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a. Properties of Fluids
2 3
(Wet region)
Latent heat of fusion: Heat required for change of phase at a constant temperature
accompanied by a reduction of specific volume.
Latent enthalpy of fusion: Since pressure is constant, heat transfer is equal to the change
of enthalpy.
Sensible enthalpy: This is enthalpy change of a substance while its temperature changes.
Latent heat of vaporization: This is the heat required to turn the liquid to vapor at a
constant temperature.
Latent enthalpy of vaporization: This is the enthalpy change associated with latent heat
of vaporization.
Saturated liquid line: Line separating the liquid and two phase region.
Dry saturated vapor: A vapor in a state lying along the saturated vapor line.
Unsaturated/ superheated vapor: Vapor on the right side of the saturated vapor line.
The different states through which a liquid passes through during expansion 1-2-3-4 are:
2: It is a saturated liquid
3: It is a saturated vapor
Cycles composed of reversible processes is called ideal cycles. Various ideal cycles are
analyzed. The Carnot cycle is considered first and the Rankine cycle is presented as a
logical modification of this to meet certain practical considerations. Steam is used as a
working fluid because it is cheap and chemically stable. The principles presented apply
equally to any condensable vapor.
b. Carnot Cycle
1
2
4
3
At the boiler (heat exchanger 1-2), heat is taken in at constant temperature Ta and at the
condenser (heat exchanger 3-4) heat is rejected at a lower temperature Tb. It consists of
two reversible isothermal processes at Ta and Tb connected by two reversible adiabatic
(isentropic) processes.
Ta
Tb
ܳ = ܳଵଶ = ݄ଶ െ ݄ଵ = ݄ െ ݄
The steam is expanded isentropically to state 3 while doing work in the turbine or
reciprocating engine where ݏଶ = ݏଷ = ݏ @ . The work transfer is:
ܹ௨௧ = െܹଶଷ = ݄ଷ െ ݄ଶ
After expansion the steam is then partially condensed at a constant pressure while heat is
rejected.
ܳ௨௧ = ܳଷସ = ݄ସ െ ݄ଷ
݄ଷ = ݄ + ݔଷ ݄
ܹ݅݊ = ܹସଵ = ݄ଵ െ ݄ସ
A more direct indication of relative sizes of steam plant is provided by the specific steam
consumption (SSC). It is expressed in kg/kWh.
1 1 ݇݃ ݏ
ܵܵ= ܥ =൮ ൲ ൨ ݔ3600[ ]
ܹ௧ ݇ܬ
ܹ ൨ ܹ݇ݏ ݄
݇݃
3600 ݇݃
=( )
݇ܬ
ܹ௧ ൨ ܹ݄݇
݇݃
Q. Calculate the heat and work transfers, cycle efficiency, work ratio and SSC of a Carnot
cycle using steam between the pressures of 30 bar and 0.04 bar.