Mass Iham2

slvet B.
Mixef li quids (A+c)50pucte c hom A wiog
B C+0 Desied
(soluent) Bthama
cshould dissolue mo20 im
(ixtnaty
highes so.Gt, im Bnan
X "C sho0d have
.Raffimde
Bsolvent (fcod) "Rolahve s alt, ß Ramd B
A+c>food (inmisi o)
"A Gmd & should have ignikcart.
F+Pc=2 cemity diffoemca.
to.
R:mas flous Aate Raffin
Notaim 2xtnatstaam which isqfuchin
slvarst)

ehroluent

ye

,(8+c)

R
(M=F+f= E+R)

. fast cansdsaing

Pute A
This w:ll mot exist Pune B
(thir fi nd Xar
Gie thoyase totay
immisle

im A

B
(slitsimto
Buhamd

two
C= 2Uquids
Phase
P=
(Peconstant)
Ptf-C-2 (E:)
(fo
Boilingfoint)

Atc R 9R A,c» omfstalymiale

food

C-imihly withP.
"Soluto fA
Btb extaad C out bse)
usmg immiuble asfo ar
shouldloe
(eamd A

Cxt,act (E) BathBowy

Conountach stoan(
lownate (vowinubwhe)
Raffimde (R)

6uoucle Mass Ralamco:

F+S=M= E+R

CBalamia:
Mamilu Point
C at M
 gt
cleta anct Get te Gines
ma Joim Famdsi
Fond Sone bmon datesmine(M)
(Totelmdicl atcim
hacd to handl
B(s)oe saloent. amy Roimt o6 time
foem C Balamce dotoumine M
(weighteA ava)
Dime Fs Ese+Re
NoTe M Fx tsys= Mam =
fo Poe solyent-M= F4
imsicle immis bb doma.it
M
" No, simce KM is

(imagimg) om mPoints '

’ Draus a lia ime
(md foint o ta tie line)

F()
(amce M,> 09s9s(ond to omimn
S fo kch ata aie ís Poss:lble

MM, fsints whose Es

intes a the dome M=Fcf ’M TesCM
M
.. MIes Sese
is

Paticca solvent -
imsida dema.
As sfa, %M bes, so Mimiting
Sinso, Mhust lie vale f M o which se cam haue
maxm amout o Solvetflouw
(Fs line tangant tocamdome Gives
that e extnadod)

Aitmig

M
 Mulk stags osJ-bslsent xhctom:- (Since Raffimate sil centoims iome G)
Sataact(E)
E2,56 E,3E,EE+¬,+ E3 ye)
Raffine R
food (F) Rs
R
unestnadod
im thefal
S3,4s Raffincte)

F+s, =M

No- of stags
(M, > knoum)
eam dta.

get se, ad iR, ’emd Bintse tie Uine tono

)demine J
M

A B()

all ae we demt

Sime)

( x e comfostiem is sRued , we fos mult tae xtsation)

R Re Rin-1 Rn Rnp-a

Np
Je
Em
Emt!
Stagea)tod antins last stae rluent inhroduce
2xatis doaum Raffimcto withdyaen

O91
 Ouenall Ralamas F+S=M E, +RNp
c Balame:

R-S= F-E = e

Rn-s +s = EntRP
RNo-s Rn-Fm
De Diff. in mat
(R-G= DR)
(Coniant )
Rng-S= F-E,= be

RNp-S= e
m stase to Np> R--E=

Givem: F, ¢, S, 9s, F+s=M

M>E,+RnpRNA im 24
whichae nmot meed
2Rvp why we
(Msplt ioto de aomd 00mot halp. ie
So daauin tie ine speal;ad)

Ra)

amd exterd
we joim E,F
Cmel@xtem
pin Rnps
(4) We

zRip-S
(A)
a
with E,3 doraw
(yE,,
2quilibium
R.since it is in
locate DR,
" Now,
(6,E)
tie line Pasing tisrough Elae 5got
them da.aus tie line Tnosh

Now Join Ae amd R to get Eglye arndso on

2mcdgo2, (alos
Sone aihemiy o tie ine the oikos,
kes Pon 9efating

lat stoe )
 R

conalate F-f,, R,-R-E,

Cam we
, Dome with tie Qine isgivom

(fnem omdfsnty
ofteline)
full
tisPlot
Comsitin
(Tn datais

Vost)

hafindeandexÉaod
(Rol gemanate
imes intesect the domeand
whoaa these91andam gives
flsttod
we idemtiy Bints (Rere Pistswhen
oRuaingy bine

Dimnes )
formi(*h-y and

(2 ton)

dirhllotm
extadiomCmd
Cue Kos
o Ntugo am
distillah'on
xtaadg
 Pot)
T6
ivoid’(B-faee
lea seheme)
toiasu
uso
to
have
B-feo0. Culatin scheme:

ate)
N flow
fioa
E,e'e
atadoa F,s',
Simgla Stage
E, Je R=Ae+Bpte
E}ME,E, F'=ftc F

S,ts

=0 (Roe)

S-B
ton Puac solvant
Ar+CF
CF
Be

AetCA Be Rant)
so
Pare
(foa

As+Cf

straaon)
im real
Guconal Blamca
F+s=M=E+R

has mo ß
(A+c)Galance (FF) fead
Belames-
B-forea
Fis Physical measuble
qantity
lene
Nomel c-B Ce
N,- Bs Cs =MEyetRxR
Fxe t Sys
- E+k'sa
8-f00. C edlance
Faets,=Mx
 ’Fx=My

’a
foad Bint:(XF. NE)
Np iskmon
(: food has mo B

N,s'=N-M= NeE + Ne2

+
; NE=D
Assuomptiom

= Bs Asmpion)
S(neasuace

N,.s=s|

NM'= S
GNM= S
M'

Cam Point M be

kimom F
aoe knom
’ FXp.Ne) Gmd M(XM,N)
N

TieLime

F(Xe. M)

soluent Point( N

(fom
M (S Poimt camtloe
locoBed)
 " Now doaus tie ime though M.
from graph, wget, (Ye, NE) omd (xa, NA)

M'XM=EeteXA

R' allatot

E= E'(2+ NE)

SPE
iAN
CASE
R=R(t NA)

Cfraa Cal.latiens
(o'8)
mmis ly
(A)
(B)
Crthact(B+e)
immisai
Aand Bttaly
Raffimte

foad (A+ R) toontain)

(Atc) Nomall
Rlfincteco

(B)

Goss-flous fuato:

Balace(C):-(on C-froeBasi)
Solite

(nhstagt)
(Ae,matbaifea)

A
AR,m-s

(ARny=A- fo,all Aage)

X
 B B
Atc
(
staçe eugsny fom *
Celyacton Gos
flow M.tistose
(e) (oa')on Poist
whose
ho foint he
isAlot egm the omect line
wit. edaas ’
Basis) C-free Plot (£4m
on
yr-ye-
-A
toge simgle foan
9c -
A-) Bnli-):
 Co»tud
sth
soluont liquid loncing
aiS
TREYBAL
onching solidl
is a cenliqaidsolid, (Gemalse
(must
loe ).Tochmique
()
Comoihn (oso%
kmown
Basi) C-faae
=
Asp +
Brj's Relame
Bt Ancpt Consant
Np) slase eitesd kich Same
w Bh
isamound (Re
Jm J
(e4m)
2p-1
(a
Satme 15
at as
Bqids inioltl with flow basent CounlCoutimos
e *
 salids)
ooussoli'd (Bod of (Conion)

Somesltothoa

iq,+ rolite
ymongmous to oaching Rafeas to loa cing alA.a Bom woodonnash:
To wih tire
(Rae soluet )
( Cenlinuo us

Solitolsolid) Lauid
Just du mf)Plocathakslid
\>leaing which liid lasas slate)
(Solte concuntnt im
(soli) solite !!
whonaistho soluent incuan)
lseimsicde cansnien
Soluto cam
Connie9 loahabla only
(soliteisthe caieti
atsusfoeob whem
at bothPlaces solite
Porous)
(ones Bxosiem solute
Soluentcoamguach
Omd disolue it )
Coseicn

longey ot the suafacei

matencl whem is
Satsation: oaching ea
>les time Cemsumig)
lowtemfatisa(Roo tomenctläo)
gamslall, lesfomed ct to omain
(A) Cmd soluen (B)
’ Btaai¡n is
wamt casnios.
(blc we
immisae )
’ solonsolidshold e at hgh tamfaituse
’ Lonching as slabhlit es witt temfesátiae.

o Docodtin: Ghem soluent. used fo Bhehing

(Doing loachimj at maxm fosilda
temfoatun. umdes 2tim Bessuse)
>(As igh towf as Posibe oa
Soluont ,but ft shoald loe in
Riapid Phase)
 Rasobiquidl.
fO:ffaomie Lwohave
entons torogh thefora dene
(2) Liquid imsico tho Baois
dissths
Tn-ste
8) Cencontnhon Graciat
(3) hikls Cm:>Cno out)
aifrue
(solte mlela
imisabe ).
moosivinrgfaaton
Thoteis
ciffusiem)
Soludoroic slame Tiechamgas slota laomeve tYeva

fon offodtve Qtndion ’ highe indaual temiom

is cdasiaca

Solute imside a Solid caoas1

(s olid)
Jleachad outs
bysloant (ligyso luont)

Solidto oe laachedsld NoTATONS(leacin

loahad
B=Tlassinslla A>solwnt
F- (A+c) im feed >loacho slution.
C>Slastfstatita
loaimg sluort
fooo,calolation.
"F- (Atc) in sold >
>(B+F)
. <Tötal mma s faad
. F= (RtG) lnfoed to doryfond P
Ne= BE Be_ (fondoy fed)

10 (fos doy fesd)

A+C
 solvent »AFzo)
Dr teacd No
Ry Ma %so?
F- (A+c) ln foed Leahed oltion (Ra)

A+c &all insolae

Cysmall
Leached sola CEa)
B-fnee) B Mar iniolul
Jeachim sokuent
Ro (Mass essent)

Bin
Ne, so
No Bs. (Nosolocmt) CA+clE

ssluont C:o) (a)

Solds cae
dvoid ohc
/Tm the sold fhos shola b moA
mo C)

fecd cR,Nzo
NF
aften

soRvcmt. NE, = o
tim)

Fl1,Np)

(o0) R(loaced s) [e, o]

’ he. Cmoft signißcant assumftion is the imsolues

aftos, edauadi on is doy
Sustoumed Inteastrtial. spaces Bio tho solid fogtde is
voip.
Void x
 Tsolbfa, aso aloa
Soaked| Sushounded
Tirteaststiels,
void
wtth liquid)
doesmit
happom: Umda hacical con ji clonaiam
beam
( eae sTiR0 asuoning, ale c har
(The is mo A bn C loa checd out)
loach
’Tnsolbes alscys suaomcled by

(Tnsoleg
) Je >not o
uneache
insole)
is
ths
the
Tie line is Vestical)
s im smt
Camaimdoe
vatical
lime
F Te
amy moe
(Paedical
vdaticl
tielime (A+c)im jslle to cgn sideratin)

CRoock solti¡n. vERTAL TE LiNES)

leached)
alO Chas mot Ben
(Some C
igide
Now, censdeaung insice
loachsolm + som C

Censeqemce (9e+ e)
Atc Bem C,t Aame.
leach soln nsole have more
loach s9
C,
B
(Ac):s Cqack.
e
Denomineon oa-) Je, >highestham

NE
E, Teo.