CN115282783A - Reverse Osmosis Membrane and Preparation Method and Application Thereof - Google Patents

11/13/23, 9:17 AM CN115282783A - Reverse osmosis membrane and preparation method and application thereof - Google Patents
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Reverse osmosis membrane and preparation method and application thereof
Abstract
CN115282783A
The invention relates to a reverse osmosis membrane and a preparation method and application
China
thereof. The preparation method of the reverse osmosis membrane comprises the following steps
of providing a support membrane; sequentially placing a water phase solution and an oil phase
solution on a first surface of a support membrane, and then carrying out heat treatment to form a Download PDF Find Prior Art Similar
separation layer, wherein the water phase solution comprises polyamine, phosphate, a first metal
salt and a water-based polymer, a molecular chain of the water-based polymer comprises hydroxyl Other languages: Chinese
and a phosphate group, and the oil phase solution comprises polyacyl chloride; placing an alkaline
Inventor: 陈可可, 陈涛, 张宇, 刘文超, 谭惠芬, 潘巧明
aqueous solution on the surface of the separation layer far away from the support membrane, and
carrying out decomposition reaction on the aqueous polymer, wherein the separation layer contains Current Assignee : Hangzhou Water Treatment Technology
phosphate radicals to obtain a prefabricated membrane; and forming an anti-pollution layer on the Development Center Co Ltd , Bluestar Hangzhou Membrane
surface of the separation layer far away from the support membrane to obtain the reverse osmosis Industry Co Ltd
membrane. The preparation method can enable the water-based polymer to be uniformly and stably
dispersed in the separation layer, and simultaneously, the anti-pollution layer is prevented from
Worldwide applications
falling off, so that the prepared reverse osmosis membrane has excellent anti-pollution performance
and water flux. 2022 CN
Classifications Application CN202211227992.2A events
2022-10-09 Application filed by Hangzhou Water Treatment

B01D67/0079 Manufacture of membranes comprising organic and inorganic components Technology Development Center Co Ltd, Bluestar
Hangzhou Membrane Industry Co Ltd
View 5 more classifications
2022-10-09 Priority to CN202211227992.2A
2022-11-04 Publication of CN115282783A
2023-02-03 Application granted
2023-02-03 Publication of CN115282783B
Status Active
2042-10-09 Anticipated expiration
Info: Patent citations (11), Cited by (3), Legal events, Similar

documents, Priority and Related Applications
External links: Espacenet, Global Dossier, Discuss
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Claims (10) Hide Dependent
1. A preparation method of a reverse osmosis membrane is characterized by comprising the following steps:
providing a support film;
sequentially placing a water phase solution and an oil phase solution on the first surface of the support membrane, and then carrying out heat treatment to form a separation
layer, wherein the water phase solution comprises polyamine, phosphate, a first metal salt and a water-based polymer, a molecular chain of the water-based polymer comprises
hydroxyl and a phosphate group, and the oil phase solution comprises polyacyl chloride;
placing an alkaline aqueous solution on the surface of the separation layer, which is far away from the support membrane, and carrying out decomposition reaction on the
aqueous polymer, wherein the separation layer contains phosphate radicals, so as to obtain a prefabricated membrane; and
and forming an anti-pollution layer on the surface of the separation layer far away from the support membrane to obtain the reverse osmosis membrane.
2. The method of manufacturing a reverse osmosis membrane according to claim 1, wherein the aqueous polymer is selected from the group consisting of ammonium
polyvinyl alcohol phosphate;
and/or the mass fraction of the water-based polymer in the aqueous phase solution is 0.2-1.5%.
3. The method of preparing a reverse osmosis membrane according to claim 1, wherein said phosphate is selected from at least one of sodium hexametaphosphate,
sodium tripolyphosphate, or sodium dimeric phosphate; the first metal salt is selected from at least one of magnesium chloride, calcium chloride or magnesium sulfate.
4. The method for preparing a reverse osmosis membrane according to claim 1, wherein the mass fraction of the phosphate in the aqueous solution is 1.0% to 3.5%, and
the mass fraction of the first metal salt in the aqueous solution is 0.2% to 1.5%.
5. The method of preparing a reverse osmosis membrane according to any one of claims 1-4, wherein the aqueous alkaline solution has a pH of from 12.5 to 13.5.
6. The method of preparing a reverse osmosis membrane according to claim 5, wherein the step of performing the decomposition reaction is performed at a temperature
of 15 ℃ to 35 ℃ for a time of 15s to 45s.
7. The method of producing a reverse osmosis membrane according to any one of claims 1 to 4, further comprising the step of washing the prefabricated membrane
before the step of forming an anti-contamination layer on the surface of the separation layer remote from the support membrane.
8. The method for producing a reverse osmosis membrane according to any one of claims 1 to 4, wherein the step of forming an anti-contamination layer on the surface
of the separation layer remote from the support membrane comprises:
sequentially forming an aqueous solution of a second metal salt and an aqueous solution of a high polymer on the surface of the separation layer away from the support
membrane; or forming a mixed aqueous solution of a second metal salt and a high polymer on the surface of the separation layer away from the support membrane;
and then carrying out heat treatment, wherein the second metal salt and the high polymer are subjected to flocculation reaction to form an anti-pollution layer, so as to
obtain the reverse osmosis membrane.
9. A reverse osmosis membrane produced by the method for producing a reverse osmosis membrane according to any one of claims 1 to 8, comprising a support
membrane, a separation layer and an anti-contamination layer which are arranged in a stacked state.
10. Use of the reverse osmosis membrane of claim 9 in a water treatment device.
Description
Reverse osmosis membrane and preparation method and application thereof
Technical Field
The invention relates to the technical field of water treatment, in particular to a reverse osmosis membrane and a preparation method and application thereof.
Background
The reverse osmosis membrane is a core component of the reverse osmosis technology, and can effectively remove dissolved salts, colloids, microorganisms and
organic matters in water.
In order to prevent the membrane pores of the reverse osmosis membrane from being blocked due to pollution of organic matters, mineral oil and the like in the using
process, a hydrophilic anti-pollution layer is usually formed on the surface of the reverse osmosis membrane, but the traditional anti-pollution layer is easy to fall off, and
the water flux of the reverse osmosis membrane is greatly reduced, so that the membrane performance is influenced. Therefore, in order to reduce the influence of the
anti-pollution layer on the performance of the reverse osmosis membrane, polyvinyl alcohol is conventionally added into an aqueous phase solution for preparing a
separation layer, but due to the viscosity characteristic of the polyvinyl alcohol and the instant completion of an interfacial reaction, a polyvinyl alcohol aqueous polymer
cannot diffuse into the separation layer in time, and the water flux of the reverse osmosis membrane cannot be improved.
Disclosure of Invention
In view of the above, there is a need to provide a reverse osmosis membrane, a method for preparing the same, and applications thereof; the preparation method can
uniformly and stably disperse the water-based polymer in the separation layer, and can prevent the anti-pollution layer from falling off, so that the prepared reverse
osmosis membrane has excellent anti-pollution performance and high water flux.
The invention provides a preparation method of a reverse osmosis membrane, which comprises the following steps:
providing a support film;
sequentially placing a water phase solution and an oil phase solution on the first surface of the support membrane, and then carrying out heat treatment to form a
separation layer, wherein the water phase solution comprises polyamine, phosphate, a first metal salt and a water-based polymer, a molecular chain of the water-based
polymer comprises hydroxyl and a phosphate group, and the oil phase solution comprises polyacyl chloride;
placing an alkaline aqueous solution on the surface of the separation layer, which is far away from the support membrane, and carrying out decomposition reaction on
the aqueous polymer, wherein the separation layer contains phosphate radicals, so as to obtain a prefabricated membrane; and
and forming an anti-pollution layer on the surface of the separation layer far away from the support membrane to obtain the reverse osmosis membrane.
In one embodiment, the aqueous polymer is selected from ammonium polyvinyl alcohol phosphates;
and/or the mass fraction of the water-based polymer in the aqueous phase solution is 0.2-1.5%.
In one embodiment, the phosphate is selected from at least one of sodium hexametaphosphate, sodium tripolyphosphate, or sodium dimeric phosphate; the first metal
salt is selected from at least one of magnesium chloride, calcium chloride or magnesium sulfate.
In one embodiment, the mass fraction of the phosphate in the aqueous solution is between 1.0% and 3.5%, and the mass fraction of the first metal salt in the aqueous
solution is between 0.2% and 1.5%.
In one embodiment, the pH of the basic aqueous solution is from 12.5 to 13.5.
In one embodiment, the step of performing the decomposition reaction is performed at a temperature of 15 ℃ to 35 ℃ for a time of 15s to 45s.
In one embodiment, before the step of forming the anti-contamination layer on the surface of the separation layer away from the support membrane, the method further
comprises the step of cleaning the prefabricated membrane.
In one embodiment, the step of forming an anti-contamination layer on the surface of the separation layer away from the support membrane comprises:
sequentially forming a second metal salt aqueous solution and a high polymer aqueous solution on the surface of the separation layer away from the support membrane;
or forming a mixed aqueous solution of a second metal salt and a high polymer on the surface of the separation layer away from the support membrane;
and then carrying out heat treatment, wherein the second metal salt and the high polymer are subjected to flocculation reaction to form an anti-pollution layer, so as to
obtain the reverse osmosis membrane.
A reverse osmosis membrane prepared by the preparation method of the reverse osmosis membrane comprises a support membrane, a separation layer and an anti-
pollution layer which are arranged in a stacked mode.
An application of the reverse osmosis membrane in a water treatment device.
In the preparation method of the reverse osmosis membrane provided by the invention, the phosphate and the first metal salt can generate a water-soluble complex
compound to form a water-soluble three-dimensional network; meanwhile, the molecular chain of the water-based polymer comprises hydroxyl and phosphate groups, so
that the water-based polymer has the excellent water-solubility property of salt and the long molecular chain characteristic of a high molecular compound; therefore, the
water-solubility property of the water-soluble polymer enables the water-soluble polymer to be doped in a water-soluble three-dimensional network, and the long
molecular chain characteristic of the water-soluble polymer can enable the water-soluble polymer and the water-soluble three-dimensional network to be rapidly diffused
into a water-oil interface together; on one hand, the water-soluble three-dimensional network can participate in the process of interfacial polymerization reaction and
serve as a soft template for interfacial polymerization, so that sequential crosslinking of the separation layer is guaranteed, and defects are reduced; on the other hand,
the aqueous polymer can be stably doped in a separation layer generated by an interface reaction and is not easy to fall off.
Because the aqueous polymer can be stably doped in the separation layer, in the step of decomposition reaction, the alkaline aqueous solution can enable ammonium
phosphate groups in the aqueous polymer to generate decomposition reaction to form phosphate groups, so that a large amount of hydroxyl groups and phosphate
groups are uniformly distributed in the separation layer, the hydrophilicity of the separation layer is greatly improved, and the prefabricated membrane has certain
pollution resistance and high water flux; meanwhile, the anti-pollution layer is further formed on the surface of the separation layer and is obtained by flocculation
reaction of high polymer and metal salt, so that the anti-pollution layer is of a loose structure and cannot reduce the water flux of the separation layer.
Therefore, in the reverse osmosis membrane prepared by the invention, phosphate radicals in the separation layer and the anti-pollution layer are cooperated, so that the
reverse osmosis membrane has excellent water flux, anti-pollution and salt rejection rate.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the accompanying examples. This invention may, however, be embodied in many
different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be
thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this
invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be
limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The reverse osmosis membrane provided by the invention and the preparation method and application thereof will be further explained below.
The preparation method of the reverse osmosis membrane provided by the invention comprises the following steps:
s10, providing a support film;
s20, sequentially placing a water phase solution and an oil phase solution on the first surface of the support membrane, and then carrying out heat treatment to form a
separation layer, wherein the water phase solution comprises polyamine, phosphate, first metal salt and a water-based polymer, a molecular chain of the water-based
polymer comprises hydroxyl and a phosphate group, and the oil phase solution comprises polyacyl chloride;
s30, placing an alkaline aqueous solution on the surface of the separation layer, which is far away from the support membrane, and carrying out decomposition reaction
on the aqueous polymer, wherein the separation layer contains phosphate radicals, so as to obtain a prefabricated membrane; and
and S40, forming an anti-pollution layer on the surface of the separation layer far away from the support membrane to obtain the reverse osmosis membrane.
In step S10, the material of the support membrane may include at least one of polysulfone, polypropylene, or polyacrylonitrile, wherein polysulfone is cheap and easily
available, the membrane is simple to manufacture, the mechanical strength is good, the compression resistance is good, the chemical properties are stable, non-toxic,
and biodegradable, and therefore the material of the support membrane is preferably polysulfone.
In order to increase the strength of the support film, the second surface of the support film is laminated and provided with a non-woven fabric layer.
In step S20, a water-soluble three-dimensional network is formed because the phosphate and the first metal salt can generate a water-soluble complex; meanwhile, the
molecular chain of the water-based polymer comprises hydroxyl and phosphate groups, so that the water-based polymer has the excellent water-solubility property of
salt and the long molecular chain characteristic of a high molecular compound; therefore, the water-solubility property of the water-soluble polymer enables the water-
soluble polymer to be doped in a water-soluble three-dimensional network, and the long molecular chain characteristic of the water-soluble polymer can enable the water-
soluble polymer and the water-soluble three-dimensional network to be rapidly diffused into a water-oil interface together; on one hand, the water-soluble three-
dimensional network can participate in the process of interfacial polymerization reaction and serve as a soft template of interfacial polymerization to adjust the density
of the generated separation layer; on the other hand, the aqueous polymer can be stably doped in a separation layer generated by an interface reaction and is not easy to
fall off.
In one embodiment, the phosphate is at least one selected from sodium hexametaphosphate, sodium tripolyphosphate and sodium dipolyphosphate, and the sodium
hexametaphosphate has more charged groups in the structural formula, so that a water-soluble complex can be better formed, and a water-soluble three-dimensional
network can be better formed.
It should be noted that the water-soluble complex formed by the phosphate and the first metal salt is removed by dissolving in water during washing and use, and
therefore, in order to better improve the compactness of the separation layer and the water flux, in one embodiment, the mass fraction of the phosphate in the aqueous
phase solution is 1.0% to 3.5%, including but not limited to 1.0%, 1.2%, 1.4%, 1.6%, 1.8%, 2.0%, 2.2%, 2.4%, 2.6%, 2.8%, 3.0%, 3.2%, 3.4% or 3.5%, preferably 1.8% to 3.5%.
In one embodiment, the first metal salt is selected from at least one of magnesium chloride, calcium chloride or magnesium sulfate.
In order to better improve the compactness of the separation layer and the water flux, in one embodiment, the mass fraction of the first metal salt in the aqueous phase
solution is 0.2% to 1.5%, including but not limited to 0.2%, 0.4%, 0.6%, 0.8%, 1.0%, 1.2%, 1.4% or 1.5%, preferably 0.2% to 0.8%.
For better generation of the water-soluble complex, a water-soluble three-dimensional network is formed, and the mass ratio of the phosphate to the first metal salt in the
aqueous phase solution is 4.
In one embodiment, the aqueous polymer is selected from ammonium polyvinyl alcohol phosphates; in one embodiment, the mass fraction of the aqueous polymer in the
aqueous solution is between 0.2% and 1.5%, including but not limited to 0.2%, 0.4%, 0.6%, 0.8%, 1.0%, 1.2%, 1.4%, or 1.5%, preferably between 0.2% and 0.8%, combined
with economy and membrane functionality.
The present invention is not particularly limited in kind of the polyamine and the polybasic acid chloride, and in one embodiment, the polyamine is at least one selected
from the group consisting of an aromatic polyamine, an aliphatic polyamine, and an alicyclic polyamine, and preferably, the polyamine is at least one selected from the
group consisting of m-phenylenediamine and piperazine; in one embodiment, the polyamine is present in the aqueous solution at a mass fraction of 0.5% to 1.5%.
In one embodiment, the polybasic acid chloride is selected from at least one of aromatic polybasic acid chloride and aliphatic polybasic acid chloride, preferably, the
polybasic acid chloride is selected from at least one of trimesoyl chloride or adipoyl chloride, and in one embodiment, the mass fraction of the polybasic acid chloride in
the oil phase solution is 0.05% -0.30%.
The solvent of the oil phase solution is selected from isoparaffin solvents, which in one embodiment comprises at least one of isododecane or isometradecane.
It is understood that the polyamine and the polyacyl chloride can be crosslinked to form a polyamide molecular chain, and in step S20, the separation layer includes the
polyamide molecular chain, and the phosphate reacts with the first metal salt to form the water-soluble complex and the aqueous polymer.
In order to absorb a byproduct generated by a cross-linking reaction of polyamine and polybasic acyl chloride, the aqueous phase solution further comprises an acid-
binding agent, wherein in one embodiment, the acid-binding agent is selected from triethylamine, and the mass fraction of the acid-binding agent in the aqueous phase
solution is 0.1-0.3%.
In one embodiment, the step of sequentially placing the aqueous phase solution and the oil phase solution on the first surface of the support membrane specifically
comprises: firstly, coating a water phase solution on the first surface of a support membrane, standing for a period of time to enable the water phase solution to fill holes
in the surface layer of the support membrane, then pouring out the redundant water phase solution and drying the surface of the support membrane by blowing; and
finally, coating the oil-phase solution on the first surface of the support membrane, standing for a period of time, and then pouring out the redundant oil-phase solution.
In one embodiment, in the step of heat treatment in step S20, the temperature is 50 ℃ to 100 ℃ for 2min to 10min.
In the step S30, since the aqueous polymer can be stably doped into the separation layer, in the step of decomposition reaction, the alkaline aqueous solution can
decompose ammonium phosphate groups in the aqueous polymer to form phosphate groups, so that a large amount of hydroxyl groups and phosphate groups are
uniformly distributed in the separation layer, and the hydrophilicity of the separation layer is greatly improved, so that the prefabricated membrane has certain
contamination resistance and high water flux.
In the course of the decomposition reaction, NH is formed 3 Can be used as an acid-binding agent for interfacial polymerization, can ensure more complete
polymerization of the separation layer, and ensures the salt rejection rate of the separation layer.
In order to better avoid hydrolysis of the polyamide molecular chains in the alkaline aqueous solution and at the same time to more completely decompose the
phosphate groups to form phosphate groups, in one embodiment the pH of the alkaline aqueous solution is in the range of 12.5 to 13.5.
In one embodiment, the step of performing the decomposition reaction is performed at a temperature of 15 ℃ to 35 ℃ for a time of 15s to 45s.
In the step S40, the anti-pollution layer is further formed on the surface of the separation layer, and is obtained by flocculation reaction of high polymer and metal salt, so
that the anti-pollution layer is in a loose structure, the water flux of the separation layer cannot be reduced, in addition, the anti-pollution layer and hydroxyl on the surface
layer of the separation layer can form a hydrogen bond effect, the anti-pollution layer can be firmly adsorbed on the surface of the separation layer and is not easy to fall
off, a water channel can be formed, and the water flux is further improved on the basis of a prefabricated membrane.
In step S40, in order to better avoid the generation of metal hydroxide due to the contact of the metal salt with the alkaline aqueous solution, in one embodiment, before
step S40, a step of washing the prefabricated membrane is further included, and preferably, the prefabricated membrane is washed with water.
In one embodiment, the step of forming the anti-contamination layer on the surface of the separation layer away from the support membrane comprises:
sequentially forming a second metal salt aqueous solution and a high polymer aqueous solution on the surface of the separation layer away from the support membrane;
or forming a mixed aqueous solution of the second metal salt and the high polymer on the surface of the separation layer away from the support membrane;
and then carrying out heat treatment, and carrying out flocculation reaction on the second metal salt and the high polymer to form an anti-pollution layer so as to obtain
the reverse osmosis membrane.
In one embodiment, the second metal salt is selected from at least one of magnesium chloride, calcium chloride, or magnesium sulfate; the mass fraction of the second
metal salt is 0.5-2%.
In one embodiment, the high polymer is selected from at least one of anionic polyacrylamide, cationic polyacrylamide or quaternary ammonium salt chitosan, and the
mass fraction of the high polymer is 0.1% -0.5%.
In one embodiment, in the step of heat-treating in step S40, the temperature is 50 ℃ to 100 ℃ for 2min to 10min.
The invention also provides a reverse osmosis membrane which is prepared by the preparation method of the reverse osmosis membrane and comprises a support
membrane, a separation layer and an anti-pollution layer which are arranged in a laminated manner.
In the reverse osmosis membrane prepared by the invention, the phosphate radical and the phosphate radical in the separation layer are cooperated with the anti-
pollution layer, so that the reverse osmosis membrane has excellent water flux, anti-pollution performance and salt rejection rate.
In one embodiment, a nonwoven fabric layer is further stacked on the surface of the support membrane remote from the separation layer.
The invention also provides application of the reverse osmosis membrane in a water treatment device.
Specifically, the invention also provides a water purifier comprising the reverse osmosis membrane, wherein in the water purifying process, raw water to be purified enters
from the anti-pollution layer of the reverse osmosis membrane, and the raw water permeates the reverse osmosis membrane under the action of pressure to form pure
water.
Hereinafter, the reverse osmosis membrane and the method and use thereof will be further described by the following specific examples, in which ammonium
polyvinylalcohol phosphate is available from michelin under the trade name 821233; anionic polyacrylamide was purchased from mcelin under the designation P821239.
Example 1
A polysulfone base film is provided.
Adding m-phenylenediamine, magnesium chloride, sodium hexametaphosphate, ammonium polyvinyl alcohol phosphate and triethylamine into water, and uniformly
mixing to obtain an aqueous phase solution, wherein the mass fraction of the ammonium polyvinyl alcohol phosphate in the aqueous phase solution is 0.5%, the mass
fraction of the magnesium chloride is 0.5%, the mass fraction of the sodium hexametaphosphate is 2%, the mass fraction of the m-phenylenediamine is 1.0%, and the
mass fraction of the triethylamine is 0.2%; preparing an oil phase solution of trimesoyl chloride with the mass fraction of 0.15%, wherein the solvent of the oil phase
solution is an isoparaffin solvent Isopar L.
Coating the water phase solution on the first surface of the polysulfone basement membrane, standing for 60s, pouring out the redundant water phase solution, and
drying the first surface by cold air; and coating the oil phase solution on the blow-dried first surface, standing for 30s, pouring out the redundant oil phase solution, and
putting the membrane into a 80 ℃ forced air drying oven for heat treatment for 2min to form a separation layer.
And then coating NaOH solution with the pH value of 13 on the surface of the separation layer, which is far away from the polysulfone bottom membrane, for
decomposition reaction at the temperature of 25 ℃, pouring out the redundant NaOH solution after 30s, washing with water, and drying in the shade to obtain the
prefabricated membrane.
Preparing a mixed solution of calcium chloride and anionic polyacrylamide, wherein the mass fraction of the calcium chloride is 1%, and the mass fraction of the anionic
polyacrylamide is 0.2%, coating the mixed solution on the surface of a separation layer in a prefabricated membrane, standing for 30s, pouring out the redundant
aqueous solution, and drying in a 90 ℃ oven to obtain the reverse osmosis membrane.
Example 2
A polysulfone base film is provided.
Adding m-phenylenediamine, magnesium sulfate, sodium hexametaphosphate, ammonium polyvinyl alcohol phosphate and triethylamine into water, and uniformly
mixing to obtain an aqueous phase solution, wherein the mass fraction of the ammonium polyvinyl alcohol phosphate in the aqueous phase solution is 1%, the mass
fraction of the magnesium sulfate is 0.6%, the mass fraction of the sodium hexametaphosphate is 3%, the mass fraction of the m-phenylenediamine is 1.0%, and the
mass fraction of the triethylamine is 0.2%; preparing an oil phase solution of trimesoyl chloride with the mass fraction of 0.15%, wherein the solvent of the oil phase
solution is an isoparaffin solvent Isopar L.
Coating the water phase solution on the first surface of the polysulfone basement membrane, standing for 60s, pouring out the redundant water phase solution, and
drying the first surface by cold air; and coating the oil phase solution on the blow-dried first surface, standing for 30s, pouring out the redundant oil phase solution, and
putting the membrane into a forced air drying oven at 80 ℃ for heat treatment for 2min to form a separation layer.
And then coating NaOH solution with the pH value of 13 on the surface of the separation layer, which is far away from the polysulfone base membrane, for
decomposition reaction at the temperature of 25 ℃ for 30s, pouring out the redundant NaOH solution, washing with water, and drying in the shade to obtain the
Preparing a mixed solution of magnesium chloride and anionic polyacrylamide, wherein the mass fraction of the magnesium chloride is 1.5%, and the mass fraction of
the anionic polyacrylamide is 0.3%, coating the mixed solution on the surface of a separation layer in a prefabricated membrane, standing for 30s, pouring out excessive
aqueous solution, drying in the shade, and drying in an oven at 90 ℃ to obtain the reverse osmosis membrane.
Example 3
Example 3 reference is made to example 1 except that sodium hexametaphosphate is replaced by sodium tripolyphosphate.
Example 4
Example 4 was conducted with reference to example 1, except that the mass fraction of sodium hexametaphosphate in the aqueous phase solution was 3.5%, and the
mass fraction of magnesium chloride in the aqueous phase solution was 0.6%.
Example 5
Example 5 was carried out with reference to example 1, except that the mass fraction of sodium hexametaphosphate in the aqueous phase solution was 1.0%, and the
mass fraction of magnesium chloride in the aqueous phase solution was 0.2%.
Example 6
Example 6 the process is carried out as in example 1, except that the mass fraction of ammonium polyvinyl alcohol phosphate in the aqueous solution is 1.0%.
Example 7
Example 7 was conducted with reference to example 1, except that the mass fraction of ammonium polyvinylalcohol phosphate in the aqueous solution was 0.2%.
Comparative example 1
Comparative example 1 reference was made to example 1 except that ammonium polyvinyl phosphate was not added to the aqueous solution.
Comparative example 2 reference was made to example 1 except that ammonium polyvinylalcohol in aqueous solution was replaced with polyvinyl alcohol.
Comparative example 3 was conducted with reference to example 1 except that magnesium chloride and sodium hexametaphosphate were not included in the aqueous
solution.
Comparative example 4 was conducted with reference to example 1 except that the decomposition reaction was conducted without treating with NaOH solution after the
separation layer was formed.
Comparative example 5 was conducted with reference to example 1 except that sodium hexametaphosphate was replaced with trisodium phosphate.
Comparative example 6 was conducted with reference to example 1, except that an anti-contamination layer was not formed on the surface of the separation layer of the
Test example 1
The reverse osmosis membranes of examples 1 to 7 and comparative examples 1 to 6 were tested for rejection and flux, respectively, under the following test conditions:
the concentrated water is 500ppm sodium chloride aqueous solution, the test pressure is 0.75MPa, the concentrated water flow is 1.0GPM, the pH value of the
concentrated water is 7.0, the environmental temperature is 25 ℃, and the effective membrane area is about 19cm 2 The results are described in table 1.
TABLE 1
In table 1, the membrane water flux (F) is calculated from the volume of water passing through the reverse osmosis membrane over a certain time, and the formula is: f =
V/(a × T), where V is the volume of water passing through the reverse osmosis membrane per unit time, a is the effective membrane area, and T is the time.
The retention rate (R) is calculated by the concentration of the concentrated water and the concentration of the permeate, and the calculation formula is as follows: r = (1-
C) 1 /C 0 ) X 100%, wherein C 1 Is the concentration of concentrated water, C 0 The concentration of the permeate was used.
Respectively soaking the reverse osmosis membranes of the embodiment 1 and the embodiment 2 in 70 ℃ water bath for 120h, respectively testing the rejection rate
and the water flux of the reverse osmosis membranes according to the testing method, wherein after soaking, the water flux of the reverse osmosis membrane of the
embodiment 1 is 89L/(m) 2 H), the rejection rate is 99.7%, and the water flux of the reverse osmosis membrane of example 2 is 87L/(m) 2 H), the retention rate is 99.6%.
The technical features of the above embodiments can be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the above
embodiments are not described, but should be considered as the scope of the present specification as long as there is no contradiction between the combinations of the
technical features.
The above examples only show several embodiments of the present invention, and the description thereof is specific and detailed, but not to be construed as limiting the
scope of the invention. It should be noted that various changes and modifications can be made by those skilled in the art without departing from the spirit of the
invention, and these changes and modifications are all within the scope of the invention. Therefore, the protection scope of the present patent shall be subject to the
appended claims.
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中心有限公司
CN113262641A * 2021-04-02 2021-08-17 蓝星（杭州）膜工业有限 Anti-pollution reverse osmosis membrane and preparation method and
公司 application thereof
CN113289498A * 2021-05-10 2021-08-24 蓝星（杭州）膜工业有限 Positively charged nanofiltration membrane and preparation method thereof
公司
CN113368693A * 2021-07-29 2021-09-10 陕西鼎澈膜科技有限公司 Preparation method of high-flux reverse osmosis membrane
CN114028956A * 2021-11-18 2022-02-11 浙江机电职业技术学院 Reverse osmosis membrane and preparation method and application thereof
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CN114053884A * 2021-11-23 2022-02-18 浙江机电职业技术学院 Nanofiltration membrane and preparation method and application thereof
CN115646211A * 2022-12-26 2023-01-31 杭州水处理技术研究开发中心有 Positively charged nanofiltration membrane and preparation method and
限公司 application thereof
CN115945071A * 2023-03-13 2023-04-11 杭州水处理技术研究开发中心有 Positively charged nanofiltration membrane and preparation method and
限公司 application thereof
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CN115282783A - Reverse Osmosis Membrane and Preparation Method and Application Thereof - Google Patents

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11/13/23, 9:17 AM CN115282783A - Reverse osmosis membrane and preparation method and application thereof - Google Patents

Patents assignee:(Hangzhou Water Treatment Technology Development Center Co Ltd) 8 of 261

Reverse osmosis membrane and preparation method and application thereof

Classifications Application CN202211227992.2A events

2022-10-09 Application filed by Hangzhou Water Treatment

2022-11-04 Publication of CN115282783A

2023-02-03 Application granted

2023-02-03 Publication of CN115282783B

2042-10-09 Anticipated expiration

Info: Patent citations (11), Cited by (3), Legal events, Similar

External links: Espacenet, Global Dossier, Discuss

Claims (10) Hide Dependent

providing a support film;

providing a support film;

An application of the reverse osmosis membrane in a water treatment device.

s10, providing a support film;

A polysulfone base film is provided.

A polysulfone base film is provided.

Patent Citations (11)

Publication number Priority date Publication date Assignee Title

WO2011088505A1 * 2010-01-19 2011-07-28 Flinders University Of Low-fouling filtration membranes

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* Cited by examiner, † Cited by third party

Publication number Priority date Publication date Assignee Title

Family To Family Citations

* Cited by examiner, † Cited by third party, ‡ Family to family citation

Publication Publication Date Title

CN109663511B 2021-11-16 Composite nanofiltration membrane and preparation method thereof

CN110536743A 2019-12-03 Composite semipermeable membrane and its manufacturing method

CN111790276A 2020-10-20 Preparation method of alkali-resistant nanofiltration composite membrane

CN110947307B 2020-08-28 Preparation method of composite desalination layer nanofiltration membrane

Priority And Related Applications

Priority Applications (1)

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Applications Claiming Priority (1)

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2022-11-04 PB01 Publication

2022-11-04 PB01 Publication

2022-11-22 SE01 Entry into force of request for substantive examination

2022-11-22 SE01 Entry into force of request for substantive examination

2023-02-03 GR01 Patent grant

2023-02-03 GR01 Patent grant

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