No.

of pages - 8 (M)
MARKING SCHEME
MID-TERM EXAMINATION (2022-23)
CLASS : XI
SUBJECT: CHEMISTRY (043)
Time Allowed : 3 hours Maximum Marks : 70

Section-A

1. (d) 6.02 × 1023 atoms C 1

h
2. (a) 6 1
2
3. (b) A 1
4. (b) CH3 1
1
5. (c) 4, 0, 0, 1
2
6. (a) F 1
7. (c) C2H6 1
8. (b) K 1
9. (c) sp2 1
10. (c) SF4 follows the Lewis outer rule 1
11. (d) C  O  N  F 1
12. (b) ns2 np5 1
13. (c) 22.4 L of CO2 at NTP 1
14. (c) 2×1015 s-1 1
15. (c) Assertion is correct but reason is wrong statement. 1
16. (a) Assertion and reason both are correct but reason is correct explanation
for assertion. 1

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17. (b) Assertion and reason both are correct but reason is not correct
explanation for assertion. 1
18. (c) Assertion is correct but reason is wrong statement. 1
Section-B
19. (i) Due to more stable half filled electronic configuration N(1s2 2s2 2p3). 1
(ii) Because of fully filled octet of Noble gases / highly stable electronic
configuration of noble gases. 1
OR
(i) Group 16 / oxygen family 1
(ii) Lithium 1
20. (a) sp to sp2 1
(b) 1

h
21.  ½
mv

.634 1034
 ½
9.11031  2107

6.634 1010 6.634 1010

  ½
9.1 2 18.2
= 0.36 × 10-10 m ½
22. Refer NCERT for definition
- stronger 1, 1

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23. H 2  C 2  2HC

2g H2req. 71 gC 2

71
103g H2 req. 103 gC 2
2
= 35.5 × 103 gC 2 ½

Hence from the above C 2 is limiting reagent amount of HC formed is

decide by C 2 . ½

71 gC 2 73 g HC

73
1g C 2 gives HC
71
73
20 × 103 g C 2 gives  20 103 gHC ½
71
= 20.56 × 103 g of HC ½

24. (a) n=3 1

(b) four subhslells 1
25. In H2O, 2 lone pairs are present hence have more repulsion than NH3, which
is having one lonepair. 1,1

OR

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 #
C1s 2 2s 1
2p1z 2px1 2py1
 1
sphybridization

1
Section-C
26. (i) XeF2 1

(ii) SF4 1

(iii) NH3 1

OR
(a) sp2 1
(b) CO2 (180°) 1
1
(c) B.O.  (4  4)  0
2
as B.O. is zero for Be2, hence does not exist. 1

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27. (a) F 1
(b) C 1
(c) C 1
28. (a) Refer NCERT 1
(b) (i) The energies of the orbits in which the electrons revolve are fixed.1
(ii) Due to significant mass of cricket ball, the wavelength of wave
associated with it too small to detect. 1
29. (a) Refer to NCERT solved question number 1.3 of chapter 1 1½
(b) Refer to NCERT solved question number 1.4 of chapter 1 1½
30. (i) 2s 1
(ii) 4d 1
(iii) 3p 1
Section-D
31. (i) (b) 4  2 1

(ii) (b) 1s 2 2s 2 2p6 3s 2 1

(iii) (a) 1 1
(iv) (d) Magnetic quantum number 1
OR
(a) 2
32. (i) (c) sp > sp2 > sp3 1
(ii) (b) N 1
OR
(a) F
(iii) (c) Si  P  C  N 1
(iv) (a) Si 1

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 Section-E
33. (a) According to Bohr postulate
h
Angular momentum is mur = n (i) 1
2
According to de Broglie equation.
h h
 and mv  (ii) ½
mv 
From equation (i) and (ii)

h nh
r  ½
 2
h = 2r 1
(b) Refer to NCERT solved problem 2.16 of chapter 2 2
z = 26
P = 26 ½
A= P+N
56 = 26 + N
N = 30 ½
OR

(a) Cu(29)  1s 2 2s 2 2p 6 3s 2 3p 6 3d10 4s1 1

Because fully filled subshell (3d10) is symmetrical and have more

magnitude of exchange energy than partially filled subshells (3d9). 1
(b) Refer to NCERT solved problem 2.10 of chapter 2 2
(c) (i) Not applicable on multi-electron system. ½,½
(ii) Cannot explain fine spectrum of hydrogen atom.
(or any other correct limitations)

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34. (a) Refer to NCERT exercise question No. 4.23 of Chapter 4 2
(b) (i) No change both have sp3 1
(ii) sp3d to sp3 1
(iii) sp2 to sp3 1
OR
(a) Sigma bond is formed by axial overlapping, whereas pie bond is
prepared by side ways over lapping
Sigma bond is stronger whereas pie is a weak bond. 2
(or any other two correct differences)

(b) P  (Ne)3s1
3px1 3py

1
3pz1 3dz2 3dz1
 1
5[sp3d]

As axial bonds are present at bond angle of 90°, whereas equitorial bond at
120°, hence axial bonds experience more repulsions, due to which longer. 1
35. (a) Mol mass of CuSO4 = 159.5g,
159.5g CuSO4 have 63.5g cu ½
63.5
100g of CuSO4 = 100  39.8g ½
159.5
12
(b) Amount of ‘c’ in 3.30g CO2 =  3.38  0.9218g ½
44
2
Amount of ‘H’ in 0.690 g H2O =  0.690  0.0767g ½
18
0.9218
% of ‘C’ in welding gas = 102  92.3% ½
0.9985

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% of ‘H’ = 100 – 92.3 = 7.7% ½
Determination of E.F.
% by mass Molar Simplest molar ratio
C 92.3 92.3 1
 7.69
12
H 7.7 7.7 1
 7.7
1

E.F. = CH
E.F. Man = 13
Determination of mol. man
PO.OL of gas at STP weigh = 11.6g
11.6
22.4L of gas at STP weigh =  22.4  26g 1
10
MF 26
n  2
EF 13
Molecular formula = C2H2 1

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