No.

of pages - 11 (M)
MARKING SCHEME
COMMON PRE-BOARD SCHOOL EXAMINATION (2022-23)
CLASS : XII
SUBJECT: CHEMISTRY (043)
Time Allowed : 3 hours Maximum Marks : 70

Section-A

1. (c) order of the reaction 1

2. (a) [Co(ONO)3(NH3)3] 1

3. (d) Lactose 1

4. (c) 2 1

5. (c) [Cr(H 2O)6 ]C 3 1

6. (c) 2, 3,1 1

7. (b) (CH3)3–C–I 1

8. (b) Zr, Hf 1

9. (b) Lowering in vapour pressure 1

10. (b) (CH3)2NH 1

O
11. (d) || 1
CH 3  CH 2  C  CH 2  CH 3

12. (b) 2-Methyl propan-2-ol 1

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1. (a) C6 H 5SO 2C 1

CH 3  CH  CH 3
14. (b) | 1
OH

15. (a) Assertion and reason both are correct statements and Reason is the
correct explanation of Assertion. 1

16. (b) Assertion and reason both are correct statements, but Reason is not the
correct explanation of Assertion. 1

17. (a) Assertion and reason both are correct statements and Reason is the
correct explanation of Assertion. 1

18. (c) Assertion is a correct statement but Reason is a wrong statement. 1

Section-B

19. (A)0 = a

30a 70a
(A) = a  
100 100

2.303 (A)0
K log ½
t (A)

2.303 100
 log
40 70a

2.303
 (log100  log 70) ½
40

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 2.303 2.303
 (2 1.8451)  .1549
40 40

= 0.0089

0.693 0.693
t1/ 2    77.7 min ½
k .0089

(or any other correct method)

20. (i) CH 3CHO  3I2 


NaOH
 CHI3 yellow ppt 1

(ii) CH 3CH 2CHO  3I 2  

NaOH

 No yellow ppt 1

O
||
CH 3  C  CH 3  3I 2  
NaOH

 CHI3 yellow ppt

(or any other correct chemical test)

21. (i) Because the hydrogen bonds are formed between specific pairs of
base. 1

(ii) Because the –CHO group in glucose is involved in hemiacetal

formation and thus not free/due to cyclic structure of glucose, –CHO
group is not free. 1

22. (i) pentaamninechlorido cobalt (III) chloride 1

(ii) potassium hexacyanidoferrate (III) 1

3 XII-CHEMISTRY-M
 OR

23. (a) 3 1

(mol L1 )1x

(b) k n=2 1
time

k = mol–1 L1 Time–1

2 4
24. A 2O3  A  O 2
3 3

n=4 ½

G = –xF Ecell ½

(960 103 )
 E cell ½
4  96500

Ecell = 2.48 V

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 (or any other correct method)

25. ½+½

OR

1+1

Section-C

26. For name reaction ptc refers NCERT chapter amines. 1x3=3

OR

(i) A  CH 3CH 2CN, B  CH3CH 2 CH 2 NH 2 , C  CH 2 CH 2CH 2OH 3×½=1½

(ii) A  CH 3CONH 2 , B  CH 3CH 2 NH 2 , C  C6 H5SO 2  NHCH 2CH 3 3×½=1½

27. (a) n=2

G   nFEcell ½

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 300103  296500E cell
0
½

3 00 103
E 0
 ½
2960 00
cell

3000 3000
   1.53V ½
2965 1930

(b)  0 MgC 2  o Mg 2 0 C ½

= 106 + 2 × 76.3

= 258.6 s cm2 mo1 ½

28. (i) Sp3, paramagnetic ½+½

(ii) d2 Sp3, diamagnetic ½+½

(iii) Sp3d2, paramagnetic ½+½

29. (i) Aspirin is formed

(ii) Benzoquinone is formed

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 (iii) 1

30. 1+1+1

31. (a) anode = Zn cathode = Ag ½+½

(b) Cell stop working after same time 1

(c) When Eext > Einternal

(d) (i) When cell is dead or discharged Ecell will be zero and the cell
will be at equilibrium. Then concentration of zn2+ and Ag+ will
not change. 1

(ii) During dilution the number of ions per unit volume decrease
hence conductivity decreases. 1

7 XII-CHEMISTRY-M
32. (a) Globular proteins are soluble in water and fibrous proteins are
insoluble in water fibrous proteins are structural in nature while
globular proteins are functional. 1

(or any other correct differences)

(b) Because amino acid exists as Zwitter ion, hence have ionic
interactions between polar water molecules and zwitter ion of amino
acids. 1

(c) adsorbe/absorbe during denutration of protein. 1

Section-E

33. (a) (i) They show variable oxidation state and form complexes/they
provide large surface area, due to which activation energy
decreases 1

(ii) Because of similarities in their physical and chemical properties

/ lanthanoid contraction 1

(iii) due to completely filled d-orbital they form weak metallic

bond. 1

(b) (i) 2Na 2CrO 4  H 2SO 4  Na 2Cr2O 7  Na 2SO 4  H 2O 1

(ii) MnO 2  4KOH  O 2  2K 2 MnO 4  2H 2O 1

34. (a) Osmatic pressure because work of room temperature / Molarity

is used instead of molarity / its magnitude is large even for very dilute
solution. 1+1

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(b) Pt  PA  PB

 PA0 X A  PB0 X B 1

given  PA0  450, PBo  700

Pt = 600

600  450X A  700(1  X A )

 450X A  700  700X A 1

100  240X A

10 0
XA   0.4
25 0

X B  1  X A  1  0.4  0.6 1

OR

(a) Refers NCERT chapter solution 2

(b) Tg  0  (0.068)  0.068 ½

Tg  ikf  m

0.068 = i × 1.86 × 0.01 ½

i = 3.65

1   (n 1) i 1
i 
1 n 1

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 for AC 3  A 3  3C ½

n=4

3.65 1
  0.8833 ½
4 1

% dissociation =  × 100 = 88.33 ½

(or any other correct method)

35. (a) 1+1+1

(b) (i) CH 3  CH  CH  CO  CH 3  3I 2 

NaOH

 CHI3 yellow ppt 1

CH 3  CH 2  CO  CH  CH 2  3I 2 
NaOH
 No yellow ppt

10 XII-CHEMISTRY-M
 1

(Or any other correct chemical test)

OR

(a) (i) CH3 – CH2 – CH3 1

(iii) CH2 = CH – CH2 – CHO 1

(b) 1

(c) 1

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