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where peaks are observed related to the atomic structure of the sample.
Most materials are made up of many small crystals like sand on a beach.
X-rays are high-energy light with a repeating period called the wavelength.
If the waves are out of alignment, the signal is destroyed. This is called
"destructive interference".
Electrons occupy special energy states around an atom. Since this is not enough
energy for the electron to be released,
the energy must be re-emitted in the form of a new X-ray, but the same energy as
the original.
When the atomic planes are exposed to an X-ray beam, X-rays are scattered by the
regularly spaced atoms.
The angle between the incident and the scattered beam is called 2-theta.
In order for constructive interference to occur, the scattered waves must be in
alignment,
meaning that the second wave must travel a whole number of wavelengths.
and one half on the scattered side, yielding one additional wavelength.
both the incident and the scattered side resulting in two wavelengths.
The exact angle at which diffraction occurs will be determined from the red
triangle.
The angle at the top is theta, half the angle between the incident and scattered
beams.
The long side is the distance between the atomic planes and the short side we know
is one half of a wavelength.
and the spacing between the atoms can be determined by applying the sine function.
named after Sir William Henry and William Lawrence Bragg, the father-son team who
won the Nobel Prize in 1915
This technique of X-ray diffraction is used today for a wide variety of materials,
ranging from
based on their mineral components and understand how the arrangement of atoms
Advances in equipment design have made X-ray diffraction easier to use, and more
powerful than ever.