D - F Block - Ncert Based Exercise Solution

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Chapter Name
D & F Block Elements
NCERT Exercise
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&-->
b
+3 O
X 3e
+
>X
CAUJ3dS [Ar33d"us
2
At. N0. = 26
2. 2 3
-
a cu(#) is more stable in aqueous solution.
12.3.7
-
d
cu(Fact 1
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Coaching for NEET
&- 40]
b +2
CuF2 ·Cu +270
↳
[Ar] 3d9
↑2 I 1 +
unpaired to
12.5-7
a H
MnOk ~
MUcOn
12.6-x
↓
which has highest unpaired electrons (i.e. *3dS
TG: @Chalnaayaaar
12.73
b 3
↓
0.No. is common for all lanthanoids.
D.8;7 oxidation
a I
↓
+ 2
Cu -
(u # CU
⑦
Reduction
· xidation
3
+ 6 +7 -> 4
2
& Mnox + un -
MnO 4
F
t Mn0z +
2120
*
Reduction
best Sunil Sir
Learn Chemistry from faculty of Kota -
2.95)
↑
Because lante acts as

Autocatalyst.
R.10->
-v
↑ 11
Tm lanthanoid
=>
series element.
2.1103
a T
↓
- 2
↓
2 G
+2
Mnox + 15 * Mn + S
eq. of MnoF =
eg. of AS
nanog x 5
n(sx2 Eg
=
=
nino4
=
smole Cuiven)
TG: @Chalnaayaaar
(2- 2.)
a
V20s, (V2O3 =
Amphoteric oxide.
22.1,03
a
ad =(xe)47sd'652
64
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R. 14.7
-
d
They are
chemically less reactive -
Tre
12. 5.7
↳ cut3 = CAr33d3 *
Unpaired eP(n) =
3
u 3.87B.M.
.n(n + 2)BM
=
=
C2.16. T
C
2kn0 + 10 + k=>
2Mnx + 2040 +
k503
22-15.3
a cu does not liberates it gas from acids due
to less reactive than Hydrogen. **e
R. ->
2
(v,0j- >Crt3
+
C
*
4
+ sn t SR
TG: @Chalnaayaaar
12. 192
& Because in covalent compounds flarine can form
single Bond only while forms double

oxygen
bond.
&2.2.0-T
L Because both have similar radius due to
Canthanide contraction.
( 21.)
-
b +2
KM04
C1
+HC) > Mn ->
o xidising Agent.
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1.22.3
a
(i) 3 C
(ii) I d
(iii) > b
Lix) I e
(V) T a
12.2.3.3
d (i) 3 b
(ii) I a
(iii) > d
Lix) - 2
(V) > [
TG: @Chalnaayaaar
*.24.3
L (i) 3 C
(ii) - a
(iii) - b
12.25.3
a (i) 3 C
(ii) I a
(iii) > e
Lix) I b
best Sunil Sir

2- 26.7
d
(i) >d
(ii) I a
(iii) - b
Lix) - 2
(V) - F
2-27.3
a
(i) - b
(ii) - d
(iii) - a
Lix) -e
2
(V) -
TG: @Chalnaayaaar
R.28.7
C
(i) 3 C
(ii) - d
(iii) -b
Lix) - a
2.29.7
I
a
#o n both
correct, R is correct explanation of A.
+ 2 t
(u + 5- 3 (x + 52
top
1.3807
b #o both correct but is not correct explanation.

of A
12 5.3
-
C *
= correct
*
wrong
=
1.3.2.7
#o n
explanation of
a
both R is correct A.
correct,
1.53.3
#o
b both correct but is not correct explanation
6) A.
[Os -sd-series element]
TG: @Chalnaayaaar
1.3
d0>
a chromate obtained by the fusion of chromite one
with sodium carbonate in free access of air.
2.35.3
+3
b
Y6
*3
Pmt3 Lets (a
12.36.7
a Because i tions convert chromate ions to dichromate
ions.
&.37.T
· third ionisation enthalpy of Man is much larger due
to stable half filled delectronic configuration
07Mn
+
2.
2.38.3
b
Fet3 = CAr33dS
Half filled configuration
(more stable
2 -
59.3 2
a
(n - )d' 10ns"

Coaching for NEET
TG: @Chalnaayaaar
1.4,03
b
&Mn0z + 4k0H +02 >
2K2Mn0x +
21z0
P ⑫
- 2
3 Mn04+4H*, aknop Mnoc

+ +
2150
R
2kn0 + 10 + k=>
2Mnx + 2040 +
k503
Learn chemistry from best
faculty of Kota-Sunil Sir s
a 17
a
cute =
(Av] 3d => unpaired electron
& Paramagnetic
zn
+2 =
(Av]3d10 -zero unpaired electron
& Diamagnetic)
&-4.3
a
MnO MngO4<MncOs <MnOz <MMeOT
cidic
* Nature & 0.NO.
2.4,.7
a u
U
11 1
00
00 -
-- -
Cy
S
[CVc0j2]
! b
TG: @Chalnaayaaar
& 4-3
& Because in covalent compounds flarine can form
single Bond only while forms double

oxygen
bond.
2.45-3
C
A
KMan04 c
Kenanox +
Mnoz + O
2
P D R
KOH (KNO3
-
KeMnOk
top
Con- 1504, Nacl

MnOu *
Mn(lz + Cz
D
S
R 6.7
a
NacCuz0> + 2k(1 >
kz(rz0x + aNacl
12.4,
3
&
Kc(V20 +
T1504 +6k5 c(ve(SO41s + 352 + 4K25Ok
THU
-
TG: @Chalnaayaaar
R 8.3
b
i >
52
ii >
503
1.4.9.3
C +2 ⑥
IR - zn ↓
20
[ArJ3d10
↓
No unpaired electrons
2 colourless)

Coaching for NEET
1.5.0.3
d
Fet =
[Ar]3d6
11 +(* (*
~ unpaired electrons
u n(n + 2)BM
=
1- 510)
"3
d s =
CAr], diamagnetic (No unpaired e0)
T it4 =
CAr] ,
.. "I
<kr>4d8,
+
Pd =>
Paramagnetic (Paired et)
3
[AV]3d9,
+
=
(u "
I S
TG: @Chalnaayaaar
12.52.3
b
due in
to increase
effective Nuclear charge
1053.3
b
Nac[(dC14]
2 x x 0
=
+ -
↓
x +2 =
=
Cd = (Kv] 4dN, No unpaired 20 +
colourless
best Sunil Sir

1.54.7
a 2
↓T s +4
+ 2
+2 + 3
KMnO4 Fe 2
+
- +2CO2
FeCOn > - MU
n 5
=
-9
&+ of
Feczon = 2 x1 = 3
eg.of KMno4 =
eg. Of FeCz04
↑ xS 1 3
KMNO4 = x
nk+n0p 35
=
TG: @Chalnaayaaar
(2.55,
b
(is, (iii) & (ix) are correct.
2.56.7
d
(v = [ArT3dS 45'
W
↓,
ultimate
↑
shell
Penultimate
shell
1.57.3
C
MnOz + K0H +O2 > K2MnO4 +10
top
1 58.3
-
a
fact [3P option correct]
1-59.7
b
Reduction
aanoz + noz
6
↓
Mnox+
+
un +
an
·
&
· xidation
2.6803
C
3 + 3
Nit2
+ 2
ke Lu cut
unpaired et = S 3 2 B
TG: @Chalnaayaaar
R.1->
a
2sMn
=
(AV3d5us-, n5 =
u nnt 2)
=
BM 5.9 BM
=
&2 62.7
-
3
d xe+ =
(xe]u +,n 1 =
un(n +=
2)Bm = 10732
12-607
Because of ability
their multiple oxidation
·
to adopt states
and to form complexes.

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1064.3
a
on 2n12 colourless (No unpaired 20)
12. 65.7
Mn0z + k0l +02> K2Mn04 +10 (correct)
1.66.3
d
(vOcLI2
x - -
2 w
=
x +6 =
TG: @Chalnaayaaar
2.5.3
b is
3s0q2
ii> 3s0c2
3
iii) 6fe
1. 58.3
a
i > MnO2
+2
ii > +n
iii) MnOu2
best Sunil Sir
2.69.3
↑
species which they
a is stability of the lower to are
reduced.
12-78.)
↳ + 2
cut -(u + (u
2.7.3
-95% of a lanthanoid metal, 5% of iron & traces of 5.2, La
& Al
2.72.3
↓ Because oxygen produced from Kinnon is used up to
· xidise HCI to (12.
TG: @Chalnaayaaar
12.75-7
C 3
(v20," ccr+
-
52
-
+ 5 +
CG-74.3
C *
= True
R
= False
2.75.7
+ 2
X
MR
a H -
KMnOu
prct
N entral
pH MNO2
*
=
T
1y-
*
PKs I
Mn0y
2
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1-
76.3
↓
A o both correct but R is not correct explanation
of A
2.7,73
b
LAS - (ii)
(B) ->
(iii)
(c) -> (ix)
(D) -> (T)
TG: @Chalnaayaaar
1078.x
a Due to lanthanoid contraction.
1-7.3
c
Pdclc catalyses the oxidation of ethyne to ethanal
in the walker Process. (True]
2.0.
a
ability
s of complexes Yes as the size of lanthanoidbes
2- 1.7
b
Because of
regular tes in ionisation enthalpy.

Coaching for NEET
&.82.3
d last element of 3rd transition series is Hg.
1.83.3
a La =
d-block element
2.84.3
↓ due to less difference bow of ad orbitals than
blw uf &SdOrbitals.
2 85.7
-
C
Mn >(r > Fe>(0
TG: @Chalnaayaaar
12-86.3
d uth option incorrect (fact)
Cradii bes (
&-853
A o and his
both explanation of
·
correct correct A
R-88.7
b 0 *
11
c
*
O O & O
O - (v ~
" 1
↓ crto bonds are equivalent due to Resonance
best Sunil Sir
Learn chemistry from faculty of Kota -
1 89.7
-
d due to did transition.
2.90.3
a (n -
2) +1(n -1)do-ns"
& 91.3
-
↓ #& TH are correct.
=> *
Lalobby most Basic among hydroxides of
Ianthanides
TG: @Chalnaayaaar
22.92-3
a
Tet is more stable than its due to inert Pair
Effect
1.95.7
a
K2LVz0 T
2.9407
neither typically ionic
C non-stoichiometric & are
n or covalent.
top
1.95.7
b
CuF2
↓
+2
(u => one unpaired to
2-96.3
b <ets & ant- -> s unpaired electrons
[Ar] 3dS
2.97-3
-
voi3& VOnT
d
TG: @Chalnaayaaar
1-98.3
↓ Because large value of second ionisation enthalpy of cu
is compressed by much more Negative hydration

energy of cut21ag)
12-99-7
C
b
Is (6d-series
12-188-3
C have similar Atomic Radius.
12-1017
+2
C
<e
1.102.3
↳ ↓es across the lanthanoid series
& -
103.3
d 28

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D - F Block - Ncert Based Exercise Solution

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TG: @Chalnaayaaar

a cu(#) is more stable in aqueous solution.

0.No. is common for all lanthanoids.

Because lante acts as

& Because in covalent compounds flarine can form

single Bond only while forms double

L Because both have similar radius due to

best Sunil Sir

b #o both correct but is not correct explanation.

a chromate obtained by the fusion of chromite one

with sodium carbonate in free access of air.

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3 Mn04+4H*, aknop Mnoc

MnO MngO4<MncOs <MnOz <MMeOT

& Because in covalent compounds flarine can form

single Bond only while forms double

Con- 1504, Nacl

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best Sunil Sir

and to form complexes.

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Mn0z + k0l +02> K2Mn04 +10 (correct)

· xidise HCI to (12.

in the walker Process. (True]

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d due to did transition.

↓ #& TH are correct.

is compressed by much more Negative hydration

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