Chemistry A Molecular Approach Canadian 1st Edition Tro Test Bank

Chemistry A Molecular Approach
Canadian 1st Edition Tro Test Bank

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Chemistry: A Molecular Approach, 1ce
Chapter 10: Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and Molecular Orbital Theory
Chapter 10 Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and
Molecular Orbital Theory
Multiple Choice Questions
1) Give the approximate bond angle for a molecule with a trigonal planar shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
2) Give the approximate bond angle for a molecule with a tetrahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: A
3) Give the approximate bond angle for a molecule with a linear shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: B
4) Give the approximate bond angle for a molecule with an octahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
Copyright © 2014 Pearson Canada Inc. 10-1

5) Give the approximate bond angle between the axial position and the equatorial position for a molecule
with a trigonal bipyramidal geometry.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
6) Give the approximate bond angle between two equatorial positions for a molecule with a trigonal
bipyramidal geometry.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: C
7) Determine the electron geometry (eg) and molecular geometry (mg) of BCl3.
A) eg = trigonal planar, mg = trigonal planar
B) eg = tetrahedral, mg = trigonal planar
C) eg = tetrahedral, mg = trigonal pyramidal
D) eg = trigonal planar, mg = bent
E) eg = trigonal bipyramidal, mg = trigonal bipyramidal
Answer: A
8) Determine the electron geometry (eg) and molecular geometry (mg) of CO32⁻.
A) eg = tetrahedral, mg = tetrahedral
B) eg = tetrahedral, mg = trigonal pyramidal
C) eg = trigonal planar, mg = bent
D) eg = trigonal planar, mg = trigonal planar
E) eg = tetrahedral, mg = trigonal planar
Answer: D
9) Determine the electron geometry (eg) and molecular geometry (mg) of CH3+1.
D) eg = trigonal planar, mg = trigonal planar
E) eg = tetrahedral, mg = trigonal planar
Answer: D

10) Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.
A) eg = tetrahedral, mg = trigonal pyramidal
B) eg = octahedral, mg = square planar
C) eg = trigonal bipyramidal, mg = trigonal pyramidal
D) eg = tetrahedral, mg = bent
E) eg = tetrahedral, mg = tetrahedral
Answer: E
11) Determine the electron geometry (eg) and molecular geometry (mg) of PF5.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal
B) eg = octahedral, mg = octahedral
C) eg = trigonal bipyramidal, mg = tetrahedral
D) eg = tetrahedral, mg = trigonal pyramidal
E) eg = trigonal planar, mg = octahedral
Answer: A
12) Determine the electron geometry (eg) and molecular geometry (mg) of CO2.
B) eg = linear, mg = trigonal planar
D) eg = linear, mg = linear
E) eg = trigonal planar, mg = trigonal planar
Answer: D
13) Determine the electron geometry (eg) and molecular geometry (mg) of NCl3.
E) eg = tetrahedral, mg = trigonal pyramidal
Answer: E
14) Give the approximate bond angle for a molecule with trigonal planar electron geometry and bent
molecular geometry.
A) <90°
B) 90°
C) <120°
D) <109.5°
E) 120°
Answer: C

15) Give the approximate bond angle for a molecule with tetrahedral electron geometry and trigonal
pyramidal molecular geometry.
A) 180°
B) <180°
C) <109.5°
D) 109.5°
E) <120°
Answer: C
16) Give the approximate bond angle for a molecule with tetrahedral electron geometry and bent
molecular geometry.
A) 180°
B) <180°
C) <109.5°
D) 109.5°
E) <120°
Answer: C
17) Give the approximate bond angle for a molecule with trigonal bipyramidal electron geometry and
seesaw molecular geometry.
A) <120° (equatorial), 90° (axial)
B) 120° (equatorial), <90° (axial)
C) <90° (equatorial), <90° (axial)
D) 120° (equatorial), 90° (axial)
E) <120° (equatorial), <90° (axial)
Answer: E
18) Give the approximate bond angle for a molecule with T-shape molecular geometry.
A) <90°
B) 90°
C) >90°
D) <120°
E) 120°
Answer: A
19) Give the approximate bond angle for a molecule with trigonal bipyramidal electron geometry and
linear molecular geometry.
A) 180°
B) <180°
C) >180°
D) <109.5°
E) <120°
Answer: A
20) Give the approximate bond angle for a molecule with octahedral electron geometry and square

pyramidal molecular geometry.

A) 90°
B) 180°
C) >120°
D) <90°
E) >90°
Answer: D
21) Give the approximate bond angle for a molecule with octahedral electron geometry and square planar
molecular geometry.
A) 90°
B) 180°
C) >120°
D) <90°
E) <120°
Answer: A
22) Determine the electron geometry (eg) and molecular geometry (mg) of BrF3.
A) eg = trigonal planar, mg = trigonal planar
B) eg = trigonal bipyramidal, mg = T-shape
D) eg = trigonal bipyramidal, mg = seesaw
E) eg = tetrahedral, mg = trigonal pyramidal
Answer: B
23) Determine the electron geometry for the molecule PF3.

A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal bipyramidal
E) Octahedral
Answer: C
24) Determine the molecular geometry for the molecule PF3.

A) Trigonal pyramidal
B) Trigonal planar
C) Tetrahedral
D) T-shaped
E) Bent
Answer: A

25) Determine the electron geometry for the molecule SBr2.

A) Linear
B) Trigonal planar
C) Tetrahedral
E) Octahedral
Answer: C
26) Determine the molecular geometry for the molecule SBr2.

A) Trigonal pyramidal
B) Trigonal planar
C) Tetrahedral
D) T-shaped
E) Bent
Answer: E
27) Determine the electron geometry for the molecule CS2.

A) Linear
B) Trigonal planar
C) Tetrahedral
E) Octahedral
Answer: A
28) Determine the molecular geometry for the molecule CS2.

A) Trigonal planar
B) Bent
C) Linear
D) T-shaped
E) Square planar
Answer: C
29) Determine the electron geometry for the molecule PCl5.

A) Linear
B) Trigonal planar
C) Tetrahedral
E) Octahedral
Answer: D

30) Determine the molecular geometry for the molecule PCl5.

A) Linear
B) Seesaw
C) Square pyramidal
E) Square planar
Answer: D
31) Determine the electron geometry for the molecule BrF3.

A) Linear
B) Trigonal planar
C) Tetrahedral
E) Octahedral
Answer: D
32) Determine the molecular geometry for the molecule BrF3.

A) Square pyramidal
B) Seesaw
C) T-shaped
D) Square planar
E) Trigonal planar
Answer: C
33) Determine the electron geometry for the molecule XeF4.

A) Linear
B) Trigonal planar
C) Tetrahedral
E) Octahedral
Answer: E
34) Determine the molecular geometry for the molecule XeF4.

A) Square planar
B) Tetrahedral
C) T-shaped
D) Square pyramidal
E) Trigonal planar
Answer: A

35) Determine the electron geometry (eg) and molecular geometry (mg) of ICl2⁻.
A) eg = tetrahedral, mg = bent
C) eg = trigonal bipyramidal, mg = linear
D) eg = trigonal bipyramidal, mg = trigonal planar
E) eg = octahedral, mg = linear
Answer: C
36) Determine the electron geometry (eg) and molecular geometry (mg) of XeF2.
A) eg = trigonal bipyramidal, mg = bent
B) eg = linear, mg = linear
C) eg = tetrahedral, mg = linear
D) eg = trigonal bipyramidal, mg = linear
E) eg = tetrahedral, mg = bent
Answer: D
37) Determine the electron geometry (eg) and molecular geometry (mg) of XeF4.
C) eg = tetrahedral, mg = bent
D) eg = trigonal bipyramidal, mg = tetrahedral
E) eg = octahedral, mg = square planar
Answer: E
38) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
Answer: A
39) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
Answer: C

40) Consider the molecule below. Determine the molecular geometry at each of the two labelled carbons.
A) C1 = tetrahedral, C2 = linear
B) C1 = trigonal planar, C2 = bent
C) C1 = bent, C2 = trigonal planar
D) C1 = trigonal planar, C2 = tetrahedral
E) C1 = trigonal pyramidal, C2 = seesaw
Answer: D
41) Consider the molecule below. Determine the molecular geometry at each of the three labelled atoms.
A) 1 = trigonal planar, 2 = tetrahedral, 3 = trigonal pyramidal

B) 1 = tetrahedral, 2 = tetrahedral, 3 = tetrahedral
C) 1 = trigonal planar, 2 = tetrahedral, 3 = tetrahedral
D) 1 = tetrahedral, 2 = tetrahedral, 3 = trigonal planar
E) 1 = trigonal planar, 2 = trigonal pyramidal, 3 = trigonal pyramidal
Answer: A
42) Place the following in order of increasing X-Se-X bond angle, where X represents the outer atoms in
each molecule.
SeO2 SeCl6 SeF2
A) SeCl6 < SeF2 < SeO2

B) SeF2 < SeO2 < SeCl6
C) SeF2 < SeCl6 < SeO2
D) SeO2 < SeF2 < SeCl6
E) SeCl6 < SeO2 < SeF2
Answer: A

43) Place the following in order of increasing F-A-F bond angle, where A represents the central atom in
each molecule.
PF3 OF2 PF4⁺
A) PF3 < OF2 < PF4⁺

B) OF2 < PF3 < PF4⁺
C) OF2 < PF4⁺ < PF3
D) PF4⁺ < OF2 < PF3
E) PF4⁺ < PF3 < OF2
Answer: B
44) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom and
X represents the outer atoms in each molecule.
N2O NCl3 NO2⁻
A) NCl3 > NO2⁻ > N2O

B) NO2⁻ > N2O > NCl3
C) N2O > NO2⁻ > NCl3
D) NCl3 > N2O > NO2⁻
E) N2O > NCl3 > NO2⁻
Answer: C
45) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom and
CS2 CF4 SCl2
A) CS2 > SCl2 > CF4

B) SCl2 > CF4 > CS2
C) CF4 > SCl2 > CS2
D) CS2 > CF4 > SCl2
E) CF4 > CS2 > SCl2
Answer: D

46) Place the following in order of increasing X-A-X bond angle, where A represents the central atom and
HCN H2O H3O⁺
A) H3O+ < HCN < H2O

B) H3O⁺ < H2O < HCN
C) HCN < H3O⁺ < H2O
D) H2O < HCN < H3O⁺
E) H2O < H3O⁺ < HCN
Answer: E
47) A pilot checks for water in the gas before flying a small airplane. How does she do it?
A) She drains a little bit of gas from the bottom and looks for two layers.
B) She smells it.
C) She shakes the wings.
D) She pipets the liquid from the top of the tank and looks for two layers.
E) She checks the gas gauge.
Answer: A
48) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO3.
A) eg = tetrahedral, mg = trigonal pyramidal, polar
B) eg = tetrahedral, mg = tetrahedral, nonpolar
C) eg = trigonal planar, mg = trigonal planar, nonpolar
D) eg = trigonal bipyramidal, mg = trigonal planar, polar
E) eg = trigonal pyramidal, mg = bent, nonpolar
Answer: C
49) How many of the following molecules are polar?
BrCl3 CS2 SiF4 SO3
A) 1
B) 2
C) 3
D) 4
E) 0
Answer: A

XeCl2 COF2 PCl4F SF6
A) 0
B) 3
C) 1
D) 2
E) 4
Answer: B
XeO2 SiCl2Br2 C2Br2 SeCl6
A) 1
B) 4
C) 2
D) 3
E) 0
Answer: C
PCl5 COS XeO3 SeBr2
A) 2
B) 0
C) 1
D) 3
E) 4
Answer: D
53) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2.
A) eg = tetrahedral, mg = bent, polar
B) eg = trigonal planar, mg = bent, polar
C) eg = linear, mg = linear, nonpolar
D) eg = tetrahedral, mg = tetrahedral, nonpolar
E) eg = trigonal pyramidal, mg = trigonal pyramidal, polar
Answer: B

54) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SF6.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
B) eg = tetrahedral, mg = tetrahedral, polar
C) eg = trigonal bipyramidal, mg = seesaw, polar
D) eg = octahedral, mg = trigonal bipyramidal, nonpolar
E) eg = octahedral, mg = octahedral, nonpolar
Answer: E
55) Determine the electron geometry (eg), molecular geometry (mg), and polarity of TeCl6.
A) eg = octahedral, mg = octahedral, nonpolar
B) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
C) eg = octahedral, mg = square planar, polar
D) eg = trigonal bipyramidal, mg = seesaw, polar
E) eg = tetrahedral, mg = trigonal pyramidal, polar
Answer: A
56) Determine the electron geometry (eg), molecular geometry (mg), and polarity of XeO3.
A) eg = trigonal planar, mg = trigonal planar, nonpolar
B) eg = tetrahedral, mg = trigonal pyramidal, polar
C) eg = trigonal planar, mg = trigonal pyramidal, polar
D) eg = trigonal bipyramidal, mg = trigonal planar, nonpolar
E) eg = octahedral, mg = tetrahedral, nonpolar
Answer: B
57) Determine the electron geometry (eg), molecular geometry (mg), and polarity of HBrO2.
A) eg = trigonal bipyramidal, mg = trigonal planar, nonpolar
B) eg = octahedral, mg = square planar, nonpolar
C) eg = tetrahedral, mg = bent, polar
D) eg = tetrahedral, mg = linear, nonpolar
E) eg = linear, mg = linear, polar
Answer: C
58) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SF6.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
B) eg = tetrahedral, mg = tetrahedral, polar
C) eg = trigonal bipyramidal, mg = seesaw, polar
D) eg = octahedral, mg = trigonal bipyramidal, nonpolar
E) eg = octahedral, mg = octahedral, nonpolar
Answer: E

59) Choose the compound below that contains at least one polar covalent bond but is nonpolar.
A) HCN
B) CF4
C) SeBr4
D) ICl3
E) Both B and C are nonpolar and contain a polar covalent bond.
Answer: B
60) Choose the compound below that contains at least one polar covalent bond but is nonpolar.
A) GeH2Br2
B) SCl2
C) AsCl5
D) CF2Cl2
E) All of the above are nonpolar and contain a polar covalent bond.
Answer: C
61) Place the following in order of increasing dipole moment.
I. BCl3 II. BIF2 III. BClF2
A) I < II = III
B) II < III < I
C) I < II < III
D) II < I < III
E) I < III < II
Answer: E
62) Place the following in order of decreasing dipole moment.
I. cis-CHCl=CHCl II. trans-CHCl=CHCI III. cis-CHF=CHF
A) III > I > II

B) II > I > III
C) I > III > II
D) II > III > I
E) I = III > II
Answer: A

63) Determine the electron geometry (eg), molecular geometry (mg), and polarity of N2O (N central).
A) eg = linear, mg = linear, nonpolar
B) eg = tetrahedral, mg = linear, nonpolar
C) eg = tetrahedral, mg = bent, polar
D) eg = linear, mg = linear, polar
E) eg = trigonal planar, mg = bent, polar
Answer: D
64) Describe a pi bond.

A) side by side overlap of p orbitals
B) end to end overlap of p orbitals
C) s orbital overlapping with the end of a p orbital
D) overlap of two s orbitals
E) p orbital overlapping with a d orbital
Answer: A
65) Describe a sigma bond.

A) side by side overlap of p orbitals
B) end to end overlap of p orbitals
C) side by side overlap of d orbitals
D) overlap of two s orbitals
E) p orbital overlapping with a d orbital
Answer: B
66) A molecule containing a central atom with sp hybridization has a ________ electron geometry.
A) linear
B) trigonal bipyramidal
C) trigonal planar
D) tetrahedral
E) bent
Answer: A
67) Identify the number of electron groups around a molecule with sp hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: B

68) A molecule containing a central atom with sp2 hybridization has a ________ electron geometry.
A) linear
C) trigonal planar
D) tetrahedral
E) bent
Answer: C
69) Identify the number of electron groups around a molecule with sp2 hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: C
70) A molecule containing a central atom with sp3 hybridization has a(n) ________ electron geometry.
A) linear
C) octahedral
D) tetrahedral
E) bent
Answer: D
71) Identify the number of electron groups around a molecule with a tetrahedral shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: D
72) A molecule containing a central atom with sp3d hybridization has a(n) ________ electron geometry.
A) tetrahedral
B) linear
C) octahedral
D) trigonal planar
E) trigonal bipyramidal
Answer: E

73) Identify the number of electron groups around a molecule with a trigonal bipyramidal shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: E
74) A molecule containing a central atom with eight electron groups has a(n) ________ electron geometry.
A) octahedral
C) tetrahedral
D) trigonal planar
E) trigonal pyramidal
Answer: A
75) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3CN.
Answer: D
76) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3CN.
Answer: A
77) Determine the electron geometry (eg) and molecular geometry (mg) of H2CO.
Answer: E

78) Draw the Lewis structure for OF2. What is the hybridization on the O atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
79) Draw the Lewis structure for H3O+. What is the hybridization on the O atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
80) Draw the Lewis structure for SO3. What is the hybridization on the S atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: C
81) Draw the Lewis structure for BrO4⁻. What is the hybridization on the Br atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
82) Draw the Lewis structure for CCl4. What is the hybridization on the C atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
83) Draw the Lewis structure for CO2. What is the hybridization on the C atom?

A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: A
84) Draw the Lewis structure for BF3. What is the hybridization on the B atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
85) Draw the Lewis structure for COCl2. What is the hybridization on the C atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
86) Draw the Lewis structure for SO2-3. What is the hybridization on the S atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
87) Draw the Lewis structure for N2H2. What is the hybridization on the N atoms?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
88) Draw the Lewis structure for C2H2. What is the hybridization on the C atoms?
A) sp

B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: A
89) Consider the molecule below. Determine the hybridization at each of the two labelled carbons.
A) C1 = sp3, C2 = sp3d
B) C1 = sp, C2 = sp2
C) C1 = sp2, C2 = sp3d
D) C1 = sp3d, C2 = sp3d2
E) C1 = sp2, C2 = sp3
Answer: E
90) Consider the molecule below. Determine the hybridization at each of the three labelled atoms.
A) 1 = sp2, 2 = sp3, 3 = sp2

B) 1 = sp2, 2 = sp3, 3 = sp3
C) 1 = sp3, 2 = sp3, 3 = sp3
D) 1 = sp3, 2 = sp3, 3 = sp2
E) 1 = sp, 2 = sp2, 3 = sp2
Answer: B

91) How many of the following molecules have sp hybridization on the central atom?
C2Cl2 CO2 O3 H2O
A) 0
B) 1
C) 2
D) 3
E) 4
Answer: C
92) How many of the following molecules have sp3 hybridization on the central atom?
XeCl4 CH4 SF4 C2H2
A) 0
B) 4
C) 3
D) 2
E) 1
Answer: E
93) How many of the following molecules have sp3d hybridization on the central atom?
SiCl4 BrF5 AsF5 BrF3
A) 2
B) 0
C) 4
D) 1
E) 3
Answer: A
94) How many of the following molecules have sp3d2 hybridization on the central atom?
SeCl6 XeF4 IF5 AsCl5
A) 1
B) 3
C) 0
D) 2
E) 4
Answer: B
95) How many of the following molecules have sp2 hybridization on the central atom?
HCN SO2 OCl2 XeCl2
A) 4
B) 3
C) 2
D) 1
E) 0
Answer: D
96) Give the electron geometry (eg), molecular geometry (mg), and hybridization for CH3-.
A) eg = tetrahedral; mg = trigonal pyramidal; sp3
B) eg = tetrahedral; mg = tetrahedral; sp3
C) eg = trigonal pyramidal; mg = trigonal pyramidal; sp3
D) eg = trigonal planar; mg = trigonal planar; sp2
Answer: A
97) List the number of sigma bonds and pi bonds in a single bond.
A) 1 sigma, 0 pi
B) 0 sigma, 1 pi
C) 1 sigma, 1 pi
D) 1 sigma, 2 pi
Answer: A
98) List the number of sigma bonds and pi bonds in a double bond.
A) 1 sigma, 1 pi
B) 2 sigma, 1 pi
C) 2 sigma, 2 pi
D) 1 sigma, 2 pi
Answer: A
99) List the number of sigma bonds and pi bonds in a triple bond.
A) 1 sigma, 1 pi
B) 2 sigma, 1 pi
C) 2 sigma, 2 pi
D) 1 sigma, 2 pi
Answer: D

100) Draw the Lewis structure for the molecule CH2CHCH3. How many sigma and pi bonds does it
contain?
A) 8 sigma, 1 pi
B) 9 sigma, 0 pi
C) 9 sigma, 1 pi
D) 7 sigma, 2 pi
E) 8 sigma, 2 pi
Answer: A
101) Draw the Lewis structure for the molecule CH3CH2CCH. How many sigma and pi bonds does it
contain?
A) 11 sigma, 0 pi
B) 9 sigma, 1 pi
C) 8 sigma, 3 pi
D) 9 sigma, 2 pi
E) 8 sigma, 2 pi
Answer: D
102) Consider the following compound. How many sigma and pi bonds does it contain?
CH3CHCHCO2H
A) 9 sigma, 4 pi
B) 11 sigma, 2 pi
C) 9 sigma, 2 pi
D) 13 sigma, 0 pi
E) 6 sigma, 2 pi
Answer: B
103) Draw the Lewis structure for the molecule C3H4. How many sigma and pi bonds does it contain?
A) 7 sigma, 1 pi
B) 8 sigma, 0 pi
C) 6 sigma, 2 pi
D) 10 sigma, 0 pi
E) 8 sigma, 2 pi
Answer: C

104) How many of the following molecules contain at least one pi bond?
C2H6 Cl2CO C2Cl4 SeS3
A) 0
B) 1
C) 3
D) 4
E) 2
Answer: C
105) Which of the following statements is TRUE?

A) The total number of molecular orbitals formed doesn't always equal the number of atomic orbitals in
the set.
B) A bond order of 0 represents a stable chemical bond.
C) When two atomic orbitals come together to form two molecular orbitals, one molecular orbital will be
lower in energy than the two separate atomic orbitals and one molecular orbital will be higher in energy
than the separate atomic orbitals.
D) Electrons placed in antibonding orbitals stabilize the ion/molecule.
E) All of the above are true.
Answer: C

106) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D

107) Use the molecular orbital diagram shown to determine which of the following is least stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F21⁻
Answer: E

108) Use the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above is paramagnetic.
Answer: D

109) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D

110) Use the molecular orbital diagram shown to determine which of the following is least stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B21⁺
Answer: E

111) Use the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
112) Draw a molecular orbital diagram and use it to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D

A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D
114) A molecule or ion with four electrons in bonding orbitals and two electrons in an antibonding orbital
has a bond order of:
A) 1
B) 1.5
C) 2
D) 2.5
E) 3
Answer: A
115) A molecule or ion with five electrons in bonding orbitals and two electrons in an antibonding orbital
has a bond order of:
A) 0.5
B) 1
C) 1.5
D) 2
E) 3
Answer: C
116) A molecule or ion with seven electrons in bonding orbitals and two electrons in an antibonding
orbital has a bond order of:
A) 0.5
B) 1
C) 1.5
D) 2
E) 2.5
Answer: E
117) A molecule or ion with eight electrons in bonding orbitals and two electrons in an antibonding
A) 1
B) 1.5
C) 2
D) 2.5
E) 3
Answer: E

118) A molecule or ion with three electrons in bonding orbitals and two electrons in an antibonding
A) 0.5
B) 1
C) 1.5
D) 2
E) 3
Answer: A
119) A molecule or ion with two electrons in a bonding orbital and two electrons in an antibonding
orbital would have a bond order of:
A) 0
B) 1
C) 1.5
D) 0.5
E) -1
Answer: A
120) Draw a molecular orbital diagram and use it to determine which of the following is paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above is paramagnetic.
Answer: D
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D

122) Draw a molecular orbital diagram and use it to determine which of the following is paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
123) In molecular orbital theory the acronym HOMO stands for

A) homogenous orbital-molecular orientation.
B) highly ordered molecular orbital.
C) highest occupied molecular orbital.
D) highest orbital-molecular orientation.
E) It has no meaning.
Answer: C
124) In molecular orbital theory the acronym LUMO stands for

A) lowest unhybridized molecular orientation.
B) lowest unoccupied molecular orbital.
C) lowest unhybridized molecular orbital.
D) linear-uninteresting molecular orientation.
Answer: B
125) In molecular orbital theory the acronym LCAO stands for

A) linear combination of atomic orbitals.
B) lowest combined atomic orbitals.
C) least consumed advanced orientation.
D) linearly created available orbital.
Answer: A
126) Draw the Lewis structure for SF6. What is the hybridization on the S atom?
A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: Content removed

127) Draw the Lewis structure for BrF5. What is the hybridization on the Br atom?
A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: A
128) Draw the Lewis structure for BrCl3. What is the hybridization on the Br atom?
A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: B
Algorithmic Questions
1) What geometric arrangement of charge clouds is expected for an atom that has four charge clouds?
A) trigonal bipyramidal
B) octahedral
C) tetrahedral
D) square planar
Answer: C
2) What is the molecular geometry of ClF4 -?

A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral
Answer: B
3) What is the molecular geometry of NCl3?

A) T-shaped
B) tetrahedral
C) trigonal planar
D) trigonal pyramidal
Answer: D

4) What is the molecular geometry of SF5-?

A) octahedral
B) seesaw
C) square pyramidal
D) trigonal bipyramidal
Answer: C
5) Which of the following best describes ClF2-? It has a molecular geometry that is
A) linear with no lone pairs on the Cl atom.
B) linear with lone pairs on the Cl atom.
C) nonlinear with no lone pairs on the Cl atom.
D) nonlinear with lone pairs on the Cl atom.
Answer: B
6) What is the molecular geometry of TeCl4?

A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral
Answer: A
7) Using the VSEPR model, the electron-domain geometry of the central atom in BrF4- is ________.
A) linear
B) trigonal planar
C) tetrahedral
E) octahedral
Answer: E
8) Using the VSEPR model, the molecular geometry of the central atom in XeF2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: A

9) Using the VSEPR model, the molecular geometry of the central atom in BF3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: B
10) Using the VSEPR model, the molecular geometry of the central atom in CF4 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: C
11) Using the VSEPR model, the molecular geometry of the central atom in SO2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: D
12) Using the VSEPR model, the molecular geometry of the central atom in NCl3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: E
13) Using the VSEPR model, the molecular geometry of the central atom in XeF4 is ________.
A) tetrahedral
B) seesaw
C) square planar
E) square pyramidal
Answer: C

14) Using the VSEPR model, the electron-domain geometry of the central atom in BF3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
E) octahedral
Answer: B
15) Using the VSEPR model, the electron-domain geometry of the central atom in SF2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
E) octahedral
Answer: C
16) Using the VSEPR model, the electron-domain geometry of the central atom in SF4 is ________.
A) linear
B) trigonal planar
C) tetrahedral
E) octahedral
Answer: D
17) What is the O-B-O bond angle in BO33-?

A) less than 109.5°
B) 109.5°
C) 120°
D) greater than 120°
Answer: C
18) What are the F-Po-F bond angles in PoF6?

A) 60°
B) 90°
C) 109.5°
D) 120°
Answer: B

19) The VSEPR model predicts the H—O—H bond angle in H3O+ to be
A) 60°.
B) 90°.
C) less than 109.5° but greater than 90°.
D) 109.5°.
Answer: C
20) The orbital hybridization on the carbon atoms in C2H2 is ________.

A) sp
B) sp2
C) sp3
D) sp3d2
Answer: A
21) The hybrid orbital set used by the central atom in NO3- is ________.
A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2
Answer: B
22) The hybrid orbital set used by the central atom in NCl3 is ________.
A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2
Answer: C
23) The hybrid orbital set used by the central atom in KrF2 is ________.
A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2
Answer: D

Matching Questions
Match the following.
A) tetrahedral
B) nonpolar, but contains a polar covalent bond
C) sp hybridized central atom
E) trigonal planar
F) polar
G) linear
H) seesaw molecular geometry
I) octahedral
J) octahedral electron geometry
K) polar, but contains no polar bonds
L) sp2 hybridized central atom
1) SF4
Diff: 3 Type: MA Var: 1 Page Ref: 10.4
2)XeCl4
3) CH2F2
4) BCl3
5) sp
6) sp2
7) sp3
8) sp3d
9) sp3d2
10) BeF2
Answers: 1) H 2) J 3) F 4) B 5) G 6) E 7) A 8) D 9) I 10) C

Short Answer Questions
1) Is it possible for a molecule to be nonpolar even though it contains polar bonds? Explain your answer
and give an example.
Answer: Yes. The polarity of a molecule depends on the molecular geometry and whether or not all of
the dipoles (polar bonds) cancel one another. If the molecular geometry causes all of the dipoles to cancel,
the molecule will be nonpolar. An example is CF4, where there are four polar bonds but the dipoles sum
to 0, making the molecule nonpolar.
Diff: 1 Type: SA Var: 1 Page Ref: 10.5
2) Explain why oil and water do not mix.

Answer: Water molecules are polar and oil molecules are nonpolar.
3) Determine the molecular geometry about each interior atom in the following structure. Sketch the
three-dimensional structure and label the interior atoms with the corresponding molecular geometry.
CH2CHCCCH3
Answer: The sketch should show all of the appropriate multiple bonds, with a double bond between
carbons 1 and 2 and a triple bond between carbons 3 and 4. The first two carbons are trigonal planar, the
second carbons are linear, and the last carbon is tetrahedral.
4) Give the electron geometry, molecular geometry, and hybridization for both carbons in CH3COOH.
Answer: eg = tetrahedral; mg = tetrahedral; sp3 and eg = trigonal planar; mg = trigonal planar; sp2
5) Determine the hybridization about each interior atom in the following structure. Sketch the three-
dimensional structure and label the interior atoms with their corresponding hybridization.
CH2CHCCCH3
Answer: The sketch should show all of the appropriate multiple bonds, with a double bond between
carbons 1 and 2 and a triple bond between carbons 3 and 4. The first two Cs are sp2 hybridized, the next 2
Cs are sp hybridized , and the last C is sp3 hybridized.
6) According to molecular orbital theory, what is an antibonding orbital?

Answer: An antibonding orbital is formed when two orbitals destructively interfere with one another.
An antibonding orbital is usually higher in energy than the two separated atoms and has a node in the
internuclear region.

7) Use molecular orbital theory to determine whether He22⁺ or He2⁺ is more stable. Draw the molecular
orbital diagram for each and explain your answer.
Answer: The molecular orbital diagram should show He22⁺ with two electrons in the bonding orbital
and the molecular orbital diagram of He2⁺ should show two electrons in the bonding molecular orbital
and one electron in the antibonding molecular orbital. The He22⁺ ion is more stable since it has a higher
bond order (bond order =1) than He2⁺ (bond order = 1/2).

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Multiple Choice Questions

Copyright © 2014 Pearson Canada Inc. 10-1

Copyright © 2014 Pearson Canada Inc. 10-2

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Copyright © 2014 Pearson Canada Inc. 10-4

pyramidal molecular geometry.

23) Determine the electron geometry for the molecule PF3.

24) Determine the molecular geometry for the molecule PF3.

Copyright © 2014 Pearson Canada Inc. 10-5

25) Determine the electron geometry for the molecule SBr2.

26) Determine the molecular geometry for the molecule SBr2.

27) Determine the electron geometry for the molecule CS2.

28) Determine the molecular geometry for the molecule CS2.

29) Determine the electron geometry for the molecule PCl5.

Copyright © 2014 Pearson Canada Inc. 10-6

30) Determine the molecular geometry for the molecule PCl5.

31) Determine the electron geometry for the molecule BrF3.

32) Determine the molecular geometry for the molecule BrF3.

33) Determine the electron geometry for the molecule XeF4.

34) Determine the molecular geometry for the molecule XeF4.

Copyright © 2014 Pearson Canada Inc. 10-7

Copyright © 2014 Pearson Canada Inc. 10-8

A) 1 = trigonal planar, 2 = tetrahedral, 3 = trigonal pyramidal

SeO2 SeCl6 SeF2

A) SeCl6 < SeF2 < SeO2

Copyright © 2014 Pearson Canada Inc. 10-9

PF3 OF2 PF4⁺

A) PF3 < OF2 < PF4⁺

N2O NCl3 NO2⁻

A) NCl3 > NO2⁻ > N2O

CS2 CF4 SCl2

A) CS2 > SCl2 > CF4

Copyright © 2014 Pearson Canada Inc. 10-10

HCN H2O H3O⁺

A) H3O+ < HCN < H2O

49) How many of the following molecules are polar?

BrCl3 CS2 SiF4 SO3

Copyright © 2014 Pearson Canada Inc. 10-11

50) How many of the following molecules are polar?

XeCl2 COF2 PCl4F SF6

51) How many of the following molecules are polar?

XeO2 SiCl2Br2 C2Br2 SeCl6

52) How many of the following molecules are polar?

PCl5 COS XeO3 SeBr2

Copyright © 2014 Pearson Canada Inc. 10-12

Copyright © 2014 Pearson Canada Inc. 10-13

61) Place the following in order of increasing dipole moment.

I. BCl3 II. BIF2 III. BClF2

62) Place the following in order of decreasing dipole moment.

I. cis-CHCl=CHCl II. trans-CHCl=CHCI III. cis-CHF=CHF

A) III > I > II

Copyright © 2014 Pearson Canada Inc. 10-14

64) Describe a pi bond.

65) Describe a sigma bond.

Copyright © 2014 Pearson Canada Inc. 10-15

Copyright © 2014 Pearson Canada Inc. 10-16

Copyright © 2014 Pearson Canada Inc. 10-17

Copyright © 2014 Pearson Canada Inc. 10-18

Copyright © 2014 Pearson Canada Inc. 10-19

A) 1 = sp2, 2 = sp3, 3 = sp2

Copyright © 2014 Pearson Canada Inc. 10-20