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0) Migration in Lithosphere
It is positive on ong storage of the waste, the radioactive waste on storage in
repositories or waste storage area is likely to escape in the environment releasing
airborn contamination. Also surface contamination gives way to lithosphere through
container for
water which percolates to porous rocks. Pit impervious rocks acts as
migration occurres
Jong-term storage but their concentration is very dilute. The
actinide ions
through fissures of soil. The study revealed that displacement of
concentration of other cations
from binding sites on rock matrix by quite large
and increasingly easier displacement by more
highly charged ions. Radioactivity
held by stony materials leading tothe slow rate of migration. A small
of actinides species. This shows while considering
fraction migrates rapidly than bulk of the
constructs waste depository which is isolated
chemical and geological media, one
instrusion of water.
from environment in spite of major
Radioactive Waste
(ii) Characteristics of Waste is characterised at low
waste is nuclear fuel cycle.
The main source of contaminated waste. Qualitywise first two are identical
curie/
level, high-level, or actinideconcentration of activity. Low-level waste has 1
In contents but
different in
Burying in soil is disposal method for it,
microcurrents/ft). fuel, present in
It of activity (-30 originates from reprocessing of spent reactorgenerates heat.
Duthigh-level waste to 1000 curie/gallon of activity and it
more than 710
liquid form. It has 100 contaminated or actinide waste has
Iransuranium elements
nanocuries/gm of actinide nuclides.
Waste place
(0) Source of Radioactive mining,refining, enrichment
parts of nuclear cycle e.g.,
reprocessing. Mining produces mainlyis
It is produced in all
reactor and operation and While making yellowcake
fuel fabrication,
underground mining is preferred. give'milltailings'. It affects
dust and radon, so produced during refiningtoproducessmallactive nuclide
is
injurious dust it to UF, during enrichment
(U;0)
our lungs. U;Og conversion further processing produces active waste.
are made and
effluents. UF, on effluents. The rods
are washed throughin activityis lost in
Laser enrichment is best as no
500 Environmental Pollution Monitoring and Control
cladded with zirconium leading to loss of U, Th, Pa in waste water.
Maximum
waste is produced by reactor operations. Spent fuel contains active elements. The
spent fuel is not reprocessed but disposed off. However, U238, U235. Pu is extracted
in reprocessing plant from spent reactor fuel (Table 22.5). Washings have 10000
gallon of activity. Fuel cladding made of zirconium is contaminated and
generatesfor
solid active waste. In absence of reprocessing. liquid waste is stored in tanks
disposal sometime. But capacity of tank gets full in 5 to 9 yrs demanding closer oe
reactor. Nuclear reactor is to be shut after 30to 35 years for decontamination
decommissioning. However, fromthe point of safety. Dresdent reactor in Chicago
was decontaminated at 75% of construction cost in 25 years.
Table 22.5 Radionuclides in spent reactor fuel
parts of country.
all over the world
Table 22.7 Reactors with capacity
S. Name of the Capital
Total reactors Capacity of
(J990) reactor (MW)
No. country
Reojo Galio 2 1020
1. Argentina 4 1632
2. Bulgaria 6 3474
Belgium Anteweip
Reo de Janiro 1 626
4. Brazil 16 9521
5. Canada Ottawa
Paris 41 32,993
6. France
4 2310
7. Finland
Frankfurt 19 16,133
8.W. Germany DR 2882
Berlin 5
9. E. Germany FR 1194
10. Czechoslovakia Prague 3
2 820
11. Hungary Budapesi
12. Italy Millan 3 1194 (1273)
13. India Delhi 1020
14. Japan Tokyo 21.751
15. Korea (South) Sou 1790
16. Netherland Amsterdam 2 508
17. Pakistan Islamabad 125 (600)
18. Spain Madrid 4690
19. Switzerland Zurich 2882
20. Sweden Copen Hagen 10 7355
21. South Africa Pretoria 1 921
22. United States of Washington 85 68,867
America
23. USSR (undivided) Moscow 46 22,997
24. United Kingdom London 37 9564
25. Yugoslavia 632
The Table 22.7 list countries which posses nuclear reactor with their optimum
capacity. It will be seen that America, France, Japan and Russian all super P
have 85, 41, 31 and 46 reactors Bangladeshhus
respectively. The less developed reactors.
no reactor, Pakistan boast of any one reactors while India posses five ofticial
Much depends upon capacity varying from 68000 to 22000 MW. This iscountries
information. One does not know any additional capacity is procured by
without the knowledge of IAEAin Vienna.
(ii) Space Disposal earthit
Outer space is ideal garbage dumping site, but due to possible hazards on vertical
appears to be dubious proposition. Waste if placed in orbital transfer in
Radioactive Waste and
Environment 503
spacecraft and ejected to Venus, or Moon or Sun. But it needs
eject it in outer sphere force beyond very high energY to
ozone layer. It isfurther depleted and UVgravitation of the earth. The worst being
The cost will be prohibitive. If the radiation enters in the earth's atmosphere.
spacecraft fails to lift and returns with
radioactivity will be spread all over upper stratosphere of earth.
waste to ejection site is also big problem, but Transportation of
this mode of disposal. NASA very much interested in
is
by day several spent fuel assemblies are growingaround nuclear reactors although
good amount of electricity is also generated.
(ii) Hazards
Pu causes lung cancer. Small amount of radioactivity escaped in environment
causes damage of health. It accumulates in animals, plants and enter human body
through food chain (Tables 22.9 to 22.11).
(iii) Successful Disposal Mode
Though several technologies have been developed for safe disposal none of them
are full proof. Solidification andemplacement is one method. The disposal in
space and specially on sun but is not fissible is ideal.
(iv) Past Practice
No one in past was interested in safe disposal of radioactive waste including federal
agencies. So, at several places radioactivity leakage is detected.
(v) Current Programme
Though present practice of disposals is good it is not full proof and much less
attention is given on priority basis. Temporary measures are adequate and reliable
but permanent long-term solution is yet to be arrived at. A problem is not only
technical but has ramification to political and social problems.
The technologyof X-ray has made greater strides in the field of medicine. It is
used for noble cause of diagnosing problems of health e.g. lung. It is used by
certain nations for diagnosing sex of foetus before delivery in form of Sonography.
InIndia the Sonographic applications are totally prohibited. The X-rays are also
used for brain and stomach examination. Table 22.12 shows that in Germany large
number of cases are diagonised from head and brain. While Ramania used it
extensively for study of lungs and chest (-850). Japan has used it for diagonising
diseases of stomach (285). One has to use X-ray very judiciously as pregnant and
lactating mothers should not be strictly exposed to excessive exposure to X-ray
radiation inorder to protect foetus in her body.
Apart from medical sciences, X-rays are used extensively for the elucidation
of the structure of chemical compounds.There are few variety of X-ray as X-ray
fluoroscences (XRF) and X-ray diffraction (XRD) with single or double crystal
models.
With recent tragedy at Fukoshima in estern Japan due to breaking
Tsunami, the scientist are reluctant to go in for new reactor in Japan atreactors with
Fukoshima.
In relation to developing countries, India has to make
greater strides in future
years for shortage of coal, we will have to replace all the thermal
with nuclear reactor with clean technology in near power plantS
future.
22.15 CONCLUSION
When the conflicts are brewing between two
level best efforts are made to produce nuclear neighbouring countries on global,
but for manufacture of atomic and energy not only for power generau
on life are known since long, no hydrogen bomb. Although effects of radiation
serious consideration is givento this problemtill
nuclear energy is used for generation of electricity. Several source of radiation
available however the main source remains to be nuclear
radioactivity is emitted from fewsources like TVit is notreactor. Although natue
very injurious to nea
To evaluate the effects of radiation evolve
on man, it is very much
standards of radiation. Number of standards are necessary to
evolved in terms of curie, rongten,
Radioactive Waste and Environment 509