L.H.

Patil English Medium School, Wawadade

C.B.S.E Affiliation No.1130364 P-2 Academic Year-2023-24
Year
Class:- 12th Total Marks:- 20 Sub: Chemistry
Sub:-
Name:-
General Instructions
(i) All questions are compulsory.
(ii)Question number 1 to 7 are very short Mcq based answer questions carry 1 mark each.
(iii) Question number 8 & 9 are short answer question & carry 2 mark each.
(iv) Question number 11 is case based question carry 4 mark each.
(v) Question number 12 is long answer type question carry 5 mark.
Q.1) Which of the following is allylhalide?
allylhalide
a) CH2 = CH-C1 b) CoH5CH2Cl c) C6H5Cl d)

Q.2) The order of reactivity of alcohols with halogen acid follows:

follows
0 0 0 0 0 0
a) 1  2  3 b) 2 1 3 c) 3010 20 d) 302010

Q.3) The heating of phenylmethyl ether with HI produces.

produces
a) Iodobenzene b) phenol c) Benzene d) Ethyl chloride

Q.4) Find the product of the given reaction :

a) b
b) c) d)

Q.5) Inversion of configuration observed in.

in
2 1
a) SN b) SN c) Neither SN1 or SN2 d) SN1 as well as SN2

In a statement of assertion followed by statement of a reason is given.

given choose the
correct answer out of the following choices.
choices
a) Both A & R are true & R iss the correct explanation of A.
A
b) Both A & R are true but R is not the correct explanation of
o A

Q.6) Assertion A :- Chlorobenzene is less reactive towards nucleophilic substitution reaction.

reaction
Reason R : Nitro group in chlorobenzene increases its reactivity towards nucleophilic substitution reaction.
reaction

Q.7) Assertion A :- In monohaloarenes,

monohaloarenes further electrphilic substitution occurs at ortho & para positions.
Reason (R) :- Halogen atom is a ring deactivator.
deactivator

Q.8) How would you obtain.

i) Picric acid (2, 4, 6 – trinitrophenol) from phenol.

ii) 2 – methylpropene from 2 methyl propanol?

propanol

Q.9) Racemisation occurs in SN1 reactions.

reactions why?
Q.10) Read the given passage & answer the questions that follow.
Alcohol plays very important role in our daily life. Ordinary spirit used as an antiseptic contains
methanol. Ethanol is present in cough syrups, tonics, wine, beer and whiskies, Sugar, starch,
cellulose are carbohydrates which also contain large number - OH groups. Phenol is also an
antiseptic in low concentration (0.2%) where as 2% solution of phenol is used as disinfectant
The fragrance of rose is due to citronellol (unsaturated alcohol). Phenol is used for preparation
of many useful compounds like aspirin, methyl salicylate (lodex) and phenyl salicylate (salol) used in instestine
antiseptic.

a) What happens when cumen hydroperoxide is hydrolysed?

b) Why does phenol become pink on long standing?

c) Convert phenol to____

i) P – nitro phenol ii) Picric acid.

d) Distinguish between phenol & picric – acid.

Q.11) Predict the major product of acid catalysed dehydration of.

i) l – methylcyclohexanol
ii) butane 1 – ol