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Source of Oil
• Composition of crude oil and Theories of oil source.
• Petroleum (also called crude oil) is a naturally mixture of hydrocarbons,
generally in the liquid state, that may also include compounds of sulfur,
nitrogen, oxygen, and metals and other elements. Inorganic sediment and
water may also be present. Thus, for the purposes of this text, a petroleum
product is any product that is manufactured during petroleum refining
and, as a consequence, petrochemical products are not included in this
definition.
• Where:
• G is the specific gravity and TB is the average boiling point of the petroleum
fraction as determined by the standard distillation method (ASTM D-86, ASTM
D-1160).
•
• ٭Another derived number, the UOP (characterization factor, is also a widely
used method for defining petroleum; the Characterization Factor is derived from
the formula:
Kw = TB1/3/ G
• Where:
• TB is the average boiling point in degrees Rankine (°F + 460) and G is the
specific gravity (60°/60°F).
• The Watson characterization factor :KW ~15 for highly paraffinic compounds ,
KW <10 for highly aromatic materials and KW vary from 10.5 to 12.9. For a
highly naphthenic crude it is 10.5 to 12.9 for a paraffinic base crude.
Composition of Crude Oil
Carbon 83 to 85%
Over the time, the layers of the organic material were compressed under
the weight of the sediment above them. The increase in pressure and
temperature changed the mud, sand, slit in to rock and organic matter in
petroleum.
Liquid petroleum flowed upward through porous rock until it became
trapped and could flow no further forming the oil and gas that we
explore for at present as shown in figure (4).
But the chemistry of the hydrocarbons found in the end product (oil,
and gas) differs somewhat from those we find in living thing. Thus
changes, transformation, take place between the deposition of the
organic remains and the creation of petroleum oil and gas:
• Petroleum end product = ([Raw material + Accumulations
+Transformation + Migration] = Geological time).
• The complication is that Petroleum is complex mixtures of many
hydrocarbons occurring in homologous series with no two Petroleum
exactly alike in composition. This is probably due to variations in
primary source materials and subsequent processes during formation
such as catalysis, polymerization, pressure and temperature changes.
Although the components of petroleum unite to form complex
mixtures.
Petroleum Assay
Density
The density, or more precisely, the volumetric mass density, of a
substance is its mass per unit volume. The symbol most often used
for density is ρ, although the Latin letter D can also be used.
Mathematically, density is defined as mass divided by
volume: ρ=m/V
Where ρ is the density, m is the mass, and V is the volume.
• In some cases (for instance, in the United States oil and gas industry),
density is loosely defined as its weight per unit volume, although this is
scientifically inaccurate – this quantity is more specifically called specific
weight.
•Light crude oil has an API gravity higher than 31.1° (i.e., less than
870 kg/m3)
•Medium oil has an API gravity between 22.3 and 31.1° (i.e., 870 to
920 kg/m3)
•Heavy crude oil has an API gravity below 22.3° (i.e., 920 to
1000 kg/m3)
•Extra heavy oil has an API gravity below 10.0° (i.e., greater than
1000 kg/m3)
https://www.engineeringtoolbox.com/api-gravity-d_1212.html
• However, not all parties use the same grading. The United States
Geological Survey uses slightly different ranges. Crude oil with
API gravity less than 10° is referred to as extra heavy
oil or bitumen. Bitumen derived from oil sands deposits in Alberta,
Canada, has an API gravity of around 8°. It can be diluted with
lighter hydrocarbons to produce diluted bitumen, which has an API
gravity of less than 22.3°, or further "upgraded" to an API gravity
of 31 to 33° as synthetic crude.
Viscosity
The viscosity of a fluid is a measure of its resistance to gradual
deformation by shear stress or tensile stress. For liquids, it
corresponds to the informal concept of "thickness".
Definition
1-Dynamic (shear) viscosity
Laminar shear of fluid between two plates. Friction between the fluid and
the moving boundaries causes the fluid to shear. The force required for
this action is a measure of the fluid's viscosity.
• The dynamic (shear) viscosity of a fluid expresses its resistance to
shearing flows, where adjacent layers move parallel to each other with
different speeds.
• The magnitude of this force is found to be proportional to the speed and
the area of each plate, and inversely proportional to their separation :
2-Kinematic viscosity
• The kinematic viscosity (also called "momentum diffusivity") is the ratio
of the dynamic viscosity μ to the density of the fluid ρ. It is usually
denoted by the Greek letter nu (ν).
3- Bulk viscosity
• When a compressible fluid is compressed or expanded evenly, without shear, it
may still exhibit a form of internal friction that resists its flow. These forces are
related to the rate of compression or expansion by a factor σ, called the volume
viscosity, bulk viscosity or second viscosity.
• The bulk viscosity is important only when the fluid is being rapidly compressed or
expanded, such as in sound and shock waves. Bulk viscosity explains the loss of
energy in those waves, as described by Stokes' law of sound attenuation.
•
4- Viscosity in solids
• The viscous forces that arise during fluid flow must not be confused with
the elastic forces that arise in a solid in response to shear, compression or extension
stresses. While in the latter the stress is proportional to the amount of shear
deformation, in a fluid it is proportional to the rate of deformation over time.
• However, many liquids (including water) will briefly react like elastic solids when
subjected to sudden stress. Conversely, many "solids" (even granite) will flow like
liquids, albeit very slowly, even under arbitrarily small stress. Such materials are
therefore best described as possessing both elasticity (reaction to deformation) and
viscosity (reaction to rate of deformation); that is, being viscoelastic.
• Indeed, some authors have claimed that amorphous solids, such
as glass and many polymers, are actually liquids with a very high
viscosity (e.g. greater than 1012Pa·s).
• Viscoelastic solids may exhibit both shear viscosity and bulk viscosity.
The extensional viscosity is a linear combination of the shear and bulk
viscosities that describes the reaction of a solid elastic material to
elongation. It is widely used for characterizing polymers. In geology,
earth materials that exhibit viscous deformation at least three orders of
magnitude greater than their elastic deformation.
5- Viscosity of slurry
• The term slurry describes mixtures of liquid and solid particles that retain
some fluidity. The viscosity of slurry can be described as relative to the
viscosity of the liquid phase:
• Where μs and μl are respectively the dynamic viscosity of the slurry and
liquid (Pa·s), and μr is the relative viscosity (dimensionless).
Pour point
• The pour point of petroleum is an index of the lowest temperature at which
the crude oil will flow under specified conditions. The maximum and
minimum pour point temperatures provide a temperature window where
petroleum, depending on its thermal history, might appear in the liquid as
well as the solid state. The pour point data can be used to supplement other
measurements of cold flow behavior, and the data are particularly useful for
the screening of the effect of wax interaction modifiers on the flow behavior
of petroleum.
• In any determination of the pour point, petroleum that contains wax
produces an irregular flow behavior when the wax begins to separate. Such
petroleum possesses viscosity relationships that are difficult to predict in
pipeline operation. In addition, some waxy petroleum is sensitive to heat
treatment that can also affect the viscosity characteristics. This complex
behavior limits the value of viscosity and pour point tests on waxy
petroleum. However, laboratory pump ability tests (ASTM D-3245, IP 230)
are available that give an estimate of minimum handling temperature and
minimum line or storage temperature.
Salt Content
• The salt content of crude oil is highly variable and results principally from
production practices used in the field and, to a lesser extent, from its handling
aboard the tankers bringing it to terminals. The bulk of the salt present will be
dissolved in coexisting water and can be removed in desalters, but small amounts of
salt may be dissolved in the crude oil itself.
• Salt may be derived from reservoir or formation waters or from other waters used in
secondary recovery operations. Aboard tankers, ballast water of varying salinity may
also be a source of salt contamination. Salt in crude oil may be deleterious in several
ways. Even in small concentrations, salts will accumulate in stills, heaters, and
exchangers, lead in got fouling that requires expensive cleanup. More importantly,
during flash vaporization of crude oil certain metallic salts can be hydrolyzed to
hydrochloric acid according to the following reactions:
2NaCl + H2O →2 HCl+ Na2O
MgCl2+ H2O →2 HCl + MgO
• The hydrochloric acid evolved is extremely corrosive, necessitating the injection of
a basic compound, such as ammonia, into the overhead lines to minimize corrosion
damage. Salts and evolved acids can also contaminate both overhead and residual
products, and certain metallic salts can deactivate catalysts.
Open access peer-reviewed chapter “Crude Oil Desalting Process”
By Juan Pereira, Ingrid Velasquez, Ronald Blanco, Meraldo Sanchez, César Pernalete and Carlos Canelón
Submitted: October 9th 2014Reviewed: July 28th 2015Published: September 30th 2015
• Thus knowledge of the content of salt in crude oil is important in
deciding whether and to what extent the crude oil needs desalting.
Carbon Residue
• The carbon residues of petroleum and petroleum products serve as
an indication of the tendency of the sample to form carbonaceous
deposits (thermal coke) under the influence of heat.
• Tests for Conradson carbon residue (ASTM D-189, IP 13), Rams
bottom carbon residue (ASTM D-524, IP 14), the micro carbon
residue (ASTM D4530, IP 398), are sometimes included in
inspection data on petroleum.
• The data given indication of the amount of coke that will be formed
during thermal processes as well as an indication of the amount of
high-boiling constituents in petroleum.
Production problems
Q / Estimate the barrels of crude oil per metric ton for crude oil
density range between (815 – 978 kg/m3) and the average boiling
point range (58 - 77 °C). Also calculate characterization factor in order
to know crude oil type if (paraffinic, naphthenic, or aromatic).
Note : Each student taking value differs for other students with two
decimal grades.