8 40. 4 42. 43. 44. 45. Which among the following molecules is on polar? (2022) ON) © cr Her (B) (D) NH; CoH If the mixture of 7 g of Nz and 8 g of Ar in a cylinder has the total pressure 27 bar. What is the partial pressure of Nz? (At mass. of N= I4e mol! Ar=402 mol!) 12022] (A) 18 bar (B) 12 bar (C) 15 bar (D) 9 bar What is the new volume if the pressure of 11.2 dm* of a gas is doubled at constant temperature? 12022) (A) 224m? (B) 2.8dm* (© U2dm* (D) 5.6dm* Find the pressure of the 21 gram nitrogen gas having volume 10 dm’ at 300 K. 0.0821 atm dm’ K"' mot", molar mass, 1, = 28 g mol) (2022) (A) 2.78 atm (B) 5.55 atm (©) 3.7 atm (D) 1.85 atm Find the temperature of gas when its initial volume 3 dm’ at 300 K is doubled keeping pressure constant. [2022] (A) 450K (B) 750K (©) 300K (D) 600K Which of the following is NOT correct for ideal gas? [2022] (A) Actual volume is negligible as compared to total volume of a gas. (B) Molecules are note perfectly elastic. (C)_ Value of compressibility factor is 1 (D) Collisions are without loss of kinetic energy. What is the volume of 0.5 mole of a gas having pressure 2 atm at 300 K? (R= 0.0821 dm} atm K"' mol!) [2022] (A) 9.15 dm* (B) 3.08 dm° (C) 6.16 dm* (D) 12.0 dm? Calculate the pressure of 1.5 mole of gas having volume 3 dm’ at 300K, (R= 0.0821 dm’ atm K mol!) (2022) (Ay 15.3.atm (B) 146 aim (C) 10.25 atm (D) 12.32 aim Calculate the number of moles of the as having volume 2.5 liter at 300 K and 4.5 utr? (R= 0.082: im’ K ' mol!) 12022) (Ay 0.46 (3) 0.70 (Cy 0.62 (dD) 0.56 46 Calculate the final volume of gas if pressure changes form 0.75 atm to 1.0 atm at same temperature. (Initial volume is 50 mL) [2023) (A) 25 mL. (B) 40 mL (C) 50mL (D) 37.5 mL What is the new volume of a gas at 400 K if the same gas occupies 1.5 x 10* dm’ at 300 K a constant pressure? (2022) (A) 2.0x10%dm’ — (B) 3.0.x 10° dm’ (C) 1.75«10%dm> = (DD) 1.5 x 10° dm’ Which of the following is the St unit of coefficient of viscosity? (2023) (A) Ns'm? (B) Nsm? (©) Nsm (D) Ns'm'! Find the temperature in degree Celsius if volume and pressure of 2 mole ideal gas is 20 dm’ and 4.926 atmosphetes respectively, (R=0-0821 dm’ atm K"'mol"') [2023] (A) 273 (B) 327 (C) 600 (D) 453 Equal masses of Haye) and He,,, are enclosed ina container at constant temperature. The ratio of partial pressure of Hz to He is [2023] (A) Ll @) 1:2 (©) 21 (@) 14 Which of the following molecules is non-polar? 12023) (A) (B) ICl © (D) CoH A hot air balloon has volume of 2000 dm’ at 99 °C. What is the new volume if air in balloon CyHoCl HF cools to 80 °C? (2023) (A) 2428.9 dm? (B) 2656.9 dm’ (©) 2814.9 dm* (D) 1897.8 dm’ If-at 0°C and 1 atmospheric pressure, 22.4 L of CH, contain Na number of molecules, Find the number of molecules of O2 in 22.4 L at same temperature and pressure. (2023) wm % ®) Na (© 2Na (D) (a? wi of the following is TRUE for ideal gas? [2023] (A) _ Strictly obeys Boyle's law. (B) Molecules are not perfectly elastic. (©) Undergo liquefaction at low temperature when compressed, (D) Hy and O; behave as ideal gases. What is the St unit for rate of diffusion? 2023] (A) em! minu (B) dm hour! (©) dm's (D) mL hour"56. 60. 61. The volume of mass of a gas is 4 dm’ at 0 °C Calculate new volume of the gas at constant pressure when temperature is. decreased. by 10°C. , 12023} (A) 321 dm? (B) 3.85 dm? (©) 4.14 dm’ (D) 6.14dm? ALO °C a gas occupies 22.4 liters, What is the temperature in Kelvin to reach the volume of 224 liters? 12023] (A) 546K (B) 273K (©) 2730K (D) 5460 What is the volume of 1 mole real gas at STP (Vo = 22.4 dm’), if compressibility factor of real gasis 1.1 at STP? [2023] (A) 22.40 dm (B) 23.64 dm? (C) 24.64 dm? (D) 23.50 dm? If Nz gas is compressed at 2 atmosphere from 9.0 L to 3.0 L at 300 K,, find the final pressure at same temperature. [2023] (A) 1.66 atm (8) 3.32atm (C) 6.0atm (@) 9.0m ‘A. closed container contains mixture of non-reacting gases A and B. Partial pressure of A and B are 4.5 bar and 5.5 bar respectively. Find mole fraction of A and B respectively. 12023] (A) 0.035 and 0.065 (B) 0.055 and 0.045 (©) 0.45 and 0.55 (D) 0.55 and 0.45 A neon-dioxygen mixture contains 64 g O» and 160 g Ne. If the total pressure is 25 bar, calculate the partial pressure of doxygen. [2023] 02. 63. 64, 6s. 66. (A) (B) 7.5 bar © (D) 20bar Which of the following alkane has. strong S bar 10 bar London dispersion forces? [2023] (A) Butane (B) _iso-Butane (©) m-Pentane (D) _ neo-Pentane Calculate the volume of 2 moles of a gas at 27°C and at | atm, (R= 0.0821 atm dm’ K"! mol") (2023) (A) 45.42 dm (B) 49.28 dm’ (©) 38.20dm* (D) 47.43 dm’ Calculate the volume of 32 gram oxygen gas having pressure 1.5 atm at 300 K (R= 0.0821 atm dm’ K"' mol) [2023] (A) 32.84 dm! (B) 24.21 dm? (©) 16.42 dm’ (D) 20.12 dm* Calculate the volume of gas at 10 °C and at constant pressure if the volume of the gas at 0°C is 2.dm*, (To = 273.15 K) (A) 2.17 dm’ (B) 1.93 dm? (C) 2.07 dm* (D) 2.27dm° Which of the following pair of liquids has dipole-induced dipole interaction? [2023] (A) Water and ammonia (B) Water and chloroform (C) Water and benzene (D) decrease space blow37. 38. 39. 40. 4L. 42. 43. 44. (D) Benzene (CeH«) has zero dipole moment; hence it is nonpolar. (© y= 8 = 0.25 mol 28 g mol n= —*8, =0.20 mol = 0g mol =—ts_ = 025 _ 2056 Agta, 0254020 P, Partial pressure of No = 0.56 x 27 bar $.12 bar (D) According to Boyle’s law, PLVi = P2V2 Vy BML BE N.2 dm 5.6 i? P, 2P, — 718 _ = 0.75 mol 28 g mor" According to ideal gas equation, PV=nRT pa BRT Vv = 0.75 0.0821 300 10 = 1.85 atm (D) According to Charles’ law v_Y, WaxT, _ (2x3) dm? «300K _ 699 K vo 3 dm (B) Ideal gas molecules are perfectly elastic. So, no kinetic energy loss occurs after coll (©) Pv=aRT y= BRE 0.5%0.0821%300 = 6 16 Gey? P 2 (D) n=1.5 mol, V=3 dm’, T= 300K, R= 0.0821 dm’ atm K"' mol", According to ideal gas equation, PV=nRT pe Okt Vv 1S mol><0.0821 dmn’atm K"! mol"!300 K 3am? = 12.315 am46. 47. 48. 49. 30, (A) V=2.5 dm’, T= 300K, P= 4.5 atm, R= 0.0821 atm dm? K"" mot! According to ideal gas equation, PV=nRT. Py RT AS atmx2.5 dm? = OOS 0.0821 aim dm? K mol 300K =0.46 mol (D) Pi =0.75 at V5? According to Boyle's Law, P,V) = PVs (at constant temperature) = BM, 0.7550 1 atm, V) = 50 mL, y; 7.5 mL. = 300 K, T= 400k, 5x 10° dm’, v> According to Charles” law, (at constant pressure) 1.510" 400 4 dm? = 2x 10" de’ 8) (B) According to ideal gas equation, PV=nRT _ PY _ 4.926% 20 aR 12x 0.0821 T=600K Temp. in °C = 600 ~ 273 = 327 °C Caution - 0.49 Make sure to convert temperature from Kelvin scale to Celsius scale. (C) Let the mass be ‘x’. si. 52. 53. 54, 55. 56. 57. (D) CiHyCl, ICI and HF are polar while CsHs is non-polar. (D)_ Using Charles’ law, vv TT 2000dm’ __V, 32K 353K V2 = 2000% 353 _ 1897.8 dm? 372 Thinking Hatke - Q.52 According to Charles’ law, at constant pressure, the volume of a fixed mass of a gas is directly Proportional to its temperature in kelvin, Therefore, as temperature decreases, volume will decrease, Hence, only option (D) is valid, (B) STP condition = 0°C and 1 atm pressure 1 mol of any gas at STP = 22.4 L 22.4 L of CH, at STP = 1 mol of CH, Na molecules 22.4 L of 0} at STP = Ng molecules Alternate metho: Using Avogadro's law, equal volumes of all Bases of the same temperature and pressure Contain equal number of molecules. 22.4 L of O; at STP contain Na number of molecules. (A) (C) Rate of diffusion of a gas Volume of agas diffused Time required for diffusion SI Unit for rate of diffusion is dm’ s"', (B) Here, T,=0°C= 273K T, =-10°C= 263 K Using Charles’ law, Vv, _\,; T, T, 4dm’ __Y, 2K 263K V2 =3.85 dm? (C) According to Charles" law, {at constant n and P)60. Vreat = Z % Vigea= el x 22.4 = 24.64 dm? Alternate method: z-2v aRT i= ev 15 0.08206 273 _ iy 0.08206 273 V = 24.64 dm’ (C)_ According to Boyle's law, PiV. = P2V2 (at constant n and T) = PM _2x90_ Vv. "30 P, 6.0 bar Thinking Hatke - 0.59 ‘At constant temperature, the volume of a given amount of gas is inversely proportional to its pressure. Therefore, if the volume is reduced to one-third of its original value, the pressure will correspondingly increase by a factor of three. Hence, correct answer is option (C). (C) Prow =Pat Pa 5+5.5 0.0 bar Pa = Xa x Prout 8 me 2 =02 28 10 Moat 1X Pyygy = 0.2 x 25 = 5 bar (C) The strength of London forces increases with increase in molecular mass. n-Pentane is longer and somewhat spread out, whereas neo-pentane is more spherical ang compact. London dispersion forces are stronger in a long chain of atoms where molecules are not compact. Hence, n-pentane has strong London dispersion forces. (B) According to ideal gas equation, PV=nRT y= BRT _ 2040821300 P 1 (C) According to ideal gas equation, PV=nRT y= ART P (©) T= 10°C=283.15 K Now, according to Charles” law, M2 (at constant n and P) Tt XT 2428315 9 97 gad 7 273.15 9.26 dm? V2 (©) When polar molecule like H,0 and nonpolar molecule like benzene approach each other, the H,0 induce dipole in the benzene. Hence ‘Temporary dipoles’ are formed by shifting of electron clouds. The force of attraction developed between the polar and nonpolar molecule is of the type dipole - induced dipole interaction