1(C) 4.(D) 5.(B) 6.(0) 7B) 8D) 12.00) 13D) 1540) Solutions - Advanced Problem Package | Chemistry Gaseous State PLL. = Weratptner = (oveight of balloon + weight of gas) 1 2.(B) CO()+=0; CO,)3 ea eae 24 Waragtacs =v *d $2 (uo) x.2= 5008.6 Nayg)* O2(@) > 2NO() n1soxe-(100 208) [rv=stt foe ue] y y 7 R M 0) = 5028.6 (100 -+ 1117.5) = 3811.1 kg. Ba x E ==RT sell) 3() KE permole= 5 equation (i) and (ii)x =6&y = 4 ; RT oe quation (i) and {ii)x = 6&y KE por molecule = 357-547 Key K.B. o Tink. 9(C) PV=nRT — If Vconstant Pee T. Ty > 12 > Ty AL critical point pressure applied is minimum —49.¢c) PM=dRT, and below this point gas enn be liquified eas Py _ da Mp, Pa Vapour pressure is pressure corresponding to the Py My liquifaction curve. At tempernture above critical temperature gas 11.(C) Ex = 3KTN can’t be liquefied whatever pressure is applied. 2 For liquifaction ‘a’ should be greater and ‘ Ex TN, Ey _130N yoy should be smaller. E) T)N2' 2E, 300Nz Fe) >) *Ree) Vxt Die: ag He(g) R300. —}+> | atm, 300K 2xV Mie tT. Rx 400 2v___V__ 600v-400v__ 200v__ IV. 400R 300R 120000R_-——*120000R600R, Abeta pov 4 Y_ _ S00V+600V __1200V ® GooR T= Goo *300R~ 180000R ~ 180000R Rx600 v AM _ ZnRT : PaVp ” ZpnRTy" a4 14.(B) PM =dRT Np +3Hy == *2NH3 t=0 11 12 - t=eq 9 6 4 Nig) + H20qy > NH,OH) 3.58L Free volume for gases 203.58 = 16.42 Gaseous moles = ny, +My al ly PV = nRT > 22.5aim16(B) > T, x moles will move to B PAV =(n—x)RT} PyV=(n+x)RT n(Ti=T2) T+% r/ Finally Px 2V = 2nkT T v=2251 substitute in above and calculate Pa IT(ABC) Vee T (constant n and P) 18.(ABD) As temperature increased number of collision increases, hence presence of gas molecules increases. The energy of ‘gas molecules also increases duc to increase of T, on) = Pee ET , U wil be doubled when P or T is made mesa constant volume 20(ABC) Refer to theory 21.(BCD) With increase in T molecules with less speed will becomes less and with more speed will increase and with near about mps will also increase, 2 22(BC) | P+“ |(v—nb)=net, 7, = (rote) vane an For negligible intermolecular forces, P>> when Vg >> of P+ }0v0)= RT When V,,>>b & Pon then (P\(Vq,)=RT 2 + then (P)(Vqq—b) = RT PVq _ Pb Vq-Pb=RT = Pim Pb_, => PVq~Pb=R’ ae Pb Smee 27.(ABD) 151.24 = Zx 0,0821%250 PV=nRT 1SV=1 x 0.0821 * 250 V=1366 V=1.368-0.12 28.B) Refer totheory 24 Te>Te 24.(BQ) d= %, 2, = VIn0? Vay": 1 ene t2ag eS) ny 3 r 25(CD) ay +2ap = (T 5 2m x300 zu T=500K 26.AD) At very law pressure, Vig >>b a RIV, Athigh pressures, P>> a z=14 2b RT29,AC) Equal no. of moles of both He & Ne shall exert equal pressure. RT Average molecular speed, Cyyy = fy in ar spect Cave ™ ang Helium has higher Cyyg than Neon 30.(CD) At constant V & n, Pet Bon HT, tam i Tn a AUSTP, (Von ident = 224U- (Vpn > 240 As Z.> 1. the gas will become I BI(AD) Z vefiable. 32,(ABC) At critical temperature, Te, densities of liquid and gas become same, 33(AC) For 11& He, Zs obvays greater than 1 For all other real gos, Z.< Vat low pressure 3 [Ass] [8p] [Cr] [D-al Aste mR On moving along B-> _Atconstant temperature, D> — Atconstant pressure, theline from ito f, P= V will increase or decrease depending upon the equation of straight line. Pel/V C+ — Atconstant volume, Pat VaT [A-p, qy #1 > [B-s] > [C-s] > [Ds] Molecular speed of gas molecules is dependent on temperature and molecular mass of molecules. ‘At constant temperature, speed of gas molecules will not change Also, PM = dRT Ifdensity $ is lowered, pressure also decreases in same proportion hence speed remains constant [e« | 36.(6) Volume of CHa; x mL Volume of CO; y mL Volume of Ne: z mL. Final reduction of volume when passed through alkaline pyrogallol Pyrogaltol in alkaline medium absorbs oxygen. Thus, O; was not the limiting reagent. CH, +202 + C02 +2H;0 \dicates there was residual oxygen. Soe kK CO+1/203 + C02 yo yi2oy Reduction of volume when passed through KOH means: x +y=9 mL (must be CO;)......i) Total volume initially used 40+ 10= 50 mL On cooling 36.5 mL means (HzO gets condensed)37.8) 38.02) 39.(4) 40.(7) 41.4) 42.(7) It =50-365=13.5mL Oxygen consumed ‘Thus solving (i) and (ii) equations x = 6 mL, y=3mL CqHy +02 C02 + 1,0 \6mol—48mal_48mol Applying POAC for *C* xxI6= IAB x=3 Applying POAC for ‘H yxl6= 2x48 yr6 So, the formula of hydrocarbon is CsHs. PM mith PaVz ngTy a AMT ny Pz; 15x 164x500 _2 “415x300 T 4xvolume of molecule in rest Let m be the mass of SO; and O: enclosed in the vessel. ‘Number of moles of SO; Partial pressure of SOs, Pq = 5> Partial pressure of O2, Py = oF Now Fa 32,2 Php 80m 5 Hence, the sum of the ratio of partial pressures of SOs and O3is 2+5=7 Under identical conditions of T and P, volumes are in the ratio of their number of moles. Moles of CHy = 1.216. Moles of hydrocarbon, CyHzq-2 =8.1/M 12/16 _ Ike, asa 817M 2b Molecular mass of C,Hpq-2 = 12n-+2n~ Mn = 56 4, PV; = n)RT, for the first bulb P)V2 =ngRT, for the second bulb or RM +PV2=(m+ma)RT,When stopcock is opened the total volume is (Vi + V2) and total no. of motes is (7, +74). Suppose the equilibrium pressure at each bulb is P atm. Then, PCW #Va)=(nitna)RT sll) From equations (i) and (i), we have, RAY +P2V2 = P(V Va) or 9x S46% 10=P x15 P=7aim 43.(4) Given, T; = 400K, T; = 60K Molecular weight of X,Mi= 40 Molecular weight of Y,Mz=? Given, Vins(x) GRxA00 _ [ARX6O = 40 My 30-0 Myed My 44(6.26) CO+H 0 —> CO, +H 1 mol of CO will produce 1 mol Hy = 2.4L of CO at STP will produce 22.4 L of Hy => Water gas sample contains $0%H, 45%CO and 5% CO, 1 L of sample contains 0.45 L CO that will produce 0.45 LH on reaction with steam, +0.5L of H already present. => 1 Lofsample will give 0.95 L Hy => SLof Hy will be produced by ms = 5.263L, 45(8.25) Feample = 0.9810, => Maanpte = 33.33gmol sample "0 > M, ample ‘Sample contains O; and O3 X0,"Mo, +X0,*Mo, = 33.33 > (1X9, )324X0,48= 33.33 Total Imole => 0.33 mol = x5, = 3333-32 _ 0805 > %0s - S00K ISL 1 0 1 300K ISL Final‘Ale adding wae, Z(g) vl dislve to fom asoluion and | mol of Xis le in ISL skal 300K, PVenRT PxdSL = Imobs0601 Lak"! nak PeL6tan 4023 Des of ive (C0#C0,)= 7g" aSTP, PM=6RT Fatma M = 11690" <00021 Lain"! no 23K Mz 30Menot! Aq’ 284(1-1¢q)44= 3945 Ibigg=455 9 gp = 285