PREBOARDCHANDI

GARHREGI
ON(
2022-
23)
CLASS–XII MAXMARKS70
SUBJECT-CHEMI
STRY TI
ME-3HRS
MARKI
NGSCHEME
SN ANSWERS M

1 c 1

2 b 1

3 b 1

4 d 1

5 d 1

6 b 1

7 c 1

8 c 1

9 b 1

10 c 1

11 d 1

12 c 1

13 b 1

14 b 1

15 c 1

16 d 1

17 a 1

18 d 1

19 a)d2sp3,oct
ahedr
al 2
b)dichlori
dobi
s(ethane1,
2di
ami
ne)I
ron(
II
I)

-
2-
20 uni
tforK =molL2s-1andor
derofr
eact
ioni
s3 2

OR
K=2.303l
og a
t a-
x
t=2.
303 log ax10
60 a
t=2.
303/60=0.
038s

21 K2/
K1=2 2
l
og(K2/
K1)=Ea/R(1/
T1–1/
T2)
Ea=2.303X8.314X298X308X0.
3010/
10=52.
89kJ/
mol

22 a)(
i)
CH3Brduet
olessst
eri
chi
ndr
ance 2
 (i
i
)CH3Br,Brbet
terl
eavi
nggp.
(b)
chl
orof
ormformspoisonousPhosgenegas
2CHCl
3+O2 2 COCl2+2 HCl

23 (
i) cor
rectr
eact
ions. 2
(
ii
) cor
rectr
eact
ions.

24 (
a)Thet wohemiacetalformsofglucosedi ff
eronlyintheconfi
gurat
ionsof 2
thehy dr
oxy
lgroupatC1cal ledanomer iccarbon.Suchisomersare
call
edanomer s.Fore.g.αandβ- D-
glucose.
(
b)Anyt wocorr
ectexampl es.(
Bgr oupv i
taminsandv i
taminCar ewater
soluble)
OR
(
a)

Whengl
ucosei
str
eat
edwi
thbr
omi
newat
er,
itgi
vesgl
uconi
caci
dasapr
oduct
.
Br
omi
newat
eri
sanoxi
dizi
ngagent
.
b)Gl
ucosepent
aacet
atei
sfor
med.

25 W =ZI
t 2
t=W/ZI=1.5x96500/
1.5x108
=893.
51sec
3 1
26 (
a)t2g  
eg 3
(
b)sp3, tet
rahedr
al,
diamagnet
ic
(
c)EDTA

27 a)Thev ari
ousquant it
iesknowntousareasf ol
l
ows: 57X10-3bar
Π =2. , 3
V=200cm3=0. 200litr
e
T=300K
R=0. 083Lbarmol -
1K- 1
Substit
utingt hesevaluesinequationweget
M2=WbxRT/ πxV =. 26g×0. 083LbarKmol ×300K/
2.
57×10bar×0.200L
=61,022gmol -1
(b)
duet of ormat i
onofofH- bondofbetweenthem
OR
a)∏=i.w.R.T
M. V
=3x0.025x0. 0821x298
174x2
=0.0052at m
(b)
Cor r
ectr eason

28 (
a) 3
 (
b) CH3CH2Cl
+
Mg(indr
yether
)  CH3CH2MgCl
(
c)CH3Br+AgNO2  CH3NO2+AgBr

29 (
a)Itisbecauseethanol i
sassociatedwi t
hi nt
ermolecularH-
bonding. 3
Theref
ore,ethanolhashigherboili
ngpoi ntthanthatofmethoxymet hane
whichisnotassociatedwithIntermolecularH-bonding.
(
b)Phenol i
smor eacidicthanethanolbecausephenoxi dei
onismor e
stabl
eduet oresonanceascompar edt oethoxideionwhichisunstable
duetopositi
v ei
nductiveeff
ectofet hylgroup.

(
c)I
tisbecause- NO2gr oupisanel
ectr
onwithdrawinggroup(
-Reff
ect)
,it
i
ncreasest hestabil
it
yofo-andp-nit
rophenoxideionascomparedto
phenoxide.
d)30al
( coholsgiv
eal kenesondehydr
ati
on.

30 3
(
i)ani
l
inei
sfor
med.

31 (a)B 4
(b)Maximum boilingAzeotrope
(c)Respir
ati
on,sof tdri
nks,anoxia,scubaseadi
v i
ng.
OR
Raoult’
slawstatest hatpar
tialpressureofavol
atil
ecomponentofa
solut
ionisdir
ectlyproporti
onal t
oi t
smol ef
ract
ion.I
tisaspeci
alcaseof
Henry’l
awbecause  i
tbecomest hesamewhen“ KH”(Henr
yconstant
)is
equaltopressur
eofpur esolvent.

32 (a)Becausebodyl acksenzymestodi gestbet

ali
nks. 4
(b)Gly
cosidi
clinkage.
(c)Twocor r
ectdiffer
ences.
OR
Classi
fi
cati
on of car bohydr
ates i nt
o monosacchar
ides,
oli
gosacchari
desandpol ysacchar
ides.
3+
33 a)Al(s)|
Al (0.
01M)|
|Fe2+(
0.02M)|
Fe(
s) 1+1+
E0CELL=1.22V 1+1+
Ecell=1.209V 1=5

b)Cor
rectel
ect
roder
eact
ions.
OR
Ther
elat
ions
hipbe
twee
nconduc
ti
vi
ty
 κ,
res
ist
anc
eRandt
hec
ell
cons
tantbi
s
κ=R1​
×
b
κ=31.
6Ω1​
×
0.367/
cm
κ=0.
0116S/
cm
 Ther
elat
ions
hipbe
twee
nmol
arc
onduc
ti
vi
ty
 Λm​
,
conduc
ti
vi
ty
 κ 
andmol
ar
c
onc
ent
rat
ionCi
s
Λm​
=C1000κ​
Λm​
=0.
05m1000×
0.0116S/
cm​
Λm​
=232.
3Sc
m2/
mol
Hnc e
, t
hemolarconducti
vi
tyis 
232.3Scm2/mol
(b)Forstr
ongelect
rol
ytes,molarconducti
vi
tysl
owlyi
ncr
ease
swit
hdil
uti
on.
Forweake l
ectr
olyt
es,molarconducti
vit
yincr
easesst
eepl
yondi
l
uti
on,e
speci
al
ly
nearlowerconcent
rat
ions.

34 (
i)ThisisbecausePCCi sami l
doxi disingagentandcanoxi demet hanol t
o 5
methanal only .
Whi leKMnO4bei ngst r
ongoxi di
singagentoxi disesi
tto
methanoi caci d
(
ii
)(CH3) 3C—CHOdoesnotunder goal dol condensat ionduet oabsenceofαH
(
ii
i)
 forms2, 4-DNPder ivative  Al dehy deorKet one
 r educesTonen' sr eagent al dehy de
 under goesCanni zzaro'sreact i
on αH i snotpr esent
 Onv igor ousoxi dati
oni tgives1, 2-benzenedi car boxyli
caci d benzene
ri
ngwi thtwogr oupsat1, 2posi ti
on
Sot hecompoundi s2- Ethylbenzal dehyde
OR.
(i
).Propanol andpr opanone:
Pr opanal beinganal dehy der educesTol len'sr eagentt oSil
vermi r
rorbut
propanonebei ngaket onedoesnot .
+ − 2 −
3 2 +2[( 3) 2] +3 ⟶ 3 +2 ↓
+4 3+2 2
(i
) Benzal dehy deandacet ophenone:
Acet ophenonegi vesy ell
owpptofi odof ormt estwi t
hNaOI( NaOH+I 2)
wher easbenzal dehy dedoesnot .
3 6 5+3 ⟶ 6 5 + 3+2

Acetophenone yell
owppt
(b)(i
)Met hyltert-butylketone<Acet one<Acet aldehy de(reactiv
itytowards
HCN)
(i
i)4- met hoxy benzoi cacid<benzoi cacid<3, 4- dini
trobenzoicacid.
(i
i
i) 3 2 < 3 (Br)− 2 <
( )
 2−
35 (1)(
i) 2 7 +1 4 ++6 −⟶ 2 3+
+7 2 +3 2 5
− − + 2+ −
(i
i)2 4 +5 2 +6 ⟶2 +5 3 +3 2
(2)(
a)thetransitionmet alsform al
argenumberofcompl excompound
becauseofpr esenceofv acantdorbi
tal
,highnuclearchar
ge
(b)Duetocompar abl
eener gyof7s,6d,5for bi
tal
s.
(c)Duetolessener gygapbet weennsand( n-
1)d.

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*ENDOFPAPER*
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