Chapter 17 Electrochemistry 1. Answer (1) Cell constant = 0.66 cm-', resistance = 210 ohm Conductivity (k) = cell constant x z 1 aot 23.1410 Som" Boonm 4x10" Sem = 0.66 xem" x kx1000 Molar conductivity (A,,, Sem? mol-! 3.1410? «1000 0.07 2. Answer (1) Due to presence of H* ion of highest conductivity, aqueous solution of HCI will have highest conductivity 3. Answer (1) A (AgCl) = AS, (AgNO,)+.A2(NaCl)— Ag(NaNO,) 16.5 + 110.3 105.2 = 121.6 S cm? mol 4. Answer (4) Oxidation and reduction are reference terms means if there is oxidation than only reduction is possible. 5. Answer (4) For, Fe? + Sn -> Fe + Sn? E° = -0.44— (0.14) =-0.44 + 0.14=-0.3V 6 Answer (3) 0 0.0591), | Sn? 1 Eee > o| S| With increase of [Ag*] or decrease of [Sn”*], E,,y will Increase. 7. Answer (4) = 314.28 S cm? mol" E 0.0591 1 0.0591, 4928 =1.33- tog) —1_ | -1.33- 1og(10?*) = 1.0542 V 6 “lar 6 atte”) ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Del 1110005 Ph. 011-47623456Solutions Electrochemistry 197 8, Answer (3) He E44 = 0.0591log [| | 107 Egy = 0.0591 10g 0.0591 x 5 = 0.2955 V 9. Answer (1) Aj (NH,OH) = 43 (NHC) +5435 [Ba(OH),]- Aj (BaCl,) = 130+ J (628 - 260) = 251.5 Sm? mot! = 251.5 Sm? mol 40. Answer (2) Et _ wy _ 83.5/2x0,965 «6060 96500 ‘96500 > Xx 0.2% 63.5 = 1.143 x=0.09L 11. Answer (3) Cell reaction: Cu2*(aq) + Zn(s) -> Cu(s) + Zn2*(aq) =1.1439 . Ean = Eo 2 SP Miog| 20 2 Cu** + When NH, is added to Cu2* compartment, Complex formation occur and Cu* J. 12. Answer (3) As Cu2* tor Zn? 1, Eogy Maximum amount of work (AG*) = -RFEGa, (+ E8y =0.4-(-0.87) = 0.4 +0.87 =1.27V) = AG? 2x96500x1-27 = — 245.11 kJ = -2.45 x 105 J 13. Answer (4) For hydrogen concentration cell, Ezy, = SPP ] RT ,[P: jorEan =e in EI 14. Answer (4) 2H,(g) + 40H- (aq) > 4H,0(0) + 4e-, Oxidation reaction Oxidation occur at anode 48. Answer (2) Af (MgCl) = Ap (Mg) +2A%, (Cr) = 100 + 2 x 75 = 100 + 150 = 250 = 250 S cm? mol? 16. Answer (3) During discharging of lead storage battery, Pb converts into PbSO, at anode. ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456198 Electrochemistry Solutions 7. 18, 19, 20. 24 22, 23. 24. 25. ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Del Answer (2) (Kear Ki,0) «1000 s (4.9 -3.1) «10% x1000 $ 28, (Agc!) = 14( 14x10 «1000 140 K,,(AgCl) =[Ag'] [Cr] = sxs ‘Answer (3) EAE ag ~ERyting 4 0-0591109 K,, (Ag) 10 40)? =10°% = 0.799 + 0.0591 (- 16.07) 0.150 V =-0.149V Answer (4) Metals of high positive reduction potential than copper, can oxide Cu into Cu?* ion (Blue colour ion) so unable to use in the formed of spoon. Answer (3) 1 2x «100 aq = £21000 _ "200-100 § cm? ea o.1 ‘Answer (2) Ngq(BaCl,) = A2,(Ba**) + AS,(CI) = 127 #73. = 200 S om? eqy Answer (1) For hydrogen concentration cell, E,.5 = 259 ig, For spontaneity; AG < 0 and for which E,., >-0 SoP,>P, Answer (3) E° =E2anode ~ESnode = 1-5 —(-0.25) = 1.75 V Answer (4) Overall reaction of electrolysis of acidified water. we oo 21,0) > 2H,(a) + O29) OF H,01) >H2(a)+40,(9) So, for 2F of electricity, 1.5 mol of gases are produced So, volume at STP = 1.5 « 22.4 = 33.6 L Answer (4) Metals lying above hydrogen in the electrochemical series are of negative SRP. Mg, Ni and Ti all are above hydrogen in electrachemical series, so all are of negative SRP. 1110005 Ph. 011-47623456Solutions Electrochemistry 199 26. 27. 28. 29. 30, 31 32. Answer (2) Specific conductance or conductivity (k), decrease on increase in dilution due to decrease no of ions in unit volume. Answer (4) Calomel electrode (E° = 0.244 V) can be used as reference electrode. Answer (4) E? = Beate 34-(-0.75)=1.1V ‘Answer (2) E = Exatode ~Eenode = -0-42 -(-0.72)=0.3 V Now E = Ee_0.0591),,_fanode] n [cathode] = 0.30 - 2.0594} 10-1. 6 (0.01 £=0.30— Mog 10 E=0.29V ‘Answer (4) Cu**(aq) + 2e" > Cu(s) 0 0.0591 1 E-E°- tog) “lar fe Koy =Lcu?"] lor T= mig lag [cu J=10-* E-E° 0,34~ 9.0591, 49 0.22 0.0591, ( Flea Answer (3) Electrolytic oxidation of acidified sulphate solutions at hydrolysis gives H,0,, current density gives S,03-, which on Cathode : 2H"(aq)+2e" - H,(g) Anode : 2480; (aq) -» H,S,O, + 2e7 Lh 2HSO; + 2H" +H,0; ‘Answer (4) 2 * Cell constant (a) = 1222 _ 9.362 em~ 45 om 1 250 * Conductivity (k 53x 103 S cmt = 0.382 em’ La an kx1000 153x107 x1000 Ma 005 = 30,58 = 30.58 S cm? eqy* ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456200) Electrochemistry 33, 34, 36. 36. 37. 38. 39, Solutions Answer (1) ‘AS (CH,COOH) = A3,(CH,CONa) + AS (HCI)— AS (NaCl) = Am 144 ae got 87 Answer (1) 0.0591, (4 B69 2007 g/t er a Intercept Siope =0.34 + Oo Nog 0 4 Cu(s) > Cu?*(aq)+2e (6.0591 a e-© CS) atou Intercept Slope = -0.34 0.0591, «9-(-0 34+ } ‘Answer (1) 9.0591), 91 + 426 — 126 = 391 S cm? mot If both electrodes (Cathode and anode) are made of same electrode then cell will be concentration cell Answer (3) “1 “ CH $o, -¥6CO,+3H,0 Mass CeHs 49 ___it x3x 60x60 qe *°°" 6500" 96500 Mass CsHs = 0.291 g Answer (2) Agq(BaCl,) = AS,(Ba”*)+ A34(CI") = 127 + 76 = 203 ohm om? eq? Answer (2) 9.0591 (P,) RT, (Py Esa tool 5) - ale] J Answer (4) Mol Cl, x2=—_ 36500 ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Deihi-110005 Ph. 011-47623456Solutions Electrochemistry 204 40. a 42. 43. 44, 48. 46. 56» _ix3x60x60 224"*~~ 96500 i=4.47=45A8 Answer (4) (i) Fe + 2e-— Fe; AG} = -2F(-0.44) (li) Fo?" + 30- Fo; AG? = -3F(-0.036) 0-0 Fe%* + e~ > Fe?*, AG? = AG} -AG? AG" =-3F (-0.036) + 2F(-0.44) Et =-3(0,036) +2 x0.44=0.72V Answer (4) ean ~Ky,0)% 1000 ag, ~ Kathu) $ «10% x 10x10" => 160 -(906=0.06)210° 10.10% K,,= 82 = 4 x 10-10 s=2% 10% Answer (1) Higher is the reduction potential of electrode, better is its oxidizing power. So, correct order of reducing power: B > C >A Answer (3) Primary cells (e.g. Dry cell or Leclanche cell) do not have rechargeable property. Answer (1) Na,SO, (aq) > 2Na" (aq) + SO%-(aq) Cathode : H,0(1) +6" » ZHa(a) + OH (aq) Anode: 100) -»40,6)+ 2H ag) 207 Answer (1) AS AM + nem » >) _ (0.059) E=(&)- } toga" Ku) & aan) Intercept Slope IFA" <1, slope will be positive IFAT > 4, slope will be negative Answer (4) ( Exay = 0.0891 log] 98 cll 9 Ag jz (21) 0.0591log{ 2-1 3 502) ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456202) Electrochemistry Solutions = 0.0591 log (5) = 0.0414 V 47. Answer (3) Cell reaction : Pb2*(aq) + Zn(s) -> Pb(s) + Zn?*(aq) 0.0591, - lo 2 | 202 Pe 0591 2.0591, 29 E-E° = (0.126 +0.763) 48. Answer (1) On increasing dilution or decrease in concentration, specific conductance decreases. 49. Answer (1) Due to smallest size of H’ ion, it has highest ionic conductance at infinite dilution. 50. Answer (3) Hg:Cle, Calomel electrode can be used as reference electrode. 51. Answer (4) (i) MnOz->Mn® ; E°= 1.54; aG=—5.F (1.51) (ii) MnO, —> Mn?" ; Ee = 1.23; AG3=—2F (1.23) (i - i) MnO; ->MnO,, AG = 2F(1.28)-5F(1.51) _ {5(1.51)-2(1.23)} 3 Ee 5.09 =208 -1.69v 3 52. Answer (4) Due to more reduction potential of Mn®“/Mn?* than Oz/H20, Mn* can oxidises HzO to O2. 53. Answer (4) ( (Fe) ty 2.25Migg( Foy 4 PHT 0.0591 Joa 10" a oad 0.0591 4 54, Answer (2) 0.0591, (Pay). cal =—g 09] 4 (Poy ds } 31.67 - 21.67 - log(10) =1.566 = 1.57 V E 0.0591 (1) = Fo loal 5 |= 0.0282 ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Deihi-110005 Ph. 011-47623456Solutions Electrochemistry 203 55. Answer (4) ‘AgNO, (aq) -> Ag’ (aq) +NO5(aq) Cathode : Ag’ (aq) +e” > Ag(s) Anode : H,0(1) » 40,19) + 2H"(aq) +267 Hence, resulting solution will be acidic. 56. Answer (4) Faraday’ required for depostion of 1g of Mg = x2 = 2 So, cost of electricity (per faraday) =60Rs & 7 2 Faraday's required for deposition of 10 g of Al = Bs 2 Cost required = 42.60 =66.67 Rs 57. Answer (2) Ho — O fuel cell generally contains platinum,electrodes, where after cell reaction, H2O is formed as product 58. Answer (3) Both molar and equivalent conductance increase with increase in dilution, while specific conductance decreases with increase of dilution. 59, Answer (2) CuSO, +Zn-> Cu+ZnSO, 2 0.0591, Eset = Eten -——5 log 21.40.0594, (2 } 10 = 1.1 + 0.0591 = 1.1591 V 60. Answer (1) log5 = 0.0206 V = 0.021V 61. Answer (2) Ee ag tg = Edy ing *0-0591 log K,p(Agl) = 0.8 - 0.0591 pKep (Agl) 8 - 0.0591 x 16 =— 0.1456 V ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456204) Electrochemistry Solutions 62. 63. 64, 65. 66. er. 68. 69. 70. m1. ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Del Answer (2) Specific conductance (k) = Bla wis 002s Set 50 “0.0004 Answer (4) AS, (NaBr) = AS, (NaCl) + A2,(KBr)— A2,(KCI) 26.5 + 151.5 — 150 = 128 AZ,(Na') + A(BF°) =128 AS,(Na* ) = 128 — AS,(Br") = 128 -78 = 50 S cm? equ Answer (4) a oa * Miacor = ‘Answer (2) E° of oxidation and reduction of same electrode are equal but they are of opposite sign and itis an intensive property Answer (3) Boon = Eeatnode ~ Esnode 0.34-(-2.37)=2.71V Answer (3) NO; (E® = 0.96 V) cannot oxidise Au into Aus Answer (4) Zn?*(aq) + Mg(s) -» Zn(s)+Mg*-(aq), AG-<0 Hence, when Zn is added to solution of MgCl, no reaction takes place. ‘Answer (3) Ene? -0.0591),,{ [OH ) 4 ({Teos]) = -0.57 — 2-959 119g (10-12) = -0.57 + 0.0591 x 3 = -0.3927 V Answer (1) AG <0, means cell reaction should be spontaneous. For given cell, AG < 0 will be possible when C2 > Cr. Answer (3) For equilibrium, AG = 0 or E = 0 and Q=K So from Nerst equation E° = E° ~ reg Q o RT, e° = TTiogk 1110005 Ph. 011-47623456Solutions Electrochemistry 205 72. 73. 74, 75. 76. Answer (3) ‘AZ4(CHjCOOH) = AS, (CH;COONa) + AS, (HCI) — A2, (NaCl) = 90 + 425 - 125 = 390 S om? equ" Answer (3) ixt MolCu)xn, =—et_ OK Cu) = S600 Let molarity of aq, solution of CuSOs is M then Mx05%2=05 m= 4s05m 2 Answer (2) CuSO, (aq) + Zn -» Cu + ZnSO, (aq) 0 0.0594), | Zn? Eco ~ 2258 oF 0. a 2 =1A- om | When Zn?* decrease or Cu increase, Eo increase, On addition of conc. NHs in ZnSOx solution container, due to complex formation, Zn®* decrease and Exan increase. Answer (1) AG? =-nFE® 4. 96500 * E° So potential difference is 2.5 V ‘Answer (3) 0.0591, [ Zn® | = Boy log] 9 Z ! 0.0591), 0. ta tv =44- log) 55 ‘Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456