768865
NH3 0.5023508E-01
CARB 0.2709965
UREA 0.1788885E-02
KMOL/DAY 14534.19
BLOCK: A02 MODEL: RSTOIC

------------------------------
INLET STREAM: S09
OUTLET STREAM: S10

TOTAL BALANCE
MOLE(KMOL/DAY) 50528.0 56627.4 6099.36 -0.128488E-15
MASS(KG/HR ) 76269.6 76269.6 0.133285E-06

NET STREAMS CO2E PRODUCTION 5592.33 KG/HR
TOTAL CO2E PRODUCTION 5592.33 KG/HR
*** INPUT DATA ***


U-O-S BLOCK SECTION
BLOCK: A02 MODEL: RSTOIC (CONTINUED)

STOICHIOMETRY MATRIX:
REACTION # 1:
SUBSTREAM MIXED :
CARB -1.00 CO2 1.00 NH3 2.00
REACTION CONVERSION SPECS: NUMBER= 1

REACTION # 1:
SUBSTREAM:MIXED KEY COMP:CARB CONV FRAC: 1.000
ONE PHASE TP FLASH SPECIFIED PHASE IS LIQUID

SPECIFIED TEMPERATURE C 72.4000
SPECIFIED PRESSURE KG/SQCM 141.000
MAXIMUM NO. ITERATIONS 30
CONVERGENCE TOLERANCE 0.000100000
SIMULTANEOUS REACTIONS
GENERATE COMBUSTION REACTIONS FOR FEED SPECIES NO
*** RESULTS ***

OUTLET TEMPERATURE C 72.400
OUTLET PRESSURE KG/SQCM 141.00
REACTION EXTENTS:
REACTION REACTION
NUMBER EXTENT
KMOL/DAY
1 3049.7
BLOCK: E01 MODEL: RADFRAC

-------------------------------
INLETS - S06 STAGE 1
S07 STAGE 10
OUTLETS - S08 STAGE 1
S09 STAGE 10

TOTAL BALANCE
MOLE(KMOL/DAY) 109093. 125052. 15958.7 -0.232734E-15
MASS(KG/HR ) 158437. 158437. 0.168200E-06
ENTHALPY(MMKCAL/H) -289.021 -273.021 -0.553591E-01

U-O-S BLOCK SECTION
BLOCK: E01 MODEL: RADFRAC (CONTINUED)

**********************
**** INPUT DATA ****
**********************
**** INPUT PARAMETERS ****
NUMBER OF STAGES 10
ALGORITHM OPTION STANDARD
INITIALIZATION OPTION STANDARD
HYDRAULIC PARAMETER CALCULATIONS NO
INSIDE LOOP CONVERGENCE METHOD NEWTON
DESIGN SPECIFICATION METHOD NESTED
MAXIMUM NO. OF OUTSIDE LOOP ITERATIONS 100
MAXIMUM NO. OF INSIDE LOOP ITERATIONS 15
MAXIMUM NUMBER OF FLASH ITERATIONS 30
FLASH TOLERANCE 0.000100000
OUTSIDE LOOP CONVERGENCE TOLERANCE 0.000100000
**** COL-SPECS ****
MOLAR VAPOR DIST / TOTAL DIST 1.00000

CONDENSER DUTY (W/O SUBCOOL) MMKCAL/H 0.0
REBOILER DUTY MMKCAL/H 0.0
**** REAC-STAGES SPECIFICATIONS ****
STAGE TO STAGE REACTIONS/CHEMISTRY ID

1 10 REACT1
***** REACTION PARAGRAPH REACT1 *****


U-O-S BLOCK SECTION
**** REACTION PARAMETERS ****
RXN NO. TYPE PHASE CONC. TEMP APP TO EQUIL CONVERSION

BASIS K
1 EQUILIBRIUM VAPOR FUGACITY 0.0000
** STOICHIOMETRIC COEFFICIENTS **
RXN NO. UREA CARB CO2 NH3 H2O

1 0.000 1.000 -1.000 -2.000 0.000
RXN NO. N2 O2
1 0.000 0.000
**** HEATERS ****
STAGE HEATERS STAGE 2 RATE, MMKCAL/H 2.00000

3 2.00000
4 2.00000
5 2.00000
6 2.00000
7 2.00000
8 2.00000
9 2.00000
**** PROFILES ****
P-SPEC STAGE 1 PRES, KG/SQCM 141.000

10 141.000
**** COMPONENT VAPORIZATION EFFICIENCY ****

STAGE UREA CARB CO2 NH3 H2O N2
1 MISSING MISSING 1.3200 1.4600 0.7100 MISSING
**** COMPONENT VAPORIZATION EFFICIENCY ****

STAGE O2
1 MISSING
*******************
**** RESULTS ****
*******************
*** COMPONENT SPLIT FRACTIONS ***
OUTLET STREAMS
--------------
S08 S09
COMPONENT:
UREA .22819E-02 .99772
CARB .17163E-02 .99828
CO2 .96603 .33965E-01
NH3 .94728 .52723E-01

U-O-S BLOCK SECTION
OUTLET STREAMS
--------------
S08 S09
COMPONENT:
H2O .93711E-01 .90629
N2 .99720 .27963E-02
O2 .98858 .11424E-01
*** SUMMARY OF KEY RESULTS ***
TOP STAGE TEMPERATURE C 185.052

BOTTOM STAGE TEMPERATURE C 165.961
TOP STAGE LIQUID FLOW KMOL/DAY 76,379.8
BOTTOM STAGE LIQUID FLOW KMOL/DAY 50,528.0
TOP STAGE VAPOR FLOW KMOL/DAY 74,523.7
BOILUP VAPOR FLOW KMOL/DAY 20,586.9
REBOILER DUTY MMKCAL/H 0.0
**** MAXIMUM FINAL RELATIVE ERRORS ****
DEW POINT 0.77864E-04 STAGE= 10

BUBBLE POINT 0.59394E-04 STAGE= 10
COMPONENT MASS BALANCE 0.97408E-08 STAGE= 2 COMP=N2
ENERGY BALANCE 0.12807E-04 STAGE= 1
**** PROFILES ****

**NOTE** REPORTED VALUES FOR STAGE LIQUID AND VAPOR RATES ARE THE FLOWS
FROM THE STAGE INCLUDING ANY SIDE PRODUCT.
ENTHALPY
STAGE TEMPERATURE PRESSURE CAL/MOL HEAT DUTY
C KG/SQCM LIQUID VAPOR MMKCAL/H
1 185.05 141.00 -69731. -40292.

2 184.94 141.00 -70610. -46857. 2.0000
3 185.53 141.00 -70012. -49146. 2.0000
4 186.44 141.00 -69148. -50782. 2.0000
5 187.47 141.00 -68272. -52572. 2.0000
6 188.51 141.00 -67470. -54817. 2.0000
7 189.39 141.00 -66824. -57801. 2.0000
8 189.56 141.00 -66480. -61989. 2.0000
9 186.83 141.00 -66824. -68304. 2.0000

U-O-S BLOCK SECTION
ENTHALPY
10 165.96 141.00 -70254. -78805.
STAGE FLOW RATE FEED RATE PRODUCT RATE

KMOL/DAY KMOL/DAY KMOL/DAY
LIQUID VAPOR LIQUID VAPOR MIXED LIQUID VAPOR
1 0.7638E+05 0.7452E+05 .90577+05 .74524+05
2 0.7235E+05 0.6432E+05
3 0.6975E+05 0.5787E+05
4 0.6737E+05 0.5252E+05
5 0.6496E+05 0.4737E+05
6 0.6243E+05 0.4222E+05
7 0.5971E+05 0.3702E+05
8 0.5668E+05 0.3171E+05
9 0.5313E+05 0.2624E+05
10 0.5053E+05 0.2059E+05 .18516+05 .50528+05
**** MASS FLOW PROFILES ****

KG/HR KG/HR KG/HR
1 0.1201E+06 0.8217E+05 .12550+06 .82168+05
2 0.1142E+06 0.7674E+05
3 0.1089E+06 0.7089E+05
4 0.1036E+06 0.6554E+05
5 0.9841E+05 0.6030E+05
6 0.9318E+05 0.5508E+05
7 0.8793E+05 0.4985E+05
8 0.8264E+05 0.4460E+05
9 0.7740E+05 0.3931E+05
10 0.7627E+05 0.3407E+05 .32940+05 .76270+05
**** MOLE-X-PROFILE ****

STAGE UREA CARB CO2 NH3 H2O
1 0.22350 0.17058 0.10825E-01 0.21138 0.38365
2 0.23592 0.16339 0.12624E-01 0.18516 0.40284
3 0.24466 0.14973 0.13081E-01 0.17626 0.41620
4 0.25327 0.13444 0.13313E-01 0.16972 0.42919
5 0.26265 0.11838 0.13541E-01 0.16221 0.44314
6 0.27326 0.10175 0.13825E-01 0.15246 0.45861
7 0.28565 0.84703E-01 0.14209E-01 0.13922 0.47612
8 0.30081 0.67607E-01 0.14755E-01 0.12054 0.49619
9 0.32077 0.52363E-01 0.15619E-01 0.92977E-01 0.51816
10 0.33722 0.60356E-01 0.17622E-01 0.49640E-01 0.53507

U-O-S BLOCK SECTION

STAGE N2 O2
1 0.46005E-04 0.22090E-04
2 0.46580E-04 0.21656E-04
3 0.49608E-04 0.23230E-04
4 0.52902E-04 0.24901E-04
5 0.56567E-04 0.26781E-04
6 0.60648E-04 0.28942E-04
7 0.65084E-04 0.31436E-04
8 0.69500E-04 0.34262E-04
9 0.72179E-04 0.37117E-04
10 0.62802E-04 0.37269E-04
**** MOLE-Y-PROFILE ****

1 0.52293E-03 0.70357E-04 0.33981 0.60471 0.37512E-01
2 0.49430E-03 0.58441E-04 0.41960 0.52221 0.38203E-01
3 0.49758E-03 0.51585E-04 0.44698 0.49116 0.39713E-01
4 0.50811E-03 0.45562E-04 0.46626 0.46779 0.41597E-01
5 0.51934E-03 0.39407E-04 0.48737 0.44198 0.43700E-01
6 0.52842E-03 0.32911E-04 0.51401 0.40986 0.45948E-01
7 0.53158E-03 0.26028E-04 0.54975 0.36773 0.48187E-01
8 0.52008E-03 0.18791E-04 0.60050 0.30963 0.49888E-01
9 0.46637E-03 0.11455E-04 0.67858 0.22446 0.48808E-01
10 0.24842E-03 0.50885E-05 0.81352 0.92142E-01 0.33325E-01

STAGE N2 O2
1 0.15185E-01 0.21866E-02
2 0.17108E-01 0.23291E-02
3 0.19012E-01 0.25866E-02
4 0.20949E-01 0.28509E-02
5 0.23228E-01 0.31620E-02
6 0.26064E-01 0.35491E-02
7 0.29733E-01 0.40501E-02
8 0.34713E-01 0.47303E-02
9 0.41954E-01 0.57193E-02
10 0.53464E-01 0.72905E-02
**** K-VALUES ****

1 0.23399E-02 0.41249E-03 23.780 1.9595 0.13772
2 0.20953E-02 0.35771E-03 25.179 1.9318 0.13357
3 0.20338E-02 0.34454E-03 25.887 1.9086 0.13439
4 0.20062E-02 0.33891E-03 26.533 1.8879 0.13651
5 0.19773E-02 0.33289E-03 27.268 1.8662 0.13889
6 0.19338E-02 0.32344E-03 28.167 1.8413 0.14111
7 0.18609E-02 0.30727E-03 29.312 1.8092 0.14254
8 0.17289E-02 0.27792E-03 30.833 1.7594 0.14160
9 0.14538E-02 0.21874E-03 32.916 1.6535 0.13266
10 0.73658E-03 0.84291E-04 34.977 1.2714 0.87717E-01

U-O-S BLOCK SECTION
**** K-VALUES ****

STAGE N2 O2
1 330.04 98.978
2 367.25 107.54
3 383.23 111.34
4 395.99 114.49
5 410.64 118.07
6 429.76 122.63
7 456.86 128.84
8 499.51 138.07
9 581.32 154.10
10 851.44 195.64
**** RATES OF GENERATION ****

KMOL/DAY
1 0.000 1996. -1996. -3992. 0.000 0.000
2 0.000 -1207. 1207. 2415. 0.000 0.000
3 0.000 -1376. 1376. 2753. 0.000 0.000
4 0.000 -1386. 1386. 2772. 0.000 0.000
5 0.000 -1367. 1367. 2735. 0.000 0.000
6 0.000 -1337. 1337. 2674. 0.000 0.000
7 0.000 -1294. 1294. 2588. 0.000 0.000
8 0.000 -1225. 1225. 2450. 0.000 0.000
9 0.000 -1050. 1050. 2100. 0.000 0.000
10 0.000 267.6 -267.6 -535.1 0.000 0.000

KMOL/DAY
STAGE O2
1 0.000
2 0.000
3 0.000
4 0.000
5 0.000
6 0.000
7 0.000
8 0.000
9 0.000
10 0.000
**** MASS-X-PROFILE ****

1 0.35575 0.35297 0.12627E-01 0.95415E-01 0.18319
2 0.37390 0.33664 0.14662E-01 0.83218E-01 0.19152
3 0.39224 0.31205 0.15368E-01 0.80135E-01 0.20016
4 0.41202 0.28431 0.15871E-01 0.78296E-01 0.20945
5 0.43382 0.25418 0.16390E-01 0.75981E-01 0.21957
6 0.45809 0.22174 0.16984E-01 0.72481E-01 0.23063
7 0.48536 0.18710 0.17692E-01 0.67081E-01 0.24268
8 0.51633 0.15086 0.18560E-01 0.58675E-01 0.25549
9 0.55102 0.11693 0.19662E-01 0.45292E-01 0.26701
10 0.55902 0.13007 0.21407E-01 0.23336E-01 0.26608

U-O-S BLOCK SECTION

STAGE N2 O2
1 0.34158E-04 0.18735E-04
2 0.34437E-04 0.18288E-04
3 0.37098E-04 0.19843E-04
4 0.40144E-04 0.21584E-04
5 0.43583E-04 0.23569E-04
6 0.47425E-04 0.25852E-04
7 0.51585E-04 0.28461E-04
8 0.55647E-04 0.31336E-04
9 0.57836E-04 0.33972E-04
10 0.48564E-04 0.32919E-04
**** MASS-Y-PROFILE ****

1 0.11868E-02 0.20758E-03 0.56516 0.38919 0.25538E-01
2 0.10366E-02 0.15933E-03 0.64486 0.31057 0.24034E-01
3 0.10164E-02 0.13698E-03 0.66908 0.28450 0.24334E-01
4 0.10189E-02 0.11877E-03 0.68518 0.26601 0.25023E-01
5 0.10209E-02 0.10071E-03 0.70211 0.24639 0.25770E-01
6 0.10136E-02 0.82070E-04 0.72256 0.22296 0.26440E-01
7 0.98771E-03 0.62869E-04 0.74855 0.19376 0.26858E-01
8 0.92526E-03 0.43459E-04 0.78290 0.15622 0.26624E-01
9 0.77900E-03 0.24875E-04 0.83064 0.10632 0.24457E-01
10 0.37560E-03 0.10002E-04 0.90141 0.39509E-01 0.15115E-01

STAGE N2 O2
1 0.16075E-01 0.26441E-02
2 0.16736E-01 0.26026E-02
3 0.18114E-01 0.28151E-02
4 0.19595E-01 0.30461E-02
5 0.21300E-01 0.33120E-02
6 0.23321E-01 0.36274E-02
7 0.25770E-01 0.40097E-02
8 0.28808E-01 0.44841E-02
9 0.32689E-01 0.50902E-02
10 0.37708E-01 0.58735E-02
**** VAPORIZATION EFF ****

1 1.0000 1.0000 1.3200 1.4600 0.71000
2 1.0000 1.0000 1.3200 1.4600 0.71000
3 1.0000 1.0000 1.3200 1.4600 0.71000
4 1.0000 1.0000 1.3200 1.4600 0.71000
5 1.0000 1.0000 1.3200 1.4600 0.71000
6 1.0000 1.0000 1.3200 1.4600 0.71000
7 1.0000 1.0000 1.3200 1.4600 0.71000
8 1.0000 1.0000 1.3200 1.4600 0.71000
9 1.0000 1.0000 1.3200 1.4600 0.71000
10 1.0000 1.0000 1.3200 1.4600 0.71000

U-O-S BLOCK SECTION
**** VAPORIZATION EFF ****

STAGE N2 O2
1 1.0000 1.0000
2 1.0000 1.0000
3 1.0000 1.0000
4 1.0000 1.0000
5 1.0000 1.0000
6 1.0000 1.0000
7 1.0000 1.0000
8 1.0000 1.0000
9 1.0000 1.0000
10 1.0000 1.0000
BLOCK: E02 MODEL: RSTOIC

------------------------------
INLET STREAM: S02
OUTLET STREAM: S03

TOTAL BALANCE
MOLE(KMOL/DAY) 129290. 96107.2 -33182.7 0.225105E-15
MASS(KG/HR ) 138744. 138744. -0.398609E-06

*** INPUT DATA ***

STOICHIOMETRY MATRIX:
REACTION # 1:
SUBSTREAM MIXED :
CARB 1.00 CO2 -1.00 NH3 -2.00
REACTION CONVERSION SPECS: NUMBER= 1

REACTION # 1:
SUBSTREAM:MIXED KEY COMP:NH3 CONV FRAC: 0.4021

U-O-S BLOCK SECTION
BLOCK: E02 MODEL: RSTOIC (CONTINUED)

TWO PHASE TP FLASH
SIMULTANEOUS REACTIONS
GENERATE COMBUSTION REACTIONS FOR FEED SPECIES NO
*** RESULTS ***

REACTION EXTENTS:
REACTION REACTION
NUMBER EXTENT
KMOL/DAY
1 16591.
V-L PHASE EQUILIBRIUM :
COMP F(I) X(I) Y(I) K(I)

UREA 0.72819E-03 0.12146E-02 0.22606E-05 0.18612E-02
CARB 0.24222 0.40442 0.13307E-03 0.32904E-03
CO2 0.92957E-01 0.14356E-01 0.21027 14.647
NH3 0.51341 0.36400 0.73640 2.0231
H2O 0.13698 0.21578 0.19384E-01 0.89835E-01
N2 0.11922E-01 0.15619E-03 0.29482E-01 188.76
O2 0.17799E-02 0.70536E-04 0.43309E-02 61.399
BLOCK: E03 MODEL: RADFRAC

-------------------------------
INLETS - S05 STAGE 5
S13 STAGE 1
OUTLETS - S15 STAGE 1
S17 STAGE 5
U-O-S BLOCK SECTION

TOTAL BALANCE
MOLE(KMOL/DAY) 27539.1 22053.9 -5485.17 -0.132102E-15
MASS(KG/HR ) 34028.5 34028.5 -0.268771E-06
***CO2 EQUIVALENT SUMMARY ***

**********************
**** INPUT DATA ****
**********************
**** INPUT PARAMETERS ****
NUMBER OF STAGES 5
ALGORITHM OPTION STANDARD
INITIALIZATION OPTION STANDARD
HYDRAULIC PARAMETER CALCULATIONS NO
INSIDE LOOP CONVERGENCE METHOD NEWTON
DESIGN SPECIFICATION METHOD NESTED
MAXIMUM NO. OF OUTSIDE LOOP ITERATIONS 200
MAXIMUM NO. OF INSIDE LOOP ITERATIONS 20
MAXIMUM NUMBER OF FLASH ITERATIONS 30
FLASH TOLERANCE 0.000100000
OUTSIDE LOOP CONVERGENCE TOLERANCE 0.00100000
**** COL-SPECS ****
MOLAR VAPOR DIST / TOTAL DIST 1.00000

REBOILER DUTY MMKCAL/H -3.20000

U-O-S BLOCK SECTION
**** REAC-STAGES SPECIFICATIONS ****
STAGE TO STAGE REACTIONS/CHEMISTRY ID

1 5 REACT1
***** REACTION PARAGRAPH REACT1 *****
**** REACTION PARAMETERS ****
RXN NO. TYPE PHASE CONC. TEMP APP TO EQUIL CONVERSION

BASIS K
1 EQUILIBRIUM VAPOR FUGACITY 0.0000
** STOICHIOMETRIC COEFFICIENTS **
RXN NO. UREA CARB CO2 NH3 H2O

1 0.000 1.000 -1.000 -2.000 0.000
RXN NO. N2 O2
1 0.000 0.000
**** PROFILES ****
P-SPEC STAGE 1 PRES, KG/SQCM 141.000
TEMP-EST STAGE 1 TEMP, C 86.0000

2 90.0000
3 103.000
4 128.000
5 160.000
X-EST
1 1.8000-02 0.3000 1.6000-02 2.0000-02 0.6780 2.0000-04
5 1.4000-03 0.3000 1.0000-02 0.2300 0.4600 7.0000-04
X-EST
STAGE O2
1 2.0000-04
5 4.0000-04
Y-EST
1 2.0000-08 5.0000-08 5.0000-02 1.0000-02 4.0000-03 0.8300
5 1.0000-06 2.0000-05 0.2100 0.3700 3.0000-02 0.3300
Y-EST
STAGE O2
1 0.1100
5 5.0000-02

U-O-S BLOCK SECTION
*******************
**** RESULTS ****
*******************
OUTLET STREAMS
--------------
S15 S17
COMPONENT:
UREA .86011E-06 1.0000
CARB .10440E-07 1.0000
CO2 .24040 .75960
NH3 .34915E-02 .99651
H2O .49198E-03 .99951
N2 .98723 .12768E-01
O2 .94812 .51881E-01
*** SUMMARY OF KEY RESULTS ***
TOP STAGE TEMPERATURE C 86.2468

BOTTOM STAGE TEMPERATURE C 154.240
TOP STAGE LIQUID FLOW KMOL/DAY 14,364.5
BOTTOM STAGE LIQUID FLOW KMOL/DAY 20,728.3
TOP STAGE VAPOR FLOW KMOL/DAY 1,325.60
BOILUP VAPOR FLOW KMOL/DAY 2,548.89
MOLAR BOILUP RATIO 0.12297
REBOILER DUTY MMKCAL/H -3.20000
**** MAXIMUM FINAL RELATIVE ERRORS ****
DEW POINT 0.18031E-03 STAGE= 2

BUBBLE POINT 0.21450E-03 STAGE= 1
COMPONENT MASS BALANCE 0.57082E-07 STAGE= 1 COMP=CO2
ENERGY BALANCE 0.37581E-05 STAGE= 1

U-O-S BLOCK SECTION
**** PROFILES ****
**NOTE** REPORTED VALUES FOR STAGE LIQUID AND VAPOR RATES ARE THE FLOWS
FROM THE STAGE INCLUDING ANY SIDE PRODUCT.
ENTHALPY
1 86.247 141.00 -90004. -4506.1

2 90.611 141.00 -90783. -17217.
4 114.54 141.00 -89222. -24270.
5 154.24 141.00 -83936. -25603. -3.2000

KMOL/DAY KMOL/DAY KMOL/DAY
1 0.1436E+05 1326. .14534+05 1325.6003
2 0.1437E+05 1553.
4 0.1492E+05 1761.
5 0.2073E+05 2549. .13005+05 .20728+05
**** MASS FLOW PROFILES ****

KG/HR KG/HR KG/HR
1 0.2120E+05 1607. .20783+05 1606.6246
2 0.2142E+05 2019.
4 0.2226E+05 2350.
5 0.3242E+05 3085. .13246+05 .32422+05

1 0.18100E-02 0.28802 0.15827E-02 0.23075E-01 0.68507
2 0.18096E-02 0.29217 0.57938E-02 0.14758E-01 0.68505
4 0.17425E-02 0.29195 0.80476E-02 0.34502E-01 0.66320
5 0.14961E-02 0.32236 0.96892E-02 0.16513 0.50025

STAGE N2 O2
1 0.21030E-03 0.23208E-03
2 0.19990E-03 0.21438E-03
4 0.29902E-03 0.25715E-03
5 0.68436E-03 0.39100E-03

U-O-S BLOCK SECTION

1 0.20122E-07 0.52627E-07 0.47950E-01 0.90473E-02 0.38504E-02
2 0.31494E-07 0.98843E-07 0.18254 0.66932E-02 0.50120E-02
4 0.95666E-07 0.56351E-06 0.25362 0.25116E-01 0.10873E-01
5 0.52812E-06 0.10688E-04 0.23541 0.24803 0.24866E-01

STAGE N2 O2
1 0.82742 0.11173
2 0.70823 0.97523E-01
4 0.62457 0.85814E-01
5 0.43207 0.59615E-01
**** K-VALUES ****

1 0.11115E-04 0.18266E-06 30.299 0.39208 0.56198E-02
2 0.17400E-04 0.33819E-06 31.508 0.45350 0.73154E-02
4 0.54900E-04 0.19301E-05 31.516 0.72796 0.16395E-01
5 0.35300E-03 0.33156E-04 24.296 1.5020 0.49707E-01
**** K-VALUES ****

STAGE N2 O2
1 3935.4 481.53
2 3543.4 454.97
4 2088.7 333.71
5 631.32 152.46

KMOL/DAY
1 0.000 198.5 -198.5 -397.1 0.000 0.000
2 0.000 60.55 -60.55 -121.1 0.000 0.000
4 0.000 142.4 -142.4 -284.8 0.000 0.000
5 0.000 2325. -2325. -4650. 0.000 0.000

KMOL/DAY
STAGE O2
1 0.000
2 0.000
4 0.000
5 0.000

1 0.30696E-02 0.63498 0.19670E-02 0.11097E-01 0.34851
2 0.30375E-02 0.63753 0.71266E-02 0.70249E-02 0.34493
4 0.29227E-02 0.63661 0.98921E-02 0.16411E-01 0.33370
5 0.23935E-02 0.67041 0.11359E-01 0.74916E-01 0.24007

U-O-S BLOCK SECTION

STAGE N2 O2
1 0.16636E-03 0.20971E-03
2 0.15651E-03 0.19173E-03
4 0.23396E-03 0.22982E-03
5 0.51070E-03 0.33330E-03

1 0.41545E-07 0.14125E-06 0.72548E-01 0.52970E-02 0.23847E-02
2 0.60624E-07 0.24734E-06 0.25750 0.36536E-02 0.28941E-02
4 0.17938E-06 0.13736E-05 0.34851 0.13355E-01 0.61160E-02
5 0.10920E-05 0.28728E-04 0.35671 0.14543 0.15423E-01

STAGE N2 O2
1 0.79685 0.12292
2 0.63592 0.10002
4 0.54629 0.85735E-01
5 0.41673 0.65679E-01
BLOCK: F01 MODEL: FLASH2

------------------------------
INLET STREAM: S04
OUTLET VAPOR STREAM: S05
OUTLET LIQUID STREAM: S06

IN OUT RELATIVE DIFF.
TOTAL BALANCE
MOLE(KMOL/DAY) 103582. 103582. 0.140487E-15
MASS(KG/HR ) 138743. 138743. 0.00000

U-O-S BLOCK SECTION
BLOCK: F01 MODEL: FLASH2 (CONTINUED)
*** INPUT DATA ***

TWO PHASE PQ FLASH
PRESSURE DROP ATM 0.0
SPECIFIED HEAT DUTY MMKCAL/H 0.0
*** RESULTS ***

V-L PHASE EQUILIBRIUM :
COMP F(I) X(I) Y(I) K(I)

UREA 0.16492 0.18855 0.38543E-03 0.20442E-02
CARB 0.10653 0.12182 0.49357E-04 0.40514E-03
CO2 0.40208E-01 0.12797E-01 0.23112 18.059
NH3 0.38428 0.34904 0.62976 1.8043
H2O 0.29134 0.32725 0.41249E-01 0.12604
N2 0.11062E-01 0.38423E-03 0.85430E-01 222.35
O2 0.16514E-02 0.16380E-03 0.12012E-01 73.336
BLOCK: M01 MODEL: MIXER

-----------------------------
INLET STREAMS: S01 S08 S17
OUTLET STREAM: S02

TOTAL BALANCE
MOLE(KMOL/DAY) 129290. 129290. 0.646302E-06
MASS(KG/HR ) 138743. 138744. -0.467086E-05


U-O-S BLOCK SECTION
BLOCK: M01 MODEL: MIXER (CONTINUED)
*** INPUT DATA ***

TWO PHASE FLASH
OUTLET PRESSURE: MINIMUM OF INLET STREAM PRESSURES
BLOCK: R01 MODEL: RPLUG

-----------------------------
UREA SYNTHESIS REACTOR
INLET STREAM: S03
OUTLET STREAM: S04

TOTAL BALANCE
MOLE(KMOL/DAY) 96107.2 103582. 7474.72 -0.140487E-15
MASS(KG/HR ) 138744. 138743. 0.356405E-05
ENTHALPY(MMKCAL/H) -237.996 -237.996 0.00000

*** INPUT DATA ***
REACTOR TYPE:
ADIABATIC
TWO-PHASE
REACTOR TUBE LENGTH METER 28.956
REACTOR DIAMETER METER 2.2921
REACTOR RISE METER 0.0000
NUMBER OF REACTOR TUBES 1
REACTOR VOLUME L 0.11948E+06
PRESSURE DROP OPTION: SPECIFIED
HOLDUP OPTION: NO-SLIP
ERROR TOLERANCE 0.10000E-04

INTEGRATION METHOD GEAR
CORRECTOR METHOD NEWTON
INITIAL STEP SIZE FACTOR 0.10000E-02
CORRECTOR TOLERANCE FACTOR 0.10000
MAXIMUM NUMBER OF STEPS 1000

U-O-S BLOCK SECTION
BLOCK: R01 MODEL: RPLUG (CONTINUED)
REACTION PARAGRAPH ID: REACT2 TYPE: USER

SUBROUTINE NAME USURA
GLOBAL BASES:
KBASIS MOLE-GAMMA
CBASIS MOLARITY
SBASIS LOCAL
STOICHIOMETRY:
REACTION NUMBER: 1
SUBSTREAM: MIXED
CARB 1.0000 CO2 -1.0000 NH3 -2.0000
REACTION NUMBER: 2
SUBSTREAM: MIXED
CARB -1.0000 CO2 1.0000 NH3 2.0000
REACTION NUMBER: 3
SUBSTREAM: MIXED
UREA 1.0000 CARB -1.0000 H2O 1.0000
REACTION NUMBER: 4
SUBSTREAM: MIXED
UREA -1.0000 CARB 1.0000 H2O -1.0000
REAC-DATA ENTRIES:
REACTION NO TYPE PHASE DELT BASIS

K
1 KINETIC L 0.0000 MOLARITY
*** RESULTS ***
REACTOR DUTY MMKCAL/H 0.0000

RESIDENCE TIME HR 0.44466
REACTOR MINIMUM TEMPERATURE C 167.00
REACTOR MAXIMUM TEMPERATURE C 183.00

U-O-S BLOCK SECTION
*** RESULTS PROFILE (PROCESS STREAM) ***
LENGTH PRESSURE TEMPERATURE VAPOR FRAC RES-TIME

METER KG/SQCM C HR
0.0000 141.00 167.00 0.40121 0.0000

2.8956 141.00 175.66 0.27797 0.32373E-01
5.7912 141.00 179.70 0.18844 0.70530E-01
8.6868 141.00 181.92 0.14541 0.11392
11.582 141.00 182.70 0.13098 0.16009
14.478 141.00 182.92 0.12696 0.20723
17.374 141.00 182.98 0.12591 0.25465
20.269 141.00 182.99 0.12564 0.30213
23.165 141.00 183.00 0.12557 0.34964
26.060 141.00 183.00 0.12556 0.39715
28.956 141.00 183.00 0.12555 0.44466
LENGTH DUTY LIQUID HOLDUP

METER MMKCAL/HR
0.0000 0.0000 0.25439
2.8956 0.0000 0.33994
5.7912 0.0000 0.43746
8.6868 0.0000 0.50244
11.582 0.0000 0.52816
14.478 0.0000 0.53575
17.374 0.0000 0.53777
20.269 0.0000 0.53829
23.165 0.0000 0.53842
26.060 0.0000 0.53845
28.956 0.0000 0.53846
*** TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) ***
LENGTH UREA CARB CO2 NH3

METER
0.0000 0.72819E-03 0.24222 0.92957E-01 0.51341

2.8956 0.67980E-01 0.18818 0.70509E-01 0.45952
5.7912 0.12170 0.14191 0.54282E-01 0.41850
8.6868 0.15057 0.11808 0.44988E-01 0.39577
11.582 0.16092 0.10974 0.41551E-01 0.38750
14.478 0.16388 0.10737 0.40559E-01 0.38512
17.374 0.16465 0.10675 0.40297E-01 0.38450
20.269 0.16485 0.10659 0.40230E-01 0.38434
23.165 0.16490 0.10655 0.40213E-01 0.38430
26.060 0.16492 0.10654 0.40209E-01 0.38429
28.956 0.16492 0.10653 0.40208E-01 0.38428

U-O-S BLOCK SECTION
*** TOTAL MOLE FRACTION PROFILE (PROCESS STREAM) ***
LENGTH H2O N2 O2
METER
0.0000 0.13698 0.11922E-01 0.17799E-02

2.8956 0.20049 0.11595E-01 0.17309E-02
5.7912 0.25065 0.11283E-01 0.16844E-02
8.6868 0.27779 0.11132E-01 0.16619E-02
11.582 0.28756 0.11081E-01 0.16543E-02
14.478 0.29035 0.11067E-01 0.16522E-02
17.374 0.29109 0.11063E-01 0.16516E-02
20.269 0.29128 0.11062E-01 0.16515E-02
23.165 0.29133 0.11062E-01 0.16514E-02
26.060 0.29134 0.11062E-01 0.16514E-02
28.956 0.29134 0.11062E-01 0.16514E-02
*** TOTAL MASS FRACTION PROFILE (PROCESS STREAM) ***

METER
0.0000 0.12622E-02 0.54579 0.11808 0.25236

2.8956 0.12116 0.43601 0.92094E-01 0.23226
5.7912 0.22290 0.33788 0.72858E-01 0.21737
8.6868 0.27951 0.28497 0.61200E-01 0.20835
11.582 0.30009 0.26604 0.56786E-01 0.20493
14.478 0.30601 0.26063 0.55501E-01 0.20394
17.374 0.30756 0.25921 0.55162E-01 0.20367
20.269 0.30796 0.25885 0.55075E-01 0.20361
23.165 0.30806 0.25875 0.55052E-01 0.20359
26.060 0.30809 0.25873 0.55047E-01 0.20358
28.956 0.30810 0.25872 0.55045E-01 0.20358
LENGTH H2O N2 O2
METER
0.0000 0.71225E-01 0.96395E-02 0.16438E-02

2.8956 0.10719 0.96395E-02 0.16438E-02
5.7912 0.13771 0.96396E-02 0.16438E-02
8.6868 0.15469 0.96396E-02 0.16438E-02
11.582 0.16087 0.96396E-02 0.16438E-02
14.478 0.16264 0.96396E-02 0.16438E-02
17.374 0.16311 0.96396E-02 0.16438E-02
20.269 0.16323 0.96396E-02 0.16438E-02
23.165 0.16326 0.96396E-02 0.16438E-02
26.060 0.16327 0.96396E-02 0.16438E-02
28.956 0.16327 0.96396E-02 0.16438E-02

U-O-S BLOCK SECTION
*** LIQUID MOLE FRACTION PROFILE (PROCESS STREAM) ***

METER
0.0000 0.12146E-02 0.40442 0.14356E-01 0.36401

2.8956 0.94076E-01 0.26059 0.13752E-01 0.36478
5.7912 0.14988 0.17484 0.13605E-01 0.36073
8.6868 0.17613 0.13817 0.13168E-01 0.35370
11.582 0.18511 0.12627 0.12913E-01 0.35041
14.478 0.18765 0.12297 0.12829E-01 0.34940
17.374 0.18832 0.12212 0.12805E-01 0.34913
20.269 0.18849 0.12190 0.12799E-01 0.34906
23.165 0.18853 0.12184 0.12798E-01 0.34904
26.060 0.18854 0.12183 0.12797E-01 0.34904
28.956 0.18855 0.12182 0.12797E-01 0.34904
LENGTH H2O N2 O2
METER
0.0000 0.21578 0.15619E-03 0.70537E-04

2.8956 0.26651 0.21202E-03 0.92902E-04
5.7912 0.30054 0.28578E-03 0.12329E-03
8.6868 0.31834 0.34570E-03 0.14799E-03
11.582 0.32476 0.37275E-03 0.15910E-03
14.478 0.32660 0.38117E-03 0.16255E-03
17.374 0.32708 0.38344E-03 0.16348E-03
20.269 0.32721 0.38403E-03 0.16372E-03
23.165 0.32724 0.38418E-03 0.16378E-03
26.060 0.32725 0.38422E-03 0.16379E-03
28.956 0.32725 0.38422E-03 0.16380E-03
*** LIQUID MASS FRACTION PROFILE (PROCESS STREAM) ***

METER
0.0000 0.17215E-02 0.74516 0.14911E-01 0.14631

2.8956 0.15017 0.54076 0.16087E-01 0.16513
5.7912 0.25851 0.39202 0.17196E-01 0.17644
8.6868 0.31371 0.31992 0.17188E-01 0.17866
11.582 0.33307 0.29535 0.17027E-01 0.17880
14.478 0.33857 0.28844 0.16962E-01 0.17877
17.374 0.34002 0.28663 0.16944E-01 0.17876
20.269 0.34039 0.28617 0.16939E-01 0.17876
23.165 0.34048 0.28605 0.16938E-01 0.17876
26.060 0.34051 0.28602 0.16937E-01 0.17876
28.956 0.34051 0.28601 0.16937E-01 0.17876

U-O-S BLOCK SECTION
*** LIQUID MASS FRACTION PROFILE (PROCESS STREAM) ***
LENGTH H2O N2 O2
METER
0.0000 0.91743E-01 0.10326E-03 0.53269E-04

2.8956 0.12762 0.15788E-03 0.79017E-04
5.7912 0.15549 0.22992E-03 0.11331E-03
8.6868 0.17010 0.28723E-03 0.14045E-03
11.582 0.17529 0.31285E-03 0.15253E-03
14.478 0.17677 0.32080E-03 0.15627E-03
17.374 0.17716 0.32295E-03 0.15727E-03
20.269 0.17726 0.32350E-03 0.15753E-03
23.165 0.17729 0.32364E-03 0.15760E-03
26.060 0.17729 0.32368E-03 0.15762E-03
28.956 0.17729 0.32369E-03 0.15762E-03
*** VAPOR MOLE FRACTION PROFILE (PROCESS STREAM) ***

METER
0.0000 0.22606E-05 0.13307E-03 0.21027 0.73640

2.8956 0.19504E-03 0.10300E-03 0.21794 0.70561
5.7912 0.31356E-03 0.71999E-04 0.22947 0.66732
8.6868 0.36456E-03 0.56683E-04 0.23200 0.64303
11.582 0.37998E-03 0.51384E-04 0.23156 0.63355
14.478 0.38404E-03 0.49886E-04 0.23125 0.63076
17.374 0.38509E-03 0.49493E-04 0.23115 0.63001
20.269 0.38535E-03 0.49392E-04 0.23112 0.62982
23.165 0.38542E-03 0.49367E-04 0.23112 0.62978
26.060 0.38544E-03 0.49360E-04 0.23111 0.62976
28.956 0.38544E-03 0.49358E-04 0.23111 0.62976
LENGTH H2O N2 O2
METER
0.0000 0.19384E-01 0.29482E-01 0.43309E-02

2.8956 0.29007E-01 0.41161E-01 0.59857E-02
5.7912 0.35774E-01 0.58645E-01 0.84078E-02
8.6868 0.39456E-01 0.74528E-01 0.10560E-01
11.582 0.40754E-01 0.82128E-01 0.11574E-01
14.478 0.41120E-01 0.84546E-01 0.11895E-01
17.374 0.41216E-01 0.85203E-01 0.11982E-01
20.269 0.41241E-01 0.85372E-01 0.12005E-01
23.165 0.41247E-01 0.85416E-01 0.12010E-01
26.060 0.41249E-01 0.85427E-01 0.12012E-01
28.956 0.41249E-01 0.85429E-01 0.12012E-01

U-O-S BLOCK SECTION
*** VAPOR MASS FRACTION PROFILE (PROCESS STREAM) ***

METER
0.0000 0.58722E-05 0.44936E-03 0.40026 0.54246

2.8956 0.49853E-03 0.34224E-03 0.40823 0.51146
5.7912 0.78316E-03 0.23377E-03 0.42001 0.47266
8.6868 0.90007E-03 0.18193E-03 0.41976 0.45021
11.582 0.93474E-03 0.16432E-03 0.41744 0.44198
14.478 0.94384E-03 0.15938E-03 0.41648 0.43960
17.374 0.94617E-03 0.15809E-03 0.41620 0.43898
20.269 0.94676E-03 0.15775E-03 0.41613 0.43882
23.165 0.94691E-03 0.15767E-03 0.41611 0.43878
26.060 0.94695E-03 0.15765E-03 0.41611 0.43876
28.956 0.94696E-03 0.15764E-03 0.41610 0.43876
LENGTH H2O N2 O2
METER
0.0000 0.15105E-01 0.35724E-01 0.59943E-02

2.8956 0.22242E-01 0.49076E-01 0.81521E-02
5.7912 0.26804E-01 0.68326E-01 0.11189E-01
8.6868 0.29222E-01 0.85830E-01 0.13891E-01
11.582 0.30074E-01 0.94242E-01 0.15171E-01
14.478 0.30316E-01 0.96924E-01 0.15577E-01
17.374 0.30379E-01 0.97652E-01 0.15687E-01
20.269 0.30395E-01 0.97840E-01 0.15715E-01
23.165 0.30399E-01 0.97888E-01 0.15722E-01
26.060 0.30400E-01 0.97901E-01 0.15724E-01
28.956 0.30401E-01 0.97904E-01 0.15725E-01
BLOCK: SP1 MODEL: SEP

---------------------------
INLET STREAM: S10
OUTLET STREAMS: S11 S12

TOTAL BALANCE
MOLE(KMOL/DAY) 56627.4 56627.4 0.00000
MASS(KG/HR ) 76269.6 76269.6 0.190796E-15
ENTHALPY(MMKCAL/H) -149.514 -149.343 -0.114037E-02

U-O-S BLOCK SECTION
BLOCK: SP1 MODEL: SEP (CONTINUED)

*** INPUT DATA ***
INLET PRESSURE KG/SQCM 141.000
FLASH SPECS FOR STREAM S11

TWO PHASE TP FLASH
FLASH SPECS FOR STREAM S12

TWO PHASE TP FLASH
PRESSURE DROP ATM 0.0
FRACTION OF FEED
SUBSTREAM= MIXED
STREAM= S11 CPT= CO2 FRACTION= 1.00000
NH3 1.00000
MOLE-FLOW (KMOL/DAY)
SUBSTREAM= MIXED
STREAM= S11 CPT= UREA FLOW= 26.0000
CARB 0.0
H2O 9,838.00
N2 0.0
O2 0.0
*** RESULTS ***
HEAT DUTY MMKCAL/HR 0.17050
COMPONENT = UREA
STREAM SUBSTREAM SPLIT FRACTION
S11 MIXED 0.0015259
S12 MIXED 0.99847

U-O-S BLOCK SECTION
BLOCK: SP1 MODEL: SEP (CONTINUED)
COMPONENT = CO2
S11 MIXED 1.00000
COMPONENT = NH3
S11 MIXED 1.00000
COMPONENT = H2O
S11 MIXED 0.36389
S12 MIXED 0.63611
COMPONENT = N2
S12 MIXED 1.00000
COMPONENT = O2
S12 MIXED 1.00000

STREAM SECTION
S01 S02 S03 S04 S05

-------------------
STREAM ID S01 S02 S03 S04 S05

FROM : ---- M01 E02 R01 F01
TO : M01 E02 R01 F01 E03
CONV. MAX. REL. ERR: 0.0 -2.2384-05 0.0 0.0 0.0

SUBSTREAM: MIXED
PHASE: LIQUID MIXED MIXED MIXED VAPOR
COMPONENTS: KMOL/DAY
UREA 0.0 69.9846 69.9846 1.7083+04 5.0125
CARB 0.0 6687.3374 2.3279+04 1.1035+04 0.6419
CO2 0.0 2.5525+04 8933.8709 4164.7954 3005.6389
NH3 3.4038+04 8.2526+04 4.9343+04 3.9805+04 8189.9556
H2O 0.0 1.3165+04 1.3165+04 3.0178+04 536.4355
N2 0.0 1145.8125 1145.8125 1145.8125 1111.0106
O2 0.0 171.0566 171.0566 171.0566 156.2201
COMPONENTS: KG/HR
UREA 0.0 175.1218 175.1218 4.2746+04 12.5428
CARB 0.0 2.1754+04 7.5725+04 3.5896+04 2.0880
CO2 0.0 4.6807+04 1.6382+04 7637.1589 5511.5652
NH3 2.4154+04 5.8561+04 3.5014+04 2.8246+04 5811.6471
H2O 0.0 9882.0602 9882.0602 2.2653+04 402.6681
N2 0.0 1337.4248 1337.4248 1337.4248 1296.8030
O2 0.0 228.0669 228.0669 228.0669 208.2857
TOTAL FLOW:
KMOL/DAY 3.4038+04 1.2929+05 9.6107+04 1.0358+05 1.3005+04
KG/HR 2.4154+04 1.3874+05 1.3874+05 1.3874+05 1.3246+04
L/MIN 688.3390 9437.1371 6573.3185 4191.3659 1934.4580
STATE VARIABLES:
TEMP C 34.0000 140.1583 167.0000 182.9992 182.9989
PRES KG/SQCM 160.0000 141.0000 141.0000 141.0000 141.0000
VFRAC 0.0 0.6686 0.4012 0.1256 1.0000
LFRAC 1.0000 0.3314 0.5988 0.8744 0.0
SFRAC 0.0 0.0 0.0 0.0 0.0
ENTHALPY:
CAL/MOL -1.5808+04 -4.0844+04 -5.9433+04 -5.5144+04 -3.0523+04
CAL/GM -928.1947 -1585.8542 -1715.3607 -1715.3668 -1248.6680
MMKCAL/HR -22.4192 -220.0273 -237.9956 -237.9956 -16.5394
ENTROPY:
CAL/MOL-K -44.6410 -33.4447 -54.8950 -50.4317 -20.6480
CAL/GM-K -2.6212 -1.2986 -1.5844 -1.5688 -0.8447
DENSITY:
MOL/CC 3.4340-02 9.5140-03 1.0153-02 1.7162-02 4.6686-03
GM/CC 0.5848 0.2450 0.3518 0.5517 0.1141
AVG MW 17.0306 25.7549 34.6472 32.1469 24.4442

STREAM SECTION
S06 S07 S08 S09 S10

-------------------

FROM : F01 ---- E01 E01 A02
TO : E01 E01 M01 A02 SP1
SUBSTREAM: MIXED
PHASE: LIQUID VAPOR VAPOR LIQUID LIQUID
UREA 1.7078+04 0.0 38.9707 1.7039+04 1.7039+04
CARB 1.1034+04 0.0 5.2433 3049.6817 0.0
CO2 1159.1566 1.7076+04 2.5324+04 890.3864 3940.0681
NH3 3.1615+04 0.0 4.5065+04 2508.1962 8607.5595
H2O 2.9641+04 190.0000 2795.5376 2.7036+04 2.7036+04
N2 34.8020 1100.0000 1131.6287 3.1733 3.1733
O2 14.8364 150.0000 162.9533 1.8831 1.8831
COMPONENTS: KG/HR
UREA 4.2734+04 0.0 97.5160 4.2636+04 4.2636+04
CARB 3.5894+04 0.0 17.0561 9920.4874 0.0
CO2 2125.5937 3.1313+04 4.6438+04 1632.7387 7225.0670
NH3 2.2434+04 0.0 3.1979+04 1779.8327 6107.9816
H2O 2.2250+04 142.6210 2098.4330 2.0294+04 2.0294+04
N2 40.6218 1283.9512 1320.8691 3.7039 3.7039
O2 19.7812 199.9925 217.2629 2.5107 2.5107
TOTAL FLOW:
KMOL/DAY 9.0577+04 1.8516+04 7.4524+04 5.0528+04 5.6627+04
KG/HR 1.2550+05 3.2940+04 8.2168+04 7.6270+04 7.6270+04
L/MIN 2256.8945 2126.5425 1.0811+04 1178.9213 1151.7659
STATE VARIABLES:
TEMP C 182.9989 100.0000 185.0525 165.9606 72.4000
PRES KG/SQCM 141.0000 141.0000 141.0000 141.0000 141.0000
VFRAC 0.0 1.0000 1.0000 0.0 0.0
LFRAC 1.0000 0.0 0.0 1.0000 1.0000
SFRAC 0.0 0.0 0.0 0.0 0.0
ENTHALPY:
CAL/MOL -5.8679+04 -8.7575+04 -4.0292+04 -7.0254+04 -6.3367+04
CAL/GM -1764.6247 -2051.1638 -1522.6459 -1939.2868 -1960.3320
MMKCAL/HR -221.4563 -67.5644 -125.1122 -147.9086 -149.5137
ENTROPY:
CAL/MOL-K -54.7081 -8.6050 -20.2589 -54.6562 -51.0431
CAL/GM-K -1.6452 -0.2015 -0.7656 -1.5087 -1.5791
DENSITY:
MOL/CC 2.7870-02 6.0466-03 4.7872-03 2.9764-02 3.4143-02
GM/CC 0.9268 0.2582 0.1267 1.0782 1.1037
AVG MW 33.2529 42.6954 26.4617 36.2268 32.3248

STREAM SECTION
S11 S12 S13 S15 S17

-------------------

FROM : SP1 SP1 A01 E03 E03
TO : A01 ---- E03 ---- M01
SUBSTREAM: MIXED
PHASE: MIXED LIQUID LIQUID VAPOR LIQUID
UREA 26.0000 1.7013+04 26.0000 2.6674-05 31.0125
CARB 0.0 0.0 3938.7165 6.9762-05 6681.9444
CO2 3940.0681 0.0 1.3516 63.5629 200.8414
NH3 8607.5595 0.0 730.1265 11.9931 3422.9168
H2O 9838.0000 1.7198+04 9838.0000 5.1040 1.0369+04
N2 0.0 3.1733 0.0 1096.8249 14.1856
O2 0.0 1.8831 0.0 148.1152 8.1049
COMPONENTS: KG/HR
UREA 65.0596 4.2571+04 65.0596 6.6746-05 77.6023
CARB 0.0 0.0 1.2812+04 2.2693-04 2.1736+04
CO2 7225.0670 0.0 2.4784 116.5580 368.2913
NH3 6107.9816 0.0 518.1026 8.5104 2428.9246
H2O 7384.7635 1.2909+04 7384.7635 3.8313 7783.6004
N2 0.0 3.7039 0.0 1280.2451 16.5579
O2 0.0 2.5107 0.0 197.4796 10.8061
TOTAL FLOW:
KMOL/DAY 2.2412+04 3.4216+04 1.4534+04 1325.6003 2.0728+04
KG/HR 2.0783+04 5.5487+04 2.0783+04 1606.6247 3.2422+04
L/MIN 495.0591 772.3657 303.5358 210.3153 514.4904
STATE VARIABLES:
TEMP C 72.4000 72.4000 72.4000 86.2468 154.2404
PRES KG/SQCM 141.0000 141.0000 141.0000 141.0000 141.0000
VFRAC 0.1786 0.0 0.0 1.0000 0.0
LFRAC 0.8214 1.0000 1.0000 0.0 1.0000
SFRAC 0.0 0.0 0.0 0.0 0.0
ENTHALPY:
CAL/MOL -5.2765+04 -7.0193+04 -8.7524+04 -4506.0724 -8.3936+04
CAL/GM -2370.8330 -1803.5036 -2550.3552 -154.9120 -2235.9665
MMKCAL/HR -49.2727 -100.0705 -53.0037 -0.2489 -72.4942
ENTROPY:
CAL/MOL-K -34.1360 -62.7497 -65.6478 -7.8490 -66.2027
CAL/GM-K -1.5338 -1.6123 -1.9129 -0.2698 -1.7636
DENSITY:
MOL/CC 3.1438-02 3.0764-02 3.3252-02 4.3770-03 2.7979-02
GM/CC 0.6997 1.1973 1.1412 0.1273 1.0503
AVG MW 22.2558 38.9201 34.3183 29.0879 37.5392

PROBLEM STATUS SECTION
BLOCK STATUS
------------
****************************************************************************
* *
* Calculations were completed normally *
* *
* All Unit Operation blocks were completed normally *
* *
* All streams were flashed normally *
* *
* All Convergence blocks were completed normally *
* *
****************************************************************************

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ASPEN PLUS IS A TRADEMARK OF HOTLINE:

PLATFORM: WIN-X64 AUGUST 9, 2023

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE I

ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

RUN CONTROL SECTION.................................... 1

U-O-S BLOCK SECTION.................................... 8

PROBLEM STATUS SECTION................................. 39

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE 1

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

RUN CONTROL INFORMATION

THIS COPY OF ASPEN PLUS LICENSED TO CARNEGIE MELLON UNIV

TYPE OF RUN: NEW

INPUT FILE NAME: _4527jmv.inm

OUTPUT PROBLEM DATA FILE NAME: _4527jmv

PDF SIZE USED FOR INPUT TRANSLATION:

CALLING PROGRAM NAME: apmain

SIMULATION REQUESTED FOR ENTIRE FLOWSHEET

STAMICARBON CO2 STRIPPING PROCESS H.P. SYNTHESIS SECTION This

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

FLOWSHEET CONNECTIVITY BY STREAMS

STREAM SOURCE DEST STREAM SOURCE DEST

FLOWSHEET CONNECTIVITY BY BLOCKS

BLOCK INLETS OUTLETS

CONVERGENCE STATUS SUMMARY

TEAR STREAM SUMMARY

STREAM VARIABLE MAXIMUM MAX. ERR. ABSOLUTE CONV

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

VALUES OF ACCESSED FORTRAN VARIABLES:

CONVERGENCE BLOCK: C-1

*** FINAL VALUES ***

VAR# TEAR STREAM VAR STREAM SUBSTREA COMPONEN UNIT VALUE

*** ITERATION HISTORY ***

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

CONVERGENCE BLOCK: C-1 (CONTINUED)

ITERATED: SENTENCE=CONV VARIABLE=CONV ID1=1 IN UOS BLOCK E02

ITERATION VARIABLE ERROR ERR/TOL

TEAR STREAMS AND TEAR VARIABLES:

ITERATION MAX-ERR/TOL VAR# STREAM ID VAR DESCRIPTION SUBSTREA COMPONEN

2 -234.1 3 S02 MOLE-FLO MIXED CARB

3 -135.2 3 S02 MOLE-FLO MIXED CARB

5 -166.6 3 S02 MOLE-FLO MIXED CARB

6 -64.51 3 S02 MOLE-FLO MIXED CARB

7 -39.38 3 S02 MOLE-FLO MIXED CARB

8 87.80 3 S02 MOLE-FLO MIXED CARB

9 97.49 3 S02 MOLE-FLO MIXED CARB

10 62.69 3 S02 MOLE-FLO MIXED CARB

11 68.57 3 S02 MOLE-FLO MIXED CARB

12 -293.0 3 S02 MOLE-FLO MIXED CARB

13 47.75 3 S02 MOLE-FLO MIXED CARB

14 18.47 3 S02 MOLE-FLO MIXED CARB

15 -81.57 3 S02 MOLE-FLO MIXED CARB

16 -1.155 3 S02 MOLE-FLO MIXED CARB

17 -3.017 3 S02 MOLE-FLO MIXED CARB

18 -1.191 3 S02 MOLE-FLO MIXED CARB

19 -166.0 3 S02 MOLE-FLO MIXED CARB

20 -0.2238 3 S02 MOLE-FLO MIXED CARB

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 08/09/2023 PAGE 5

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

SEQUENCE USED WAS:

OVERALL FLOWSHEET BALANCE

*** MASS AND ENERGY BALANCE ***

*** CO2 EQUIVALENT SUMMARY ***

UREA SYNTHESIS BY CO2 STRIPPING - HIGH-PRESSURE LOOP

ID TYPE ALIAS NAME

* FINAL VALUES *

* ITERATION HISTORY *

* MASS AND ENERGY BALANCE *

* CO2 EQUIVALENT SUMMARY *

* MASS AND ENERGY BALANCE *

* CO2 EQUIVALENT SUMMARY *

* INPUT DATA *

* RESULTS *

* MASS AND ENERGY BALANCE *

* CO2 EQUIVALENT SUMMARY *

* INPUT DATA *

* RESULTS *

* MASS AND ENERGY BALANCE *

* CO2 EQUIVALENT SUMMARY *

INPUT PARAMETERS

COL-SPECS

REAC-STAGES SPECIFICATIONS

* REACTION PARAGRAPH REACT1 *

REACTION PARAMETERS

HEATERS

PROFILES

COMPONENT VAPORIZATION EFFICIENCY

COMPONENT VAPORIZATION EFFICIENCY

* COMPONENT SPLIT FRACTIONS *

* SUMMARY OF KEY RESULTS *

MAXIMUM FINAL RELATIVE ERRORS

PROFILES

MASS FLOW PROFILES

MOLE-X-PROFILE

MOLE-X-PROFILE

MOLE-Y-PROFILE

MOLE-Y-PROFILE

K-VALUES

K-VALUES

RATES OF GENERATION