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Non-
Colligative Colligative
properties properties
I. Osmotic pressure
II. Vapor pressure lowering
PV = nRT
osmotic pressure ( ) in a diluted solution was equal to the
pressure exerted by the solute if it was a gas occupying the
same volume
V = nRT = Osmotic pressure
= n/V RT T = absolute temperature
n = number of moles
=cRT V = volume in liter
=mRT c = molarity (n/V)
m = molality (n/wt)
K2SO4 3 times
FeCl3 4 times
V = i n RT = i m RT
(i = dissociation factor )
For strong electrolyte
i = number of ions produced by ionization of
strong electrolytes (in diuted solution)
For weak electrolyte
i = total no. of particles (ions or molec) divided by
initial no. before ionization
For non-electrolyte
i=1
When non-volatile solute is dissolved in solvent, the
vapor pressure of solvent is lowered
Solvent molecules on the surface which can escape
into vapor is replaced by solute molecules have little
(if any) vapor pressure.
o
(1 X A ) X B XA = mole fraction of solvent
PA XB= mole fraction of solute
P o A PA
i.e relative vapor pressure lowering P o is equal
A
P XB
For a solution:
the vapor pressure of the
solvent is lower at any
given temperature.
Therefore, a higher
temperature is required to
boil the solution than the
pure solvent.
If we represent the difference in boiling point between the pure
solvent and a solution as Tb,
we can calculate that change in boiling point from the following
formula:
pressure
equilibrium under 1 atm. vapor
In order for a liquid to freeze it must achieve a very ordered state that
results in the formation of a crystal.
If there are impurities in the liquid, i.e. solutes, the liquid is inherently
less ordered. Therefore, a solution is more difficult to freeze than the
pure solvent so a lower temperature is required to freeze the liquid
In analogy to the boiling point elevation, we can calculate the
amount of the freezing point depression using the following
formula:
the –ve sign because the freezing point of the solution is less
than that of the pure solvent.
Osmotic pressure
COLLIGATIVE
PROPERTIES
AFTER STUDYING THIS SECTION, STUDENTS
SHOULD KNOW:
When you dissolve salt or sugar into water, the molecules / ions
are surrounded by water molecules which “trap” them into the
solvent
PA = XAPA
where
• XA is the mole fraction of compound A
• PA is the normal vapor pressure of A at that temperature
Solve: To calculate the mole fraction of water in the solution, we must determine the number of
moles of C3H8O3 and H2O:
SAMPLE EXERCISE 13.8 continued
We now use Raoult’s law to calculate the vapor pressure of water for the solution:
The vapor pressure of the solution has been lowered by 0.6 torr relative to that of
pure water.
PRACTICE EXERCISE
The vapor pressure of pure water at 110°C is
1070 torr. A solution of ethylene glycol and
water has a vapor pressure of 1.00 atm at 110°C.
Assuming that Raoult’s law is obeyed, what is
the mole fraction of ethylene glycol in the
solution?
Answer: 0.290
Ideal Solution
• All intermolecular attractions are the same.
• Solute-Solute
• Solvent-Solvent Attractions are the
same
• Solute-Solvent
• This is like an Ideal Gas – do you think Ideal
Solutions are the same as Real Solutions?
Boiling Point Elevation and
Freezing Point Depression
Solute-solvent
interactions also
cause solutions to
have higher boiling
points and lower
freezing points than
the pure solvent.
Boiling Point Elevation
Section 18.4
AFTER READING SECTION
18.4, YOU SHOULD KNOW:
How to calculate molality (m)
Mole fraction
nA = moles of solute A nB moles
of solvent B
BOILING POINT ELEVATION
Change in boiling point temperature
ΔTb = Kb * m
___4. Automobile battery acid is 38% H2SO4 and has a density of 1.29
g/mL. Calculate the molality of this solution.
Osmotic Terms
Colligative Properties
Osmotic Pressure is related to concentration.
Recall the Ideal Gas Law PV = nRT
Rearrange the equation so the concentration is (n/V)
P = (n/V) R T
Change the symbols P to P for osmotic pressure
and (n/V) to c
The resulting equation for Osmotic Pressure is
P=cRT R = .082 L x atm
mol x K
Colligative Properties
Osmosis
isotonic similar concentrations of solutes