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CD1

C ontents

Introduction

Features & Benefits

Faster Dispersion

Color Acceptance Advantage

Additional Performance Benefits

Improved Gloss

Improved Rheology

Improved Color Development

Stability

Incorporation & Use

I ntroduction

Troy Corporation supplies a complete line of performance


additives for the coatings, printing ink, colorant, and
adhesive industries. These additives include rheological
modifiers, grind aids, pigment dispersants, substrate
wetting agents, biocides, slip and mar additives, defoamers,
and anti-settling agents. This literature is intended to
demonstrate the effectiveness of Troy’s premier dispersant,
TroysperseTM CD1.

2
F eatures & Benefits

The dispersion of a pigment in a vehicle/resin requires come into direct contact with and become surrounded by
mechanical energy (grind) to break up the clumps of the vehicle.
pigment into small and smaller particles. Under optimum
Dispersants also assist in the removal of gas bubbles,
conditions, there should be a minimum of pigment
moisture, and other contaminants from between the
agglomeration remaining after the grind phase of the
pigment particles. They also prevent flocculation after the
process. Exhibit 1
dispersion is completed.
Agglomeration Wetting
Troysperse CD1 is a highly effective dispersing and grinding
aid for a wide range of pigments in mineral spirit based
systems.

• Improves Color Development


• Provides Deeper Shades at Equal Amount of
Dispersion Accelerates Pigment
Pigment Wetting
• Provides More Complete Dispersion of the
Pigment Than Most Commonly Used Dispersing
Agents
• Achieves in Many Cases Optimum Particle Size in
Less Time Than Most Commonly Used Dispersing
Agents
A dispersing agent is usually added to assist with • Troysperse CD1 is a nonionic polymeric oil
the wetting out of the pigment surface, to aid in the derivative dispersant, 70% solids in mineral
deagglomeration and to allow the particles of pigment to spirits.

F aster Dispersion
Exhibit 2
Because of its excellent pigment wetting properties,
TroysperseTM CD1 provides faster grinding of pigment
Carbon Black Tinting Paste
Faster Dispersion Time With TroysperseTM CD1*
dispersions. This translates into reduced manufacturing
costs by decreasing energy consumption and increasing 7
product through-put. 6

Exhibit 2 shows the improvement in grind possible by use 5


of Troysperse CD1. Hegman
Formulation 1 Grind 4
3
Typical Properties
Med. Alkyd Solids ................................................................ 14% 2
Carbon Black ....................................................................... 32% Troysperse CD1
1
Troysperse CD-1 .................................................................... 6% Control
Paint Thinner ........................................................................ 48% 0
5 10 15 20 25 30 35
Time in Minutes
The use of Troysperse CD1 results in the obtaining of * Dispermat Small Media Mill, 1.2mm glass beads, 300 rpm
Hegman grinds up to twice as fast as coatings without
dispersant. This equates to increased production capacity
without increasing capital costs.

3
CD1
C olor Acceptance Advantage

Formulation 2 Formulation 3

Alkyd Gloss Enamel Medium Oil Alkyd Enamel


Tint Base Formulation Tint Base Formulation
Ingredients Control TroysperseTM CD1 Ingredients Control Troysperse CD1
(% Wt.) (% Wt.) (% Wt.) (% Wt.)
Uralac AH263(DSM) 7.30 7.30 Beckosol 11-045-50 (RCI) 15.89 15.80
Mineral Spirits 3.00 3.00 White Spirits 2.64 2.63
Troysperse CD1 ------- 0.75 Troysperse CD1 ------ 0.63
RCL 575 TiO2 37.75 37.75 Troythix A 0.52 0.42
(millennium) TroysolTM AFP 0.42 0.42
High Speed Dispersion (7 + Hegman) 2020 TiO2 (Kronos) 21.18 21.07
Troythix® 150ACS 0.85 0.85 Mikhart 10.59 10.53
Uralac AH263(DSM) 39.40 39.40 (Provencale s.a.)
TroymaxTM Cobalt 5% 0.50 0.50 High Speed Dispersion; Temperature 60° C.,
Hegman Grind 6
Troymax Perma Dry 0.15 0.15
Beckosol 11-045-50 (RCI) 40.57 40.35
Troymax Zirconium 12% 4.00 4.00
White Spirits 7.04 7.00
n-Butanol 0.50 0.50
Troymax AntiSkin B 0.20 0.20 Troymax Cobalt 6% 0.17 0.17

Mineral Spirits 6.35 5.60 Troymax Calcium 10% 0.77 0.77

Totals 100.00 100.00 Troymax AntiSkin B 0.21 0.21


The above formulations were tinted with 2% (wt/wt) Engelhard, G1F Red Iron oxide tint paste, Totals 100.00 100.00
and 2% Huls, colortrend 888 Phthalo Blue tint paste

Formulation 4

Carbon Black Pigment Dispersion


Ingredients Control Troysperse CD1
(% Wt.) (% Wt.)
Duramac 2438 (McWhorter) 40.00 40.00
Mineral Spirits 40.00 36.60
Troysperse CD1 ------- 3.40
Raven Black 5000 Beads 20.00 20.00
(Columbian Chemical Co.)
Totals 100.00 100.00

4
I mproved Gloss

The gloss of a coating is enhanced by the degree


of dispersion of the pigment in the system. The
greater the dispersion and wetting of the pigment,
the higher the gloss of the finish coatings.
TroysperseTM CD1 excels in promoting gloss when
compared with competitive dispersants.

I mproved Rheology
Exhibit 3
The efficiency and compatibility of Troysperse CD1
promotes lower viscosity mill bases. Other benefits
to the formulator include: larger batch sizes, higher
pigment loading, higher production rates (may reduce mill
time), and an opportunity for raw materials cost savings.
Additionally, with the use of Troysperse CD1, the long term
stability of a finished pigmented system is maintained.

Troysperse CD1
After Three Months

Control
After Two Weeks

5
CD1
I mproved Color Development

TroysperseTM CD1 was evaluated for color development


and tint strength versus several competitive products.
The photographs illustrate the improvement in these
properties when Troysperse CD1 was used.

Long Oil
Alkyd Enamel
Tinted 2% Red Iron Oxide Universal Colorant

Control Troysperse CD1

Medium Oil
Alkyd Enamel
Tinted Carbon Black Tinting Paste

Control Troysperse CD1

Long Oil
Alkyd Enamel
Tinted 2% Phthalo Universal Colorant

Control Troysperse CD1

Troysperse CD1 increases tinting strength and eliminates rub-up without any change in milling equipment.

6
B etter Package Stability

The use of TroysperseTM CD1 promotes a stable aged


viscosity and reduced settling. This will result in fewer
complaints and lower rework costs.

H ow to evaluate Troysperse CD1

Each pigment type has a unique affinity for a dispersant in an easy process and can be performed in your laboratory.
a given formulation. We call that the Dispersant Demand First, prepare a series of samples, dispersant free, from
Level, or DDL. It is necessary for coatings formulators the same master pre-grind mix. Next, add Troysperse CD1
to determine and satisfy the DDL in order to optimize to the samples in incremental steps, all within the range
processing efficiency. Adding more dispersant than the suggested in the table below. Disperse the samples in
DDL wastes raw material and provides no improved benefit. like fashion: same type mill, same media, same speed,
Formulating below the DDL causes less color development same temperature, and same time. The samples are then
and increases grind times. Variables affecting the DDL evaluated for viscosity and color development. Observe
include such factors as pigment particle size, particle color strength for chromatic pigments. Check hiding
shape, chemical nature of the pigment, electron charge, power for white pigments. The sample that has the lowest
and the amount of pigment being dispersed. Once the viscosity, and has the highest hiding power or color
DDL is determined, the maximum economic benefit of strength, is the sample where the Dispersant Demand
Troysperse CD1 can be realized. Determining the DDL is Level has been satisfied.

Troysperse CD1 Use Level


Weight on Pigment Weight
Titanium Dioxide 1-2%
Fillers & Extenders 1-2%
Inorganic Pigments 2-5%
Organic Pigments 5-15%
Carbon Black 15-20%

7
S ervices

An ISO 9001:2000 and ISO 14001:2004


As a Performance Partner, Troy offers a variety of services Certified Company
to support our product line of preservatives and additives to
meet customer needs and provide market solutions.

Troy invites you to take advantage of the Troy services that can
help you achieve your market objectives.
Troy Corporation
• Technical Service representatives can provide formulation
8 Vreeland Road
assistance, product evaluation, and microbiological,
Florham Park, NJ USA 07932
analytical, and field testing to assist you in developing an
973-443-4200
optimum formulation that meets your product objective.
973-443-0843
• Regulatory support is offered globally with regional and
national expertise to meet your needs. Canada
905-760-7902
• R&D scientists constantly work to anticipate future industry 905-760-7904
needs and develop innovative technology. Contact your
Europe
Troy representative to discuss your unique requirement
31-10-592-7494
that may not be met by materials currently on the market. 31-10-592-8877
In fact, Troy may have just what you need already under
Asia Pacific
development and if not, may be able to work with you to
66-2-361-4515
achieve your objective. 66-2-361-4520
• A global supply network is in place to ensure product Brasil
availability and fast delivery. Contact your local 55-115575-0090
representative to ensure the product you need is available 55-115575-9080
when you need it. Middle East & Africa
44-162-878-1800
Call your nearest Troy representative for immediate assistance 44-162-867-6600
or visit us online at www.troycorp.com. When visiting the
website, become a registered user to obtain access to a wide For further information visit our website:
range of resources. www.troycorp.com

NO WARRANTY IS MADE, WHETHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PUR-
POSE FOR THESE PRODUCTS. NO STATEMENTS OR RECOMMENDATIONS CONTAINED HEREIN ARE TO BE CONSTRUED AS INDUCEMENTS TO INFRINGE ANY
RELEVANT PATENT, NOW OR HEREAFTER IN EXISTENCE. UNDER NO CIRCUMSTANCES SHALL TROY CORPORATION OR ITS AFFILIATES BE LIABLE FOR INCI-
DENTAL, CONSEQUENTIAL OR OTHER DAMAGES FROM ALLEGED NEGLIGENCE, BREACH OF WARRANTY, STRICT LIABILITY OR ANY OTHER THEORY ARISING
OUT OF THE USE OR HANDLING OF THESE PRODUCTS. THE SOLE LIABILITY OF TROY CORPORATION AND ITS AFFILIATES FOR ANY CLAIMS ARISING OUT OF
THE MANUFACTURE, USE OR SALE OF ITS PRODUCT SHALL BE FOR THE BUYER'S PURCHASE PRICE. NEITHER TROY CORPORATION NOR ANY AFFILIATES
ASSUMES ANY OBLIGATION OR LIABILITY FOR THE INFORMATION IN THIS DOCUMENT OR THE RESULTS OBTAINED. THE INFORMATION IN THIS DOCUMENT
IS PROVIDED WITHOUT WARRANTY AND IS TO BE UTILIZED BY CUSTOMERS OF THE PRODUCTS AT THE CUSTOMER'S SOLE RISK. CUSTOMERS SHOULD
CONDUCT THEIR OWN TESTS IN ACTUAL USE CONDITIONS BEFORE COMMERCIAL USE OF THE PRODUCTS.

Troysperse™, Troysol™, Troymax™, and Troythix® are trademarks of Troy.

TB0112 5/2006
2006 Troy Corporation

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