GNANASAGAR EDUCATIONAL TRUST

1st PUC Chemistry Mid-term Examination – 2014-15

Date: Marks : 70

Part - A
I. Answer ALL the questions each carries one mark: - 10  1 = 10
1) What is the oxidation state of sulphur in ?
2) State modern periodic law.
3) What is electromeric effect?
4) State Aufbau principle
5) Define molarity?
6) Nitrogen has higher ionisation enthalpy than that of oxygen give reason.
7) What is the shape of p-orsotals
8) Define mole
9) Give the composition of water gas
10)What is catenation?

Part - B
II. Answer any FIVE questions each carries two marks: - 5  2 = 10
11)State law of multiple proportions.
12)How many significant figures are present in the a) 2.0034, b) 500 .
13)Write the electronic configuration of chromium (At No. 24)
14)What are isoelectronic species? Give examples.
15)Define groups and periods in a modern periodic table.
16)Write any two differences between inductive effect and resonance effect.
17)What is homologons series? Give example.

Part - C
III. Answer any FIVE of the following each carries 3 marks: - 5  3 = 15
18)a) arrange the following in the decreasing order of their ionic radius Al3+, Mg2+, Na+, O2.
b) Give the IUPAC name of element with atomic number 112
19)What is ionisation enthalpy? How does it vary across the period and down a group
20)Balance the redox reaction using oxidation number method.

21)a) How are elements classified on the Basis of electronic configuration.

b) Name the element which has highest electron gain enthalpy.
22)Draw the diagram of Daniel cell, write symbolic representation and cathode, anode reactions.
23)Give an example for the following redox reactions.
a) combination reaction
b) disproportional reaction
c) decomposition reaction
( P.T.O )
 Part - D
IV. Answer any FIVE questions (Each Question carries five marks): - 5  5 = 25
24)a) Define (i) Limiting reagent (ii) Molar mass.

b)
Calculate the mass of CaO and CO2(g) produced on complete decomposition of 5g of CaCO3
(Given molar mass of CaO = 56g, CO2 = 44g)
25)a) A compound contains 4.07% hydrogen 24.27% carbon and 71.65% chlorine. Its molar
mass is 98.96 calculate its empherical and molecular formulae.
b) What is the value of 1amu?
26)a) Write the characteristics of cathode rays.
b) State and explain Hund’s rule.
27)a) Write the significance of each quantum numbers.
b) What is the value of Avogadio’s number?
28)a) Define (i) Critical temperature (ii) Charle’s law (iii) Ideal gas (iv) Viscosity
b) What is the value of universal gas constant ‘R’.
29)a) Write any four postulates of Kinetic theory of gases.
b) Write Vander Waal’s equation for one mole of gas.

Part - E
V. Answer any TWO questions. Each carries five marks: - 2  5 = 10
30)a) How is carbon and hydrogen estimated? Write diagram and formula.
b) Write the bond line formula of .

31)Give the IUPAC name.

a)

b) What are electrophiles and nucleophiles?

c) What is hyper conjugation effect?
32)a) What is functional isomerism? Give an example.
b) Give a test for nitrogen.
c) Give an example for Heterocyclic compound.

~~~~~~~~~