Enthusiast/ACME/Pre-Medical

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CHEMISTRY DPP # 1 (SOLID STATE)                                             BATCH: ACME

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1. Which of the following is a non -crystalline solids? 7. Triclinic crystal system has the following unit cell
parameters :-
(1) CsCl (2) NaCl
(1) a = b = c, α = β = γ = 90°
(3) CaF2 (4) Glass
(2) a = b ≠ c, α = β = γ = 90°
2. Which of the following statement is incorrect about
amorphous solids? (3) a ≠ b ≠ c, α ≠ β ≠ γ ≠ 90°

(1) They are anisotropic  (4) a = b ≠ c, α = β = 90°, γ = 120°

(2) They are rigid and incompressible 8. Relation a ≠ b ≠ c and α = β = γ = 90° is correct
for which crystal system
(3) They melt over wide range of temperature (1) Cubic (2) Monoclinic
(4) There is no orderly arrangement of particles (3) Orthorhombic (4) Hexagonal
3. Which is incorrect for graphite? 9. A match box exhibits ......... geometry.
(1) Network solid (2) Anisotropic (1) Cubic (2) Triclinic
(3) Covalent solid (4) Metallic solid (3) Orthorhombic (4) Monoclinic
4. Which is/are amorphous solids - 10. How many crystal systems have body centred type
unit cell :
(1) Rubber (2) Plastics
(1) 2 (2) 3 (3) 4 (4) 7
(3) Glass (4) AII
11. Number of Bravais lattices are :-
5. Which of the following is a network solid? (1) 14 (2) 7 (3) 3 (4) 2
(1) SO2(solid) (2) I2 12. In a simple cubic cell, each point on a corner is
(3) Diamond (4) Ice shared by
(1) 2 unit cells (2) 1 unit cell
6. Match the solids given in Column I with their types
given in Column II and identify the correct code (3) 8 unit cells (4) 4 unit cells
Column I Column II 13. Distance between two nearest atom in SC unit cell
a. I2 (i) Covalent solids (1) a (2) √3a
b. ZnS (ii) Molecular solids √ 2 4
(3) 2a (4) a
c. Ag (iii) Ionic solids
14. In the primitive cubic unit cell, the atoms are
d. AIN (iv) Metallic solids present at the:
(1) a(iii), b(ii), c(iv), d(i) (1) corners of the unit cell
(2) a(ii), b(iii), c(iv), d(i) (2) centre of the unit cell
(3) a(ii), b(iii), c(i), d(iv) (3) centre of each face of the unit cell 
(4) a(i), b(ii), c(iii), d(iv) (4) one set of faces of the unit cell
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15. The fraction of volume occupied by atoms in a 21. Correct relation about FCC is
primitive cubic unit cell is :- (1) 4r = 3a √

(1) 0.48 (2) 0.52 (3) 0.55 (4) 0.68 (2) Coordination number = 6
16. Match the following (3) Packing efficiency =  π
  Unit cell   Rank (Z) 3√ 3
A. Simple cubic P. 4 (4) r = a
2√ 2
B. Body centred cubic Q. 1
22. If a is the length of unit cell, then which one is
C. Face centered cubic R. 2 correct relationship- 
(1) A - R, B - Q, C - P (2) A - Q, B - R, C - P (1) For simple cubic lattice, Radius of metal atom
(3) A - P, B - R, C - Q (4) A - P, B - Q, C - R a
= 
2
17. The coordination number for an atom in a primitive (2) √3a
unit cell is :- For bcc lattice, Radius of metal atom = 
4
(1) 6 (2) 8 (3) For fcc lattice,Radius of metal atom =  a
2√ 2
(3) 10 (4) 12
(4) All
18. Lithium crystallizes in a body - centred cubic
lattice of unit cell length 352pm. The distance 23. The maximum percentage of available volume that
between nearest neighbours  can be filled in a face centred cubic system by an
atom is- 
(1) 150 pm (2) 75 pm
(1) 74% (2) 68% (3) 34% (4) 26%
(3) 304 pm (4) 122 pm
24. In a face-centred cubic cell, an atom at the face
19. The vacant space in B.C.C. unit cell is- contributes to the unit cell :-
(1) 32% (2) 10% (1) 1/4 part (2) 1/8 part
(3) 23% (4) 46% (3) 1 part (4) 1/2 part 
20. For bcc structure, packing fraction and co- 25. A lattice of an element has 12.08 × 1023 F.C.C. unit
ordination number would be respectively: cell. Total number of atoms in the given lattice are
(1) π 3 √ (2) π 2 √ :-
, 8 , 6
8 6 (1) 24.16 × 1023 (2) 48.32  × 1023 
(3) π 2 √
(4) None
, 8 (3) 12.08 × 1023 (4) None of these
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