B V R AJ U IN S T IT U T E O F T E C H N O L O G Y , N AR S A P U R (UGC - AUTONOMOUS) I M.TECH II Semester Supplementary Examinations, Jan 2021 ADVANCED REACTION ENGINEERING (Che mical E ng ineer ing) Time: 3 Hours Max Marks: 70 Note: This Question Paper contains two Parts A and B • Part A is compulsory which carries 10 marks. Five questions from six units. Answer all questions in Part A at one place only. • Part-B consists of 6 Questions (numbered from 2 to 13) carrying 10 marks each. Each of these questions is from one unit and may contain a, b, c as sub-questions. For each question there will be an either/or choice (that means there will be two questions from each unit and the student should answer only one question). PART – A (5x2 = 10 Marks) 1. Marks Bloom CO Level a Mention factors to be considered while selecting the reactors. 2 K2 1 b Mention the energy balance equation of PFR. 2 K2 2 c How to find out which resistance is controlling in non-catalytic 2 K1 3 fluid-particle reaction for shrinking core model? d List the types of deactivation methods in a catalyst. 2 K1 4 e How will you represent enzyme fermentation and microbial 2 K2 6 fermentation? PART – B (6x10 = 60 Marks) Marks Bloom CO Level 2 Derive the performance equation of ideal mixed flow reactor 10 K3 1 and represent it graphically. OR 3 Substance A in liquid phase produces R and S by 10 K4 1 A→ R, rR=k1 CA A→ S, rS=k2 CA. Feed (CAo=1.0, CRo=CSo=0) enters 2 CSTRS in series (τ1=2 min,τ2=5 min).Knowing the compositions in the first reactor CA1=0.4, CR1=0.4,CS1=0.2.Find the composition leaving the second reactor, using fractional yield concept.
4 An irreversible isomerization reaction is carried out in liquid 10 K4 2
phase in mixed reactor. A→R, first order reaction. Rate constant at 165oC=0.7 hr-1. Activation energy =120000 J/mol. heat of reaction=-350kJ/kg. Heat capacity of reactants and products=1.95kJ/kg.K. Volumetric flow rate = 0.33 m3/hr. FeedHtemperature=20oC.Conversion expected=95%. Calculate the reactor size and temperature of the reaction mixture is operated adiabatically. OR 5 Derive energy balance equation for adiabatic operation and 10 K3 2 graphically represent it.
6 Explain the determination of rate controlling step in fluid- 10 K2 3
particle reaction. OR 7 Discuss about the various aspects of gas-solid reactions in 10 K2 3 fluidized bed reactors.
8 A first order reaction is carried out in a non-ideal tubular 10 K3 4
reactor. Assuming that the axial dispersion model is valid, derive the expression for conversion in the reactor. 0R 9 A sample of tracer was injected as pulse into a vessel to be 10 K4 4 used as reactor and the effluent concentration is measured as a function of time. The data collected in given below: CA, 0 1 5 8 10 8 6 4 3 2.2 1.5 0.6 0 3 g/m t, 0 1 2 3 4 5 6 7 8 9 10 12 14 min Construct C and E curves. Find the fraction of material leaving the reactor that has spent 3 and 8 min.
10 Write short notes on PBE modelling and its applications. 10 K1 5
OR 11 Discuss about the various aspects of population balance of 10 K1 5 gas-solid reactions in Rotary kiln.
12 Describe the steps involved in design procedure of 10 K3 6
immobilized cell reactor. OR 13 The E. coli microbe grows contentedly on glucose according 10 K4 6 to Monod kinetics as follows
What feed rate of glucose solution (CAo = 6 kg/m3) to a mixed
flow reactor (V = 1 m3) would give the maximum consumption rate of glucose, and maximum production rate of E. coli cells?