AITS 2223 FT II JEEM TD 7 1 23 Sol

FIITJEE
ALL INDIA TEST SERIES

FULL TEST – II
JEE (Main)-2023
TEST DATE: 07-01-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. D
Sol. The fringe–width  is given by
D  D'
 = and  ’=
2d 2d
Where  is the wavelength of light used, D is the distance of the screen from the two slits and 2 d
is the separation between two slits.
Now  –  ’ =  (D  D' )
2d
(  ' ) 2d
  =
D  D'
(3  10 5 )(10 3 )
 =
5  10 2
–6
= 0.6 × 10 m = 6000 Å
2. B
3. D
4. B
5. A
Sol. The image formation is shown in fig.
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AITS-FT-II-PCM(Sol.)-JEE(Main)/2023 2
The rays through optical centres O1 and O2 pass undeflected. The image of O are formed at I1
and I 2 due to upper and lower lenses respectively.
The number of images formed = two
1 1 1
For a convex lens, – =
v u f
Here u = – 0.3 m and f = 0.2 m
1 1 1 1 1 1
 = + =– + =
v u f 0 .3 0.2 0.6
u = 0.6 m
Let d be the distance between the two images I1 and I 2 . From  OO1O2 and  II1I2, we have
d uv
=
O1O 2 u
d 0.3  0.6
or =
0.0005  0.0005 0 .3
Solving we get d = 0.003 m
6. A
7. B
8. A
9. A
Sol. According to given data, ionization energy of Li++ ion is 122.4 eV
 Excitation energy of this ion

1 1 
= 122.4  2 – 2 
1 2 
 1
= 122.4 1 – 
 4
3
= 122.4 × eV
4
 Eex = 91.8 eV
Hence, the value of the first excitation potential
= 91.8 V
10. B
11. B
3 AITS-FT-II-PCM(Sol.)-JEE(Main)/2023
Sol. In one half-life the number of active nuclei reduces to half the original number. Thus, in two half-
1 1
lives the number is reduced to     of the original number. The number of remaining active
 2  2
1 1
nuclei is, therefore, 6.0 × 1018 ×   ×   = 1.5 × 1018
2
   2
12. C
13. D
Sol. Moseley’s equation is
 = a (Z – b).
c
Thus = a(Z1 – b) …(i)
1
c
and = a (Z2 – b) …(ii)
2
Using equations (i) and (ii), we get
 1 1 
c   = a (Z1 – Z2)
   2 
 1
c  1 1 
 a=  
 
( Z1  Z 2 )  2 
 1
Putting given values
a = 5.06 × 107 Hz
Dividing equation (i) by (ii), we get
2 Z b
= 1
1 Z2  b
178.5 42  b
 =
71 27  b
 b = 1.37
14. A
Sol. Let the frequency of the fork be n. In the first case, the length of the wire is 70 cm (0.70 m).
Therefore,
1 T
n= ...(1)
2  0.70 m
On decreasing the length of the wire, its frequency will increase. Hence in the second case when
the length is 69 cm = 0.69 m, then
1 T
n+4= ...(2)
2  0.69 m
dividing equation (1) by (2), we get
n 0.69
 
n 4 0.70
 n × 0.70 = (n + 4) × 0.69
4  0.69
n = = 276 sec–1
0.01
15. A
L 1 / C
Sol. tan 60º = , tan 60º = .
R R
1
 L = .
C
 impedance of the circuit,
1
 2
 1  2
Z =  R 2   L    = R.
  C  
Current in the circuit,
V V 200
i0 = 0 = 0 = = 2 ampere.
Z R 100
1
Average power, P = V0 i0 cos  .
2
 L  1 / C
But tan  = = 0,  cos  = 1.
R
1
 P = × 200 × 2 × 1 = 200
2
16. C
Sol. From the law of length of stretched string, we have n1  1 = n2  2 = n3  3
Here n1 : n2 : n3 = 1 : 3 : 15
 n 3  n
 1  1 = and 1  3 = 15/1
2 n2 1  3 n1
 
 2  1 and  3  1
3 15
The total length of the wire is 105 cm.
Therefore  1 +  2 +  3 = 105
  21 1
or  1 + 1 + 1 = 105 or = 105
3 15 15
105  15
1= = 75 cm.
21
 75
 2 = 1 = = 25 cm
3 3
 75
3 = 1 = = 5 cm
15 15
Hence the bridge should be placed at 75 cm and (75 + 25) = 100 cm from one end.
17. B
Sol. We know that

i= (1– e t/  )
R

i= (given)
R
 
n = (1 – e–t /  )
R R
or e–t/  = 1– 
1
or t=  In
1 
18. A
19. A
20. C
SECTION – B
21. 9
Sol. Field inside the shell is zero, so potential is uniform
kq
V= =9 kilo volts
2R
22. 0
23. 9
24. 0
25. 4
26. 4
27. 8
28. 2
Sol. t   1    t 1.5  1    t = 2
29. 3
Sol. Energy required removing the electron from the third orbit
13.6
 2
eV  1.5 eV = 1.5  1.6  10–19J = 3 eV
3
30. 6
Chemistry PART – B
SECTION – A
31. C
Sol. Due to back bonding between lone pair of oxygen atom and vacant d-orbital of Cl atom,
3 2
hybridization of oxygen atom changes from sp to sp , so the bond angle increases.
O+
–
Cl Cl
32. B
Sol. Be atom has it’s configuration 1s2.2s2 so, B– has it’s configuration 1s2, 2s2, 2p1 and therefore it will
be most destabilized.
33. B
34. B
Sol. Stability order is I > II > III > IV, because I is neutral, while in II all atoms with complete octet
system while III is more stable than IV because in case of IV oxygen is positive with incomplete
octet system.
35. B
Sol. In (III) carbocation cannot be formed because of the bridge head.
36. A
37. B
Sol. CH3–CH–CH–CH3 It can be prepared by the hydrogenation of only two alkenes.
CH3 CH3
H2C=C–CH–CH3 and H3C–C=C–CH3
CH3 CH3 CH3 CH3
38. B

Sol. CHCl3 + t–BuO–k+  t–BuOH + CCl 3
CCl3  :CCl2 + Cl–
CH3–CH=CH–CH3 + :CCl2 CH3–CH–CH–CH3
C
Cl Cl
39. D
Sol.  Tf = kf × Molality
Tf number of moles of glucose 1 weight of glucose (in g)
  molality   
kf mass of water (in kg) 1000 180  1
 weight of glucose (in g) = 0.18 g
40. B
CH3
Sol. Steric hinderence of two –CH3 groups makes –N group out of plane of benzene ring. So,
CH3
lone pair on nitrogen atom is not involved in resonance, therefore, this amine is most basic.
41. B
42. B
43. D
44. B
Sol. –
Na+ OCH3
H3C– CH3OH CH3O CH3
O OH
45. D
46. B
47. B
48. C
49. A

Sol. (CH3–COO)2Ca + (H–COO)2Ca 
 2CH3–CHO + 2CaCO3
50. A
SECTION – B
51. 73
Sol. Let the volume of the tank be V litres.
As the number of moles of N2 before and after connecting it to the tank will be same,
21.4  55 1.5  (55  V )  PV 
RT
=
RT  n  RT 
 
(moles of N2 before connection) (moles of N2 after connection)
 V = 726 litres.
52. 48
Sol. 18mL water  18g water = 1 mole water
= NA water molecules
 One water molecule contains 8 neutrons
 total number of neutrons in the given sample = 8NA.
53. 5
1 1
Sol. At equilibrium, Ecell = 0, Cell reaction is D2(g) + H+  D+ + H2(g)
2 2
[D  ]
 E ocell = 0.0591 log  0.003
[H  ]
[D  ] Eocell 0.003
 log 
   0.05
[H ] 0.0591 0.0591
54. 4
+ + –
Sol. ksp of AgI = [Ag ] [4g ] × [I ]
–16 + –4
1.0 × 10 = [Ag ] × 10
+ –12
 [Ag ] = 1.0 × 10
So, solubility of AgI = [Ag+] = 1 × 10–12 mol/L
55. 2
weight (in g ) 0. 7
Sol. Total number of equivalents of Na2CO3.xH2O = 
Equivalent weight 53  9x
(n factor of Na2CO3.xH2O = 2)
Total number of equivalents of HCl required for complete neutralization
 0.1  19.8 
  5
 1000 
0. 7 0.1  19.8  5
so, 
53  9x 1000
 x=2
56. 1
Sol. For a zero order reaction,
C0 – Ct = Kt
 C0 = Ct + Kt = 0.5 + 2 × 10–2 × 25 = 1.0 M
57. 5
58. 25
59. 20
Sol. N2O4(g) 2NO2(g)
at 300k, 1mole 0 mole P = 1 atm
at 600k, 1–0.2 = 0.8 moles 0.4 moles P=?
total number of moles at 600k = 1.2 moles
 P  nT
P1 n1T1
  were n is number of moles and T is the temperature in ‘K’.
P2 n 2 T2
1 1  300
   P2 = 2.4 atm
P2 1.2  600
60. 6
2– 2+
Sol. In ZnS lattice, S ions are present as FCC with Zn ions occupying alternate tetrahedral voids.
3a
  rZn 2   rS2  
4
4
a= (0.83 + 1.74) = 5.94 A°  6
3
Mathematics PART – C
SECTION – A
61. C
Sol. Function is many one so inverse does not exist.
62. B
Sol. Let x   / 3  t, x   / 3  t  0
sin  t 
lim
t 0 2 cos  t   / 3   1
63. C
Sol. f  x  is decreasing, so  f '  x   0
64. C
1 1

Sol.  x 3 x 5 dx, let t  2  2  1
2 1 x2 x4
2 2  4
x x
65. D
66. D
67. C
x 2 +2x+c
Sol. y= , apply nature of roots
x 2 +4x+3c
68. C
Sol.
2 3 4
Let terms a, ar, ar , ar , ar given that ar 2  2 , product of five terms
5
 a. ar. ar 2 . ar 3 . ar 4   ar 2   25
69. C
70. A
71. D
72. D
73. C
74. A
75. B
2
Sol. Put x  1, x   & x  
76. A
77. C
78. C
1
Sol. x 2
x
a 2  3a  3  1 

a 2  3a  3  0 
79. B
80. D
   
Sol.  a b c   a. b  c
   
SECTION – B
81. 2
Sol. ln cos 1 x  0
1  x  1
82. 3
83. 4
84. 0
Sol. k  0, & D  0
85. 2
 
2.  2 r 2  2 r  1   2 r 2  1  2 r  
Sol.   2r
r 1
2
 2r  1 .  2 r 2  1  2 r 
86. 9
87. 7
Sol.   0 , also  x   y   z  0 and atleast one co-factor of   0
88. 3
89. 4
90. 5
Sol. log b a  x  a  b x

AITS 2223 FT II JEEM TD 7 1 23 Sol

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

 Excitation energy of this ion

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