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1. 3.
2.
Ans: Ans:
Ans:
propyl Butyl
Isopropyl (common name); 1-
methylethyl (IUPAC)
4. 5.
Ans: Ans: 6.
sec-Butyl (common name); 1- Isobutyl (common name); 2- Ans:
methylpropyl (IUPAC) methylpropyl (IUPAC) tert-Butyl (common name); 1,1-
dimethylethyl (IUPAC)
9.
7. Ans: 3-ethyl-2-methylhexane
8.
Ans: 4-ethyl-3-methylheptane Ans: 3-ethyl-4-methylhexane
10. Degree of unsaturation (DUS) 11. Give the major product.
for C11H14BrO2N (CH3)3CH+ Br2 12.
Ans:[(11*2+2+1)-(14+1)]/2=5 Ans: (CH3)3CBr Ans:
13. 14.
Ans: 2-ethyl-1,1- 15.
Ans:
dimethylcycloalkane
Ans:
18-2).若一對映異構物之比旋
光是[a]=(±) 20o ; 當測得一光學
16. 純度是(-)20%時,請問(-): (+)左
Ans: 右旋異構物比值是多少?
18-3).若一對映異構物之比旋
光是[a]=(±)20o ,當測此對掌異
構物混合之旋光度是-5o 時,請
問(-): (+)左右旋異構物比值是
多少?
1). Identify the constitutional isomer (denoted by CI), stereoisomers (denoted by S) or conformations
(denoted by CF), for the pairs.
2). Circle the compounds having chiralities.
a)
b)
Ans: CF Ans: S
c) d)
Ans: CF
Ans: CF
e) f)
Ans: CF Ans: CI
g) h)
Ans: S Ans: S
Ans:
請問 A/B 是何種關係?
Ans:因鏡像無法重疊,是 Enantiomer,即是鏡像異構/對掌異構物/對映異構物/光學異構物或旋光異構
物。
C/D 是何種關係?
Ans:是 Meso,即是內消旋化合物,因鏡像可以重疊是相同分子/化合物。