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— ements Ath tS RN
Le . 5: .
a. Experiment. To classify compounds as jonic or
covalent based on their physical
properties
Physical properties such as melting, solubility and conductivity of electricity depend on the type
of bonds present in a compound. These properties can be used to distinguish between ionic and
covalent substances,
lonic compounds have very strong electrostatic forces of attraction which result in high melting
points. The cations and anions are both charged particles and allow for good interaction with
water molecules since the water molecules are polar. This leads to ion-solvent interactions and
results in ionic compounds being soluble in water. When ionic compounds melt or dissolve in wa-
ter the ions are set free and this allows for conduction to take place. Mobile charge carriers are
present in the form of ions in ionic compounds.
Covalent compounds are usually held together by weak forces of attraction with few exceptions
such as diamond and graphite. They possess no charged particles and are expected to have
low melting points. They are insoluble in polar solvents such as water and are non-conductors
of electricity since no mobile charge carriers are present.
Apparatus & maierials
+ compounds labelled A, B, C and D (e.g. solid
samples of sodium chloride, copper Il) sulphate,
sulphur, & iodine )
+ test tubes, rack & holder
+ glass rod
250 cm* beaker
+ spatula
+ Bunsen burner
+ electrical circuit
+ propanone
+ distilled waterProcedure
Fm
4. Placo a small amount of sample Ain a test tube and
heat gently at first, then more strongly until no further
change occurs. (Heat samples in a fume cup-
board.) Record your observations.
2. Add.asmall amount of sample A to about 20 cm? of
distilled water, Record whether it dissolves or not
Then test the mixture with the electrical circuit to find
out if it conducts electricity.
3. Repeat step (2) using propanone instead of distilled
water.
4. Repeat steps (1) to (3) with the other samples B, C
and D.
Table 1: Tests carried out on samples A, B, C and D
Samples A B
Effect of heat
Solubility in water
Electrical conductivity in water
Solubility in propanone
Electrical conductivity in propanone
(al =~ Data analysis
4. Onheating, which sampies
(i) melted readily?
(ii) sublimed readily?
(iii) remained unchanged?What do these observations suggest about the forces
of attraction in these samples?
Which samples
() dissolved in water?
(i) conducted electricity in water?
What do these observations suggest about the type
of bonds in these samples?
Which samples
())_ dissolved in propanone?
(ii) did not conducted electricity?
What do these observations suggest about the type
of bonds in these samples?
Using the results of the experiment, classify the
compounds A, B, C and D as ionic or covalent in
nature.