Table A.

Calculation of Molar Mass of Unknown Liquid

Video Member 1 Member 2 Member 3
1. Trial 1 mass watch 0.0745 0.0766 0.0700
(g) of unknown 06:50
2. Trial 2 mass watch 0.0773 0.0738 0.0718
(g) of unknown 06:50
3. Trial 3 mass watch 0.0702 0.0771 0.0743
(g) of unknown 06:50
4. Trial 4 mass watch 0.0716 0.0777 0.0744
(g) of unknown 06:50
5. Average mass solve = 0.0734 0.0763 0.072625
(g) of unknown
6. Standard solve= 0.00315700279801 0.00147082743152 0.00212347984842
deviation of 38 73 49
mass (g) of
unknown
7. Pressure (Pa) 100800 100800 100800 100800
8. Temperature 100 100 100 100
(°C)
9. Temperature 373.15 373.15 373.15 373.15
(K)
10. Mass (g) of watch 18.234 18.234 18.234
Dumas Tube 05:19
11. Mass (g) of watch 34.123 35.341 37.444
Dumas Tube 08:19
with Water
12. Mass (g) of solve = 15.889 17.107 19.21
water
13. Density 1.00
(g/cm3) of Water
14. Volume solve = 15.889 17.107 19.21
(cm3) of Gas
15. Moles of solve = 5.1625x10^-4 5.5583^-4 6.2416 x10^-4
Gas
16. Molar Mass solve = 142.179 137.272 116.356
(g/mol) of
Unknown
17. Possible Trichloroethyne Trichloroethyne 2-Bromopropane
Identity of the (C2HCL3O) (C2HCL3O) (C3H7Br)
Unknown
18. Percent solve = 8.203 4.469 -5.394
Error (%)
19. Theoretical 8.314
R (Pa-m3/mol-
K)
20. Calculated R 8.314068 8.313980 8.313971
 (Pa-m3/mol-K)
21. % Deviation 0.0008 -0.0002 -0.0003
for Calculated R

Working computation
Average mass of unknown = mass trial 1 + mass trial 2 + mass trial 3 + mass trial 4/n
Standard Deviation = √ ∑(x−μ)2/n-1
Volume of gas(cm3) = Mass of water(g)
Moles of gas = 100800 (Mass of water) / 8.314 x 10^4 (373.15)
Molar mass of unknown = Average mass of unknown/Moles of gas
Mass of water = Mass of dumas tube with water - Mass of dumas tube
Percent Error = Molar Mass of Unknown/Moles of Gas
Calculated R = (100800)(Mass of Water(1/1,000,000))/(Moles of gas)(373.15)
Percent Deviation for Calculated R = Theoretical-Actual/Actual

Sample Calculations
Average mass of unknown
= 0.0745 + 0.0773 + 0.0702 + 0.0716
4
= 0.0734

Calculated R
= (100800) (15.889(1/1000000))
5.1625x10-4(373.15)
=8.314068

Moles of Gas
= _100800(18.889)_
8.314x104(373.15)
= 5.1625x10-4

Molar Mass of Unknown

= __0.0734__
5.1625x10-4
= 142.179