Professional Documents
Culture Documents
• Inorganic theories
– Cosmic sources: hc’s found in meteorites
• Consolidation of H and C during earth cooling.
• The discovery (Mueller, 1963) of a type of meteorite
called carbonaceous chondrites.
• Chondritic meteorites contain greater than 6%
organic matter and traces of various hydrocarbons
including amino acids.
• The chief support is that the hydrocarbons methane,
ethane, acetylene, and benzene have repeatedly
been made from inorganic sources.
Origin of Petroleum
• Inorganic theories
– Reaction of metal carbides in the earth
• Mendele’ve (1902) reasoned that metallic carbides deep
within Earth reacted with water at high temperatures to
form acetylene.
CaC2 + 2H2O = C2H2 + Ca(OH)2
• Then Porfir’ev (1974) – iron carbide react with percolating
water to form methane and other oil hydrocarbons.
FeC2 + 2H2O = CH4 + FeO2
• There is little evidence for the existence of iron carbide in
the mantle.
Origin of Petroleum
• Organic theory
• From transformation of biomatter.
• The biogenic origin of petroleum is widely accepted
on the basis of geochemical studies.
• The deposition of an organic-rich sediment is
favored by a high rate of production of organic
matter and a high preservation potential.
• The preservation of organic matter is favored by
anaerobic bottom conditions and a rapid
sedimentation rate.
Origin of Petroleum
Basic Components of Organic Matter
Average Composition of
C
C H O S N
Lipids 76 12 12 - -
Proteins 53 7 22 1 17
Carbohydra 44 6 50 - -
tes
NW SE
PERMANENT THERMOCLINE
1.5km
CH4 , H2S
Longitudinal section
525km
Productivity and Preservation of
Organic Matter
– Anoxic silled basins
• Landlocked silled basins with positive water balance:
good chance of developing anoxia.
E.g. Black Sea, Baltic Sea.
In arid-condition silled basins (Red Sea,
Mediterranean).
Productivity and Preservation of
Organic Matter
• 2 stages:
• Conversion of OM to kerogen
• Conversion of Kerogen to oil
and gas
Transformation of OM into Kerogen
Deeper subsurface
Increased pressure and temperature
Catagenesis Released: oil & gas
• Overall decrease in H and C
Metamorphism
High temperature and pressure
Metagenesis Only C remains: becomes graphite
When is oil expelled?
The result of this?
• The amount of oil generated increases
linearly with time
• The amount generated increases
EXPONENTIALLY with temperature.
• Thus, TIME IS AN IMPORTANT FACTOR
Time and oil generation
• The younger the source, the higher the
temperature required to generate oil
• RESIDENCE TIME
This Introduced the Concept of the
OIL WINDOW